Shock metamorphism investigations of quartz grains in clasts from impact breccia of the Eyreville B drill core,Chesapeake Bay impact structure,USA

Abstract– The Chesapeake Bay impact structure, approximately 85 km in diameter, has been drilled in 2005–2006 at Eyreville (Virginia, USA), to a total depth of 1766 m. In the drill cores, the abundance of shock metamorphosed material is very variable with depth. Shocked mineral and lithic clasts, as well as melt particles, are most abundant in suevitic impact breccia section (1397–1451 m depth). Shocked quartz (i.e., quartz grains with planar fractures and/or planar deformation features) and melt particles, although rare, are also dispersed in the Exmore Formation unit (444–867 m depth). Other lithologies in the Eyreville drill cores show no clear evidence of shock metamorphism. Here, we report on the investigations of 40 samples from the impact breccia section. A total of more than 27,000 quartz grains were examined in about 200 clasts. The abundance of highly shocked clasts tends to decrease with increasing depth. Crystalline clasts derived from the crystalline basement are commonly only slightly shocked (contain generally <10 rel% of shocked quartz grains). The clasts of metamorphosed sediments show a low proportion of shocked quartz grains (mostly <10 rel%). Sedimentary clasts show a wide range of proportions of shocked quartz grains, with several of them being highly shocked clasts (most values between 0 and 40 rel%). Conglomerates show the highest proportion of shocked quartz grains of all types of clasts (up to 83 rel%). Polycrystalline quartz clasts are also commonly highly shocked (contain mostly between 10 and 40 rel% of shocked quartz grains). These hard nonporous clasts are possibly more liable to show evidence of shock. The investigations suggest that the intensity of shock metamorphism is the result of several parameters, such as original position in the target (both horizontal and vertical) and the properties of each lithology (e.g., grain size, porosity, and amount of matrix). According to the universal‐stage investigations, the dominant orientations of planar deformation features in quartz are , , and also .     

Shocked quartz grains in the polymict breccia of the Granby structure,Sweden–‐Verification of an impact

Abstract— The Middle Ordovician Granby structure in Sweden is generally considered the result of an asteroidal or cometary collision with Earth, although no hard evidence, i.e., shock metamorphic features or traces of the impactor, have been presented to date. In this study, drill core samples of a sedimentary breccia from the Granby structure have been investigated for microscopic shock metamorphic evidence in an attempt to verify the impact genesis of the structure. The finding of multiple sets of decorated planar deformation features (PDFs) in quartz grains in these samples provides unambiguous evidence that the structure is impact derived. Furthermore, the orientation of the PDFs, e.g., ω {101 }, π {101 } and r, z {101 }, is characteristic for impact deformation. The fact that a majority of the PDFs are decorated implies a water‐bearing target. The shocked quartz grains can be divided into two groups; rounded grains found in the breccia matrix likely originated from mature sandstone, and angular grains in fragments from crystalline target rocks. The absence of melt particles provides an estimated maximum shock pressure for the sedimentary derived quartz of 15–20 GPa and the frequency distribution of PDF orientations in the bedrock quartz implies pressures of the order of 10 GPa.     

