Geochemistry of Heavy Oil in the T Block, Oriente Basin and its Origin

<正>Exploration and development experience show that there is obvious oil gravity difference between the southern part and northern part of the"M1"reservoir in the Fanny oil field in the slope of the Oriente Basin,Ecuador.The American Petroleum Institute Gravity(API) values of oils in the northern part are higher than the one in the southern part of the Fanny oil field,with the values of 20°and 10.0°-13.0°,respectively.So the primary purpose of this study was to analyze the heavy oil characteristics of biodegradation and the oil-oil correlation according to the biomarker data and theδ~(13)C signature of oil samples from T block.The results of the hydrocarbon gas chromatography fingermark and the inversion attribute characteristics indicated that there are fluid compartments between the"M1"reservoir of Fanny south.Finally,the models of oil-gas accumulation under the control of multiple-activities of complicated fault systems,as well as the origin of heavy oil,are contended.The early stage oils from the western part of the basin were biodegraded heavily in varying degrees in the whole basin,and the later stage oils were derived from the southern part in a large scale and were mature and lighter.Generally,oil mixing is the primary control of net oil properties,such as API gravity in Oriente Basin.We therefore predicted that the API gravity variation of oil pools radically depends on the injection amount of the later stage oil.Because of the shale barrier in the"M1"reservoir of Fanny south,the later stage hydrocarbon could not pass through and contribute to increase the oil API value.     

Delineating compositional variabilities among crude oils from Central Montana, USA, using light hydrocarbon and biomarker characteristics

Three compositionally distinctive groups of oils identified in central Montana by biomarker analyses are also recognized by the unique compositions of their light hydrocarbon (gasoline range) fraction. The majority of oils produced from Paleozoic pools (Pennsylvanian Tyler–Amsden interval) group into one broad category based on the distribution of C₂₀–C₄₀ biomarkers. These oils not only have the lowest Paraffin Indices and relative concentrations of normal heptane, but are readily distinguishable from the other compositional groups by using selected “Mango” parameters. However, the biomarker-based subdivision of this group into at least two sub-families is not reflected in the gasoline range fraction, suggesting little effect of source rock host lithology on the distribution of C₅–C₈ hydrocarbons. Oils occurring predominantly in Jurassic–Cretaceous reservoirs display different biomarker and gasoline range characteristics, including Paraffin Indices, K1 parameter and relative concentrations of C₇ compounds, and are classified in two separate compositional categories. In contrast to oils from the Tyler–Amsden interval, the oils produced from the Mesozoic strata are amongst the most mature oils in the study area. The unique biomarker/light hydrocarbon signatures are likely due to different source organic matter. Secondary alteration of oil due to biodegradation and migration, although recognized, appears less significant. The results indicate the overall usefulness of gasoline range compositions in delineating compositional affinities of crude oils in central Montana, clearly suggesting that the oils found in Paleozoic and Mesozoic reservoirs belong to different petroleum systems.     

微生物降解有机物的碳氢同位素分馏研究进展

微生物降解使有机化合物的稳定碳、氢同位素发生不同程度分馏的研究在有机污染物来源和微生物环境修复等领域取得了长足进展,并对原油和天然气微生物降解研究有借鉴意义。微生物作用下的同位素分馏为动力同位素分馏,导致重同位素在残余物中富集。影响微生物降解有机物同位素分馏的主要因素有微生物的降解代谢途径、辅酶作用、降解类型与程度、同位素质量差异和有机物碳数等。不同的微生物代谢途径代表不同的生物化学反应,造成了同位素分馏的显著差异;辅酶对反应的催化作用使微生物作用造成的同位素分馏更加复杂。低碳数正构烷烃遭受微生物降解程度越高,碳、氢同位素的分馏也越大,同位素变重与降解程度之间有明显的相关性。但对于复杂化合物,由于降解的多级反应,同位素分馏与降解程度间的相关性并不明显。在同样降解程度下,氢同位素分馏大于碳同位素分馏,低碳数正构烷烃的同位素分馏大于高碳数正构烷烃的同位素分馏。     

