A study of soil water movement combining soil water potential with stable isotopes at two sites of shallow groundwater areas in the North China Plain

In the shallow groundwater areas of the North China Plain (NCP), precipitation infiltration and evapotranspiration in the vertical direction are the main processes of the water cycle, in which the unsaturated zone plays an important role in the transformation process between precipitation and groundwater. In this paper, two typical sites in Cangzhou (CZ) and Hengshui (HS) of Hebei province with shallow water tables were selected to analyse the relationship among precipitation, soil water and groundwater. At each site, precipitation, soil water at depths 10, 20, 30, 50, 70, 100, 150, 200, 300 cm, and groundwater were sampled to analyse the stable isotope compositions of hydrogen and oxygen. The soil water potentials at the corresponding depths were observed. Although the climates at the two sites are similar, there are some differences in the infiltration process, soil water movement and groundwater recharge sources. Evaporation occurred at the upper depths, which led to the decrease of soil potential and the enrichment of heavy isotopes. At the CZ site, precipitation infiltrated with piston mode, and an obvious mixture effect existed during the infiltration process. Preferential flow may exist in the soil above 100 cm depth. However, at the HS site soil water moved in piston mode, and groundwater was mainly recharged by precipitation. When precipitation recharged the groundwater it experienced a strong evaporation effect. The results of the soil water movement mechanism provides the transformation relationship among precipitation, soil water and groundwater in the middle and eastern NCP. Copyright © 2009 John Wiley & Sons, Ltd.     

Temporal variation of stable isotopes in a precipitation–groundwater system: implications for determining the mechanism of groundwater recharge in high mountain–hills of the Loess Plateau,China

The groundwater in shallow loess aquifers in high mountain–hills in the western Loess Plateau in China is almost the sole water resource for local residents. However, the question about how the loess groundwater naturally circulates in these high mountain–hills, characterized by low precipitation and high potential evaporation, remains unclear. The objectives of this study are to evaluate the application of hydrogen and oxygen isotopes to (1) examine temporal variations of the isotopic composition of precipitation and shallow groundwater and (2) uncover the mechanism of groundwater recharge in high mountain–hills. Results from 2 years of monitoring data show a difference in the stable isotopes for groundwater and local precipitation between the winter and summer periods. Similar to precipitation, stable isotopes in groundwater are observed to be depleted in winter and enriched in summer, particularly in oxygen isotope. A prominent characteristic is that H and O isotopes of groundwater show a very clear response to strong precipitation in the rainy season in 2013. The results highlight that local precipitation is the likely recharge source for groundwater in shallow loess aquifers. Annual recharge from local precipitation maintains the groundwater resource in the shallower loess aquifer. The mechanisms governing shallow loess groundwater recharge in high mountain–hills were evaluated. In addition to possible vertical slow percolation of soil water through the unsaturated zone, rapid groundwater recharge mechanisms have been identified as temporal preferential infiltration through sinkholes, slip surface or landslide surface and through the interface of loess layer and palaeo‐soils. Most groundwater can be recharged after a heavy rainy season. Copyright © 2015 John Wiley & Sons, Ltd.     

Estimating groundwater recharge from water isotope (δ2H, δ18O) depth profiles in the Densu River basin,Ghana

Abstract

Accurate estimation of groundwater recharge is essential for the proper management of aquifers. A study of water isotope (δ²H, δ¹⁸O) depth profiles was carried out to estimate groundwater recharge in the Densu River basin in Ghana, at three chosen observation sites that differ in their altitude, geology, climate and vegetation. Water isotopes and water contents were analysed with depth to determine water flow in the unsaturated zone. The measured data showed isotope enrichment in the pore water near the soil surface due to evaporation. Seasonal variations in the isotope signal of the pore water were also observed to a depth of 2.75 m. Below that depth, the seasonal variation of the isotope signal was attenuated due to diffusion/dispersion and low water flow velocities. Groundwater recharge rates were determined by numerical modelling of the unsaturated water flow and water isotope transport. Different groundwater recharge rates were computed at the three observation sites and were found to vary between 94 and 182 mm/year (± max. 7%). Further, the approximate peak-shift method was applied to give information about groundwater recharge rates. Although this simple method neglects variations in flow conditions and only considers advective transport, it yielded mean groundwater recharge rates of 110–250 mm/year (± max. 30%), which were in the same order of magnitude as computed numerical modelling values. Integrating these site-specific groundwater recharge rates to the whole catchment indicates that more water is potentially renewed than consumed nowadays. With increases in population and irrigation, more clean water is required, and knowledge about groundwater recharge rates – essential for improving the groundwater management in the Densu River basin – can be easily obtained by measuring water isotope depth profiles and applying a simple peak-shift approach.