Vapor‐condensed phase processes in the early solar system

Abstract– Equilibrium thermodynamic calculations of the sequence of condensation of phases from a cooling gas of solar composition at total pressures thought to have prevailed in the inner part of the solar nebula successfully predict the primary mineral assemblages of refractory inclusions in CM2 and CV3 chondrites. Many refractory inclusions in CM2 chondrites contain a relatively SiO₂‐poor assemblage (spinel, hibonite, grossite, perovskite, corundum) that represents a high‐temperature stage of condensation, and some may be pristine condensates that escaped later melting. Compact Type A and Type B refractory inclusions, consisting of spinel, melilite, perovskite, Ca‐rich clinopyroxene ± anorthite, in CV3 chondrites are more SiO₂‐rich and equilibrated with the solar nebular gas at a slightly lower temperature. Textures of many of these objects indicate that they underwent melting after condensation, crystallizing into the same phase assemblage as their precursors. The Ti³⁺/Ti⁴⁺ ratio of their pyroxene indicates that this process occurred in a gas whose oxygen fugacity () was approximately 8.5 log units below that of the iron‐wüstite buffer, making them the only objects in chondrites known to have formed in a system whose composition was close to that of the sun. Relative to CI chondrites, these inclusions are uniformly enriched in a group of elements (e.g., Ca, REE, Zr, Ta, Ir) that are chemically diverse except for their high condensation temperatures in a system of solar composition. The enrichment factor, 17.5, can be interpreted to mean that these objects represent either the first 5.7 wt% of the condensable matter to condense during nebular cooling or the residue after vaporization of 94.3% of a CI chondrite precursor. The Mg and Si isotopic compositions of Types A and B inclusions are mass‐fractionated by up to 10 and 4 ‰/amu, respectively. When interpreted in terms of Rayleigh fractionation during evaporation of Mg and Si from the inclusions while they were molten, the isotopic compositions imply that up to 60% of the Mg and up to 25% of the Si were evaporated, and that approximately 80% of the enrichment in refractory (CaO+Al₂O₃) relative to more volatile (MgO+SiO₂) in the average inclusion is due to initial condensation and approximately 20% due to subsequent evaporation. The mineralogical composition, including the Ti³⁺/Ti⁴⁺ ratio of the pyroxene, in Inti, a particle sampled from Comet Wild 2 by the Stardust spacecraft, is nearly identical to that of a Type B inclusion, indicating that comets contain not only the lowest‐temperature condensates in the form of ices but the highest‐temperature condensates as well. The FeO/(FeO+MgO) ratios of olivine and pyroxene in the matrix and chondrules of carbonaceous and ordinary chondrites are too high to be made in a system of solar composition, requiring s only 1 or 2 log units below iron‐wüstite, more than 10⁵ times higher than that of a solar gas. Various ways have been devised to generate cosmic gases sufficiently oxidizing to stabilize significant FeO in olivine at temperatures above those where Fe‐Mg interdiffusion in olivine ceases. One is by vertical settling of dust toward the nebular midplane, enriching a region in dust relative to gas. Because dust is enriched in oxygen compared to carbon and hydrogen relative to solar composition, a higher results from total vaporization of the region, but the factor by which theoretical models have so far enriched the dust is 10 times too low. Another is by transporting icy bodies from the outer part of the nebula into the hot, inner part where vaporization of water ice occurs. Not only does this method fail to make the needed by a factor of 30–1000 but it also ignores simultaneous evaporation of carbon‐bearing ices that would make the even lower.     

Red Wing Creek structure,North Dakota: Petrographical and geochemical studies,and confirmation of impact origin

Abstract The 9 km diameter Red Wing Creek structure, North Dakota, is located within the oil-rich Williston Basin at 47°36′N and 103°33′W. Earlier geophysical studies indicated that this subsurface structure has a central uplift, surrounded by an annular crater moat, and a raised rim. Breccias were encountered during drilling between ～2000 and 2800 m depth in the central uplift area, and the presence of shatter cone fragments in drill core samples was suggested to indicate an impact origin of the Red Wing Creek structure. We studied the petrographic and geochemical characteristics of samples of well cuttings from two boreholes at the center of the structure: the True Oil 22–27 Burlington Northern and True Oil 11–27 Burlington Northern wells. We found planar deformation features (PDFs) in quartz with up to three sets of different crystallographic orientations in sandstone- and siltstone-dominated samples from the True Oil 11–27 borehole. U-stage measurements of the crystallographic orientations of the PDFs showed the occurrence of the shock-characteristic (0001), and orientations, with a dominance of (0001) and orientations. The relative frequencies of the orientations indicate a shock pressure of at least 12–20 GPa. These results provide unambiguous evidence for shock metamorphism at Red Wing Creek and confirm that the structure was formed by impact.     

