Spectral reflectance properties of carbonaceous chondrites: 3. CR chondrites

Powdered samples of a suite of 14 CR and CR-like chondrites, ranging from petrologic grade 1 to 3, were spectrally characterized over the 0.3–2.5 μm interval as part of a larger study of carbonaceous chondrite reflectance spectra. Spectral analysis was complicated by absorption bands due to Fe oxyhydroxides near 0.9 μm, resulting from terrestrial weathering. This absorption feature masks expected absorption bands due to constituent silicates in this region. In spite of this interference, most of the CR spectra exhibit absorption bands attributable to silicates, in particular an absorption feature due to Fe²⁺-bearing phyllosilicates near 1.1 μm. Mafic silicate absorption bands are weak to nonexistent due to a number of factors, including low Fe content, low degree of silicate crystallinity in some cases, and presence of fine-grained, finely dispersed opaques. With increasing aqueous alteration, phyllosilicate: mafic silicate ratios increase, resulting in more resolvable phyllosilicate absorption bands in the 1.1 μm region. In the most phyllosilicate-rich CR chondrite, GRO 95577 (CR1), an additional possible phyllosilicate absorption band is seen at 2.38 μm. In contrast to CM spectra, CR spectra generally do not exhibit an absorption band in the 0.65–0.7 μm region, which is attributable to Fe³⁺–Fe²⁺ charge transfers, suggesting that CR phyllosilicates are not as Fe³⁺-rich as CM phyllosilicates. CR2 and CR3 spectra are uniformly red-sloped, likely due to the presence of abundant Fe–Ni metal. Absolute reflectance seems to decrease with increasing degree of aqueous alteration, perhaps due to the formation of fine-grained opaques from pre-existing metal. Overall, CR spectra are characterized by widely varying reflectance (4–21% maximum reflectance), weak silicate absorption bands in the 0.9–1.3 μm region, overall red slopes, and the lack of an Fe³⁺–Fe²⁺ charge transfer absorption band in the 0.65–0.7 μm region.     

Photometric,spectral phase and temperature effects on 4 Vesta and HED meteorites: Implications for the Dawn mission

Phase angle and temperature are two important parameters that affect the photometric and spectral behavior of planetary surfaces in telescopic and spacecraft data. We have derived photometric and spectral phase functions for the Asteroid 4 Vesta, the first target of the Dawn mission, using ground-based telescopes operating at visible and near-infrared wavelengths (0.4–2.5 μm). Photometric lightcurve observations of Vesta were conducted on 15 nights at a phase angle range of 3.8–25.7° using duplicates of the seven narrowband Dawn Framing Camera filters (0.4–1.0 μm). Rotationally resolved visible (0.4–0.7 μm) and near-IR spectral observations (0.7–2.5 μm) were obtained on four nights over a similar phase angle range. Our Vesta photometric observations suggest the phase slope is between 0.019 and 0.029 mag/deg. The G parameter ranges from 0.22 to 0.37 consistent with previous results (e.g., Lagerkvist, C.-I., Magnusson, P., Williams, I.P., Buontempo, M.E., Argyle, R.W., Morrison, L.V. [1992]. Astron. Astrophys. Suppl. Ser. 94, 43–71; Piironen, J., Magnusson, P., Lagerkvist, C.-I., Williams, I.P., Buontempo, M.E., Morrison, L.V. [1997]. Astron. Astrophys. Suppl. Ser. 121, 489–497; Hasegawa, S. et al. [2009]. Lunar Planet. Sci. 40. ID 1503) within the uncertainty. We found that in the phase angle range of 0° < α ? 25° for every 10° increase in phase angle Vesta’s visible slope (0.5–0.7 μm) increases 20%, Band I and Band II depths increase 2.35% and 1.5% respectively, and the BAR value increase 0.30. Phase angle spectral measurements of the eucrite Moama in the lab show a decrease in Band I and Band II depths and BAR from the lowest phase angle 13° to 30°, followed by possible small increases up to 90°, and then a dramatic drop between 90° and 120° phase angle. Temperature-induced spectral effects shift the Band I and II centers of the pyroxene bands to longer wavelengths with increasing temperature. We have derived new correction equations using a temperature series (80–400 K) of HED meteorite spectra that will enable interpretation of telescopic and spacecraft spectral data using laboratory calibrations at room temperature (300 K).     