Citation Adomako, D., Maloszewski, P., Stumpp, C., Osae, S. & Akiti, T. T. (2010) Estimating groundwater recharge from water isotope (δ²H, δ¹⁸O) depth profiles in the Densu River basin, Ghana. Hydrol. Sci. J. 55(8), 1405–1416.     

Groundwater recharge in the Akaki catchment,central Ethiopia: evidence from environmental isotopes (δ18O, δ2H and 3H) and chloride mass balance

Recharge patterns, possible flow paths and the relative age of groundwater in the Akaki catchment in central Ethiopia have been investigated using stable environmental isotopes δ¹⁸O and δ²H and radioactive tritium (³H) coupled with conservative chloride measurements. Stable isotopic signatures are encoded in the groundwater solely from summer rainfall. Thus, groundwater recharge occurs predominantly in the summer months from late June to early September during the major Ethiopian rainy season. Winter recharge is lost through high evaporation–evapotranspiration within the unsaturated zone after relatively long dry periods of high accumulated soil moisture deficits. Chloride mass balance coupled with the isotope results demonstrates the presence of both preferential and piston flow groundwater recharge mechanisms. The stable and radioactive isotope measurements further revealed that groundwater in the Akaki catchment is found to be compartmentalized into zones. Groundwater mixing following the flow paths and topography is complicated by the lithologic complexity. An uncommon, highly depleted stable isotope and zero‐³H groundwater, observed in a nearly east–west stretch through the central sector of the catchment, is coincident with the Filwoha Fault zone. Here, deep circulating meteoric water has lost its isotopic content through exchange reactions with CO₂ originating at deeper sources or it has been recharged with precipitation from a different rainfall regime with a depleted isotopic content. Copyright © 2006 John Wiley & Sons, Ltd.     

Groundwater recharge in an arid grassland as indicated by soil chloride profile and multiple tracers

Previous studies have shown that shallow groundwater in arid regions is often not in equilibrium with near‐surface boundary conditions due to human activities and climate change. This is especially the case where the unsaturated zone is thick and recharge rate is limited. Under this nonequilibrium condition, the unsaturated zone solute profile plays an important role in estimating recent diffuse recharge in arid environments. This paper combines evaluation of the thick unsaturated zone with the saturated zone to investigate the groundwater recharge of a grassland in the arid western Ordos Basin, NW China, using the soil chloride profiles and multiple tracers (²H, ¹⁸O, ¹³C, ¹⁴C, and water chemistry) of groundwater. Whereas conventional water balance and Darcy flux measurements usually involve large errors in recharge estimations for arid areas, chloride mass balance has been widely and generally successfully used. The results show that the present diffuse recharge beneath the grassland is 0.11–0.32 mm/year, based on the chloride mass balance of seven soil profiles. The chloride accumulation age is approximately 2,500 years at a depth of 13 m in the unsaturated zone. The average Cl content in soil moisture in the upper 13 m of the unsaturated zone ranges from 2,842 to 7,856 mg/L, whereas the shallow groundwater Cl content ranges from 95 to 351 mg/L. The corrected ¹⁴C age of shallow groundwater ranges from 4,327 to 29,708 years. Stable isotopes show that the shallow groundwater is unrelated to modern precipitation. The shallow groundwater was recharged during the cold and wet phases of the Late Pleistocene and Holocene humid phase based on palaeoclimate, and consequently, the groundwater resources are nonrenewable. Due to the limited recharge rate and thick unsaturated zone, the present shallow groundwater has not been in hydraulic equilibrium with near‐surface boundary conditions in the past 2,500 years.     