Saqqar: A 34 km diameter impact structure in Saudi Arabia

Here we present the first proof of an impact origin for the Saqqar circular structure in northwestern Saudi Arabia (Neville et al. 2014 ), with an apparent diameter of 34 km, centered at 29°35′N, 38°42′E. The structure is formed in Cambrian–Devonian siliciclastics and is unconformably overlain by undeformed Cretaceous and Paleogene sediments. The age of impact is not well constrained and lies somewhere between 410 and 70 Ma. The subsurface structure is constrained by 2‐D reflection seismic profiles and six drilled wells. First‐order structural features are a central uplift that rises approximately 2 km above regional datums, surrounded by a ring syncline. The crater rim is defined by circumferential normal faults. The central uplift and ring syncline correspond to a Bouguer gravity high and an annular ring‐like low, respectively. The wells were drilled within the central uplift, the deepest among them exceed 2 km depth. Sandstone core samples from these wells show abundant indicators of a shock metamorphic overprint. Planar deformation features (PDFs) were measured with orientations along (0001), {103}, and less frequently along {101} and {104}. Planar fractures (PFs) predominantly occur along (0001) and {101}, and are locally associated with feather features (FFs). In addition, some shocked feldspar grains and strongly deformed mica flakes were found. The recorded shock pressure ranges between 5 and 15 GPa. The preserved level of shock and the absence of an allochthonous crater fill suggest that Saqqar was eroded by 1–2 km between the Devonian and Maastrichtian. The documentation of unequivocal shock features proves the formation of the Saqqar structure by a hypervelocity impact event.     

WIP: A Web‐based program for indexing planar features in quartz grains and its usage

Planar deformation features (PDFs) in quartz are the most important diagnostic features that allow the unambiguous identification of impact structures on Earth. In order to confirm that these features (that are characterized by planar character and form along specific crystallographic planes) are indeed PDFs, they need to be properly investigated and indexed. Following universal‐stage measurements, the process of indexing is usually performed manually, using a Wulff stereonet and following a strict procedure, which is time consuming and error prone. In this article, we present WIP, a new Web‐based program for indexing planar deformation features in quartz. The correctness of our program is shown by its application to measurements that had previously been indexed manually. The observed minor differences, especially in the absolute frequency percentage of PDFs, are negligible and not significant enough to influence the estimation of shock pressure that could be calculated from the indexed results. Usability of this program is shown using the spatial relationships between a statistically significant number of 278 quartz grains with 409 sets of PDFs analyzed within the area (~35 mm²) of a single thin section of a meta‐greywacke from the Bosumtwi impact structure. Our program is not only more accurate and faster than the manual (graphical) method but also removes the human error from the plotting process and allows control of several parameters, such as the value of estimated measurement error used in the indexing calculation or method of aggregated error handling. The program also provides information about the angles between the planes of the measured PDF sets present in a grain, which allows determination of the angles between (for example) indexed {} and {} sets.     

Planar deformation features in quartz grains from the resurge deposit of the Lockne structure,Sweden

Abstract— Microscopic planar deformation features (PDFs) in quartz grains are diagnostic of shock meta-morphism during hypervelocity impact cratering. Measurements of the poles of sets of PDFs and the optic axis of 25 quartz grains were carried out for a sample of the Loftarsten deposit from the Lockne area, Sweden. The most abundant PDFs observed in the sample from the Lockne area correspond to those found at known impact craters (i.e., ω (1013} and π (1012). This study confirms the previous suggestion that the Lockne structure is an impact crater. The Loftarsten is, therefore, interpreted as the final stage of resurge deposition after a marine impact at Lockne in the Middle Ordovician.     

