Sea-Level Changes and δO Record for the Past 34,000 yr from Mayotte Reef, Indian Ocean

New sea-level and δ¹⁸O curves for the past 34,000 yr, based on uranium–thorium chronology, are proposed for the southwestern part of the Indian Ocean. The archives include cores drilled from onshore coral reefs and submersed samples from foreslope corals of Mayotte in the Comoro Islands. The Mayotte sea-level curve shows a lowstand of 145 ± 5 m below the present level during the last glacial maximum dated at 18,400 yr. This lowstand is supported by the maximum¹⁸O enrichment in the coral colonies. The residual signal (Δδ¹⁸O), controlled by sea-surface temperature changes, indicates that surface waters 18,400 yr ago were approximately 5°C cooler than present. The deglacial sea-level rise is clearly recorded, with a mean rate of about 1.7 cm yr⁻¹between 18,400 and 10,000 yr ago. The deglaciation phase is characterized by a strong¹⁸O depletion marked by two pulses related to meltwater discharges into the North Atlantic Ocean but also characterized by responses specific to the tropical Indian Ocean.     

Changing moisture sources over the last 330,000 years in Northern Oman from fluid-inclusion evidence in speleothems

Speleothems from Hoti Cave in northern Oman provide a record of continental pluvial periods over the last 330,000 yr. Periods of rapid speleothem deposition occurred from 6000 to 10,500, 78,000 to 82,000, 120,000 to 135,000, 180,000 to 200,000, and 300,000 to 330,000 yr ago, with little or no growth during the intervening periods. During each of these five pluvial periods, δD values of water extracted from speleothem fluid inclusions (δD_FI) are between −60 and −20‰ (VSMOW) and δ¹⁸O values of speleothem calcite (δ¹⁸O_C) are between −12 and −4‰ to (VPDB). These values are much more negative than modern rainfall (for δD) or modern stalagmites (for δ¹⁸O). Previous work on the isotopic composition of rainfall in Oman has shown that northern and southern moisture sources are isotopically distinct. Combined measurements of the δD values of fluid-inclusion water with calculated δ¹⁸O values from peak interglacial speleothems indicate that groundwater was predominantly recharged by the southern (Indian Ocean) moisture source, when the monsoon rainfall belt moved northward and reached Northern Oman during each of these periods.     

Sea-land oxygen isotopic relationships from planktonic foraminifera and speleothems in the Eastern Mediterranean region and their implication for paleorainfall during interglacial intervals

The oxygen and carbon stable isotope compositions of cave speleothems provide a powerful method for understanding continental climate change. Here, we examine the question of the regionality of this isotopic record and its linkage with the marine isotopic record in the Eastern Mediterranean (EM) region. The study presents a new, accurately dated 250-kyr δ¹⁸O and δ¹³C record determined from speleothems of the Peqiin Cave, Northern Israel. Its comparison with the continuous 185-kyr isotopic record of the Soreq Cave speleothems from Central Israel reveals striking similarities. Thus, a strong regional climatic signal, brought about by variations in temperature and rainfall amount, is reflected in both cave records. Low δ¹⁸O minima in the Peqiin profile for the last 250- to 185-kyr period (interglacial marine isotopic stage 7) match the timing of sapropels 9 to 7 and are indicative of high rainfall in the EM region at these times. The combined Soreq and Peqiin δ¹⁸O record for the last 250 kyr excellently matches the published Globigerinoides ruber (G. ruber) marine δ¹⁸O record for the EM Sea, with the isotopic compositional difference Δ_{G.ruber-speleothems} remaining relatively constant at −5.6 ± 0.7‰, thus establishing for the first time a robust, exploitable link between the land and the marine isotopic records. The correspondence of low δ¹⁸O speleothem values and high cave water stands with low G. ruber δ¹⁸O values during interglacial sapropel events indicates that these periods were characterized by enhanced rainfall in the EM land and sea regions. By use of sea surface temperatures derived from alkenone data as a proxy for land temperatures at the Soreq Cave, we calculate the paleorainfall δ¹⁸O values and its amounts. Maximum rainfall and lowest temperature conditions occurred at the beginning of the sapropel events and were followed by decrease in rainfall and increase in temperatures, leading to arid conditions. The record for the last 7000 yr shows a trend toward increasing aridity and agrees well with climatic and archeological data from North Africa and the Middle East.     