Origin of sulphate in the unsaturated zone and groundwater of a loess aquifer

The use of the sulphate mass balance (SMB) between precipitation and soil water as a supplementary method to estimate the diffuse recharge rate assumes that the sulphate in soil water originated entirely from atmospheric deposition; however, the origin of sulphate in soil and groundwater is often unclear, especially in loess aquifers. This study analysed the sulphur (δ³⁴S-SO₄) and oxygen (δ¹⁸O-SO₄) isotopes of sulphate in precipitation, water-extractable soil water, and shallow groundwater samples and used these data along with hydrochemical data to determine the sources of sulphate in the thick unsaturated zone and groundwater of a loess aquifer. The results suggest that sulphate in groundwater mainly originated from old precipitation. When precipitation percolates through the unsaturated zone to recharge groundwater, sulphates were rarely dissolved due to the formation of CaCO₃ film on the surface of sulphate minerals. The water-extractable sulphate in the deep unsaturated zone (>10 m) was mainly derived from the dissolution of evaporite minerals and there was no oxidation of sulphide minerals during the extraction of soil water by elutriating soil samples with deionized water. The water-extractable concentration of SO₄ was not representative of the actual SO₄ concentration in mobile soil water. Therefore, the recharge rate cannot be estimated by the SMB method using the water-extractable concentration of SO₄ in the loess areas. This study is important for identifying sulphate sources and clarifying the proper method for estimating the recharge rate in loess aquifers.     

Soil profile evolution following land‐use change: implications for groundwater quantity and quality

Soil and vadose zone profiles are used as an archive of changes in groundwater recharge and water quality following changes in land use in an area of the Loess Plateau of China. A typical rain‐fed loess‐terrace agriculture region in Hequan, Guyuan, is taken as an example, and multiple tracers (chloride mass balance, stable isotopes, tritium and water chemistry) are used to examine groundwater recharge mechanisms and to evaluate soil water chloride as an archive for recharge rate and water quality. Results show that groundwater recharge beneath natural uncultivated grassland, used as a baseline, is about 94–100 mm year^?1 and that the time it takes for annual precipitation to reach water table through the thick unsaturated zone is from decades to hundreds of years (tritium free). This recharge rate is 2–3 orders of magnitude more than in the other semiarid areas with similar annual rainfall but with deep‐rooted vegetation and relatively high temperature. Most of the water that eventually becomes recharge originally infiltrated in the summer months. The conversion from native grassland to winter wheat has reduced groundwater recharge by 42–50% (50–55 mm year^?1 for recharge), and the conversion from winter wheat to alfalfa resulted in a significant chloride accumulation in the upper soil zone, which terminated deep drainage. The paper also evaluates the time lag between potential recharge and actual recharge to aquifer and between increase in solute concentration in soil moisture and that in the aquifer following land‐use change due to the deep unsaturated zone. Copyright © 2012 John Wiley & Sons, Ltd.     

Storage,mixing, and fluxes of water in the critical zone across northern environments inferred by stable isotopes of soil water

Quantifying soil water storage, mixing, and release via recharge, transpiration, and evaporation is essential for a better understanding of critical zone processes. Here, we integrate stable isotope (²H and ¹⁸O of soil water, precipitation, and groundwater) and hydrometric (soil moisture) data from 5 long‐term experimental catchments along a hydroclimatic gradient across northern latitudes: Dry Creek (USA), Bruntland Burn (Scotland), Dorset (Canada), Krycklan (Sweden), and Wolf Creek (Canada). Within each catchment, 6 to 11 isotope sampling campaigns occurred at 2 to 4 sampling locations over at least 1 year. Analysis for ²H and ¹⁸O in the bulk pore water was done for >2,500 soil samples either by cryogenic extraction (Dry Creek) or by direct equilibration (other sites). The results showed a similar general pattern that soil water isotope variability reflected the seasonality of the precipitation input signal. However, pronounced differences among sampling locations occurred regarding the isotopic fractionation due to evaporation. We found that antecedent precipitation volumes mainly governed the fractionation signal, temperature and evaporation rates were of secondary importance, and soil moisture played only a minor role in the variability of soil water evaporation fractionation across the hydroclimatic gradient. We further observed that soil waters beneath conifer trees were more fractionated than beneath heather shrubs or red oak trees, indicating higher soil evaporation rates in coniferous forests. Sampling locations closer to streams were more damped and depleted in their stable isotopic composition than hillslope sites, revealing increased subsurface mixing towards the saturated zone and a preferential recharge of winter precipitation. Bulk soil waters generally comprised a high share of waters older than 14 days, which indicates that the water in soil pores are usually not fully replaced by recent infiltration events. The presented stable isotope data of soil water were, thus, a useful tool to track the spatial variability of water fluxes within and from the critical zone. Such data provide invaluable information to improve the representation of critical zone processes in spatially distributed hydrological models.     