Progressive deformation of feldspar recording low‐barometry impact processes,Tenoumer impact structure,Mauritania

The Tenoumer impact structure is a small, well‐preserved crater within Archean to Paleoproterozoic amphibolite, gneiss, and granite of the Reguibat Shield, north‐central Mauritania. The structure is surrounded by a thin ejecta blanket of crystalline blocks (granitic gneiss, granite, and amphibolite) and impact‐melt rocks. Evidence of shock metamorphism of quartz, most notably planar deformation features (PDFs), occurs exclusively in granitic clasts entrained within small bodies of polymict, glass‐rich breccia. Impact‐related deformation features in oligoclase and microcline grains, on the other hand, occur both within clasts in melt‐breccia deposits, where they co‐occur with quartz PDFs, and also within melt‐free crystalline ejecta, in the absence of co‐occurring quartz PDFs. Feldspar deformation features include multiple orientations of PDFs, enhanced optical relief of grain components, selective disordering of alternate twins, inclined lamellae within alternate twins, and combinations of these individual textures. The distribution of shock features in quartz and feldspar suggests that deformation textures within feldspar can record a wide range of average pressures, starting below that required for shock deformation of quartz. We suggest that experimental analysis of feldspar behavior, combined with detailed mapping of shock metamorphism of feldspar in natural systems, may provide critical data to constrain energy dissipation within impact regimes that experienced low average shock pressures.     

Shocked quartz grains in the early Cambrian Vakkejokk Breccia,Sweden—Evidence of a marine impact

Here we present a study of the abundance and orientation of planar deformation features (PDFs) in the Vakkejokk Breccia, a proposed lower Cambrian impact ejecta layer in the North‐Swedish Caledonides. The presence of PDFs is widely accepted as evidence for shock metamorphism associated with cosmic impact events and their presence confirms that the Vakkejokk Breccia is indeed the result of an impact. The breccia has previously been divided into four lithological subunits (from bottom to top), viz. lower polymict breccia (LPB), graded polymict breccia (GPB), top sandstone (TS), and top conglomerate (TC). Here we show that the LPB contains no shock metamorphic features, indicating that the material derives from just outside of the crater and represents low‐shock semi‐autochthonous bombarded strata. In the overlying, more fine‐grained GPB and TS, quartz grains with PDFs are relatively abundant (2–5% of the grain population), and with higher shock levels in the upper parts, suggesting that they have formed by reworking of more distal ejecta by resurge of water toward the crater in a marine setting. The absence of shocked quartz grains in the TC indicates that this unit represents later slumps associated with weathering and erosion of the protruding crater rim. Sparse shocked quartz grains (<0.2%) were also found in sandstone beds occurring at the same stratigraphic level as the Vakkejokk Breccia 15–20 km from the inferred crater site. It is currently unresolved whether the sandstone at these distal sites is related to the impact or just contains rare reworked quartz grains with PDFs.     

Shock metamorphism of quartz at the submarine Mjølnir impact crater,Barents Sea

Abstract— Shock metamorphosed quartz grains have been discovered in a drill core from the central peak of the Late Jurassic, marine Mjølnir structure; this finding further corroborates the impact origin of Mjølnir. The intersected strata represent the Upper Jurassic Hekkingen Formation and underlying Jurassic and Upper Triassic formations. The appearance, orientation, and origin of shock features in quartz grains and their stratigraphic distribution within the core units have been studied by optical and transmission electron microscopy. The quartz grains contain planar fractures (PFs), planar deformation features (PDFs), and mechanical Brazil twins. The formation of PFs is the predominant shock effect and is attributed to the large impedance differences between the water‐rich pores and constituent minerals in target sediments. This situation may have strengthened tensional/extensional and shear movements during shock compression and decompression. The combination of various shock effects indicates possible shock pressures between 5 and at least 20 GPa for three core units with a total thickness of 86 m (from 74.00 m to 171.09 m core depth). Crater‐fill material from the lower part of the core typically shows the least pressures, whereas the uppermost part of the allochthonous crater deposits displays the highest pressures. The orientations of PFs in studied quartz grains seem to become more diverse as the pressure rises from predominantly (0001) PFs to a combination of (0001), , and orientations. However, the lack of experimental data on porous sedimentary rocks does not allow us to further constrain the shock conditions on the basis of PF orientations.     