Indian monsoon variability during the last 46 kyr: isotopic records of planktic foraminifera from southwestern Bay of Bengal

The Indian monsoon carries large amounts of freshwater to the northern Indian Ocean and modulates the upper ocean structure in terms of upwelling and productivity. Freshwater-induced stratification in the upper ocean of the Bay of Bengal is linked to the changes in the Indian monsoon. In this study, we test the usefulness of δ¹⁸O and δ¹³C variability records for Globigerina bulloides and Orbulina universa to infer Indian monsoon variability from a sediment core retrieved from the southwestern Bay of Bengal encompassing the last 46 kyr record. Results show that the northeast monsoon was dominant during the Last Glacial Maximum. Remarkable signatures are observed in the δ¹⁸O and δ¹³C records during the Marine Isotope Stage (MIS) 3 to MIS-1. Our study suggests that Indian monsoon variability is controlled by a complex of factors such as solar insolation, North Atlantic climatic shifts, and coupled ocean–atmospheric variability during the last 46 kyr.     

Oxygen isotope systematics in Diploastrea heliopora: new coral archive of tropical paleoclimate

Diploastrea heliopora forms dense, robust, dome-shaped coral colonies throughout the reef ecosystems of the tropical Pacific and Indian Oceans. This slow-growing (2 to 6 mm/yr) coral has the potential to yield continuous paleoclimate records spanning up to 1000 yr for the warmest waters on Earth, the Indo-Pacific Warm Pool, and has a long fossil history as a single recognizable species. Despite the potential of Diploastrea to be an important new paleoclimate archive, little is known about the systematics of geochemical tracers incorporated into its skeleton. To fill this knowledge gap, we compared skeletal δ¹⁸O signatures in live Diploastrea and Porites colonies from Southwest Lagoon, near Amédée Lighthouse, New Caledonia (at the southern latitudinal limit for Diploastrea) and Alor, Indonesia (in the core area of the Indo-Pacific Warm Pool). We designed a new microsampling technique to minimize smoothing and distortion of the isotopic records due to the complex calyx architecture and slow growth of Diploastrea. High-resolution isotope profiles from the septal portion of the Diploastrea corallite are attenuated, whereas those restricted to the central columella are similar in quality to those extracted from the well-established Porites coral archive. The δ¹⁸O-temperature relationship for the columellar portion of Diploastrea (−0.18‰/°C) is in good agreement with that derived for a nearby Porites (−0.19‰/°C; Quinn et al., 1996), on the basis of comparison with an in situ sea surface temperature record from Amédée Lighthouse. There is a measurable difference of 0.3 ± 0.1‰ between the kinetic/biological disequilibrium offsets from seawater δ¹⁸O composition for Diploastrea and Porites. Despite this offset in mean δ¹⁸O, Diploastrea accurately records the regional differences in mean temperature and salinity between New Caledonia and the Indo-Pacific Warm Pool. Additional tests show that Diploastrea records El Niño-Southern Oscillation (ENSO) interannual variability in sea surface temperature and salinity across the southwestern Pacific, indicating that it should yield dependable paleo-ENSO records. Based on these results, we propose that D. heliopora has the potential to provide an important new coral archive of tropical paleoclimate.     

Paleohydrologic regimes in the southwestern Great Basin, 0–3.2 my ago,compared with other long records of “gobal” climate

