大洋下地壳堆晶岩组成及其对蛇绿岩研究的启示

大洋下地壳是大洋岩石圈和蛇绿岩的重要组成部分,在洋中脊及俯冲带演化以及蛇绿岩成因研究中具有重要的意义。本文总结了不同构造环境形成的大洋下地壳堆晶岩的岩石组合、地球化学组成,以建立起适用于蛇绿岩中堆晶岩的构造环境判别标志。洋中脊和俯冲相关环境堆晶岩在Pearce图解上均区别于对应的熔岩成分,表明蛇绿岩中的堆晶岩无法应用Pearce图解进行构造环境判别。不同构造环境产出的堆晶岩在岩石组合、结晶顺序和地球化学上存在明显差异：(1)绝大多数洋中脊堆晶岩和弧后盆地堆晶岩较为类似,反映其来源于洋中脊玄武岩型母岩浆低压、贫水体系的分离结晶;(2)中大西洋脊DSDP 334的洋中脊堆晶岩较为类似弧前堆晶岩,是海水蚀变难熔橄榄岩重熔或混染的产物;(3)弧前堆晶岩的岩石学、地球化学特征与亏损的富水、富硅的玻安质熔体的低压分离结晶过程相吻合;(4)洋岛堆晶岩的特征与相对贫水、成分富集的洋岛玄武岩高压分离结晶的特征相吻合。最后,本文总结了应用堆晶岩进行蛇绿岩构造环境判别的一系列岩石学、地球化学指标,并结合日喀则蛇绿岩中的堆晶岩体和辉长岩脉的实例论述堆晶岩在蛇绿岩研究中的应用。     

西藏班公湖—怒江缝合带中段蓬湖蛇绿岩中的洋脊型二辉橄榄岩

蓬湖蛇绿岩产于西藏藏北湖区的蓬湖西侧,属班公湖-怒江缝合带中段白拉拉弄-依拉山亚带。该蛇绿岩主要由地幔橄榄岩、堆晶岩和辉绿岩等组成。其中地幔橄榄岩由方辉橄榄岩和二辉橄榄岩组成。蓬湖二辉橄榄岩的橄榄石Fo值介于88.85～90.33之间、斜方辉石的Al2O3含量范围在4.26%～6.60%。与原始地幔相比,蓬湖二辉橄榄岩岩石有较高的MgO含量和较低的Al2O3、CaO和TiO2等易熔组分含量;稀土元素总量介于1.11×10-6～1.53×10-6之间,明显低于原始地幔值,配分模式为轻稀土轻微亏损。在原始地幔微量元素蛛网图中,蓬湖二辉橄榄岩显示Rb、Zr亏损,U、Ta、Sr强烈富集特征。蓬湖二辉橄榄岩的铂族元素总量介于22.9×10-9～27×10-9之间,PGEs球粒陨石标准化图解显示其为接近原始地幔的"平坦型"。以上特征与深海橄榄岩相似,指示它们可能形成于大洋中脊环境。定量模拟估算表明,蓬湖二辉橄榄岩可能来源于地幔中尖晶石相二辉橄榄岩源区,系经历了约5%～10%的部分熔融残余。蓬湖堆晶岩矿物结晶顺序为橄榄石-单斜辉石-斜长石,其中异剥橄榄岩中的单斜辉石Mg#值介于86.92～89.93之间、橄榄石Fo平均值为84.45,明显不同于MOR型蛇绿岩堆晶岩。蓬湖堆晶岩的矿物组成、岩浆结晶顺序和矿物成分均与俯冲带上SSZ型蛇绿岩形成的堆晶岩类似。以上结果表明,蓬湖二辉橄榄岩形成于大洋脊环境,为尖晶石二辉橄榄岩源区经历了不超过10%部分熔融的残余,后期由于洋内俯冲作用经历了岩石-熔体反应,形成了SSZ型堆晶岩和含较高Cr#值尖晶石的方辉橄榄岩。     