The Vakkejokk Breccia: An Early Cambrian proximal impact ejecta layer in the North‐Swedish Caledonides

The ≤27 m thick Vakkejokk Breccia is intercalated in autochthon Lower Cambrian along the Caledonian front north of Lake Torneträsk, Lapland, Sweden. The spectacular breccia is here interpreted as a proximal ejecta layer associated with an impact crater, probably ~2–3 km in size, located below Caledonian overthrusts immediately north of the main breccia section. The impact would have taken place in a shallow‐marine environment ~520 Ma ago. The breccia comprises i) a strongly disturbed lower polymict subunit with occasional, in themselves brecciated, crystalline mega‐clasts locally exceeding 50 m surrounded by contorted sediments; ii) a middle, commonly normally graded, crystalline‐rich, polymict subunit, in turn locally overlain by iii) a thin fine‐grained quartz sandstone, <30 cm thick. The upper sandstone is sporadically either overlain, or replaced, by a conglomerate. In progressively more distal parts of the ejecta layer, the lower subunit is better described as only slightly disturbed strata. The lower subunit is suggested to have formed by ejecta bombardment of the strata surrounding the impact crater, even causing some net outwards mobilization of the sediments. The middle subunit and the uppermost quartz sandstone are considered resurge deposits. The top conglomerate may be caused by subsequent wave reworking and slumping of material from the elevated rim. Quartz grains showing planar deformation features are present in the graded polymict subunit and the upper sandstone, that is, the inferred resurge deposits.     

Crystallization temperature determination of Itokawa particles by plagioclase thermometry with X‐ray diffraction data obtained by a high‐resolution synchrotron Gandolfi camera

The crystallization temperatures of Itokawa surface particles recovered by the space probe Hayabusa were estimated by a plagioclase geothermometer using sodic plagioclase triclinicity. The Δ131‐index required for the thermometer, which is the difference in X‐ray diffraction peak positions between the 131 and 11 reflections of plagioclase, was obtained by a high‐resolution synchrotron Gandolfi camera developed for the third generation synchrotron radiation beamline, BL15XU at SPring‐8. Crystallization temperatures were successfully determined from the Δ131‐indices for four particles. The observed plagioclase crystallization temperatures were in a range from 655 to 660 °C. The temperatures indicate crystallization temperatures of plagioclases in the process of prograde metamorphism before the peak metamorphic stage.     

Resurge deposits associated with the shallow marine early Cambrian Vakkejokk impact,north Sweden

The lower Cambrian Vakkejokk Breccia is a proximal ejecta layer from a shallow marine impact. It is exposed for ~7 km along a steep mountainside in Lapland, northernmost Sweden. In its central parts, the layer is up to ~27 m thick. Here the breccia shows a vertical differentiation into (1) a lower subunit consisting of strongly deformed target sediments mixed with up to decameter size, mainly crystalline basement clasts (i.e., lower polymict breccia [LPB]); (2) a middle subunit consisting of a polymict, blocky to gravelly breccia, commonly graded (i.e., graded polymict breccia [GPB]), that, in turn, is sporadically overlain by (3) a few dm thick, sandy bed (i.e., top sandstone [TS]). Previous work interpreted the graded beds as deposited by resurging water during early crater modification. We made three short (<1.35 m) core drillings through the graded beds. The line‐logging technique previously used on cores from other marine‐target craters was complemented by logging of equal‐sized cells in photos made along the cores. Granulometry and clast lithology determinations provide further evidence for the top beds of the breccia being resurge deposits. However, the magnitude of this resurge can only be assessed by future deep core drilling of the infill of the crater hidden below the mountain.     

