Outer Main Belt asteroids: Identification and distribution of four 3-μm spectral groups

This paper examines the distribution and the abundance of hydrated minerals (any mineral that contains H₂O or OH) on outer Main Belt asteroids spanning the 2.5 < a < 4.0 AU region. The hypothesis we are testing is whether planetesimals that accreted closer to the Sun experienced a higher degree of aqueous alteration. We would expect then to see a gradual decline of the abundance of hydrated minerals among the outer Main Belt asteroids with increasing heliocentric distance (2.5 < a < 4.0 AU). We measured spectra (0.8–2.5 μm and 1.9–4.1 μm) of 28 outer Main Belt asteroids using the SpeX spectrograph/imager at the NASA Infrared Telescope Facility (IRTF). We identified four groups on the basis of the shape and the band center of the 3-μm feature. The first group, which we call “sharp”, exhibits a sharp 3-μm feature, attributed to hydrated minerals (phyllosilicates). Most asteroids in this group are located in the 2.5 < a < 3.3 AU region. The second group, which we call “Ceres-like”, consists of 10 Hygiea and 324 Bamberga. Like Asteroid Ceres, these asteroids exhibit a 3-μm feature with a band center of 3.05 ± 0.01 μm that is superimposed on a broader absorption feature from ～2.8 to 3.7 μm. The third group, which we call “Europa-like”, includes 52 Europa, 31 Euphrosyne, and 451 Patientia. Objects in this group exhibit a 3-μm feature with a band center of 3.15 ± 0.01 μm. Both the Ceres-like and Europa-like groups are concentrated in the 2.5 < a < 3.3 AU region. The fourth group, which we call “rounded”, is concentrated in the 3.4 < a < 4.0 AU region. Asteroids in this group are characterized by a rounded 3-μm feature, attributed to H₂O ice. A similar rounded 3-μm feature was also identified in 24 Themis and 65 Cybele. Unlike the sharp group, the rounded group did not experience aqueous alteration. Of the asteroids observed in this study, 140 Siwa, a P-type, is the only one that does not exhibit a 3-μm feature. These results are important to constrain the nature and the degree of aqueous alteration in outer Main Belt asteroids.     

Near-infrared spectroscopic survey of B-type asteroids: Compositional analysis

We present near-infrared spectra of 23 B-type asteroids obtained with the NICS camera-spectrograph at the 3.56 m Telescopio Nazionale Galileo. We also compile additional visible and near-infrared spectra of another 22 B-type asteroids from the literature. A total of 45 B-types are analyzed. No significant trends in orbital properties of our sample were detected when compared with all known B-types and all known asteroids. The reflectance spectra of the asteroids in the 0.8–2.5 μm range show a continuous shape variation, from a monotonic negative (blue) slope to a positive (red) slope. This continuous spectral trend is filling the gap between the two main groups of B-types published by Clark et al. ([2010]. J. Geophys. Res., 115, 6005–6027). We found no clear correlations between the spectral slope and the asteroids’ sizes or heliocentric distances. We apply a clustering technique to reduce the volume of data to six optimized “average spectra” or “centroids”, representative of the whole sample. These centroids are then compared against meteorite spectra from the RELAB database. We found carbonaceous chondrites as the best meteorite analogs for the six centroids. There is a progressive change in analogs that correlates with the spectral slope: from CM2 chondrites (water-rich, aqueously altered) for the reddest centroid, to CK4 chondrites (dry, heated/thermally altered) for the bluest one.     

Spectral detectability of Ca- and Mg-sulfates in Martian bright soils in the 4–5 μm wavelength range

Chemical analyses of soil samples performed at different landing sites on Mars suggest the presence of sulfate minerals. These minerals are also thought to be present in the globally mixed Martian bright soils covering large areas of the planet. However, remote soil spectra have so far provided only tentative identification of sulfates regarding mineral types and abundances. This paper concentrates on the detectability of four Ca- and Mg-sulfates (anhydrite, gypsum, kieserite, hexahydrite) in the 4–5 μm range of Martian remote soil spectra. This spectral range is important for sulfate detection as most fine-grained sulfates exhibit significant absorption bands between 4 and 5 μm, independent of the texture of the host soils (e.g., loose powdered or cemented soils). Furthermore, this is the spectral range for which the Planetary Fourier Spectrometer (PFS) and Observatoire pour la Minéralogie, l’Eau, les Glaces, et l’Activité (OMEGA) instruments onboard ESA/Mars Express mission provide high spectral and spatial resolution data. Laboratory near- and mid-IR reflectance spectra of the pure sulfates and their mixtures with a terrestrial Martian soil analog were acquired. The results show that even the smallest amount of admixed sulfate (∼5 wt%) generates significant absorption features in the portion of the 4–5 μm range not covered by the saturated Martian atmospheric CO₂ absorption band between 4.2 and 4.4 μm. Model calculations of the influence of emitted surface radiation on the detectability of sulfate features show that the depth of the features decreases strongly with increasing surface temperature of an observed area resulting in the fact that all sulfates are spectrally hidden at surface temperatures around 270 K even at ∼14 or ∼25 wt% sulfate content in the soils. Sulfates become increasingly detectable depending on the sulfate content if the surface temperature is below 260 K. The outcome of this work helps to constrain the conditions needed for remote detection of sulfates within Martian bright soils in the 4–5 μm range.     