南海陆缘盆地构造演化与烃源岩特征

受近南北向扩张机制控制,南海陆缘盆地或凹陷多呈NE向带状展布,总体上具有“南三北三”平行排列、外窄内宽的特点。新生代发生的4次重要区域构造运动具有穿时性,共发育3期盆地破裂不整合面,分别是早渐新世与晚渐新世之间、古近纪与新近纪之间、中中新世与晚中新世之间;由东往西,盆地破裂不整合面的时代逐渐变新。受构造运动与海平面升降影响,南海海域发育湖相、海陆过渡相和陆源海相3类烃源岩。由南北两侧向中央海盆,烃源岩类型由湖相逐渐过渡到海陆过渡相与陆源海相;从东向西,盆地主力烃源岩层位逐渐变新,由始新统-渐新统逐渐过渡到渐新统-中新统。南海海域烃源岩的分布规律与盆地破裂不整面存在密切关系:破裂不整合面形成早（早渐新世与晚渐新世之间）的盆地,主力烃源岩形成早（始新统湖相烃源岩）;反之,破裂不整合面形成晚（中中新世与晚中新世之间）的盆地,则烃源岩形成晚（渐新统-中新统海陆过渡相到陆源海相烃源岩）。     

Improved assessment of biodegradation extent and prediction of petroleum quality

Biodegradation of crude oil causes volumetrically important compositional changes, which lead to significant deterioration in quality, in particular during the early stages of alteration. To better understand these effects we focussed on a detailed assessment of light to moderate levels of alteration. We investigated a suite of 40 crude oil samples from five different petroleum systems to evaluate the extent of alteration occurring in reservoirs. Based on a comprehensive geochemical characterization, five individual crude oil sequences were defined, where compositional variability is mainly due to microbial activity in the reservoir. In particular, samples from the Gullfaks field (offshore Norway) and from a petroleum system offshore Angola illustrate that conventional molecular biodegradation parameters, such as the Pr/n-C₁₇ and Ph/n-C₁₈ alkane ratios are not suitable for defining the extent of biodegradation in petroleum reservoirs. Here, we suggest a new molecular biodegradation parameter, the degradative loss, that can be used to quantify depletion in individual crude oil constituents. The approach allows improved assessment of the extent of biodegradation in crude oil samples by means of the mean degradative loss. It is demonstrated that crude oil quality, as assessed from API gravity, can be predicted directly from the molecular composition of crude oils. Our data clearly indicate that the degradation patterns of light hydrocarbons and n-alkanes differ in different petroleum systems. This suggests that microbial communities are different and therefore generate different molecular degradation patterns which have to be evaluated individually for each system.     

Assessment of petroleum biodegradation using stable hydrogen isotopes of individual saturated hydrocarbon and polycyclic aromatic hydrocarbon distributions in oils from the Upper Indus Basin,Pakistan

The stable hydrogen isotopic compositions (δD) of selected aliphatic hydrocarbons (n-alkanes and isoprenoids) in eight crude oils of similar source and thermal maturity from the Upper Indus Basin (Pakistan) were measured. The oils are derived from a source rock deposited in a shallow marine environment. The low level of biodegradation under natural reservoir conditions was established on the basis of biomarker and aromatic hydrocarbon distributions. A plot of pristane/n-C₁₇ alkane (Pr/n-C₁₇) and/or phytane/n-C₁₈ alkane (Ph/n-C₁₈) ratios against American Petroleum Institute (API) gravity shows an inverse correlation. High Pr/n-C₁₇ and Ph/n-C₁₈ values and low API gravity values in some of the oils are consistent with relatively low levels of biodegradation. For the same oils, δD values for the n-alkanes relative to the isoprenoids are enriched in deuterium (D). The data are consistent with the removal of D-depleted low molecular weight (LMW) n-alkanes (C₁₄–C₂₂) from the oils. The δD values of isoprenoids do not change with progressive biodegradation and are similar for all the samples. The average D enrichment for n-alkanes with respect to the isoprenoids is found to be as much as 35‰ for the most biodegraded sample. For example, the moderately biodegraded oils show an unresolved complex mixture (UCM), loss of LMW n-alkanes (<C₁₅) and moderate changes in the alkyl naphthalene distributions. The relative susceptibility of alkyl naphthalenes at low levels of biodegradation is discussed. The alkyl naphthalene biodegradation ratios were determined to assess the effect of biodegradation. The dimethyl, trimethyl and tetramethyl naphthalene biodegradation ratios show significant differences with increasing extent of biodegradation.     