A new calibration to determine the closure temperatures of Fe‐Mg ordering in augite from nakhlites

Recently it has been shown that the relatively low closure temperature (T_c) of 500 (100)°C calculated for augite from Miller Range nakhlite (MIL 03346,13) using the available geothermometers would correspond to a slow cooling rate inconsistent with the petrologic evidence for an origin from a fast‐cooled lava flow. Moreover, previous annealing experiments combined with HR‐SC‐XRD on an augite crystal from MIL 03346 clearly showed that at 600 °C, the Fe²⁺‐Mg degree of order remained unchanged, thus suggesting that the actual T_c is close to this temperature. In order to clarify this discrepancy, we undertook an ex situ annealing experimental study at 700, 800, and 900 °C, until the equilibrium in the intracrystalline Fe²⁺‐Mg exchange is reached, using an augite crystal from Miller Range nakhlite (MIL 03346,13) with a composition of about En₃₆Fs₂₄Wo₄₀. These data allowed us to calculate the following new geothermometer calibration for Martian nakhlites: where The application of this new equation to other Martian nakhlites (NWA 988 and Nakhla) suggests that for augite with composition close to that of MIL 03346, the T_c is up to 170 °C higher with respect to the one calculated using the previous available geothermometer equation, thus suggesting a significantly faster cooling in agreement with petrologic evidence.     

Shocked quartz in polymict impact breccia from the Upper Cretaceous Yallalie impact structure in Western Australia

Yallalie is a ~12 km diameter circular structure located ~200 km north of Perth, Australia. Previous studies have proposed that the buried structure is a complex impact crater based on geophysical data. Allochthonous breccia exposed near the structure has previously been interpreted as proximal impact ejecta; however, no diagnostic indicators of shock metamorphism have been found. Here we report multiple (27) shocked quartz grains containing planar fractures (PFs) and planar deformation features (PDFs) in the breccia. The PFs occur in up to five sets per grain, while the PDFs occur in up to four sets per grain. Universal stage measurements of all 27 shocked quartz grains confirms that the planar microstructures occur in known crystallographic orientations in quartz corresponding to shock compression from 5 to 20 GPa. Proximity to the buried structure (~4 km) and occurrence of shocked quartz indicates that the breccia represents either primary or reworked ejecta. Ejecta distribution simulated using iSALE hydrocode predicts the same distribution of shock levels at the site as those found in the breccia, which supports a primary ejecta interpretation, although local reworking cannot be excluded. The Yallalie impact event is stratigraphically constrained to have occurred in the interval from 89.8 to 83.6 Ma based on the occurrence of Coniacian clasts in the breccia and undisturbed overlying Santonian to Campanian sedimentary rocks. Yallalie is thus the first confirmed Upper Cretaceous impact structure in Australia.     

The Erbisberg drilling 2011: Implications for the structure and postimpact evolution of the inner ring of the Ries impact crater