藏北果芒错蛇绿岩中堆晶岩地球化学特征及其地质意义

西藏果芒错蛇绿岩位于狮泉河—纳木错—波密蛇绿混杂岩带的中段,主要由地幔橄榄岩、铁镁质-超铁镁质堆晶杂岩、枕状熔岩、基性岩墙和硅质岩等单元组成。对果芒错蛇绿混杂岩中超铁镁质堆晶岩、基性岩岩石学及地球化学特征的研究表明,果芒错超铁镁质堆晶杂岩具很好的堆晶韵律,岩石化学特征反映了随着Mg O含量的降低其从底到顶的连续分离结晶过程;堆晶杂岩稀土元素总体上具LREE富集、Eu轻微异常特点,微量元素具有富集高场强元素、亏损大离子亲石元素的特征,且相容元素显示良好的变化规律,指示岩石来自受富集组分混染的地幔源区,并在后期经历了俯冲流体作用。果芒错基性岩具有富集型洋中脊玄武岩(E-MORB)叠加岛弧型玄武岩(IAB)的地球化学特征,并受到后期俯冲流体的影响。根据果芒错蛇绿岩地球化学属性及其构造环境判别图解,推断该地区蛇绿岩生成于扩张的弧后盆地构造环境。作为狮泉河—纳木错—波密蛇绿岩带的一部分,该区蛇绿岩以班公湖—怒江特提斯洋弧后盆地的形式存在。     

阿尔金南缘清水泉堆晶岩年代学、地球化学特征及其地质意义

为探讨清水泉地区堆晶岩成岩时代和区域地质构造，选择沿阿尔金南缘主断裂南侧分布的清水泉堆晶辉长岩开展完成了LA-ICP-MS锆石定年，对堆晶纯橄岩、辉石岩和辉长岩开展了全岩地球化学研究。堆晶辉长岩年龄为(464.8±1.3)Ma，岩石地球化学结果表明：清水泉堆晶岩主量元素具低TiO₂含量，高Mg^#值的特点。纯橄岩、辉石岩和辉长岩稀土元素配分曲线呈现“平坦型”，与富集型大洋中脊玄武岩(E-MORB)配分一致。综合清水泉堆晶岩地化特征和区域地质构造背景认为：清水泉堆晶岩为同源岩浆分异演化的产物，其形成于伸展的构造背景，表明阿尔金南缘板块碰撞在中奥陶世已基本结束。     

内蒙古苏尼特左旗地区堆晶角闪辉长岩的发现及地质意义

通过详细的野外工作和室内研究，发现苏尼特左旗附近较广泛地分布有一种主要由角闪石和外长石组成的堆晶岩，其化学成分属基性岩范畴，可定名为堆晶角闪辉长岩。这类岩体具清楚的层状构造、堆晶结构．岩石化学成分、稀土元素、结构和构造等特征均表明，该类岩石是由富水的拉斑玄武岩浆经分离结晶作用形成的，是造山带火成岩组合中的一个主要组成部分，形成于造山构造岩浆旋回的早期阶段。     

新疆克拉玛依百口泉蛇绿混杂岩中辉长岩岩石学和地球化学研究

克拉玛依蛇绿混杂岩带百口泉剖面由尖晶石蛇纹岩、辉长岩、玄武岩和硅质岩组成。岩相学研究表明,百口泉辉长岩分为堆晶岩(具堆晶结构)和辉长岩(具辉长结构)两类,且均经历了低-中级变质改造。微量元素地球化学显示其岩浆起源于亏损地幔,强烈的Sr异常和Eu异常表明强烈的斜长石堆晶过程。根据其稀土配分模式推测其源区为尖晶石相的地幔橄榄岩。结合野外地质关系和地球化学特征,白碱滩尖晶石二辉橄榄岩能够代表其源区成分,利用微量元素模拟其岩浆演化过程显示:尖晶石二辉橄榄岩发生2.5%部分熔融所形成的熔体,通过10%～20%分离结晶可以形成堆晶辉长岩,经过80%～90%分离结晶则可以形成具辉长结构的辉长岩。因此,蛇绿混杂岩中零星分布的堆晶岩和辉长岩团块是同源岩浆演化的产物。对分离结晶过程中Nb元素地球化学行为的研究表明,岩浆的结晶分异能够导致辉长岩明显亏损Nb。     