Geochemical characteristics of saturate hydrocarbons in crude oils and source rocks of the Qaidam, Tarim, Tupran basins, NW China

Based on the systematic analyses of fifteen typical crude oils and ten typical potential source rocks col-lected from the Qaidam,Tarim and Turpan basins,Northwest China,the geochemical characteristics of the oils and source rocks were investigated and oil-source rock correlations undertaken.The oils and source rocks deposited in saline lacustrine environment from the western Qaidam Basin were characterized by n-alkanes with even car-bon-number preference in the C20-C28 range,low pristane/phytane(Pr/Ph) ratios(less than 0.5),and high abundances of C27 steranes,gammacerane and C35 hopanes.The oils and source rocks deposited in marine environment from the Tarim Basin were characterized by n-alkanes with even carbon-number preference in the C14-C18 range,relatively low Pr/Ph ratios(near to 1),high abundance of C28 steranes,and relatively high gammacerane.In contrast,the oils and source rocks deposited in terrigenous bog environment from the Turpan Basin were characterized by relatively high Pr/Ph ratios(oil samples greater than 6) high abundance of C29 steranes,and relatively low gammacerane and C31-35 hopanes.The higher amounts of C37 and C38 n-alkanes of source rocks from the western Qaidam Basin and the Tarim Basin suggest an origin of these alkanes from functionalized C37 and C38 n-alkadienes and alkenones in prymnesiophytes living in lacustrine and marine environments.Oil-source rock correlations suggest oils in the west-ern Qaidam Basin were derived from the Oligocene Lower Ganchaigou Formation(E3),oils in the Tabei and Tazhong uplifts from the Tarim Basin have a genetic relationship with the Middle-Upper Ordovician source beds.Oils in the Turpan Basin generally fall into two genetic types.Most oils in the Taibei depression from the Turpan Basin were derived from the Lower-Middle Jurassic coal measures,but the fewer oils in this region are a mixed source derived from the Lower-Middle Jurassic coal measure and the Upper Permian source rocks.     

Thermal controls on biodegradation around the Peace River tar sands: Paleo-pasteurization to the west

Bitumens of the Alberta tar sands share a similar primary source rock, but exhibit varying levels of degradation. In the Peace River tar sands area, the wide range of API gravity and sulphur content in Lower Cretaceous reservoirs is investigated in terms of biodegradation processes, using detailed geochemical analyses, burial history modelling and charge/degrade modelling. Decreasing tar sand degradation to the west can be attributed to increasing reservoir temperatures which retard biodegradation. Gething oils west of the Peace River tar sands are derived from the same source, but are minimally degraded due to reservoir pasteurization at 80 °C shortly after charging. Long charge times, reservoir filling and possibly compositional or very low temperature degradation retardation have limited biodegradation of the Alberta tar sands despite long oil residence times and low reservoir temperatures.     

渤海湾盆地临南地区有效油气运聚系统分析

临南地区原油来源于临南洼陷沙三段富有机质成熟烃源岩,其中部分原油受到轻微的生物降解和水洗作用。根据轻烃、生物标志物组成及油源对比结果,将临南洼陷分为南北两个油源区,在渐新世末和中新世末两期油气运聚过程中,形成了四个有效油气运聚系统。各运聚系统的油气沿一定主导方向运移,除已知油田外,位于该主导方向上的曲堤地垒是有利勘探方向。     