The oxygen-isotope record from fossil foraminifera in deep-sea sediments is commonly used as a proxy for global ice volume. The linkage between δ¹⁸O and ice volume, however, is probably nonlinear. We have developed a simple numerical model of the isotopic response of the oceans to ice-volume change. The major features it simulates are (1) the changing mean isotopic composition of snow as a function of ice volume (colder snow temperatures forced by climate change and higher-elevation accumulation areas imply more negative mean δ¹⁸O); (2) the nonequilibrium isotopic composition of ice sheets (the past history of an ice sheet is integrated into its mean isotopic composition, which introduces a lag of isotopic “ice volume,” i.e., the measured δ¹⁸O record, scaled to ice-volume units, behind true ice volume); (3) selective preservation of isotopically more negative (colder, higher-latitude) ice (this geographic effect can selectively amplify or dampen the isotopic response to the ice-volume signal). We illustrate the response of our model to simple hypothetical ice-volume transitions of ice growth and ice decay. Sensitivity tests are illustrated for all model parameters. The results suggest that oxygen-isotope records reproduce the general patterns of ice-volume change fairly accurately. The foraminiferal isotope record, however, may misrepresent the true amplitude of the ice-volume signal and lag true ice volume by 1000 to 3000 yr.     

Patterns of Pacific decadal variability recorded by Indian Ocean corals

We investigate Pacific Decadal Oscillation (PDO) signals recorded by two bimonthly resolved coral δ¹⁸O series from La Réunion and Ifaty (West Madagascar), Indian Ocean from 1882 to 1993. To isolate the main PDO frequencies, we apply a band pass filter to the time series passing only periodicities from 16 to 28 years. We investigate the covariance patterns of the coral time series with sea surface temperature (SST) and sea level pressure (SLP) of the Indian and Pacific Oceans. In addition, the empirical orthogonal functions of the filtered SST and SLP fields (single and coupled) are related to the filtered coral times series. The covariance maps show the typical PDO pattern for SST and SLP, confirming the coupling between the Indian and Pacific Oceans. Both corals show the strongest signal in boreal summer. The La Réunion (Ifaty) coral better records SST (SLP) than SLP (SST) pattern variability. We suggest that the filtered La Réunion coral δ¹⁸O represents δ¹⁸O of seawater that varies with the South Equatorial Current, which, in turn, is linked with the SST PDO. The filtered Ifaty coral δ¹⁸O represents SST and is remotely linked with the SLP PDO variability. A combined coral record of the Ifaty and La Réunion boreal summer δ¹⁸O series explains about 64% of the variance of the coupled SST/SLP PDO time series. AGU OS06 special issue “Ocean’s role in climate change—a paleo perspective”.     

Climatic change recorded by stable isotopes and trace elements in a British Holocene tufa

Combined stable isotope (δ¹⁸O and δ¹³C) and trace element (Mg, Sr) geochemistry from bulk tufa calcite and ostracod shell calcite from an early Holocene British tufa reveal clear records of Holocene palaeoclimatic change. Variation in δ¹⁸O is caused principally by change in the isotopic composition of Holocene rainfall (recharge), itself caused mainly by change in air temperature. The δ¹³C variability through much of the deposit reflects increasing influence of soil‐zone CO₂, owing to progressive woodland soil development. Bulk tufa Mg/Ca and Sr/Ca are controlled by their concentrations in the spring water. Importantly, Mg/Ca ratios are not related to δ¹⁸O values and thus show no temperature dependence. First‐order sympathetic relationships between δ¹³C values and Mg/Ca and Sr/Ca are controlled by aquifer processes (residence times, CO₂ degassing and calcite dissolution/reprecipitation) and probably record intensity of palaeorainfall (recharge) effects. Stable isotope records from ostracod shells show evidence of vital effects relative to bulk tufa data. The ostracod isotopic records are markedly ‘spiky’ because the ostracods record ‘snapshots’ of relatively short duration (years), whereas the bulk tufa samples record averages of longer time periods, probably decades. The δ¹⁸O record appears to show early Holocene warming, a thermal maximum at ca. 8900 cal. yr BP and the global 8200 yr BP cold event. Combined δ¹³C, Mg/Ca and Sr/Ca data suggest that early Holocene warming was accompanied by decreasing rainfall intensity. The Mg/Ca data suggest that the 8200 yr BP cold event was also dry. Warmer and wetter conditions were re‐established after the 8200 yr BP cold event until the top of the preserved tufa sequence at ca. 7100 cal. yr BP. Copyright © 2004 John Wiley & Sons, Ltd.     