Near-infrared spectroscopy of 3:1 Kirkwood Gap asteroids: Mineralogical diversity and plausible meteorite parent bodies

The 3:1 Kirkwood gap asteroids are a mineralogically diverse set of asteroids located in a region that delivers meteoroids into Earth-crossing orbits. Mineralogical characterizations of asteroids in/near the 3:1 Kirkwood Gap can be used as a tool to “map” conditions and processes in the early Solar System. The chronological studies of the meteorite types provide a “clock” for the relative timing of those events and processes. By identifying the source asteroids of particular meteorite types, the “map” and “clock” can be combined to provide a much more sophisticated understanding of the history and evolution of the late solar nebula and the early Solar System.A mineralogical assessment of seven 3:1 Kirkwood Gap asteroids has been carried out using near-infrared spectral data obtained over the years 2006–2009 combined with visible spectral data (when available) to cover the spectral interval of 0.4–2.5 μm. We explore the diversity, uniqueness, and possible links between the asteroids (198) Ampella, (329) Svea, (495) Eulalia, (556) Phyllis, (623) Chimaera, (908) Buda, and (1772) Gagarin, which are located adjacent to the 3:1 resonance, and the meteorite types in the terrestrial collections.     

Spectral reflectance properties of carbonaceous chondrites: 6. CV chondrites

Multiple reflectance spectra of 11 CV chondrites have been measured to determine spectral–compositional relationships for this meteorite class and to aid the search for CV parent bodies. The reflectance of CV chondrite spectra is variable, ranging from ～5% to 13% at 0.56 μm, and ～5% to 15% at the 0.7 μm region local reflectance maximum. Overall slopes range from slightly blue to red for powders, while slab spectra are strongly blue-sloped. With increasing average grain size and/or removal of the finest fraction, CV spectra generally become more blue-sloped. CV spectra are characterized by ubiquitous absorption features in the 1 and 2 μm regions. The 1 μm region is usually characterized by a band centered near 1.05–1.08 μm and a band or shoulder near 1.3 μm that are characteristic of Fe-rich olivine. Band depths in the 1 μm region for powdered CVs and slabs range from ～1% to 10%. The 2 μm region is characterized by a region of broad absorption that extends beyond 2 μm and usually includes band minima near 1.95 and 2.1 μm; these features are characteristic of Fe²⁺-bearing spinel. The sample suite is not comprehensive enough to firmly establish whether spectral differences exist between CV_R, CV_OxA, and CV_OxB subclasses, or as a function of metamorphic grade. However, we believe that the mineralogic and petrologic differences that exist between these classes, and with varying petrologic subtype (CV3.0–>3.7), may not be significant enough to result in measurable spectral differences that exceed spectral variations within a subgroup, within an individual meteorite, or as a function of grain size. Terrestrial weathering seems to affect CV spectra most noticeably in the visible region, resulting in more red-sloped spectra for finds as compared to falls. The search for CV parent bodies should focus on the detection of olivine and spinel absorption bands, specifically absorption features near 1.05, 1.3, 1.95, and 2.1 μm, as these are the most commonly seen spectral features of CV chondrites.     

Titan’s aerosol and stratospheric ice opacities between 18 and 500 μm: Vertical and spectral characteristics from Cassini CIRS