含油流体包裹体：地球化学分析与地质应用

利用含油流体包裹体可以获得与原油和源区常规分析同等质量的可靠地球化学数据。细致而又小心谨慎地对待各测试步骤(如样品清洗、背景空白等)是成功进行包裹体油气成分分析的基础。从技术上来说，每一分析步骤都具有挑战性，但如果我们能按步骤循序渐进，就不仅能够分析那些含有大量石油包裹体的样品(如当今或古油藏样品)，而且可以测试含极少量石油包裹体的样品(如迁移路径或极古老岩石样品)。包裹体中可被测试的碳氢化合物多种多样，包括低分子量的碳氢化合物、n-链烷、类异戊二烯、生物标志物、芳香族碳氢化合物等。流体包裹体内石油成分分析在地质上有广泛应用，比如可以更好地重建储集区石油重注史、确定盆地中以前未知的活性源岩。在储集区内由生物降解造成的石油再造和(或)水洗作用经常被抹去，流体包襄体分析则可以解释储集区复杂成油阶段，当然更可以去除钻孔泥浆添加剂或其他污染物的影响。此外，也可以获知地球早期生物圈碳氢化合物的组成及多样性，以及在勘探区或盆地进行二次迁移路径填图。     

孟加拉湾盆地构造特征与动力学演化:来自卫星重力与地震资料的新认识

为了揭示孟加拉湾盆地的构造特征和中生代以来的动力学演化,对研究区卫星重力数据进行滤波、梯度和延拓等深度处理,对相关地震剖面进行标准化处理,在研究区建立了8条主干剖面.自由空气重力异常及其深度处理结果显示在盆地西部、海岭内部及盆地东部分别发育北西向破碎带、近东西向断裂和北东向线性构造,分别反映了海底北西向扩张、海岭侵位及印度洋洋壳北东向俯冲的影响.主干剖面经标准化处理后划分出上白垩统-第四系5套层系,结合重力异常与地层厚度,将孟加拉湾盆地划分为西部坳陷、85°E海岭隆起、中央坳陷、90°E海岭隆起和若开坳陷5个构造单元.85°E海岭隆起内发育的多个孤立高隆起是热点幕式喷发的响应,控制着碰撞前盆地“西厚东薄”的沉积格局,而碰撞后孟加拉扇体系在始新世至中新世期间一直向南迁移,未受到海岭的明显影响.90°E海岭南段(7°~14°N)的俯冲消减促进了安达曼增生楔的向西生长,北段(14°~20°N)的俯冲作用则控制着若开坳陷、印缅增生楔和孟加拉湾盆地沉积中心的演化.构造特征和动力学演化分析表明盆地经历了原始大洋盆地(晚白垩世-早渐新世)和残留洋盆地(晚渐新世-)2个主要演化阶段.      

Sea-level fluctuations on the northern shelf of the Eastern Paratethys in the Oligocene-Neogene

Sea-level fluctuations in the terminal Eocene, Oligocene, and Neogene of the Eastern Paratethys are quantitatively assessed on the basis of facies and old coastlines traced on the northern platform shelf, levels of river valley incisions, and the study of seismic profiles. The first data massif allows the characterization and correlation of transgression stages in the history of the Eastern Paratethys. The greatest transgressions fall within the first half of the Late Eocene, mid-Early Oligocene, initial Late Oligocene, initial Early Miocene, the initial Tchokrakian, Karaganian and Sarmatian in the Middle Miocene, the middle and late Sarmatian and early Pontian in the Late Miocene, and the Akchagylian in the Caspian basin of the Pliocene. In contrast, the greatest incisions of northern rivers running from the platform allow us to establish the time and extent of the main declines in the base levels of the erosion. Maximal incisions date back to the terminal Eocene-initial Oligocene, terminal Solenovian time in the terminal Rupelian, the terminal Maikop in the Early Miocene, the terminal Sarmatian and middle Pontian in the Late Miocene, and the Early Pliocene in the Caspian basin. Large regressions also formed unconformity surfaces, traced on seismic profiles as erosion boundaries of several orders. The surfaces are confined to the Eocene/Oligocene boundary, middle and late Maikop, Sarmatian/Meotian boundary, middle Pontian, and terminal Miocene-initial Pliocene, as well as being traced even in the most deep-water basins. The synthesis of these data suggests a preliminary version for the curve of transgression-regression cyclicity. Its correlation with the eustatic curve shows their similarity only in the lower part-prior to the initial Middle Miocene, when Paratethys became a semi-closed basin.     