Phase reddening on near-Earth asteroids: Implications for mineralogical analysis,space weathering and taxonomic classification

Phase reddening is an effect that produces an increase of the spectral slope and variations in the strength of the absorption bands as the phase angle increases. In order to understand its effect on spectroscopic observations of asteroids, we have analyzed the visible and near-infrared spectra (0.45–2.5 μm) of 12 near-Earth asteroids observed at different phase angles. All these asteroids are classified as either S-complex or Q-type asteroids. In addition, we have acquired laboratory spectra of three different types of ordinary chondrites at phase angles ranging from 13° to 120°. We have found that both, asteroid and meteorite spectra show an increase in band depths with increasing phase angle. In the case of the asteroids the Band I depth increases in the range of ～2° < g < 70° and the Band II depth increases in the range of ～2° < g < 55°. Using this information we have derived equations that can be used to correct the effect of phase reddening in the band depths. Of the three meteorite samples, the (olivine-rich) LL6 ordinary chondrite is the most affected by phase reddening. The studied ordinary chondrites have their maximum spectral contrast of Band I depths at a phase angle of ～60°, followed by a decrease between 60° and 120° phase angle. The Band II depths of these samples have their maximum spectral contrast at phase angles of 30–60° which then gradually decreases to 120° phase angle. The spectral slope of the ordinary chondrites spectra shows a significant increase with increasing phase angle for g > 30°. Variations in band centers and band area ratio (BAR) values were also found, however they seems to have no significant impact on the mineralogical analysis. Our study showed that the increase in spectral slope caused by phase reddening is comparable to certain degree of space weathering. In particular, an increase in phase angle in the range of 30–120° will produce a reddening of the reflectance spectra equivalent to exposure times of ～0.1 × 10⁶–1.3 × 10⁶ years at about 1 AU from the Sun. This increase in spectral slope due to phase reddening is also comparable to the effects caused by the addition of different fractions of SMFe. Furthermore, we found that under some circumstances phase reddening could lead to an ambiguous taxonomic classification of asteroids.     

Titan’s aerosol and stratospheric ice opacities between 18 and 500 μm: Vertical and spectral characteristics from Cassini CIRS

Vertical distributions and spectral characteristics of Titan’s photochemical aerosol and stratospheric ices are determined between 20 and 560 cm^?1 (500–18 μm) from the Cassini Composite Infrared Spectrometer (CIRS). Results are obtained for latitudes of 15°N, 15°S, and 58°S, where accurate temperature profiles can be independently determined.In addition, estimates of aerosol and ice abundances at 62°N relative to those at 15°S are derived. Aerosol abundances are comparable at the two latitudes, but stratospheric ices are ～3 times more abundant at 62°N than at 15°S. Generally, nitrile ice clouds (probably HCN and HC₃N), as inferred from a composite emission feature at ～160 cm^?1, appear to be located over a narrow altitude range in the stratosphere centered at ～90 km. Although most abundant at high northern latitudes, these nitrile ice clouds extend down through low latitudes and into mid southern latitudes, at least as far as 58°S.There is some evidence of a second ice cloud layer at ～60 km altitude at 58°S associated with an emission feature at ～80 cm^?1. We speculate that the identify of this cloud may be due to C₂H₆ ice, which in the vapor phase is the most abundant hydrocarbon (next to CH₄) in the stratosphere of Titan.Unlike the highly restricted range of altitudes (50–100 km) associated with organic condensate clouds, Titan’s photochemical aerosol appears to be well-mixed from the surface to the top of the stratosphere near an altitude of 300 km, and the spectral shape does not appear to change between 15°N and 58°S latitude. The ratio of aerosol-to-gas scale heights range from 1.3–2.4 at about 160 km to 1.1–1.4 at 300 km, although there is considerable variability with latitude. The aerosol exhibits a very broad emission feature peaking at ～140 cm^?1. Due to its extreme breadth and low wavenumber, we speculate that this feature may be caused by low-energy vibrations of two-dimensional lattice structures of large molecules. Examples of such molecules include polycyclic aromatic hydrocarbons (PAHs) and nitrogenated aromatics.Finally, volume extinction coefficients Nχ_E derived from 15°S CIRS data at a wavelength of λ = 62.5 μm are compared with those derived from the 10°S Huygens Descent Imager/Spectral Radiometer (DISR) data at 1.583 μm. This comparison yields volume extinction coefficient ratios Nχ_E(1.583 μm)/Nχ_E(62.5 μm) of roughly 70 and 20, respectively, for Titan’s aerosol and stratospheric ices. The inferred particle cross-section ratios χ_E(1.583 μm)/χ_E(62.5 μm) appear to be consistent with sub-micron size aerosol particles, and effective radii of only a few microns for stratospheric ice cloud particles.     