Vertical distributions and spectral characteristics of Titan’s photochemical aerosol and stratospheric ices are determined between 20 and 560 cm^?1 (500–18 μm) from the Cassini Composite Infrared Spectrometer (CIRS). Results are obtained for latitudes of 15°N, 15°S, and 58°S, where accurate temperature profiles can be independently determined.In addition, estimates of aerosol and ice abundances at 62°N relative to those at 15°S are derived. Aerosol abundances are comparable at the two latitudes, but stratospheric ices are ～3 times more abundant at 62°N than at 15°S. Generally, nitrile ice clouds (probably HCN and HC₃N), as inferred from a composite emission feature at ～160 cm^?1, appear to be located over a narrow altitude range in the stratosphere centered at ～90 km. Although most abundant at high northern latitudes, these nitrile ice clouds extend down through low latitudes and into mid southern latitudes, at least as far as 58°S.There is some evidence of a second ice cloud layer at ～60 km altitude at 58°S associated with an emission feature at ～80 cm^?1. We speculate that the identify of this cloud may be due to C₂H₆ ice, which in the vapor phase is the most abundant hydrocarbon (next to CH₄) in the stratosphere of Titan.Unlike the highly restricted range of altitudes (50–100 km) associated with organic condensate clouds, Titan’s photochemical aerosol appears to be well-mixed from the surface to the top of the stratosphere near an altitude of 300 km, and the spectral shape does not appear to change between 15°N and 58°S latitude. The ratio of aerosol-to-gas scale heights range from 1.3–2.4 at about 160 km to 1.1–1.4 at 300 km, although there is considerable variability with latitude. The aerosol exhibits a very broad emission feature peaking at ～140 cm^?1. Due to its extreme breadth and low wavenumber, we speculate that this feature may be caused by low-energy vibrations of two-dimensional lattice structures of large molecules. Examples of such molecules include polycyclic aromatic hydrocarbons (PAHs) and nitrogenated aromatics.Finally, volume extinction coefficients Nχ_E derived from 15°S CIRS data at a wavelength of λ = 62.5 μm are compared with those derived from the 10°S Huygens Descent Imager/Spectral Radiometer (DISR) data at 1.583 μm. This comparison yields volume extinction coefficient ratios Nχ_E(1.583 μm)/Nχ_E(62.5 μm) of roughly 70 and 20, respectively, for Titan’s aerosol and stratospheric ices. The inferred particle cross-section ratios χ_E(1.583 μm)/χ_E(62.5 μm) appear to be consistent with sub-micron size aerosol particles, and effective radii of only a few microns for stratospheric ice cloud particles.     

Mars mesospheric zonal wind around northern spring equinox from infrared heterodyne observations of CO2

We present direct observations of Mars zonal wind velocities around northern spring equinox (L_S = 336°, L_S = 355°, L_S = 42°) during martian year 27 and 29. Data was acquired by means of infrared heterodyne spectroscopy of CO₂ features at 959.3917 cm^?1 (10.4232 μm) and 957.8005 cm^?1 (10.4405 μm) using the Cologne Tuneable Heterodyne Infrared Spectrometer (THIS) at the McMath–Pierce telescope of the National Solar Observatory on Kitt Peak in Arizona and the NASA Infrared Telescope Facility on Mauna Kea, Hawaii between 2005 and 2008. Winds were measured on the dayside of Mars with an unprecedented spatial resolution allowing sampling of up to nine independent latitudes over the martian disk. Retrieved wind velocities depend strongly on latitude and season with values ranging from 180 m/s prograde to ?94 m/s retrograde. A comparison of the observational results to predicted values from the Mars Climate Database yield a reasonable agreement between modeling and observation.     

Venus Monitoring Camera for Venus Express

The Venus Express mission will focus on a global investigation of the Venus atmosphere and plasma environment, while additionally measuring some surface properties from orbit. The instruments PFS and SPICAV inherited from the Mars Express mission and VIRTIS from Rosetta form a powerful spectrometric and spectro-imaging payload suite. Venus Monitoring Camera (VMC)—a miniature wide-angle camera with 17.5° field of view—was specifically designed and built to complement these experiments and provide imaging context for the whole mission. VMC will take images of Venus in four narrow band filters (365, 513, 965, and 1000 nm) all sharing one CCD. Spatial resolution on the cloud tops will range from 0.2 km/px at pericentre to 45 km/px at apocentre when the full Venus disc will be in the field of view. VMC will fulfill the following science goals: (1) study of the distribution and nature of the unknown UV absorber; (2) determination of the wind field at the cloud tops (70 km) by tracking the UV features; (3) thermal mapping of the surface in the 1 μm transparency “window” on the night side; (4) determination of the global wind field in the main cloud deck (50 km) by tracking near-IR features; (5) study of the lapse rate and H₂O content in the lower 6–10 km; (6) mapping O₂ night-glow and its variability.     