强烈气洗作用导致原油成分变化的定量计算:以库车坳陷天然气藏为例

库车坳陷以产天然气为主,同时产出少量原油和凝析油,油气充注不同步,普遍具有"油早气晚"的特点,晚期大量天然气的侵入,必然对早期聚集的油藏发生改造作用。对气藏中原油成分变化的定量计算和讨论,可为天然气的注入强度定量评价提供直接证据。未遭受气洗的原油,正构烷烃摩尔浓度的对数与相应的碳数呈线性关系,而气洗作用可使轻组分的正构烷烃最先溶解于干气中,并随着天然气继续向前运移,原始油藏中的轻组分正构烷烃大大减少。以此为理论基础,建立了正构烷烃损失的定量计算模型。结果表明克拉2构造原油正构烷烃损失程度最高,平均可达70%左右,大北构造带原油正构烷烃损失程度差异较大,与该地区断块发育有关。气洗作用导致原油正构烷烃减少,而金刚烷、多环芳烃等在天然气中溶解度较低的化合物得以浓缩富集,相对含量大大增加。轻芳烃含量也会随之而增加,原油芳香度增加,石蜡度降低。在模拟实验基础上对气洗程度进行了定量评价,初步估算表明,克拉2构造原油遭受的气洗作用最强,是其他构造带的2～5倍。     

乌兰花凹陷原油特征及成因

乌兰花凹陷是二连盆地南部新发现的富油凹陷,对乌兰花凹陷原油物理性质和地球化学性质进行了系统的分析以揭示其特征及来源。原油物理性质显示,乌兰花凹陷原油比重（API gravity）介于20.2°~40.0°之间,主体为正常原油。原油生物标志化合物参数表明,不同构造带之间原油特征存在差异,可以划分为两类原油。一类以土牧尔构造带原油为主,具有低姥值比（Pr/Ph）和C₂₁/C₂₃三环萜烷,相对较高的伽马蜡烷/C₃₁藿烷和规则甾烷/C₃₀藿烷的特征,原油主要为烃源岩在成熟阶段早期的产物,主要以藻类来源为主。另一类原油包括赛乌苏和红井构造带原油,具有高姥值比（Pr/Ph）和C₂₁/C₂₃三环萜烷,相对较低的伽马蜡烷/C₃₁藿烷和规则甾烷/C₃₀藿烷,主要为陆源有机质和藻类有机质混合来源,原油具有更高的成熟度。原油碳同位素和正构烷烃单体烃碳同位素表明这两类原油应是一套烃源岩在不同成熟阶段的产物,原油主要来源于南洼槽阿尔善组烃源岩。阿尔善组烃源岩的非均质性和成熟度导致了两类原油的差异。      

Demethylated hopanes in crude oils and their applications in petroleum geochemistry

Analyses of some Australian crude oils show that many contain varying concentrations of A/ B-ring demethylated hopanes. These range from C₂₆ to C₃₄ and have been identified from their retention times and mass spectral data as 17α(H)-25-norhopanes. Comparison of hopane and demethylated hopane concentrations and distributions in source-related, biodegraded oils suggests that demethylated hopanes are biotransformation products of the hopanes. Further, it appears that the process occurs at a late stage of biodegradation, after partial degradation of steranes has occurred. Demethylated hopanes are proposed as biomarkers for this stage of severe biodegradation. The presence of these compounds in apparently undegraded crude oils is thought to be due to the presence of biodegraded crude oil residues which have been dissolved by the undegraded crude oil during accumulation in the reservoir sands. The timing of hopane demethylation, relative to the degradation of other compounds, has been assessed and the progressive changes in crude oil composition with increasing extent of biodegradation have been identified. The use of demethylated hopanes as maturity parameters for severely biodegraded crude oils, and the applicability of established biomarker maturity parameters to such oils, are also discussed.     