Advantages and challenges of using soil water isotopes to assess groundwater recharge dominated by snowmelt at a field study located in Canada

Seasonal signals of stable isotopes in precipitation, combined with measurements of isotope ratios in soil water, can be used for quantitative estimation of groundwater recharge rates. This study investigates the applicability of using the piston flow principle and the peak shift displacement method to estimate actual groundwater recharge rates in a humid Nordic region located in the province of Quebec, Canada. Two different sites with and without vegetation (C1 and C2) in an unconfined aquifer were tested by measuring soil water isotope ratios (¹⁸O/¹⁶O and ²H/¹H) and volumetric pore water content. Core samples were obtained along the vadose zone down to the groundwater table at the two sites (2.45 m for Site C1 and 4.15 m for Site C2). The peak shift method to estimate groundwater recharge rates was shown to be accurate only in certain specific conditions inherent to the soil properties and the topographical situation of the investigated sites. Indeed, at Site C2, recharge from the snowmelt could not be estimated because of heterogeneity in the lower part of the vadose zone. At this same site the later recharge after the snowmelt (in the period from late spring to early autumn) could be estimated accurately because the upper part of the vadose zone was homogeneous. Furthermore, at site C1, runoff/runon phenomena hampered calculations of actual infiltration and thus produced inaccurate results for recharge. These two different site effects (heterogeneity in the first site and runoff/runon in the other site) were identified as being limiting factors in the accurate assessment of actual recharge. This study therefore recommends the use of the peak shift method for (1) humid Nordic regions, (2) homogeneous and thick vadose zones, and (3) areas with few or limited site effects (runoff/runon).     

Possible soil tension controls on the isotopic equilibrium fractionation factor for evaporation from soil

The stable isotopes of hydrogen and oxygen (δ²H and δ¹⁸O) are useful conservative tracers for tracking the movement of water in soil. But although the tracking of water infiltrating through the soil profile and its movement as run‐off and groundwater recharge are well developed, water movement through the soil can also include evaporative fractionation. Soil water fractionation factors have, until now, been largely empirical. Unlike open water evaporation where temperature, humidity, and vapour pressure gradient define fractionation, soil water evaporation includes fractionation by soil matrix effects. These effects are still poorly characterized. Here, we present preliminary results from a simple laboratory experiment with four soil admixtures with grain sizes that range from sand to silt and clay. Our results show that soil tension seems to control the isotope fractionation of resident soil water. The relationship between soil tension and equilibrium fractionation appears to be independent of soil texture and appears well supported by thermodynamic theory. Although these results are preliminary, they suggest that future work should go after soil tension effects as a possible explanatory factor of soil water and water vapour fractionation.     

Evaluation of the soil water balance in an alluvial flood plain with a shallow groundwater table

Abstract

Many of the hydrological and ecological functions of alluvial flood plains within watersheds depend on the water flow exchanges between the vadoze soil zone and the shallow groundwater. The water balance of the soil in the flood plain is investigated, in order to evaluate the main hydrological processes that underlie the temporal dynamics of soil moisture and groundwater levels. The soil moisture and the groundwater level in the flood plain were monitored continuously for a three-year period. These data were integrated with the results derived from applying a physically-based numerical model which simulated the variably-saturated vertical water flow in the soil. The analysis indicated that the simultaneous processes of lateral groundwater flow and the vertical recharge from the unsaturated zone caused the observed water table fluctuations. The importance of these flows in determining the rises in the water table varied, depending on soil moisture and groundwater depth before precipitation. The monitoring period included two hydrological years (September 2009–September 2011). About 13% of the precipitation vertically recharged the groundwater in the first year and about 50% in the second. The difference in the two recharge coefficients was in part due to the lower groundwater levels in the recharge season of the first hydrological year, compared to those observed in the second. In the latter year, the shallow groundwater increased the soil moisture in the unsaturated zone due to capillary rise, and so the mean hydraulic conductivity of the unsaturated soil was high. This moisture state of soil favoured a more efficient conversion of infiltrated precipitation into vertical groundwater recharge. The results show that groundwater dynamics in the flood plain are an important source of temporal variability in soil moisture and vertical recharge processes, and this variability must be properly taken into account when the water balance is investigated in shallow groundwater environments.

Citation Pirastru, M. and Niedda, M., 2013. Evaluation of the soil water balance in an alluvial flood plain with a shallow groundwater table. Hydrological Sciences Journal, 58 (4), 898–911.     