The 26 km diameter Nördlinger Ries is a complex impact structure with a ring structure that resembles a peak ring. A first research drilling through this “inner crystalline ring” of the Ries was performed at the Erbisberg hill (SW Ries) to better understand the internal structure and lithology of this feature, and possibly reveal impact‐induced hydrothermal alteration. The drill core intersected the slope of a 22 m thick postimpact travertine mound, before entering 42 m of blocks and breccias of crystalline rocks excavated from the Variscan basement at >500 m depth. Weakly shocked gneiss blocks that show that shock pressure did not exceed 5 GPa occur above polymict lithic breccias of shock stage Ia (10–20 GPa), with planar fractures and planar deformation features (PDFs) in quartz. Only a narrow zone at 49.20–50.00 m core depth exhibits strong mosaicism in feldspar and {102} PDFs in quartz, which are indicative of shock stage Ib (20–35 GPa). Finally, 2 m of brecciated Keuper sediments at the base of the section point to an inverse layering of strata. While reverse grading of clast sizes in lithic breccias and gneiss blocks is consistent with lateral transport, the absence of diaplectic glass and melt products argues against dynamic overthrusting of material from a collapsing central peak, as seen in the much larger Chicxulub structure. Indeed, weakly shocked gneiss blocks are rather of local provenance (i.e., the transient crater wall), whereas moderately shocked polymict lithic breccias with geochemical composition and ⁸⁷Sr/⁸⁶Sr signature similar to Ries suevite were derived from a position closer to the impact center. Thus, the inner ring of the Ries is formed by moderately shocked polymict lithic breccias likely injected into the transient crater wall during the excavation stage and weakly shocked gneiss blocks of the collapsing transient crater wall that were emplaced during the modification stage. While the presence of an overturned flap is not evident from the Erbisberg drilling, a survey of all drillings at or near the inner ring point to inverted strata throughout its outer limb. Whether the central ring of the Ries represents remains of a collapsed central peak remains to be shown. Postimpact hydrothermal alteration along the Erbisberg section comprises chloritization, sulfide veinlets, and strong carbonatization. In addition, a narrow zone in the lower parts of the polymict lithic breccia sequence shows a positive Eu anomaly in its carbonate phase. The surface expression of this hydrothermal activity, i.e., the travertine mound, comprises subaerial as well as subaquatic growth phases. Intercalated lake sediments equivalent to the early parts of the evolution of the central crater basin succession confirm a persistent impact‐generated hydrothermal activity, although for less time than previously suggested.     

The Allochthonous Polymict Breccia Layer of the Haughton Impact Crater,Devon Island,Canada

Abstract— The central allochthonous polymict breccia of the Haughton impact structure is up to about 90 m thick and as much as 7.3 km in radial extent. It has been analyzed with respect to modal composition, grain-size characteristics, and degree of shock metamorphism for the grain-size ranges 10–～ 50, 1–10, 0.03–1, and <0.03 mm. The mineralogy of the breccia matrix is dominated by dolomite and calcite, with minor amounts of quartz, other silicate minerals, and rare melt particles. The following lithic clasts have been identified in the 1–10 mm size fraction (averages of vol.% given in parentheses): dolomitic rocks (51), limestones (29), crystalline rocks (10), sandstones and siltstones (3.7), chert (0.7), melt particles (1.9). The mineral clasts (1–0.03 mm) comprise (with decreasing frequency) dolomite, quartz, calcite, feldspar, biotite, amphibole, garnet, opaques, rounded quartz derived from sandstones and accessory minerals. Lithic and mineral clasts display various degrees of shock. Fragments of crystalline rocks are shocked in the 0–60 GPa range; whole rock melts from the crystalline basement are lacking and unshocked rocks are very rare. In contrast, shock-melted sandstones, shales, and chert were found in most samples. Large clasts of these melt rocks are highly concentrated near the center of the crater. Otherwise, no distinct change of the modal composition with radial range has been observed except that the frequency of limestone clasts increases slightly with radial range. The breccia near the center is more fine-grained than that beyond about 1 km radius and the sorting parameter increases somewhat with radial range. Except for the high concentration of shock-melted sedimentary rocks and highly shocked crystalline rocks near the center of the crater, the distribution of shock stages within the lithic clast population is quite uniform throughout the breccia formation. We conclude that the breccia constituents are derived from the lower part of the target stratigraphy (deeper than about 800 m) and that the total depth of excavation at Haughton is in the order of 2000 m. The mixing of sedimentary rocks of the Eleanor River Formation, Lower Ordovician, and Cambrian (～850 m thickness) with crystalline basement rocks is quite thorough and homogeneous throughout the breccia lens, at least for the analyzed part. This may require an air-borne mode of emplacement for the upper section of the breccia in analogy to the fall-back suevite in the Ries crater. A calculation of the excavation (Z-model) and of the shock pressure attenuation based on reasonable estimates of the energy and crater geometry of the Haughton impact confirms the observed maximum depth of excavation of about 2 km. Shock-melted crystalline basement rocks, if present at all, must be confined to the very center of the structure below the excavation cavity.     