The potential origins and palaeoenvironmental implications of high temporal resolution δO heterogeneity in coral skeletons

δ¹⁸O was determined at high spatial resolution (beam diameter ∼30 μm) by secondary ion mass spectrometry (SIMS) across 1-2 year sections of 2 modern Porites lobata coral skeletons from Hawaii. We observe large (>2‰) cyclical δ¹⁸O variations that typically cover skeletal distances equivalent to periods of ∼20-30 days. These variations do not reflect seawater temperature or composition and we conclude that skeletal δ¹⁸O is principally controlled by other processes. Calcification site pH in one coral record was estimated from previous SIMS measurements of skeletal δ¹¹B. We model predicted skeletal δ¹⁸O as a function of calcification site pH, DIC residence time at the site and DIC source (reflecting the inputs of seawater and molecular CO₂ to the site). We assume that oxygen isotopic equilibration proceeds at the rates observed in seawater and that only the aqueous carbonate ion is incorporated into the precipitating aragonite. We reproduce successfully the observed skeletal δ¹⁸O range by assuming that DIC is rapidly utilised at the calcification site (within 1 h) and that ∼80% of the skeletal carbonate is derived from seawater. If carbonic anhydrase catalyses the reversible hydration of CO₂ at the calcification site, then oxygen isotopic equilibration times may be substantially reduced and a larger proportion of the skeletal carbonate could be derived from molecular CO₂. Seasonal skeletal δ¹⁸O variations are most pronounced in the skeleton deposited from late autumn to winter (and coincide with the high density skeletal bands) and are dampened in skeleton deposited from spring to summer. We observed no annual pattern in sea surface temperature or photosynthetically active radiation variability which could potentially correlate with the coral δ¹⁸O. At present we are unable to resolve an environmental cue to drive seasonal patterns of short term skeletal δ¹⁸O heterogeneity.     

13ka以来东亚夏季风演变过程和全新世适宜期问题

基于湖北神农架三宝洞石笋SB43的21个230Th年龄和486个氧同位素数据,建立了13．0-0．2ka时段东亚夏季风强度演化序列,其长期演化趋势与33°N太阳辐射变化基本一致。通过对比三宝洞、董歌洞、阿曼Qunf洞及和尚洞石笋δ18O记录,发现东亚和印度季风强度在轨道尺度上呈同相位变化。石笋SB43、D4 δ18O值与Cariaco盆地Ti含量曲线整体变化一致,相关系数高达0．8,表明热带辐合带（ITCZ）的南北移动可能对亚洲中低纬季风强度起放大作用;全新世适宜期在亚洲季风区不存在显著穿时性,起止时间大体一致,约为10．2～5．7ka。早、中全新世季风强度与极地温度变化趋势一致,相关系数高达0．9,表明当时高纬冰量边界条件可能对亚洲季风强度变化（包括ITCZ的平均位置）具有贡献作用。     

Source of paleo-groundwater in the Emirate of Abu Dhabi, United Arab Emirates: evidence from unusual oxygen and deuterium isotope data

Paleo-groundwaters of 6000?years BP from the Liwa water-table sand dune aquifer in the Rub al Khali and the Gachsaran artesian carbonate aquifer, on the coast of the Emirate of Abu Dhabi (UAE), exhibit normal ??²H/??¹⁸O slopes, modest ??¹⁸O increases, and large negative deuterium excess ??d?? (Liwa aquifer: 2.19?? VSMOW and d?=??C15; Gachsaran aquifer: 3.16?? VSMOW and d?=??C28) compared to local Shamal precipitation (0.05?? VSMOW and d?=?7). This unusual isotopic signature is hypothesized to result from re-evaporation of continental runoff to the Red Sea catchment basin. It is postulated that this continental water flowed onto the surface of the Indian Ocean providing a moisture source for the monsoon that dominated precipitation during this, the last wet period in the area from 5000 to 9000 BP. Carbonate precipitation, forming speleothems, travertines, tufas, lacustrine, and capillary-zone deposits, subsequently record this ??¹⁸O isotopic signature. This rock record is thus dominated by the water source, rather than environmental conditions of deposition normally assumed to control the rock ??¹⁸O isotopic signature. As a consequence, re-evaluation of paleo-climate??¹⁸O data from the rock record may be necessary for this time period in southern Arabia.     