Spatial and temporal variations in Titan's surface temperatures from Cassini CIRS observations

We report a wide-ranging study of Titan's surface temperatures by analysis of the Moon's outgoing radiance through a spectral window in the thermal infrared at 19 μm (530 cm^?1) characterized by lower atmospheric opacity. We begin by modeling Cassini Composite Infrared Spectrometer (CIRS) far infrared spectra collected in the period 2004–2010, using a radiative transfer forward model combined with a non-linear optimal estimation inversion method. At low-latitudes, we agree with the HASI near-surface temperature of about 94 K at 10°S (Fulchignoni et al., 2005). We find a systematic decrease from the equator toward the poles, hemispherically asymmetric, of ～1 K at 60° south and ～3 K at 60° north, in general agreement with a previous analysis of CIRS data (Jennings et al., 2009), and with Voyager results from the previous northern winter. Subdividing the available database, corresponding to about one Titan season, into 3 consecutive periods, small seasonal changes of up to 2 K at 60°N became noticeable in the results. In addition, clear evidence of diurnal variations of the surface temperatures near the equator are observed for the first time: we find a trend of slowly increasing temperature from the morning to the early afternoon and a faster decrease during the night. The diurnal change is ～1.5 K, in agreement with model predictions for a surface with a thermal inertia between 300 and 600 J m^?2 s^?1/2 K^?1. These results provide important constraints on coupled surface–atmosphere models of Titan's meteorology and atmospheric dynamic.     

Spatial variability,composition and thickness of the seasonal north polar cap of Mars in mid-spring

The planetary fourier spectrometer (PFS) for the Mars express mission (MEX) is an infrared spectrometer operating in the wavelength range from 1.2 to 45 μm by means of two spectral channels, called SWC (short wavelength channel) and LWC (long wavelength channel), covering, respectively, 1.2–5.5 and 5.5–45 μm.The middle-spring Martian north polar cap (Ls∼40°) has been observed by PFS/MEX in illuminated conditions during orbit 452. The SWC spectra are here used to study the cap composition in terms of CO₂ ice, H₂O ice and dust content. Significant spectral variation is noted in the cap interior, and regions of varying CO₂ ice grain sizes, water frost abundance, CO₂ ice cover and dust contamination can be distinguished. In addition, we correlate the infrared spectra with an image acquired during the same orbit by the OMEGA imaging spectrometer and with the altimetry from MOLA data. Many of the spectra variations correlate with heterogeneities noted in the image, although significant spectral variations are not discernible in the visible. The data have been divided into five regions with different latitude ranges and strong similarities in the spectra, and then averaged. Bi-directional reflectance models have been run with the appropriate lighting geometry and used to fit the observed data, allowing for CO₂ ice and H₂O ice grain sizes, dust and H₂O ice contaminations in the form of intimate granular mixtures and spatial mixtures.A wide annulus of dusty water ice surrounds the recessing CO₂ seasonal cap. The inner cap exhibits a layered structure with a thin CO₂ layer with varying concentrations of dark dust, on top of an H₂O ice underneath ground. In the best-fits, the ices beneath the top layer have been considered as spatial mixtures. The results are still very good everywhere in the spectral range, except where the CO₂ ice absorption coefficients are such that even a thin layer is enough to totally absorb the incoming radiation (i.e. the band is saturated). This only happens around 3800 cm⁻¹, inside the strong 2.7-μm CO₂ ice absorption band. The effect of finite snow depth has been investigated through a layered albedo model. The thickness of the CO₂ ice deposits increases with latitude, ranging from 0.5–1 g cm⁻² within region II to 60–80 g cm⁻² within the highest-latitude (up to 84°N) region V.Region I is at the cap edge and extends from 65°N to 72°N latitude. No CO₂ ice is present in this region, which consists of relatively large grains of water ice (20 μm), highly contaminated by dust (0.15 wt%). The adjacent region II is a narrow region [76–79°N] right at the edge of the north residual polar cap. This region is very distinct in the OMEGA image, where it appears to surround the whole residual cap. The CO₂ ice features are barely visible in these spectra, except for the strong saturated 2.7 μm band. It basically consists of a thin layer of 5-mm CO₂ ice on top of an H₂O ice layer with the same composition as region I. A third interesting region III is found all along the shoulder of the residual cap [79–81°N]. It extends over 1.5 km in altitude and over only 2° of latitude and consists of CO₂ ice with a large dust content. It is an admixture of CO₂ ice (3–4 mm), with several tens of ppm by mass of water ice and more than 2 ppt by mass of dust. The surface temperatures have been retrieved from the LWC spectra for each observation. We found an increase in the surface temperature in this region, indicating a spatial mixture of cold CO₂ ice and warmer dust/H₂O ice. Region IV is close to the top of the residual cap [81–84°N]; it is much brighter than region III, with a dust content 10 times lower than the latter. The CO₂ grain size is 3 mm and strong CO₂ ice features are present in the data, indicating a thicker CO₂ ice layer than in region II (1–2 g cm⁻²). The final region V is right at the top of the residual cap (⩾84°N). It is “pure” CO₂ ice (no dust) of 5 mm grain sizes, with 30 ppm by weight of water ice. The CO₂ ice features are very pronounced and the 2.7 μm band is saturated. The optical thickness is close to the semi-infinite limit (30–40 g cm⁻²). Assuming a snowpack density of 0.5 g cm⁻³, we get a minimum thickness of 1–2 cm for the top-layer of regions II and III, 4–10 cm for region IV, and ⩾60–80 cm thickness for region V. These values are in close agreement with several recent results for the south seasonal polar cap.These results should provide new, useful constraints in models of the Martian climate system and volatile cycles.     