东昆仑东端扎那合惹地区元古宙蛇绿岩

扎那合惹地区元古宙蛇绿岩由超镁铁质堆晶岩组成，堆晶岩岩石化学成分、矿物组成变化较大。痕量元素、稀土元素表现出富集不相容元素的特征，而Nd同位素地球化学特征显示其源于亏损的地幔源区。超镁铁质堆晶岩Sm-Nd等时线年龄为1480±3Ma，与之紧密伴生的榴闪岩40Ar／39Ar坪年龄为（881.8±4.7）Ma（石榴石）和（852.2±1.0）Ma（角闪石），分别代表了古昆中洋扩张及俯冲消减的时限。     

新疆西准洪古勒楞蛇绿岩地球化学特征及构造环境

对西准噶尔洪古勒楞蛇绿混杂岩带进行了较系统的岩石学、地球化学和年代学方面的研究,认为其主体由超镁铁质杂岩、堆晶岩类、镁铁质岩墙、基性熔岩和深海沉积组成。岩石地球化学数据表明其具轻稀土富集、重稀土相对亏损的右倾分布模式特征,富集Ta,Yb等元素,相对富集Ba,U,Sr等元素,亏损Nb,Hf,Ti等元素,Nb具负异常,一定程度上反映其为地幔源区含岛弧火山岩组分,岩石化学数据显示该蛇绿岩形成构造环境为弧后盆地。堆晶辉长岩的LA-ICP-MS锆石U-Pb年龄为(497.2±4.2)Ma(MSWD=1.4,n=10),证实该蛇绿岩形成于晚寒武世。     

西藏丁青地区与玻镁安山岩类有关的蛇绿岩的矿物学特征

西藏丁青蛇绿岩的东杂岩体是一种与玻镁安山岩(Boninite)有关的特殊的蛇绿岩类型。其 堆晶斜方辉石岩、辉长岩和辉绿岩的岩石化学、微量元素以及稀土元素的地球化学特征均与西太平洋诸岛(伊豆—马利亚纳、巴布亚新几内亚、新喀里多尼亚等)的玻镁安山岩相似。此外,超镁铁质构造岩中的橄榄石和顽火辉石富镁,指示残余地幔具强烈亏损的性质。尖晶石的Cr含量中等至较高,与深海橄榄岩及大洋中脊玄武岩中的尖晶石不同。堆晶岩和辉长岩中的古铜辉石富镁,斜长石富钙,也明显不同于典型大洋中脊环境的特征,表明丁青东蛇绿岩形成的环境不像大洋中脊或弧后盆地,而可能是在洋内俯冲带之上的岛弧底部。     

江南造山带存在新元古代（～850 Ma）俯冲作用——来自皖南SSZ型蛇绿岩锆石SHRIMP U-Pb年龄证据

皖南伏川蛇绿岩是江南造山带上出露最完整的蛇绿岩,主要由地幔橄榄岩、堆晶岩、枕状熔岩和少量硅质岩组成.地幔橄榄岩主要是方辉橄榄岩,具有U型的稀土元素配分模式,副矿物尖晶石的Cr#较高(54～60),堆晶岩组合为纯橄岩-易剥橄榄岩-辉长岩(DIG型),这些特征指示伏川蛇绿岩形成于俯冲带之上的构造环境,属SSZ型蛇绿岩.堆晶岩异剥橄榄岩的锆石SHRIMP U-Pb年龄为827±9 Ma(n=12,MSWD=1.4),侵入到方辉橄榄岩中的辉长岩岩脉的锆石SHRIMP U-Pb年龄为848±12 Ma(n=7,MSWD=1.9),说明扬子板块和华夏板块至少在848Ma之前就开始拼合,它们之间的古大洋在新元古代(～850 Ma)之前就已经俯冲削减.     