The use of proxy chemical records in Coral skeletons to ascertain past environmental conditions in Florida Bay

This paper will discuss the use of chemical proxies in coral skeletons to reconstruct the history of salinity (from the δ¹⁸O of the skeleton) and nutrients in the water (from the δ¹³C) in Florida Bay between 1824 and 1994. Monthly salinity and water temperature data collected since 1989 were used to establish a correlation between salinity, temperature, and the δ¹⁸O of the skeleton of the coralSolenastrea bournoni from Lignumvitae Basin in Florida Bay. This relationship explains over 50% of the variance in the δ¹⁸O of the skeleton. Assuming that interannual variations in the temperature of the water are small, we have applied this relationship to the δ¹⁸O measured in the coral skeleton collected from Lignumvitae Basin which has a record between 1824 and 1993. These data provide a revised estimate of salinity variation in Lignumvitae Basin for the period when historical records for salinity were not available, and show that the highest salinity events occurred in the past 30 yr. Using the relationships between the salinity in Lignumvitate Basin and other basins, obtained using a modern dataset, we are able to estimate ranges in salinity for other portions of Florida Bay. Skeletons of specimens of the coral speciesSiderastrea radians collected from other areas of Florida Bay show similar patterns in the δ¹⁸O over the past 10 yr, indicating that corals in most portions of Florida Bay are recording salinity variations in their skeletons and therefore support the idea that salinity variations in different portions of Florida Bay can be related. Fluorescence analysis of the coral from Lignumvitae Basin shows a large change in the magnitude of the 10-yr signal coincident with the construction of the railway, confirming that this event had a significant impact upon Florida Bay. The δ¹³C of the coral skeletons reveals a long-term history of the oxidation of organic material, fixation of carbon by photosynthesis (algal blooms), and the intrusion of marine water into the bay. Since the construction of the railway from Miami to Key West there has been a long-term decrease in the δ¹³C of the coral skeleton from Lignumvitae Basin, suggesting the increased oxidation of organic material in this area. This decrease in δ¹³C appears to have reached a minimum value around 1984 and has increased since this time in the western portions of Florida Bay. The increase may be related to the algal blooms prevalent in the area or alternatively could result from intrusion of more marine water. In the eastern areas, a small increase in the δ¹⁸C between 1984 and 1988 was followed by further decline suggesting more oxidation of organic material. We have also attempted to use the concentration of barium in the coral skeleton as a proxy indicator of the nutrient status in Florida Bay.     

The marine oxygen isotope record in Pleistocene coral,Barbados, West Indies

The reef-crest coral Acropora palmata from late Pleistocene reefs on Barbados has recorded the same global variations in oxygen isotopes as planktonic and benthonic foraminifera. Although the record of oxygen isotopes in Acropora palmata is discontinuous, it offers several advantages over the isotope records from deep-sea sediments: (1) the coral grows at water depths of less than 5 m; (2) the samples are unmixed; (3) specimens may be sampled from various elevations of paleo-sea level; and (4) aragonitic corals are suitable for ${}^{230}\text{Th}{}^{234}\text{U}$ and $\text{He}\text{U}$ dating techniques. The latter advantage means that direct dating of the marine oxygen isotope record is possible. Oxygen isotope stage 5e corresponds to Barbados III, dated at 125,000 ± 6000 yr BP. Petrographic and geochemical evidence from five boreholes drilled into the south coast of Barbados indicates a major eustatic lowering (greater than 100 m below present sea level) occurred between 180,000 and 125,000 yr BP. The age and isotopic data suggest correlation of this change in sea level to Emiliani's oxygen isotope stage 6. Acropora palmata deposited at various elevations of sea level during oxygen isotope stage 6 vary by 0.11 ‰ δ¹⁸O for each 10 m of change in sea level. We further hypothesize a minimum drop of 2°C in the average temperature occurred during the regressive phase of oxygen isotope stage 6. These data indicate that temperature lowering of surface water near Barbados lagged behind a major glacial buildup during this time period. Using the δ¹⁸O vs sea level calibration herein derived, we estimate the relative height of sea stands responsible for Barbados coral reef terraces in the time range 80,000 to 220,000 yr BP.     