The O2 nightglow in the martian atmosphere by SPICAM onboard of Mars-Express

We present observations of the O₂(a¹Δ_g) nightglow at 1.27 μm on Mars using the SPICAM IR spectrometer onboard of the Mars Express orbiter. In contrast to the O₂(a¹Δ_g) dayglow that results from the ozone photodissociation, the O₂(a¹Δ_g) nightglow is a product of the recombination of O atoms formed by CO₂ photolysis on the dayside at altitudes higher than 80 km and transported downward above the winter pole by the Hadley circulation. The first detections of the O₂(a¹Δ_g) nightglow in 2010 indicate that it is about two order of magnitude less intense than the dayglow (Bertaux, J.-L., Gondet, B., Bibring, J.-P., Montmessin, F., Lefèvre, F. [2010]. Bull. Am. Astron. Soc. 42, 1040; Clancy et al. [2010]. Bull. Am. Astron. Soc. 42, 1041). SPICAM IR sounds the martian atmosphere in the near-IR range (1–1.7 μm) with the spectral resolution of 3.5 cm^?1 in nadir, limb and solar occultation modes. In 2010 the vertical profiles of the O₂(a¹Δ_g) nightside emission have been obtained near the South Pole at latitudes of 82–83°S for two sequences of observations: L_s = 111–120° and L_s = 152–165°. The altitude of the emission maximum varied from 45 km on L_s = 111–120° to 38–49 km on L_s = 152–165°. Averaged vertically integrated intensity of the emission at these latitudes has shown an increase from 0.22 to 0.35 MR. Those values of total vertical emission rate are consistent with the OMEGA observations on Mars-Express in 2010. The estimated density of oxygen atoms at altitudes from 50 to 65 km varies from 1.5 × 10¹¹ to 2.5 × 10¹¹ cm^?3. Comparison with the LMD general circulation model with photochemistry (Lefèvre, F., Lebonnois, S., Montmessin, F., Forget, F. [2004]. J. Geophys. Res. 109, E07004; Lefèvre et al. [2008]. Nature 454, 971–975) shows that the model reproduces fairly well the O₂(a¹Δ_g) emission layer observed by SPICAM when the large field of view (>20 km on the limb) of the instrument is taken into account.     

Micromega/IR: Design and status of a near-infrared spectral microscope for in situ analysis of Mars samples

MicrOmega is an ultra miniaturized spectral microscope for in situ analysis of samples. It is composed of 2 microscopes; one with a spatial sampling less or equal to 4 μm, working in 4 colors in the visible range: MicrOmega/VIS, and a NIR hyperspectral microscope working in the spectral range 0.9–4 μm with a spatial sampling of 20 μm per pixel: MicrOmega/IR (described in this paper). MicrOmega/IR illuminates and images samples a few mm in size and acquires the NIR spectrum of each resolved pixel in up to 320 contiguous spectral channels. The goal of this instrument is to analyze in situ the composition of collected samples at almost their grain size scale, in a non-destructive way. With the chosen spectral range and resolution, a wide variety of constituents can be identified: minerals, such as pyroxene and olivine, ferric oxides, hydrated phyllosilicates, sulfates and carbonates and ices and organics. The composition of the various phases within a given sample is a critical record of its formation and evolution. Coupled to the mapping information, it provides unique clues to describe the history of the parent body (planet, satellite and small body). In particular, the capability to identify hydrated grains and to characterize their adjacent phases has a huge potential in the search for possible bio-relics.     

Spectral behavior of the symbiotic nova AG Pegasi observed with IUE and HST

Ultraviolet spectra from the International Ultraviolet Explorer (IUE) and from the Hubble Space Telescope (HST) of the symbiotic novae AG Peg during the period 1978–1996 are analyzed. Some spectra showing the modulations of spectral lines at different times are presented. We determined the reddening from the 2200 Å feature, finding that E(B−V) = 0.10 ± 0.02. We studied N IV] at 1486 Å, C IV 1550 Å, and O III] at 1660 Å, produced in the fast wind from the hot white dwarf. The mean wind velocity of the three emission lines is 1300 km s⁻¹ (FWHM). The mean wind mass loss rate is ∼6 × 10⁻⁷ M_⊙ yr⁻¹. The mean temperature is ∼6.5 × 10⁵ K. The mean ultraviolet luminosity is ∼5 × 10³³ erg s⁻¹. The modulations of line fluxes in the emitting region at different times are attributed to the variations of density and temperature of the ejected matter as a result of variations in the rate of mass loss.     