Looking a gift horse in the mouth: Evaluation of wide-field asteroid photometric surveys

It has recently become possible to do a photometric survey of many asteroids at once, rather than observing single asteroids one (or occasionally a couple) at a time. We evaluate two such surveys. Dermawan et al. (Dermawan et al. [2011]. Publ. Astron. Soc. Jpn. 63, S555–S576) observed one night on the Subaru 8.2 m telescope, and Masiero et al. (Masiero, J., Jedicke, R., Durech, J., Gwen, S., Denneau, L., Larsen, J. [2009]. Icarus 204, 145–171) observed six nights over 2 weeks with the 3.6 m CFHT. Dermawan claimed 83 rotation periods from 127 detected asteroids; Masiero et al. claimed 218 rotation periods from 828 detections. Both teams claim a number of super-fast rotators (P < 2.2 h) among main belt asteroids larger than 250 m diameter, some up to several km in diameter. This would imply that the spin rate distribution of main belt asteroids differs from like-sized NEAs, that there are larger super-fast rotators (monolithic asteroids) in the main belt than among NEAs. Here we evaluate these survey results, applying the same criteria for reliability of results that we apply to all results listed in our Lightcurve Database (Warner, B.D., Harris, A.W., Pravec, P. [2009a]. Icarus 202, 134–146). In doing so, we assigned reliability estimates judged sufficient for inclusion in statistical studies for only 27 out of 83 (33%) periods claimed by Dermawan, and only 87 out of 218 (40%) periods reported by Masiero et al.; none of the super-fast rotators larger than about 250 m diameter claimed by either survey received a reliability rating judged sufficient for analysis. We find no reliable basis for the claim of different rotation properties between main belt and near-Earth asteroids. Our analysis presents a cautionary message for future surveys.     

Quantification of middle and lower cloud variability and mesoscale dynamics from Venus Express/VIRTIS observations at 1.74 μm

We present an analysis of VIRTIS-M-IR observations of 1.74 μm emission from the nightside of Venus. The 1.74 μm window in the near infrared spectrum of Venus is an ideal proxy for investigating the evolution of middle and lower cloud deck opacity of Venus because it exhibits good signal to noise due to its brightness, good contrast between bright and dark regions, and few additional sources of extinction beside the clouds themselves. We have analyzed the data from the first 407 orbits (equivalent to 407 Earth days) of the Venus Express mission to determine the magnitude of variability in the 1.74 μm radiance. We have also performed an analysis of the evolution of individual features over a span of roughly 5–6 h on two successive orbits of Venus Express. We find that the overall 1.74 μm brightness of Venus has been increasing through the first 407 days of the mission, indicating a gradual diminishing of the cloud coverage and/or thickness, and that the lower latitudes exhibited more variability and more brightening than higher latitudes. We find that individual features evolve with a time scale of about 30 h, consistent with our previous analysis. Analysis of the evolution and motion of the clouds can be used to estimate the mesoscale dynamics within the clouds of Venus. We find that advection alone cannot explain the observed evolution of the features. The measured vorticity and divergence in the vicinity of the features are consistent with evolution under the influence of significant vertical motions likely driven by a radiative dynamical feedback. We measure a zonal wind speed of around 65 m/s, and a meridional wind speed around 2.5 m/s by tracking the motion of the central region of the features. But we also find that the measured wind speeds depend strongly on the points chosen for the wind speed analysis.     

Spatial variability,composition and thickness of the seasonal north polar cap of Mars in mid-spring