The reef builder gastropod Dendropomapetreaum - A proxy of short and long term climatic events in the Eastern Mediterranean

High-resolution δ¹⁸O and δ¹³C records obtained from seven cores were drilled from ledges of the reef builder gastropod Dendropomapetreaum and used to reconstruct variations in the Levantine basin sea surface temperature, hydrology and productivity during the past 500 years. The δ¹⁸O of the aragonite shell of living D. petreaum indicate that skeletal deposition occurs under isotopic equilibrium and faithfully record the temperature and surface water δ¹⁸O during summer and autumn. The mean down core δ¹⁸O record clearly captures global and local climatic events, such as the Little Ice Age (LIA) and the recent warming of surface waters in the Eastern Mediterranean. Comparison to the Western Mediterranean vermetid δ¹⁸O record reveals changes in the freshwater/evaporation budgets of the two basins during cold and warm periods. The Eastern basin had lower surface temperatures and excess evaporation during the LIA and experienced a relatively larger warming and/or a decrease in freshwater/evaporation during the past 70 years. The D. petraeum δ¹³C is strongly related to δ¹³C of dissolved inorganic carbon and to the primary productivity of the surface water. The mean down core δ¹³C record exhibits enrichment during the LIA maximum and a strong depletion trend during the last century. The LIA δ¹³C enrichment is attributed to an increase in primary production and high nutrient levels which resulted from increased vertical mixing and upwelling. The last century δ¹³C depletion is mostly related to the increased anthropogenic emissions of ¹³C depleted carbon dioxide and to a certain decrease in primary production. The data indicate that D. petraeum isotopic signatures are unique proxies for last 500 years high-resolution reconstruction of paleo-oceanographic environments in the Mediterranean and potentially in the sub-tropical Atlantic regions.     

A comparison of radiolarian and foraminiferal paleoecology in the Southern Indian Ocean: New evidence for the interhemispheric timing of climatic change

The deglacial transition between oxygen-isotope Stages 6 and 5e (about 127,000 yr B.P.) is marked by both oxygen isotopic depletion and estimated sea-surface temperature (SST) increase in two subantarctic Indian Ocean cores. The data show synchroneity between warming of foraminifera-based SST estimates and depletion of δ¹⁸O, but an earlier warming trend on the basis of radiolarian SST estimates. These data have been previously interpreted to indicate that the high-latitude Southern Ocean warms prior to significant melting of glacial-age ice sheets. Comparison of core-top assemblages with surface and subsurface conditions in the Southern Indian Ocean reveals that (1) a three-part foraminiferal zonation reflects the surface hydrographic regime, with abrupt faunal transitions at two major fronts: the Subtropical Convergence (STC) and the Antarctic Polar Front (APF); and (2) a two-part radiolarian zonation coincides with a two-part subsurface hydrographic regime, with an abrupt faunal transition corresponding to the southern terminus of subtropical lower water (STLW) between the STC and the APF. It is suggested that shifts of these surface and subsurface regimes are recorded by these foraminiferal and radiolarian assemblages. In this interpretation, the observed lead of radiolarian SST with respect to δ¹⁸O indicates an early response to a southward shift of STLW, while the later foraminiferal SST warming indicates a southward shift of the STC. Thus, the origin of the Southern Hemisphere SST lead may be related to STLW, which emanates from the subtropical gyres, rather than the polar regions.     

Stable isotope of some selected Egyptian pectinids and their paleoenvironmental implications

Eight pectinid shells were collected and subjected to quantitative study using δ¹⁸O and δ¹³C isotopic analysis in order to study the paleoenvironment which prevailed during their calcification. The scalerochronological variations in δ¹⁸O and δ¹³C values, among these shells are also discussed. The Early Miocene pectinid shells display highly depleted δ¹⁸O and δ¹³C signature as a result of paleo-meteoric water with heavy rainfall that was produced by Tropical Cyclones when the Mediterranean Sea was open. The Early Pliocene pectinid shells reveal depleted δ¹⁸O values, related to the influx of fresh water influenced by monsoonal activity following the formation of the Tibetan Plateau. Their enrichment in the δ¹³C isotopic excursion is referred to high productivity of the Indian Ocean, which was the main source of the Red Sea water. The Pleistocene pectinid shell shows highly depleted δ¹⁸O and δ¹³C signature with obvious diagenetic shell structure, indicating that a wetter humid climate prevailed during the Early–Middle Pleistocene and long sub-arial exposure of the shell. The Recent Mediterranean pectinid shell displays slight enrichment in δ¹⁸O and δ¹³C values referring to deeper inhabitation of this species with a low temperature and high salinity environment. The scalerochronological variations in both δ¹⁸O and δ¹³C values, along these shells is referred to seasonal variations or kinetic effects.     