Line broadening in the neutral and ionized mercury spectra

The neutral, singly, doubly and triply ionized mercury (Hg I–IV, respectively) spectral line shapes and line center positions have been investigated in the laboratory helium plasma at electron densities ranging between 9.3 × 10²² m^?3 and 1.93 × 10²³ m^?3 and electron temperatures around 19,500 K, both interesting for astrophysics. The mercury (natural isotope composition) atoms were sputtered from the cylindrical amalgamated gold plates located in the homogenous part of the pulsed helium discharge operating at a pressure of 665 Pa in a flowing regime. The mercury spectral line profiles were recorded using the McPherson model 209 spectrograph and the Andor ICCD camera as the detection system. This research presents Stark broadening parameters, the width (W) and the shift (d), of one Hg I, 19 Hg II, 6 Hg III and 4 Hg IV lines, not investigated so far. Our experimental W values were compared with the data calculated applying various approaches. The shape and intensity of astrophysically important 398.4 nm Hg II spectral line was discussed taking into account the isotope shift, hyperfine structure and Penning effects. At the mentioned plasma parameters the Stark broadening is found to be a main line broadening mechanism of the lines (λ > 200 nm) in the Hg I–IV spectra.     

Stardust-NExT,Deep Impact,and the accelerating spin of 9P/Tempel 1

The evolution of the spin rate of Comet 9P/Tempel 1 through two perihelion passages (in 2000 and 2005) is determined from 1922 Earth-based observations taken over a period of 13 year as part of a World-Wide observing campaign and from 2888 observations taken over a period of 50 days from the Deep Impact spacecraft. We determine the following sidereal spin rates (periods): 209.023 ± 0.025°/dy (41.335 ± 0.005 h) prior to the 2000 perihelion passage, 210.448 ± 0.016°/dy (41.055 ± 0.003 h) for the interval between the 2000 and 2005 perihelion passages, 211.856 ± 0.030°/dy (40.783 ± 0.006 h) from Deep Impact photometry just prior to the 2005 perihelion passage, and 211.625 ± 0.012°/dy (40.827 ± 0.002 h) in the interval 2006–2010 following the 2005 perihelion passage. The period decreased by 16.8 ± 0.3 min during the 2000 passage and by 13.7 ± 0.2 min during the 2005 passage suggesting a secular decrease in the net torque. The change in spin rate is asymmetric with respect to perihelion with the maximum net torque being applied on approach to perihelion. The Deep Impact data alone show that the spin rate was increasing at a rate of 0.024 ± 0.003°/dy/dy at JD2453530.60510 (i.e., 25.134 dy before impact), which provides independent confirmation of the change seen in the Earth-based observations.The rotational phase of the nucleus at times before and after each perihelion and at the Deep Impact encounter is estimated based on the Thomas et al. (Thomas et al. [2007]. Icarus 187, 4–15) pole and longitude system. The possibility of a 180° error in the rotational phase is assessed and found to be significant. Analytical and physical modeling of the behavior of the spin rate through of each perihelion is presented and used as a basis to predict the rotational state of the nucleus at the time of the nominal (i.e., prior to February 2010) Stardust-NExT encounter on 2011 February 14 at 20:42.We find that a net torque in the range of 0.3–2.5 × 10⁷ kg m² s^?2 acts on the nucleus during perihelion passage. The spin rate initially slows down on approach to perihelion and then passes through a minimum. It then accelerates rapidly as it passes through perihelion eventually reaching a maximum post-perihelion. It then decreases to a stable value as the nucleus moves away from the Sun. We find that the pole direction is unlikely to precess by more than ～1° per perihelion passage. The trend of the period with time and the fact that the modeled peak torque occurs before perihelion are in agreement with published accounts of trends in water production rate and suggests that widespread H₂O out-gassing from the surface is largely responsible for the observed spin-up.     

Optical constants of Titan’s stratospheric aerosols in the 70–1500 cm−1 spectral range constrained by Cassini/CIRS observations

We utilized aerosol extinction coefficient inferred from Cassini/CIRS spectra in the far and mid infrared region to derive the extinction cross-section near an altitude of 190 km at 15°S (from far-IR) and 20°S (from mid-IR). By comparing the extinction cross section that are derived from observations with theoretical calculations for a fractal aggregate of 3000 monomers, each having a radius of 0.05 μm, and a fractal dimension of 2, we are able to constrain the refractive index of Titan’s aerosol between 70 and 1500 cm^?1 (143 and 6.7 μm). As the real and imaginary parts of the refractive index are related by the Kramers–Kronig equation, we apply an iterative process to determine the optical constants in the thermal infrared. The resulting spectral dependence of the imaginary index displays several spectral signatures, some of which are also seen for some Titan’s aerosol analogues (tholins) produced in laboratory experiments. We find that Titan’s aerosols are less absorbent than tholins in the thermal infrared. The most prominent emission bands observed in the mid-infrared are due to CH bending vibrations in methyl and methylene groups. It appears that Titan’s aerosols predominantly display vibrations implying carbon and hydrogen atoms and perhaps marginally nitrogen. In the mid infrared, all the aerosol spectral signatures are observed at three additional latitudes (56°S, 5°N and 30°N) and in the 193–274 km altitude range, which implies that Titan’s aerosols exhibit the same chemical composition in all investigated latitude and altitude regions.     