内蒙朝克山蛇绿岩地球化学: 洋内弧后盆地的产物？

朝克山蛇绿岩是内蒙贺根山地区出露最好的蛇绿岩之一,可能形成于中晚石炭世。朝克山蛇绿岩中的基性岩具有LREE亏损、类似N-MORB的稀土配分模式,而相对N-MORB富集大离子亲石元素,亏损Nb、Ta等高场强元素又类似岛弧火山岩的成分特征,因此,我们认为朝克山蛇绿岩应形成于弧后盆地。将朝克山蛇绿岩的基性岩与现代Mariana洋内弧后盆地和Okinawa陆缘弧后盆地的玄武岩及同属中亚造山带的、形成于洋内弧后盆地的新疆库尔提蛇绿岩对比,朝克山蛇绿岩更类似于Mariana玄武岩和库尔提蛇绿岩,因此其很可能形成于洋内弧后盆地而不是大陆边缘弧后盆地环境。     

西藏纳木错西岸蛇绿岩的地球化学特征及其形成环境

西藏纳木错西岸蛇绿岩主要由变质橄榄岩、辉长辉绿岩及玄武岩等组成。变质橄榄岩以富Mg、贫Ti、贫REE元素为特征。辉绿岩和玄武岩的主量元素、微量元素特征显示其含有洋脊拉斑玄武岩和岛弧拉斑玄武岩的双重成分,其中高场强元素Nb、Ta、Zr、Hf等亏损．大离子亲石元素Rb、Sr、Ba等相对富集,具岛弧玄武岩的特点;在球粒陨石标准化稀土元素配分模式图上为LREE亏损的平坦型,无负Eu异常,与洋中脊玄武岩的特征类似。通过与典型地区作对比并应用构造环境判别图解,推测该区蛇绿岩形成于弧后盆地的构造环境。     

南天山北缘榆树沟变质基性超基性岩的地球化学及其成因机制

榆树沟变质基性－超基性岩带出露于塔里木板块与哈萨克斯坦板块之间的南天山北缘，主要由变质橄榄岩和变质基性岩组成。变质橄榄岩富相容元素Cr、Co和Ni，贫不相容元素，太离子亲石元素Ba、Rb和Sr含量较低，与世界典型蛇绿岩相似，代表了地幔残留物特征。REE分布模式为LREE亏损型，REE含量小于或等于2．5倍球粒陨石，类似于阿尔卑斯型变质橄榄岩，显示榆树沟的变质橄榄岩是原始地幔岩部分熔融萃取出玄武岩后的残留物。变质基性岩绝大部分为LREE亏损型，类似于N－MORB。所有样品均以富集Nb和Ta、高场强元素不分异，以及微量元素含量低为特征，批示岩浆源区总体上类似于MORB，Nb、Ta富集可能与OIB型源区有关，Nd、Sr同位素特征也显示其具有OIB型源区特征。综合分析认为，榆对沟变质基性岩石的岩浆可能经历了两个阶段的演化过程，即上地幔底部或下地幔顶部的OIB型原始岩浆形成阶段和软流圈地幔亏损阶段。     

Zircon ages and geochemical data of the Biluutiin ovoo ophiolite: implication for the tectonic evolution of South Mongolia

The early Palaeozoic tectonic evolution of South Mongolia is not well constrained due to the limited exposure of early Palaeozoic rocks in the area and the scarcity of both geochemical and geochronological data. In order to help rectify this situation, we have conducted detailed studies on the Biluutiin ovoo ophiolite in South Mongolia to provide constraints on the tectonic evolution of the region during this period. The Biluutiin ovoo ophiolite consists of ultramafic rocks, mylonitic gabbro, basalt, tuff sandstone, plagiogranite, calcite, and chert. Gabbro and plagiogranite samples from the ophiolitic complex yielded SHRIMP zircon ages of 525 ± 5 Ma and 503 ± 6 Ma, respectively. Biluutiin ovoo ophiolitic basalts display LREE and LILE enrichment and strong HFSE depletion, indicating that the ophiolite is supra-subduction zone (SSZ) type. Plagiogranite with adakite-like geochemical compositions suggests that palaeo-ocean subduction occurred in South Mongolia during Cambrian time. Intruding granite yielded a SHRIMP zircon age of 353 ± 2 Ma, indicating that the ophiolite was emplaced before early Carboniferous time. Identification of the Cambrian ophiolitic complex and the occurrence of Cambrian adakites indicate that southern Mongolia underwent a period of active volcanism during the Cambrian. The Cambrian formations are likely correlated to the early Palaeozoic subduction-accretion belt of Western Mongolia.     