Groundwater recharge estimation from ephemeral streams. Case study: Wadi Tabalah,Saudi Arabia

Estimation of groundwater recharge to an unconfined aquifer is studied using analytical and numerical techniques and results are compared with field observations. There is an acute need for such estimation in water balance studies in arid climates, and the case study in this paper is for such a region. The wetting front movement in the unsaturated zone depends on antecedent soil moisture, the ponded water depth and its duration, and on the position of the water table and the hydraulic properties of the unsaturated zone. A hydraulic connection between the recharge basin and the aquifer is not immediately established because the wetting front is unsaturated. A numerical model is applied to estimate recharge in an arid-zone wadi, and its validity is tested by comparing it with an analytical solution of the equations. The calculated recharge values matched the piezometric levels observed at a well site at the edge of the wadi channel. The total recharge depths found by integration in the time domain provided a good estimate of the transmitted volume of water per unit length of wadi channel. The findings were confirmed by runoff volume measurements at gauging stations located in the basin. © 1997 John Wiley & Sons, Ltd.     

Importance of river water recharge to the San Joaquin Valley groundwater system

Groundwater is not a sustainable resource, unless abstraction is balanced by recharge. Identifying the sources of recharge in a groundwater basin is critical for sustainable groundwater management. We studied the importance of river water recharge to groundwater in the south‐eastern San Joaquin Valley (24,000 km², population 4 million). We combined dissolved noble gas concentrations, stable isotopes, tritium, and carbon‐14 analyses to analyse the sources, mechanisms, and timescales of groundwater recharge. Area‐representative groundwater sampling and numerical model input data enabled a stable isotope mass balance and quantitative estimates of river and local recharge. River recharge, identified by a lighter stable isotope signature, represents 47 ± 4% of modern groundwater in the San Joaquin Valley (recharged after 1950) but only 26 ± 4% of premodern groundwater (recharged before 1950). This implies that the importance of river water recharge in the San Joaquin valley has nearly doubled and is likely the result of a 40% increase in total recharge, caused by river water irrigation return flows and increased stream depletion and river recharge due to groundwater pumping. Compared with the large and long‐duration capacity for water storage in the subsurface, storage of water in rivers is limited in time and volume, as evidenced by cold river recharge temperatures resulting from fast infiltration and recharge. Groundwater banking of seasonal surface water flows and expansion of managed aquifer recharge practices therefore appear to be a natural and promising method for increasing the resilience of the San Joaquin Valley water supply system.     

Modelling the effects of soil type and root distribution on shallow groundwater resources

Vegetated, shallow groundwater environments typically have high environmental and economic value. A sound understanding of the complex interactions and feedbacks between surface vegetation and groundwater resources is crucial to managing and maintaining healthy ecosystems while responding to human needs. A vegetated shallow groundwater environment was modelled using the software HYDRUS 2D to investigate the effects of several combinations of soil type and root distributions on shallow groundwater resources. Three rainfall regimes coupled to both natural and anthropogenically affected groundwater conditions were used to investigate the effect that combinations of four soil types and five root distributions can have on (a) groundwater level drops, (b) groundwater depletion, (c) groundwater recharge and (d) water stress conditions. Vegetation with roots distributed across the whole unsaturated zone and vegetation with dimorphic root systems (i.e. roots having larger concentrations both near the surface and the capillary fringe) behaved differently from vegetation growing roots mainly near the saturated zone. Specifically, vegetation with roots in the unsaturated zone caused water‐table drops and groundwater depletions that were half the amount due to deep‐rooted vegetation. Vegetation with a large portion of roots near the soil surface benefited from rainfall and was less vulnerable to water‐table lowering; as such, the fraction of the total area of roots affected by water stress conditions could be 40% smaller than in the case with deep‐rooted vegetation. However, roots uniformly distributed in the unsaturated zone could halve groundwater recharge rates observed in bare soils. Our analysis provided insights that can enable the formulation of site‐ and purpose‐specific management plans to respond to both human and ecosystem water requirements. Copyright © 2015 John Wiley & Sons, Ltd.     