Search for methane and upper limits to ethane and SO2 on Mars

The IRTF/CSHELL observations in February 2006 at L_S = 10° and 63–93°W show ～10 ppb of methane at 45°S to 7°N and ～3 ppb outside this region that covers the deepest canyon Valles Marineris. Observations in December 2009 at L_S = 20° and 0–30°W included spectra of the Moon at a similar airmass as a telluric calibrator. A technique for extraction of the martian methane line from a combination of the Mars and Moon spectra has been developed. The observations reveal no methane with an upper limit of 8 ppb. The results of both sessions agree with the observations by Mumma et al. (Mumma, M.J. et al. [2009]. Science 323, 1041–1045) at the same season in February 2006 and are smaller than those in the PFS and TES maps. Production and removal of the biological methane on Mars do not significantly change the redox state of the atmosphere and the balance of hydrogen. A search for ethane at 2977 cm^?1 results in an upper limit of 0.2 ppb. However, this limit does not help to establish the origin of methane on Mars. Reanalysis of our search for SO₂ using TEXES confirms the recently established upper limit of 0.3 ppb. Along with the lack of hot spots and gas vents with endogenic heat sources in the THEMIS observations, the very low upper limit to SO₂ on Mars does not favor geological methane that is less abundant than SO₂ in the outgassing from the terrestrial planets.     

Mars mesospheric zonal wind around northern spring equinox from infrared heterodyne observations of CO2

We present direct observations of Mars zonal wind velocities around northern spring equinox (L_S = 336°, L_S = 355°, L_S = 42°) during martian year 27 and 29. Data was acquired by means of infrared heterodyne spectroscopy of CO₂ features at 959.3917 cm^?1 (10.4232 μm) and 957.8005 cm^?1 (10.4405 μm) using the Cologne Tuneable Heterodyne Infrared Spectrometer (THIS) at the McMath–Pierce telescope of the National Solar Observatory on Kitt Peak in Arizona and the NASA Infrared Telescope Facility on Mauna Kea, Hawaii between 2005 and 2008. Winds were measured on the dayside of Mars with an unprecedented spatial resolution allowing sampling of up to nine independent latitudes over the martian disk. Retrieved wind velocities depend strongly on latitude and season with values ranging from 180 m/s prograde to ?94 m/s retrograde. A comparison of the observational results to predicted values from the Mars Climate Database yield a reasonable agreement between modeling and observation.     

Observations of water vapour and carbon monoxide in the Martian atmosphere with the SWC of PFS/MEX

In the history of Mars exploration its atmosphere and planetary climatology aroused particular interest. In the study of the minor gases abundance in the Martian atmosphere, water vapour became especially important, both because it is the most variable trace gas, and because it is involved in several processes characterizing the planetary atmosphere. The water vapour photolysis regulates the Martian atmosphere photochemistry, and so it is strictly related to carbon monoxide. The CO study is very important for the so-called “atmosphere stability problem”, solved by the theoretical modelling involving photochemical reactions in which the H₂O and the CO gases are main characters.The Planetary Fourier Spectrometer (PFS) on board the ESA Mars Express (MEX) mission can probe the Mars atmosphere in the infrared spectral range between 200 and 2000 cm^?1 (5–50 μm) with the Long Wavelength Channel (LWC) and between 1700 and 8000 cm^?1 (1.2–5.8 μm) with the Short Wavelength Channel (SWC). Although there are several H₂O and CO absorption bands in the spectral range covered by PFS, we used the 3845 cm^?1 (2.6 μm) and the 4235 cm^?1 (2.36 μm) bands for the analysis of water vapour and carbon monoxide, respectively, because these ranges are less affected by instrumental problems than the other ones. The gaseous concentrations are retrieved by using an algorithm developed for this purpose.The PFS/SW dataset used in this work covers more than two and a half Martian years from Ls=62° of MY 27 (orbit 634) to Ls=203° of MY 29 (orbit 6537). We measured a mean column density of water vapour of about 9.6 pr. μm and a mean mixing ratio of carbon monoxide of about 990 ppm, but with strong seasonal variations at high latitudes. The seasonal water vapour map reproduces very well the known seasonal water cycle. In the northern summer, water vapour and CO show a good anticorrelation most of the time. This behaviour is due to the carbon dioxide and water sublimation from the north polar ice cap, which dilutes non-condensable species including carbon monoxide. An analogous process takes place during the winter polar cap, but in this case the condensation of carbon dioxide and water vapour causes an increase of the concentration of non-condensable species. Finally, the results show the seasonal variation of the carbon monoxide mixing ratio with the surface pressure.     