The planetary fourier spectrometer (PFS) for the Mars express mission (MEX) is an infrared spectrometer operating in the wavelength range from 1.2 to 45 μm by means of two spectral channels, called SWC (short wavelength channel) and LWC (long wavelength channel), covering, respectively, 1.2–5.5 and 5.5–45 μm.The middle-spring Martian north polar cap (Ls∼40°) has been observed by PFS/MEX in illuminated conditions during orbit 452. The SWC spectra are here used to study the cap composition in terms of CO₂ ice, H₂O ice and dust content. Significant spectral variation is noted in the cap interior, and regions of varying CO₂ ice grain sizes, water frost abundance, CO₂ ice cover and dust contamination can be distinguished. In addition, we correlate the infrared spectra with an image acquired during the same orbit by the OMEGA imaging spectrometer and with the altimetry from MOLA data. Many of the spectra variations correlate with heterogeneities noted in the image, although significant spectral variations are not discernible in the visible. The data have been divided into five regions with different latitude ranges and strong similarities in the spectra, and then averaged. Bi-directional reflectance models have been run with the appropriate lighting geometry and used to fit the observed data, allowing for CO₂ ice and H₂O ice grain sizes, dust and H₂O ice contaminations in the form of intimate granular mixtures and spatial mixtures.A wide annulus of dusty water ice surrounds the recessing CO₂ seasonal cap. The inner cap exhibits a layered structure with a thin CO₂ layer with varying concentrations of dark dust, on top of an H₂O ice underneath ground. In the best-fits, the ices beneath the top layer have been considered as spatial mixtures. The results are still very good everywhere in the spectral range, except where the CO₂ ice absorption coefficients are such that even a thin layer is enough to totally absorb the incoming radiation (i.e. the band is saturated). This only happens around 3800 cm⁻¹, inside the strong 2.7-μm CO₂ ice absorption band. The effect of finite snow depth has been investigated through a layered albedo model. The thickness of the CO₂ ice deposits increases with latitude, ranging from 0.5–1 g cm⁻² within region II to 60–80 g cm⁻² within the highest-latitude (up to 84°N) region V.Region I is at the cap edge and extends from 65°N to 72°N latitude. No CO₂ ice is present in this region, which consists of relatively large grains of water ice (20 μm), highly contaminated by dust (0.15 wt%). The adjacent region II is a narrow region [76–79°N] right at the edge of the north residual polar cap. This region is very distinct in the OMEGA image, where it appears to surround the whole residual cap. The CO₂ ice features are barely visible in these spectra, except for the strong saturated 2.7 μm band. It basically consists of a thin layer of 5-mm CO₂ ice on top of an H₂O ice layer with the same composition as region I. A third interesting region III is found all along the shoulder of the residual cap [79–81°N]. It extends over 1.5 km in altitude and over only 2° of latitude and consists of CO₂ ice with a large dust content. It is an admixture of CO₂ ice (3–4 mm), with several tens of ppm by mass of water ice and more than 2 ppt by mass of dust. The surface temperatures have been retrieved from the LWC spectra for each observation. We found an increase in the surface temperature in this region, indicating a spatial mixture of cold CO₂ ice and warmer dust/H₂O ice. Region IV is close to the top of the residual cap [81–84°N]; it is much brighter than region III, with a dust content 10 times lower than the latter. The CO₂ grain size is 3 mm and strong CO₂ ice features are present in the data, indicating a thicker CO₂ ice layer than in region II (1–2 g cm⁻²). The final region V is right at the top of the residual cap (⩾84°N). It is “pure” CO₂ ice (no dust) of 5 mm grain sizes, with 30 ppm by weight of water ice. The CO₂ ice features are very pronounced and the 2.7 μm band is saturated. The optical thickness is close to the semi-infinite limit (30–40 g cm⁻²). Assuming a snowpack density of 0.5 g cm⁻³, we get a minimum thickness of 1–2 cm for the top-layer of regions II and III, 4–10 cm for region IV, and ⩾60–80 cm thickness for region V. These values are in close agreement with several recent results for the south seasonal polar cap.These results should provide new, useful constraints in models of the Martian climate system and volatile cycles.     

Observations of water vapour and carbon monoxide in the Martian atmosphere with the SWC of PFS/MEX

In the history of Mars exploration its atmosphere and planetary climatology aroused particular interest. In the study of the minor gases abundance in the Martian atmosphere, water vapour became especially important, both because it is the most variable trace gas, and because it is involved in several processes characterizing the planetary atmosphere. The water vapour photolysis regulates the Martian atmosphere photochemistry, and so it is strictly related to carbon monoxide. The CO study is very important for the so-called “atmosphere stability problem”, solved by the theoretical modelling involving photochemical reactions in which the H₂O and the CO gases are main characters.The Planetary Fourier Spectrometer (PFS) on board the ESA Mars Express (MEX) mission can probe the Mars atmosphere in the infrared spectral range between 200 and 2000 cm^?1 (5–50 μm) with the Long Wavelength Channel (LWC) and between 1700 and 8000 cm^?1 (1.2–5.8 μm) with the Short Wavelength Channel (SWC). Although there are several H₂O and CO absorption bands in the spectral range covered by PFS, we used the 3845 cm^?1 (2.6 μm) and the 4235 cm^?1 (2.36 μm) bands for the analysis of water vapour and carbon monoxide, respectively, because these ranges are less affected by instrumental problems than the other ones. The gaseous concentrations are retrieved by using an algorithm developed for this purpose.The PFS/SW dataset used in this work covers more than two and a half Martian years from Ls=62° of MY 27 (orbit 634) to Ls=203° of MY 29 (orbit 6537). We measured a mean column density of water vapour of about 9.6 pr. μm and a mean mixing ratio of carbon monoxide of about 990 ppm, but with strong seasonal variations at high latitudes. The seasonal water vapour map reproduces very well the known seasonal water cycle. In the northern summer, water vapour and CO show a good anticorrelation most of the time. This behaviour is due to the carbon dioxide and water sublimation from the north polar ice cap, which dilutes non-condensable species including carbon monoxide. An analogous process takes place during the winter polar cap, but in this case the condensation of carbon dioxide and water vapour causes an increase of the concentration of non-condensable species. Finally, the results show the seasonal variation of the carbon monoxide mixing ratio with the surface pressure.     