Environmental control of the oxygen isotope composition of Porites coral microatolls

Understanding the influence of climatic and non-climatic factors on geochemical signals in corals is critical for assessing coral-derived records of tropical climate variability. Porites microatolls form large, disk-shaped colonies constrained in their upward growth by exposure at or close to mean spring low water level, and occur on Indo-Pacific reefs. Microatolls appear suitable for paleoclimate reconstruction, however the systematics of the microatoll chemistry-climate relationship are yet to be characterized. In this study, the δ¹⁸O signal in Porites microatolls from well-flushed reef flats on Kiritimati (Christmas) Island, central Pacific was investigated for intra-coral (growth aspect and extension rate effects) and between-coral effects, and to explore the climate signal contained within their skeletons. Samples for δ¹⁸O analysis were taken from six individual transects from different positions within Porites microatoll XM22. The results show that: (1) the average standard deviation for the mean δ¹⁸O values of transects that represent the same time periods is 0.03‰, and is within measurement error for a single analysis (0.04‰); (2) the average standard deviation for time-equivalent, near-monthly samples along the transects within the same microatoll is 0.07‰ and; (3) comparison of the average δ¹⁸O values of records for different microatolls from across Kiritimati Island show only a small between-coral differences of 0.04‰ and 0.11‰ for different time periods. These differences in mean δ¹⁸O are within the range for intra- and inter-colony differences in seasonal and interannual δ¹⁸O reported for dome-shaped Porites. Based on these results, a stacked microatoll δ¹⁸O record was constructed for the period 1978-2007 for comparison with published coral δ¹⁸O records for nearby dome-shaped Porites. There is a systematic offset between the two types of records, which is probably due to variations in δ¹⁸O seawater across Kiritimati Island. Despite the offset, all records show similar amplitudes for the seasonal-cycle of δ¹⁸O, and there is a strong correlation (r = −0.71) between microatoll δ¹⁸O and local sea surface temperature (SST). The δ¹⁸O-SST slope relationship for microatolls is −0.15‰/°C, very similar to that reported for fast-growing domed corals (−0.18‰ to −0.22‰/°C). Statistical analysis of the stacked microatoll δ¹⁸O record shows that it is correlated with both local and large-scale climate variables (primarily SST) at semiannual, annual and interannual timescales. Our results show that the signal reproducibility and fidelity of skeletal δ¹⁸O in coral microatolls is comparable to that observed for more conventional coral growth forms. Longer-lived, and fossil, Porites microatolls, where they have grown in suitably flushed environments, are likely to contain δ¹⁸O signals that can significantly extend instrumental records of tropical climate variability.     

Karst springs as “natural” pluviometers: Constraints on the isotopic composition of rainfall in the Apennines of central Italy