Assessing the long-term variability of Venus winds at cloud level from VIRTIS–Venus Express

The Venus Express (VEX) mission has been in orbit to Venus for more than 4 years now. The Visible and Infrared Thermal Imaging Spectrometer (VIRTIS) instrument onboard VEX observes Venus in two channels (visible and infrared) obtaining spectra and multi-wavelength images of the planet that can be used to sample the atmosphere at different altitudes. Day-side images in the ultraviolet range (380 nm) are used to study the dynamics of the upper cloud at 66–72 km while night-side images in the near infrared (1.74 μm) map the opacity of the lower cloud deck at 44–48 km. Here we present a long-term analysis of the global atmospheric dynamics at these levels using a large selection of orbits from the VIRTIS-M dataset covering 860 Earth days that extends our previous work (Sánchez-Lavega, A. et al. [2008]. Geophys. Res. Lett. 35, L13204) and allows studying the variability of the global circulation at the two altitude levels. The atmospheric superrotation is evident with equatorial to mid-latitudes westward velocities of 100 and 60 m s^?1 in the upper and lower cloud layers. These zonal velocities are almost constant in latitude from the equator to 50°S. From 50°S to 90°S the zonal winds at both cloud layers decrease steadily to zero at the pole. Individual cloud tracked winds have errors of 3–10 m s^?1 with a mean of 5 m s^?1 and the standard deviations for a given latitude of our zonal and meridional winds are 9 m s^?1. The zonal winds in the upper cloud change with the local time in a way that can be interpreted in terms of a solar tide. The zonal winds in the lower cloud are stable at mid-latitudes to the tropics and present variability at subpolar latitudes apparently linked to the activity of the South polar vortex. While the upper cloud presents a net meridional motion consistent with the upper branch of a Hadley cell with peak velocity v = 10 m s^?1 at 50°S, the lower cloud meridional motions are less organized with some cloud features moving with intense northwards and southwards motions up to v = ±15 m s^?1 but, on average, with almost null global meridional motions at all latitudes. We also examine the long-term behavior of the winds at these two vertical layers by comparing our extended wind tracked data with results from previous missions.     

Thermal infrared spectra of experimentally shocked andesine anorthosite

Andesine-rich (An_36–46) anorthosite rocks experimentally shocked to high pressures (16–57 GPa) exhibit changes in spectral features with increasing pressure in laboratory thermal infrared emission spectra (250–1400 cm^?1). These results are similar to previous studies of shocked bytownite- and albite-rich rocks, albeit with differences in absorption band centers characteristic of mineralogy and composition. Typical spectral absorptions result from Si–O antisymmetric stretch motions of the silica tetrahedral (1000–1250 cm^?1) and weaker absorptions due to Si–O–Si octahedral bending vibrations (350–700 cm^?1). Many of these features persist to higher pressures in the andesine spectra compared to similar features in measurements of shocked bytownite. This is consistent with previous thermal infrared absorption studies of shocked feldspars and likely is related to differences in density, hardness, and Al content. A transparency feature at ～832 cm^?1 observed in powdered andesine spectra also degrades with increasing pressure, intermediate between the ～828 cm^?1 and ～855 cm^?1 transparency features in spectra of powders of shocked bytownite and albitite, respectively. These data can be incorporated into thermal infrared spectral analyses of cratered planetary surfaces (or laboratory spectra of shocked samples) to help constrain the occurrence and degree of shock in plagioclase feldspars.     

Io: Volcanic thermal sources and global heat flow

We have examined thermal emission from 240 active or recently-active volcanic features on Io and quantified the magnitude and distribution of their volcanic heat flow during the Galileo epoch. We use spacecraft data and a geological map of Io to derive an estimate of the maximum possible contribution from small dark areas not detected as thermally active but which nevertheless appear to be sites of recent volcanic activity. We utilize a trend analysis to extrapolate from the smallest detectable volcanic heat sources to these smallest mapped dark areas. Including the additional heat from estimates for “outburst” eruptions and for a multitude of very small (“myriad”) hot spots, we account for ～62 × 10¹² W (～59 ± 7% of Io’s total thermal emission). Loki Patera contributes, on average, 9.6 × 10¹² W (～9.1 ± 1%). All dark paterae contribute 45.3 × 10¹² W (～43 ± 5%). Although dark flow fields cover a much larger area than dark paterae, they contribute only 5.6 × 10¹² W (～5.3 ± 0.6%). Bright paterae contribute ～2.6 × 10¹² W (～2.5 ± 0.3%). Outburst eruption phases and very small hot spots contribute no more than ～4% of Io’s total thermal emission: this is probably a maximum value. About 50% of Io’s volcanic heat flow emanates from only 1.2% of Io’s surface. Of Io’s heat flow, 41 ± 7.0% remains unaccounted for in terms of identified sources. Globally, volcanic heat flow is not uniformly distributed. Power output per unit surface area is slightly biased towards mid-latitudes, although there is a stronger bias toward the northern hemisphere when Loki Patera is included. There is a slight favoring of the northern hemisphere for outbursts where locations were well constrained. Globally, we find peaks in thermal emission at ～315°W and ～105°W (using 30° bins). There is a minimum in thermal emission at around 200°W (almost at the anti-jovian longitude) which is a significant regional difference. These peaks and troughs suggest a shift to the east from predicted global heat flow patterns resulting from tidal heating in an asthenosphere. Global volcanic heat flow is dominated by thermal emission from paterae, especially from Loki Patera (312°W, 12°N). Thermal emission from dark flows maximises between 165°W and 225°W. Finally, it is possible that a multitude of very small hot spots, smaller than the present angular resolution detection limits, and/or cooler, secondary volcanic processes involving sulphurous compounds, may be responsible for at least part of the heat flow that is not associated with known sources. Such activity should be sought out during the next mission to Io.     