Groundwater recharge sources in semiarid irrigated mountain fronts

High-elevation mountains often constitute for basins important groundwater recharge sources through mountain-front recharge processes. These processes include streamflow losses and subsurface inflow from the mountain block. However, another key recharge process is from irrigation practices, where mountain streamflow is distributed across the irrigated piedmont. In this study, coupled groundwater fluctuation measurements and environmental tracers (¹⁸O, ²H, and major ions) were used to identify and compare the natural mountain-front recharge to the anthropogenically induced irrigation recharge. Within the High Atlas mountain front of the Ourika Basin, Central Morocco, the groundwater fluctuation mapping from the dry to wet season showed that recharge beneath the irrigated area was higher than the recharge along the streambed. Irrigation practices in the region divert more than 65% of the stream water, thereby reducing the potential for in-stream groundwater recharge. In addition, the irrigation areas close to the mountain front had greater water table increases (up to 3.5 m) compared with the downstream irrigation areas (<1 m increase). Upstream crops have priority to irrigation with stream water over downstream areas. The latter are only irrigated via stream water during large flood events and are otherwise supplemented by groundwater resources. These changes in water resources used for irrigation practices between upstream and downstream areas are reflected in the spatiotemporal evolution of the stable isotopes of groundwater. In the upstream irrigation area, the groundwater stable isotope values (δ¹⁸O: −8.4‰ to −7.4‰) reflect recharge by the diverted stream water. In the downstream irrigation area, the groundwater isotope values are lower (δ¹⁸O: −8.1‰ to −8.4‰) due to recharge via the flood water. In the nonirrigation area, the groundwater has the highest stable isotope values (δ¹⁸O: −6.8‰ to −4.8‰). This might be due to recharge via subsurface inflow from the mountain block to the mountain front and/or recharge via local low altitude rainfall. These findings highlight that irrigation practices can result in the dominant mountain-front recharge process for groundwater.     

Characteristics of chemistry and stable isotopes in groundwater of Chaobai and Yongding River basin,North China Plain

To identify the groundwater flow system in the North China Plain, the chemical and stable isotopes of the groundwater and surface water were analysed along the Chaobai River and Yongding River basin. According to the field survey, the study area in the North China Plain was classified hydrogeologically into three parts: mountain, piedmont alluvial fan and lowland areas. The change of electrical conductance and pH values coincided with groundwater flow from mountain to lowland areas. The following groundwater types are recognized: Ca? HCO₃ and Ca? Mg? HCO₃ in mountain areas, Ca? Mg? HCO₃ and Na? K? HCO₃ in piedmont alluvial fan areas, and HCO₃? Na in lowland areas. The stable isotope distribution of groundwater in the study area also has a good corresponding relation with other chemical characteristics. Stable isotope signatures reveal a major recharge from precipitation and surface water in the mountain areas. Chemical and stable isotope analysis data suggest that mountain and piedmont alluvial fan areas were the major recharge zones and the lowland areas belong to the main discharge zone. Precipitation and surface water were the major sources for groundwater in the North China Plain. Stable isotopic enrichment of groundwater near the dam area in front of the piedmont alluvial fan areas shows that the dam water infiltrated to the ground after evaporation. As a result, from the stable isotope analysis, isotope value of groundwater tends to deplete from sea level (horizontal ground surface) to both top of the mountain and the bottom of the lowland areas in symmetrically. This suggests that groundwater in the study area is controlled by the altitude effect. Shallow groundwater in the study area belongs to the local flow system and deep groundwater part of the regional flow system. Copyright © 2007 John Wiley & Sons, Ltd.     

The groundwater recharge regime of some slightly metamorphosed neoproterozoic sedimentary rocks: an application of natural environmental tracers

Isotope data of precipitation and groundwater in parts of the Voltaian Basin in Northern Ghana were used to explain the groundwater recharge regime in the area. Groundwater recharge is an important parameter in the development of a decision support system for the management and efficient utilization of groundwater resources in the area. It is therefore important to establish the processes and sources of groundwater recharge. δ¹⁸O and δ²H data for local precipitation suggest enrichment relative to the Global Meteoric Water Line (GMWL) and indicate that precipitation takes place at a relative humidity less than 100%. The groundwater data plot on an evaporation line with a slope of 5, suggesting a high degree of evaporative enrichment of the precipitation in the process of vertical infiltration and percolation through the unsaturated zone into the saturated zone. This finding is consistent with the observation of high evapotranspiration rates in the area and ties in with the fact that significant clay fraction in the unsaturated zone limits vertical percolation and thus exposes the percolating rainwater to the effects of high temperatures and low humidities resulting in high evapotranspiration rates. Groundwater recharge estimates from the chloride mass balance, CMB, method suggest recharge in the range of 1.8–32% of the annual average precipitation in the form of rainfall. The highest rates are associated with areas where open wells encourage significant amount of groundwater recharge from precipitation in the area. In the northern parts of the study area, groundwater recharge is lower than 12%. The recharge so computed through the application of the CMB methodology takes on a spatial distribution akin to the converse of the spatial pattern of both δ¹⁸O and δ²H in the area. As such, the locations of the highest recharge are associated with the most depleted values of the two isotopes. This observation is consistent with the assertion that low vertical hydraulic conductivities slow down vertical percolation of precipitation down to the groundwater water. The percolating precipitation water thus gets enriched in the heavier isotopes through high evapotranspiration rates. At the same time, the amount of water that finally reaches the water table is considerably reduced. Copyright © 2013 John Wiley & Sons, Ltd.     