The planetary fourier spectrometer (PFS) onboard the European Venus Express mission

The planetary fourier spectrometer (PFS) for the Venus Express mission is an infrared spectrometer optimized for atmospheric studies. This instrument has a short wavelength (SW) channel that covers the spectral range from 1700 to 11400 cm⁻¹ (0.9–5.5 μm) and a long wavelength (LW) channel that covers 250–1700 cm⁻¹ (5.5–45 μm). Both channels have a uniform spectral resolution of 1.3 cm⁻¹. The instrument field of view FOV is about 1.6 ° (FWHM) for the short wavelength channel and 2.8 ° for the LW channel which corresponds to a spatial resolution of 7 and 12 km when Venus is observed from an altitude of 250 km. PFS can provide unique data necessary to improve our knowledge not only of the atmospheric properties but also surface properties (temperature) and the surface-atmosphere interaction (volcanic activity).PFS works primarily around the pericentre of the orbit, only occasionally observing Venus from larger distances. Each measurements takes 4.5 s, with a repetition time of 11.5 s. By working roughly 1.5 h around pericentre, a total of 460 measurements per orbit will be acquired plus 60 for calibrations. PFS is able to take measurements at all local times, enabling the retrieval of atmospheric vertical temperature profiles on both the day and the night side.The PFS measures a host of atmospheric and surface phenomena on Venus. These include the:(1) thermal surface flux at several wavelengths near 1 μm, with concurrent constraints on surface temperature and emissivity (indicative of composition); (2) the abundances of several highly-diagnostic trace molecular species; (3) atmospheric temperatures from 55 to 100 km altitude; (4) cloud opacities and cloud-tracked winds in the lower-level cloud layers near 50-km altitudes; (5) cloud top pressures of the uppermost haze/cloud region near 70–80 km altitude; and (6) oxygen airglow near the 100 km level. All of these will be observed repeatedly during the 500-day nominal mission of Venus Express to yield an increased understanding of meteorological, dynamical, photochemical, and thermo-chemical processes in the Venus atmosphere. Additionally, PFS will search for and characterize current volcanic activity through spatial and temporal anomalies in both the surface thermal flux and the abundances of volcanic trace species in the lower atmosphere.Measurement of the 15 μm CO₂ band is very important. Its profile gives, by means of a complex temperature profile retrieval technique, the vertical pressure-temperature relation, basis of the global atmospheric study.PFS is made of four modules called O, E, P and S being, respectively, the interferometer and proximity electronics, the digital control unit, the power supply and the pointing device.     

Charting thermal emission variability at Pele,Janus Patera and Kanehekili Fluctus with the Galileo NIMS Io Thermal Emission Database (NITED)

Using the NIMS Io Thermal Emission Database (NITED), a collection of over 1000 measurements of radiant flux from Io’s volcanoes (Davies, A.G. et al. [2012]. Geophys. Res. Lett. 39, L01201. doi:10.1029/2011GL049999), we have examined the variability of thermal emission from three of Io’s volcanoes: Pele, Janus Patera and Kanehekili Fluctus. At Pele, the 5-μm thermal emission as derived from 28 night time observations is remarkably steady at 37 ± 10 GW μm^?1, re-affirming previous analyses that suggested that Pele an active, rapidly overturning silicate lava lake. Janus Patera also exhibits relatively steady 5-μm thermal emission (≈20 ± 3 GW μm^?1) in the four observations where Janus is resolved from nearby Kanehekili Fluctus. Janus Patera might contain a Pele-like lava lake with an effusion rate (Q_F) of ≈40–70 m³ s^?1. It should be a prime target for a future mission to Io in order to obtain data to determine lava eruption temperature. Kanehekili Fluctus has a thermal emission spectrum that is indicative of the emplacement of lava flows with insulated crusts. Effusion rate at Kanehekili Fluctus dropped by an order of magnitude from ≈95 m³ s^?1 in mid-1997 to ≈4 m³ s^?1 in late 2001.     