青海省阿尼玛卿带布青山蛇绿混杂岩的地球化学性质及形态环境

布青山蛇绿混杂岩位于阿尼玛卿带西段，它是由早古生代和早石炭世一早二叠世两期蛇绿岩组成的复合蛇绿混杂岩带。蛇绿岩中的变质橄榄岩以方辉橄榄为主，高镁，∑PEE是球粒陨石的0．2－0．65倍，HREE是球粒陨石的0．28－0．32倍，属亏损的大洋岩石圈地幔。早古生代蛇绿岩中辉长岩、辉绿岩和玄武岩等镁铁质岩主要具N－MORB性质，少量具T－MORB性质。早石炭世一早二叠世蛇绿岩中玄武岩也主要具N－MORB性质、少量具T－MORB性质。它们均形成于洋中脊环境。本区曾存在成熟的早古生代洋盆和古特提斯洋盆，有更复杂的构造演化史。     

Geochemistry of the Boil Mountain ophiolitic complex,northwest Maine,and tectonic implications

A coherent ophiolitic complex of pyroxenite, serpentinite, metagabbro, mafic volcanics, felsic volcanics and sediments crops out in NW Maine, adjacent to the Chain Lakes massif. The complex (here informally referred to as the Boil Mountain ophiolitic complex) is about 500 m.y. old. The volcanic sequence is not typical of ophiolites in that it contains a large proportion of felsic volcanics. The mafic volcanics are divided into two geochemical groups. A stratigraphically lower group is depleted in Ti, Zr, Y, Cr and REE contents similar to basalts from supra-subduction zone ophiolites. An upper mafic group has trace element contents similar to normal mid-ocean ridge basalts. The felsic volcanics are mostly rhyolitic and similar to low-K rhyolites found in the forearc of the Marianas trench and in an island arc sequence in the Klamath Mountains, California. The flat REE patterns of the felsic volcanic rocks are similar to those found in siliceous rocks in the Oman ophiolite. The presence of thick sequences of felsic volcanics, the abundance of pyroxenite, the low Ti, Zr and REE contents of some mafic rocks, the flat REE patterns of the felsic volcanics, and the composition of clinopyroxene all suggest the complex was formed in the vicinity of a subduction zone. The complex may be correlated with ophiolitic fragments in the eastern part of the Dunnage Zone in Newfoundland, rather than the main ophiolite belt of the western Appalachians.     

西藏班公湖-怒江缝合带中段江错蛇绿岩岩石学、地球化学、年代学及地质意义

江错蛇绿岩位于班公湖-怒江缝合带中段, 位于切里湖蛇绿岩亚带的最东端, 南邻蓬湖西蛇绿岩.江错蛇绿岩岩石组合相对较全, 主要由变质橄榄岩、辉长岩和辉绿岩等组成.江错蛇绿岩辉长岩-辉绿岩与N-MORB相比具有较高的Mg#、低Ti、K、Na和P的特征, 富集大离子亲石元素Sr、Rb、Ba和亏损高场强元素Th、Hf、Ta、Nb, REE配分图总体显示为平坦型分布模式.通过地球化学元素分析认为江错蛇绿岩是形成于SSZ之上的弧后盆地扩张脊环境.对其进行辉长岩锆石SHRIMP U-Pb定年, 得出加权平均年龄为189.8±3.3 Ma(MSWD=0.97), 该结果代表了班公湖怒江缝合带中段江错地区特提斯洋的扩张时代, 与中段东巧地区蛇绿岩年龄一致, 但晚于东段洋盆发育时代且早于西段洋盆发育时代, 表明整个班公湖-怒江洋盆发育时代存在东早西晚的特点.      

Late Cretaceous subduction initiation and Palaeocene–Eocene slab breakoff magmatism in South-Central Anatolia,Turkey