Water vapor near the cloud tops of Venus from Venus Express/VIRTIS dayside data

Observations of the dayside of Venus performed by the high spectral resolution channel (–H) of the Visible and Infrared Thermal Imaging Spectrometer (VIRTIS) on board the ESA Venus Express mission have been used to measure the altitude of the cloud tops and the water vapor abundance around this level with a spatial resolution ranging from 100 to 10 km. CO₂ and H₂O bands between 2.48 and 2.60 μm are analyzed to determine the cloud top altitude and water vapor abundance near this level. At low latitudes (±40°) mean water vapor abundance is equal to 3 ± 1 ppm and the corresponding cloud top altitude at 2.5 μm is equal to 69.5 ± 2 km. Poleward from middle latitudes the cloud top altitude gradually decreases down to 64 km, while the average H₂O abundance reaches its maximum of 5 ppm at 80° of latitude with a large scatter from 1 to 15 ppm. The calculated mass percentage of the sulfuric acid solution in cloud droplets of mode 2 (～1 μm) particles is in the range 75–83%, being in even more narrow interval of 80–83% in low latitudes. No systematic correlation of the dark UV markings with the cloud top altitude or water vapor has been observed.     

The planetary fourier spectrometer (PFS) onboard the European Venus Express mission

The planetary fourier spectrometer (PFS) for the Venus Express mission is an infrared spectrometer optimized for atmospheric studies. This instrument has a short wavelength (SW) channel that covers the spectral range from 1700 to 11400 cm⁻¹ (0.9–5.5 μm) and a long wavelength (LW) channel that covers 250–1700 cm⁻¹ (5.5–45 μm). Both channels have a uniform spectral resolution of 1.3 cm⁻¹. The instrument field of view FOV is about 1.6 ° (FWHM) for the short wavelength channel and 2.8 ° for the LW channel which corresponds to a spatial resolution of 7 and 12 km when Venus is observed from an altitude of 250 km. PFS can provide unique data necessary to improve our knowledge not only of the atmospheric properties but also surface properties (temperature) and the surface-atmosphere interaction (volcanic activity).PFS works primarily around the pericentre of the orbit, only occasionally observing Venus from larger distances. Each measurements takes 4.5 s, with a repetition time of 11.5 s. By working roughly 1.5 h around pericentre, a total of 460 measurements per orbit will be acquired plus 60 for calibrations. PFS is able to take measurements at all local times, enabling the retrieval of atmospheric vertical temperature profiles on both the day and the night side.The PFS measures a host of atmospheric and surface phenomena on Venus. These include the:(1) thermal surface flux at several wavelengths near 1 μm, with concurrent constraints on surface temperature and emissivity (indicative of composition); (2) the abundances of several highly-diagnostic trace molecular species; (3) atmospheric temperatures from 55 to 100 km altitude; (4) cloud opacities and cloud-tracked winds in the lower-level cloud layers near 50-km altitudes; (5) cloud top pressures of the uppermost haze/cloud region near 70–80 km altitude; and (6) oxygen airglow near the 100 km level. All of these will be observed repeatedly during the 500-day nominal mission of Venus Express to yield an increased understanding of meteorological, dynamical, photochemical, and thermo-chemical processes in the Venus atmosphere. Additionally, PFS will search for and characterize current volcanic activity through spatial and temporal anomalies in both the surface thermal flux and the abundances of volcanic trace species in the lower atmosphere.Measurement of the 15 μm CO₂ band is very important. Its profile gives, by means of a complex temperature profile retrieval technique, the vertical pressure-temperature relation, basis of the global atmospheric study.PFS is made of four modules called O, E, P and S being, respectively, the interferometer and proximity electronics, the digital control unit, the power supply and the pointing device.