Spectroscopic survey of M-type asteroids

M-type asteroids, as defined in the Tholen taxonomy (Tholen, D.J. [1984]. Asteroid Taxonomy from Cluster Analysis of Photometry. Ph.D. Dissertation, University of Arizona, Tucson), are medium albedo bodies supposed to have a metallic composition and to be the progenitors both of differentiated iron–nickel meteorites and enstatite chondrites. We carried out a spectroscopic survey in the visible and near infrared wavelength range (0.4–2.5 μm) of 30 asteroids chosen from the population of asteroids initially classified as Tholen M-types, aiming to investigate their surface composition. The data were obtained during several observing runs during the years 2004–2007 at the TNG, NTT, and IRTF telescopes. We computed the spectral slopes in several wavelength ranges for each observed asteroid, and we searched for diagnostic spectral features. We confirm a large variety of spectral behaviors for these objects as their spectra are extended into the near infrared, including the identification of weak absorption bands, mainly of the 0.9 μm band tentatively attributed to orthopyroxene, and of the 0.43 μm band that may be associated to chlorites and Mg-rich serpentines or pyroxene minerals such us pigeonite or augite. A comparison with previously published data indicates that the surfaces of several asteroids belonging to the M-class may vary significantly.We attempt to constrain the asteroid surface compositions of our sample by looking for meteorite spectral analogs in the RELAB database and by modeling with geographical mixtures of selected meteorites/minerals. We confirm that iron meteorites, pallasites, and enstatite chondrites are the best matches to most objects in our sample, as suggested for M-type asteroids. For 22 Kalliope, we demonstrate that a synthetic mixture obtained enriching a pallasite meteorite with small amounts (1–2%) of silicates well reproduce the spectral behavior including the observed 0.9 μm feature.The presence of subtle absorption features on several asteroids confirms that not all objects defined by the Tholen M-class have a pure metallic composition.A statistical analysis of spectral slope distribution vs. orbital parameters shows that our sample originally defined as Tholen M-types tend to be dark in albedo and red in slope for increasing value of the semi-major axis. However, we note that our sample is statistically limited by our number of objects (30) and slightly varying results are found for different subsets. If confirmed, the albedo and slope trends could be due to a difference in composition of objects belonging to the outer main belt, or alternatively to a combination of surface composition, grain size and space weathering effects.     

Phase reddening on near-Earth asteroids: Implications for mineralogical analysis,space weathering and taxonomic classification

Phase reddening is an effect that produces an increase of the spectral slope and variations in the strength of the absorption bands as the phase angle increases. In order to understand its effect on spectroscopic observations of asteroids, we have analyzed the visible and near-infrared spectra (0.45–2.5 μm) of 12 near-Earth asteroids observed at different phase angles. All these asteroids are classified as either S-complex or Q-type asteroids. In addition, we have acquired laboratory spectra of three different types of ordinary chondrites at phase angles ranging from 13° to 120°. We have found that both, asteroid and meteorite spectra show an increase in band depths with increasing phase angle. In the case of the asteroids the Band I depth increases in the range of ～2° < g < 70° and the Band II depth increases in the range of ～2° < g < 55°. Using this information we have derived equations that can be used to correct the effect of phase reddening in the band depths. Of the three meteorite samples, the (olivine-rich) LL6 ordinary chondrite is the most affected by phase reddening. The studied ordinary chondrites have their maximum spectral contrast of Band I depths at a phase angle of ～60°, followed by a decrease between 60° and 120° phase angle. The Band II depths of these samples have their maximum spectral contrast at phase angles of 30–60° which then gradually decreases to 120° phase angle. The spectral slope of the ordinary chondrites spectra shows a significant increase with increasing phase angle for g > 30°. Variations in band centers and band area ratio (BAR) values were also found, however they seems to have no significant impact on the mineralogical analysis. Our study showed that the increase in spectral slope caused by phase reddening is comparable to certain degree of space weathering. In particular, an increase in phase angle in the range of 30–120° will produce a reddening of the reflectance spectra equivalent to exposure times of ～0.1 × 10⁶–1.3 × 10⁶ years at about 1 AU from the Sun. This increase in spectral slope due to phase reddening is also comparable to the effects caused by the addition of different fractions of SMFe. Furthermore, we found that under some circumstances phase reddening could lead to an ambiguous taxonomic classification of asteroids.     

Ground-based near-infrared observations of water vapour in the Venus troposphere

We present a study of water vapour in the Venus troposphere obtained by modelling specific water vapour absorption bands within the 1.18 μm window. We compare the results with the normal technique of obtaining the abundance by matching the peak of the 1.18 μm window. Ground-based infrared imaging spectroscopy of the night side of Venus was obtained with the Anglo-Australian Telescope and IRIS2 instrument with a spectral resolving power of R ～ 2400. The spectra have been fitted with modelled spectra simulated using the radiative transfer model VSTAR. We find a best fit abundance of 31 ppmv (?6 +9 ppmv), which is in agreement with recent results by Bézard et al. (Bézard, B., Fedorova, A., Bertaux, J.-L., Rodin, A., Korablev, O. [2011]. Icarus, 216, 173–183) using VEX/SPICAV (R ～ 1700) and contrary to prior results by Bézard et al. (Bézard, B., de Bergh, C., Crisp, D., Maillard, J.P. [1990]. Nature, 345, 508–511) of 44 ppmv (±9 ppmv) using VEX/VIRTIS-M (R ～ 200) data analyses. Comparison studies are made between water vapour abundances determined from the peak of the 1.18 μm window and abundances determined from different water vapour absorption features within the near infrared window. We find that water vapour abundances determined over the peak of the 1. 18 μm window results in plots with less scatter than those of the individual water vapour features and that analyses conducted over some individual water vapour features are more sensitive to variation in water vapour than those over the peak of the 1. 18 μm window. No evidence for horizontal spatial variations across the night side of the disk are found within the limits of our data with the exception of a possible small decrease in water vapour from the equator to the north pole. We present spectral ratios that show water vapour absorption from within the lowest 4 km of the Venus atmosphere only, and discuss the possible existence of a decreasing water vapour concentration towards the surface.     