The Late Cretaceous Alihoca ophiolite in the Inner Tauride suture zone (ITSZ) of South-Central Turkey represents part of a single ophiolitic thrust sheet that originated from the Inner Tauride ocean. The ophiolite contains upper mantle peridotites, cumulate wehrlites, layered-to-isotropic gabbros, and microgabbroic-to-doleritic dikes. An ophiolitic mélange beneath the Alihoca ophiolite includes blocks of limestone, peridotite, dolerite, basalt, and deep-sea sedimentary rocks (radiolarite, chert) in a matrix comprising sheared serpentinite and mudstone. Isotropic gabbro and dolerite dike rocks show enrichment in Sr, K, Rb, Ba, and Th (LILE) and depletion of Ta, Nb, Zr, Ti, and Y (HFSE), indicating an island arc tholeiite (IAT) affinity. Relatively younger dolerite rocks display low TiO₂ (<0.5 wt.%) contents, concave REE profiles with low HREE concentrations, and high LREE values, typical of boninitic affinities. The Alihoca ophiolite, hence, displays an IAT to boninitic geochemical progression in its magmatic evolution, reminiscent of many other Tethyan ophiolites in the region. It represents the remnant of a forearc oceanic crust, which developed during the early stages of subduction within the Inner Tauride ocean. Volcanic, volcano-sedimentary, and sedimentary rocks of the Uluk??la–Çamard? basin north of the ITSZ disconformably overlie the mafic-ultramafic rocks of the Alihoca ophiolite. Pillowed and massive lavas of the latest Cretaceous–Palaeocene Uluk??la Formation have alkaline basalt-to-basaltic andesite compositions, displaying relatively enriched LILE and LREE patterns with negative Nb and Ta anomalies. These geochemical features suggest that magmas of the Uluk??la–Çamard? volcanic rocks formed from partial melting of a metasomatized lithospheric mantle. This melting event was triggered by the influx of asthenospheric heat through a slab breakoff-induced window in the downgoing Tethyan oceanic lithosphere.     

东昆仑可支塔格蛇绿混杂岩的地质地球化学特征

东昆仑可支塔格蛇绿混杂岩属于木孜塔格-鲸鱼湖大断裂的西延部分,主要由辉橄岩、辉长岩、闪长岩、斜长花岗岩、辉绿岩、玄武岩及硅质岩等组成,形成时代为早石炭世。为构造强烈破坏的蛇绿混杂岩,形成于俯冲带环境,属SSZ型蛇绿岩。其中辉橄岩以相对低SiO2、TiO2、Al2O3和CaO、高MgO为特征,贫有色金属成矿元素,富集相容元素Cr、Ni、Co。稀土总量低,接近于球粒陨石稀土元素总量,以LREE略富集为特征。闪长岩SiO2、K2O含量较低,MgO、CaO、Na2O较高,稀土总量高,∑REE为90.95μg/g,LREE富集。斜长花岗岩SiO269.8%,Na2O>K2O,K2O/Na2O为0.78,A/CNK为1.68,具有大洋斜长花岗岩的岩石化学特征。闪长岩、斜长花岗岩的微量元素特征相似,表现为大离子亲石元素K、Sr、Rb、Ba相对富集,高场强元素Nb、Ta、Zr、Hf相对亏损。研究表明,辉橄岩来源于亏损的地幔岩,接近于强烈亏损的方辉橄榄岩,而明显不同于结晶分异作用成因的超镁铁质岩石。闪长岩、斜长花岗岩为蛇绿混杂岩的浅色岩组分,是地幔岩浆结晶分异的产物。     

Petrochemical and petrotectonic characterisation of ophiolitic volcanics from Great Nicobar island Andaman-Sumatra belt

In Great Nicobar island ophiolite is restricted to the eastern coast of the island and occur as small isolated out crops in the terrain of Oligocene sediments. The ophiolitic rocks are represented by pillowed basalt, massive andesite and pyroclastic andesite. These volcanics represent dismembered members of the upper part of the ophiolite. Basalt is porphyritic in nature where phenocrysts of augite and plagioclase laths are set in a fine grained glassy to chloritic matrix. Andesites consists of phenocrysts of augite, altered feldspar and minor quartz which are set in ground mass of epidote-chlorite glass. Trace element and REE pattern suggests more fertile mantle source for andesite than that of basalt. Trace element characteristics indicate that the andesites and basalts were possibly derived from the same melt where andesite represents the more fractionated product.In Andaman Islands dismembered ophiolite with complete ophiolite stratigraphy are found only within the Eocene sediments. But the field disposition suggests that in Great Nicobar emplacement of the ophiolite continued even after the Oligocene sedimentation. The characters of the ophiolitic rocks in Great Nicobar island are similar to that of the Sunda outer arc ridge.