This paper describes an indirect method to calculate the isotopic composition of rainfall by using the isotopic composition of karst springs fed by waters circulating in the most important regional aquifer of central Italy, i.e. the Mesozoic limestone sequence that forms the backbone of the Apennines. By using δ¹⁸O and δD data and the δ¹⁸O (and/or δD) average gradient for elevation, evaluated through the use of literature rainfall data and new measurements from a typical Alpine valley in northern Italy, the altitude of precipitation of their parent water has been re-calculated. Vertical descents of more than 2000 m, from recharge to discharge, have been assessed in some high flow-rate cold springs in the morphologically steep Adriatic sector of central Italy. A clear correlation between the vertical descents and more negative isotopic compositions at their relative emergence elevations is highlighted. In contrast, in the Tyrrhenian sector lower karstic drops (generally lower than 500 m) correlate with less negative isotopic composition of recharge areas.The δ¹⁸O iso-contour map of the “recalculated” parent rainfall in central Italy is more detailed than any possible isotopic map of rainfall made using pluviometers, unless large number of rainfall collectors were deployed on mountaintops. The data also show that the isotopic composition of rainfall depends on the source of the storm water. In particular, precipitation is isotopically heavier when originating in the Mediterranean Sea, and lighter when formed in the Atlantic Ocean. Consequently, the collision between air masses with such a different isotopic signature results in a relatively small latitudinal fractionation effect. The peninsular part of central Italy is very narrow, with several mountains and massifs more that 2000 m high, and any latitudinal variation in the isotopic composition between rainfall sourced in the Atlantic Ocean and in the Mediterranean Sea is much lower than that due to the isotopic fractionation due to elevation.     

Oxygen and hydrogen isotope ratios in freshwater chert as indicators of ancient climate and hydrologic regime

The oxygen and hydrogen isotopic composition of Eocene and Miocene freshwater cherts in the western United States records regional climatic variation in the Cenozoic. Here, we present isotopic measurements of 47 freshwater cherts of Eocene and Miocene age from the Great Basin of the western United States at two different sites and interpret them in light of regional climatic and tectonic history. The large range of δ¹⁸O of terrestrial cherts measured in this study, from 11.2‰ to 31.2‰ (SMOW: Standard Mean Ocean), is shown to be primarily the result of variations in δ¹⁸O of surface water. The following trends and patterns are recognized within this range of δ¹⁸O values. First, in Cenozoic rocks of northern Nevada, chert δ¹⁸O records the same shift observed in authigenic calcite between the Eocene and Miocene that has been attributed to regional surface uplift. The consistent covariation of proxies suggests that chert reliably records and retains a signal of ancient meteoric water isotopic composition, even though our analyses show that chert formed from warmer waters (40°C) than coexisting calcite (20°C). Second, there is a strong positive correlation between δ¹⁸O and δD in Eocene age chert from Elko, Nevada and Salina, Utah that suggests large changes in lake water isotopic composition due to evaporation. Evaporative effects on lake water isotopic composition, rather than surface temperature, exert the primary control on the isotopic composition of chert, accounting for 10‰ of the 16‰ range in δ¹⁸O measured in Eocene cherts. From authigenic mineral data, we calculate a range in isotopic composition of Eocene precipitation in the north-central Great Basin of −10 to −14‰ for δ¹⁸O and −70 to −100‰ for δD, which is in agreement with previous estimates for Eocene basins of the western United States. Due to its resistance to alteration and record of variations in both δ¹⁸O and δD of water, chert has the potential to corroborate and constrain the cause of variations in isotope stratigraphies.     

Controls, variation, and a record of climate change in detailed stable isotope record in a single bryozoan skeleton

The long-lived (about 20 yr) bryozoan Adeonellopsis sp. from Doubtful Sound, New Zealand, precipitates aragonite in isotopic equilibrium with seawater, exerting no metabolic or kinetic effects. Oxygen isotope ratios (δ¹⁸O) in 61 subsamples (along three branches of a single unaltered colony) range from −0.09 to +0.68‰ PDB (mean = +0.36‰ PDB). Carbon isotope ratios (δ¹³C) range from +0.84 to +2.18‰ PDB (mean = +1.69‰ PDB). Typical of cool-water carbonates, δ¹⁸O-derived water temperatures range from 14.2 to 17.5 °C. Adeonellopsis has a minimum temperature growth threshold of 14 °C, recording only a partial record of environmental variation. By correlating seawater temperatures derived from δ¹⁸O with the Southern Oscillation Index, however, we were able to detect major events such as the 1983 El Niño. Interannual climatic variation can be recorded in skeletal carbonate isotopes. The range of within-colony isotopic variability found in this study (0.77‰ in δ¹⁸O and 1.34 in δ¹³C) means that among-colony variation must be treated cautiously. Temperate bryozoan isotopes have been tested in less than 2% of described extant species — this highly variable phylum is not yet fully understood.