Water vapor near the cloud tops of Venus from Venus Express/VIRTIS dayside data

Observations of the dayside of Venus performed by the high spectral resolution channel (–H) of the Visible and Infrared Thermal Imaging Spectrometer (VIRTIS) on board the ESA Venus Express mission have been used to measure the altitude of the cloud tops and the water vapor abundance around this level with a spatial resolution ranging from 100 to 10 km. CO₂ and H₂O bands between 2.48 and 2.60 μm are analyzed to determine the cloud top altitude and water vapor abundance near this level. At low latitudes (±40°) mean water vapor abundance is equal to 3 ± 1 ppm and the corresponding cloud top altitude at 2.5 μm is equal to 69.5 ± 2 km. Poleward from middle latitudes the cloud top altitude gradually decreases down to 64 km, while the average H₂O abundance reaches its maximum of 5 ppm at 80° of latitude with a large scatter from 1 to 15 ppm. The calculated mass percentage of the sulfuric acid solution in cloud droplets of mode 2 (～1 μm) particles is in the range 75–83%, being in even more narrow interval of 80–83% in low latitudes. No systematic correlation of the dark UV markings with the cloud top altitude or water vapor has been observed.     

Absolute magnitudes of asteroids and a revision of asteroid albedo estimates from WISE thermal observations

We obtained estimates of the Johnson V absolute magnitudes (H) and slope parameters (G) for 583 main-belt and near-Earth asteroids observed at Ond?ejov and Table Mountain Observatory from 1978 to 2011. Uncertainties of the absolute magnitudes in our sample are <0.21 mag, with a median value of 0.10 mag. We compared the H data with absolute magnitude values given in the MPCORB, Pisa AstDyS and JPL Horizons orbit catalogs. We found that while the catalog absolute magnitudes for large asteroids are relatively good on average, showing only little biases smaller than 0.1 mag, there is a systematic offset of the catalog values for smaller asteroids that becomes prominent in a range of H greater than ～10 and is particularly big above H ～ 12. The mean (H_catalog ? H) value is negative, i.e., the catalog H values are systematically too bright. This systematic negative offset of the catalog values reaches a maximum around H = 14 where the mean (H_catalog ? H) is ?0.4 to ?0.5. We found also smaller correlations of the offset of the catalog H values with taxonomic types and with lightcurve amplitude, up to ～0.1 mag or less. We discuss a few possible observational causes for the observed correlations, but the reason for the large bias of the catalog absolute magnitudes peaking around H = 14 is unknown; we suspect that the problem lies in the magnitude estimates reported by asteroid surveys. With our photometric H and G data, we revised the preliminary WISE albedo estimates made by Masiero et al. (Masired, J.R. et al. [2011]. Astrophys. J. 741, 68–89) and Mainzer et al. (Mainzer, A. et al. [2011b]. Astrophys. J. 743, 156–172) for asteroids in our sample. We found that the mean geometric albedo of Tholen/Bus/DeMeo C/G/B/F/P/D types with sizes of 25–300 km is p_V = 0.057 with the standard deviation (dispersion) of the sample of 0.013 and the mean albedo of S/A/L types with sizes 0.6–200 km is 0.197 with the standard deviation of the sample of 0.051. The standard errors of the mean albedos are 0.002 and 0.006, respectively; systematic observational or modeling errors can predominate over the quoted formal errors. There is apparent only a small, marginally significant difference of 0.031 ± 0.011 between the mean albedos of sub-samples of large and small (divided at diameter 25 km) S/A/L asteroids, with the smaller ones having a higher albedo. The difference will have to be confirmed and explained; we speculate that it may be either a real size dependence of surface properties of S type asteroids or a small size-dependent bias in the data (e.g., a bias towards higher albedos in the optically-selected sample of asteroids). A trend of the mean of the preliminary WISE albedo estimates increasing with asteroid size decreasing from D ～ 30 down to ～5 km (for S types) showed in Mainzer et al. (Mainzer, A. et al. [2011a]. Astrophys. J. 741, 90–114) appears to be mainly due to the systematic bias in the MPCORB absolute magnitudes that progressively increases with H in the corresponding range H = 10–14.