Hydrogen and major element concentrations on 433 Eros: Evidence for an L‐ or LL‐chondrite‐like surface composition

A reanalysis of NEAR X‐ray/gamma‐ray spectrometer (XGRS) data provides robust evidence that the elemental composition of the near‐Earth asteroid 433 Eros is consistent with the L and LL ordinary chondrites. These results facilitated the use of the gamma‐ray measurements to produce the first in situ measurement of hydrogen concentrations on an asteroid. The measured value,  ppm, is consistent with hydrogen concentrations measured in L and LL chondrite meteorite falls. Gamma‐ray derived abundances of hydrogen and potassium show no evidence for depletion of volatiles relative to ordinary chondrites, suggesting that the sulfur depletion observed in X‐ray data is a surficial effect, consistent with a space‐weathering origin. The newfound agreement between the X‐ray, gamma‐ray, and spectral data suggests that the NEAR landing site, a ponded regolith deposit, has an elemental composition that is indistinguishable from the mean surface. This observation argues against a pond formation process that segregates metals from silicates, and instead suggests that the differences observed in reflectance spectra between the ponds and bulk Eros are due to grain size differences resulting from granular sorting of ponded material.     

Shock metamorphic features in quartz grains from the Saarijärvi and Söderfjärden impact structures,Finland

Shock metamorphic features at the Saarijärvi (D > 2 km) and Söderfjärden (D = 6.5 km) structures in Finland have so far only been studied tentatively, although both are considered to be proven impact structures. This work presents the first detailed universal stage study of planar deformation features (PDFs), feather feature lamellae (FFL), and planar fractures (PFs) in quartz grains from a polymict impact breccia dike from Söderfjärden, and from sedimentary crater‐fill rocks from Saarijärvi. Planar microstructures, particularly PDFs, are very rare and poorly developed or preserved in Saarijärvi, whereas in Söderfjärden they are much more common and well defined. Miller–Bravais indices of the planar microstructures in both Saarijärvi and Söderfjärden are indicative of relatively low‐shock pressure but high shear conditions, only compatible with an impact origin for these structures. Although a Proterozoic age for Saarijärvi cannot be ruled out, the observations of shock features throughout the sedimentary crater‐fill sequence and a brecciated sedimentary dike below the crater floor are more consistent with a Lower Cambrian (or younger) impact age.     

Oral Histories in Meteoritics and Planetary Science––XVI: Grenville Turner

Abstract– In this interview, Grenville Turner ( Fig. 1 ) recounts how he became interested in meteorites during postdoctoral research with John Reynolds at the University of California, Berkeley, after completing a DPhil with Ken Mayne at the University of Oxford. At Berkeley, he worked on xenon isotopes with fellow students Bob Pepin and Craig Merrihue, but Reynolds’ insistence that they analyze all the inert gases in their samples meant that they also made important contributions to Ne isotope studies and potassium‐argon dating leading to the Ar‐Ar technique. In 1964, Grenville obtained a teaching position at the University of Sheffield where he developed his own laboratory for inert gas isotope measurements. After the return of samples from the Moon by the Apollo program, he became involved in determining the chronology of volcanism and major impacts on the Moon. In 1988, Grenville and his team moved to the University of Manchester as part of a national reorganization of earth science departments. During the post Apollo years, Grenville’s interest turned to the development of new instrumentation (resonance ionization mass spectrometry and the ion microprobe), and to problems in terrestrial isotope geochemistry, particularly the source of inert gases in fluid inclusions. He received the Leonard Medal of the Meteoritical Society in 1999, and he has also received awards from the Royal Society, the European Association of Geochemistry, and the Royal Astronomical Society.

Figure 1 Open in figure viewer PowerPoint Grenville Turner.