Nitrate transport in the unsaturated zone: a case study of the riverbank filtration system Karany,Czech Republic

Nitrate transport in the unsaturated zone of a riverbank filtration (RBF) system in Karany, Czech Republic, was studied. Previous study of the system estimated RBF recharge as 60% riverbank filtrate and 40% local groundwater contaminated by nitrates. Nitrate concentrations observed in RBF recently cannot be explained by simple groundwater contamination and a new conception of groundwater recharge is suggested. A two‐component model based on water ¹⁸O data modelled recharge of local groundwater. One component of groundwater recharge is rainfall and irrigation water moving through the unsaturated zone of the Quaternary sediments in piston flow. The second component is groundwater from the Cretaceous deposits with a free water table. Both the components of groundwater recharge have different nitrate concentrations, and resulting contamination of groundwater depends on the participation of water from Quaternary and Cretaceous deposits. Nitrates' origins and their mixing in the subsurface were traced by ¹⁵N data. Nitrate transport from the unsaturated zone is important and time variable source of groundwater contamination. Copyright © 2011 John Wiley & Sons, Ltd.     

Contribution of storms to groundwater recharge in the semi‐arid region of Karnataka,India

This paper describes the application of environmental isotopes and injected tracer techniques in estimating the contribution of storms as well as annual precipitation to groundwater recharge and its circulation, in the semi‐arid region of Bagepalli, Kolar district, Karnataka. Environmental isotopes ²H, ¹⁸O and ³H were used to study the effect of storms on the hydrological system, and an isotope balance was used to compute the contribution of a storm component to the groundwater. Some of the groundwater samples collected during the post‐storm periods were highly depleted in stable isotope content with higher deuterium excess relative to groundwater from the pre‐storm periods. Significant variation in deuterium excess in groundwater from the same area, collected in two different periods, indicates the different origin of air masses. The estimated recharge component of a storm event of 600 mm to the groundwater was found to be in the range of 117–165 mm. There was no significant variation in environmental tritium content of post‐storm and pre‐storm groundwater, indicating the fast circulation of groundwater in the system. After completion of the environmental isotope work, an injected radiotracer ³H technique was applied to estimate the direct recharge of total precipitation to the groundwater. The estimated recharge to the groundwater is 33 mm of the 550 mm annual precipitation during 1992. Copyright © 2003 John Wiley & Sons, Ltd.     

Recharge processes during snowmelt: An isotopic and hydrometric investigation

Results from hydrometric and isotopic investigations of unsaturated flow during snowmelt are presented for a hillslope underlain by well-sorted sands. Passage of melt and rainwater through the vadose zone was detected from temporal changes in soil water ²H concentrations obtained from sequential soil cores. Bypassing flow was indicated during the initial snowmelt phase, but was confined to the near-surface zone. Recharge below this zone was via translatory flow, as meltwater inputs displaced premelt soil water. Estimates of premelt water fluxes indicate that up to 19 per cent of the premelt soil water may have been immobile. Average water particle velocities during snowmelt ranged from 6.2 × 10^?7 to 1.1 × 10^?6 ms^?1, suggesting that direct groundwater recharge by meltwater during snowmelt was confined to areas where the premelt water table was within 1 m of the ground surface. Soil water ²H signatures showed a rapid response to isotopically-heavy rain-on-snow inputs late in the melt. In addition, spatial variations in soil moisture content at a given depth induced a pronounced lateral component to the predominantly vertical transport of water. Both factors may complicate isotopic profiles in the vadose zone, and should be considered when employing environmental isotopes to infer recharge processes during snowmelt.