菲律宾海盆东北部晚始新世以来放射虫及其古海洋学意义

研究了菲律宾海盆东北部“大洋钻探工程”１２５航次７８２Ａ孔晚始新世以来的放射虫化石。根据Ｓａｎｆｉｌｉｐｐｏ等１９８５年的分带,将研究区自下而上划分为１０个带。讨论了始新世与渐新世、渐新世与中新世、中中新世与晚中新世、中新世与上新世以及上新世与第四纪的界线。研究区存在两个沉积间断,分别位于晚渐新世与早中新世晚期之间和中中新世与晚中新世之间。研究区第四纪放射虫化石仍以暖水分子为主,冷水分子分布较浅。依据放射虫化石分异度曲线得出,晚第三纪以来本区存在５个相对暖水期和５个相对较凉期,渐新世时处于冷水期,这与钙质超微化石复合分异度和碳酸钙含量曲线的变化是一致的。晚渐新世与早中新世晚期之间的沉积间断是由于中新世南极冰盖扩展造成大洋底层洋流活动加剧而形成的。     

阿尔金山脉新生代剥露历史——前陆盆地沉积记录

新疆且末县江尕勒萨依盆地位于阿尔金山脉的北西山前,其内连续沉积了中生代一新生代地层。盆地内古新统一始新统为河流相沉积;渐新统至中新统为山麓河流相灰色砾岩和棕色砂岩;上新统为山麓洪积相砾岩夹泥岩;下更新统全为砾岩层。岩性组合特征及其砂岩碎屑、砾石组分变化规律,反映出阿尔金山脉的新生代剥蚀历史：古近纪早、中期,阿尔金山脉的地形高差小,古生界双峰式火山岩首先被剥蚀;至渐新世末一中新世早期,山脉高差加大,基底元古宇开始出露地表被剥蚀;中新世末期,山脉高差进一步加大,剥蚀速率加快;至第四纪早期西域砾岩开始沉积时,地形高差加剧,中、古元古界开始暴露被剥蚀。区域资料分析表明,阿尔金山脉在新生代具有多期次阶段性隆升的特征,存在3期次快速隆升事件：渐新世末一中新世早期、中新世晚期(大约8Ma)和第四纪早期。     

塔里木盆地海相油气源与混源成藏模式

塔里木盆地油气源长期争论不休.采用单体烃同位素、包裹体成分与年代指示生物标志物等途径, 对塔里木盆地塔中、轮南典型油气藏进行了油气成因与混源成藏模式的研究.结果表明, 塔中、轮南绝大部分原油生物标志物与中上奥陶统烃源岩相似, 仅少部分原油显现与寒武系—下奥陶统烃源岩相近的特征, 但正构烷烃单体烃碳同位素分析表明, 原油绝大部分实质仍为混源油.塔中包裹烃成分分析进一步证实了原油的混源特性.利用同位素进行的混源定量结果表明, 塔中原油中寒武系—下奥陶统成因原油的混入量约为11%~100%(均值45%); 轮南地区约为11%~70%(均值36%), 表明寒武系—下奥陶统、中上奥陶统均为塔里木盆地的主力烃源岩.油气运移地化指标与地质条件的综合研究认为, 塔中地区断层是油气运移的重要通道, 塔中I号断层与斜交的走滑断层的交汇点是油气的主要注入点; 轮南地区侧向运移特征较明显.研究区存在调整型、多期充注型与原生型多种混源成藏模式.塔里木海相油气的普遍混源表明深层仍有油气勘探潜能.揭示海相混源油气成藏机制是指导塔里木海相油气勘探的关键.      

南海东北陆坡断裂特征及其对盆地演化的控制作用

南海东北陆坡断裂发育,主要有北东、北西、近南北和近东西向的4组断裂,按性质分则有张性、压性和走滑等。主干基底断裂有F1、F2、F3、F4、F5、F6、F7、F8、F9、F10等,这些断裂规模较大并决定了珠江口盆地白云凹陷、尖峰北盆地、笔架盆地和台西南盆地发育和演化。受主干断裂的控制,尖峰北盆地经历了断陷、坳陷、区域沉降3期演化,发育两套构造层;而笔架盆地则经历了渐新世断陷、渐新世末—中中新世坳陷和晚中新世—全新世构造反转3期演化,发育两套构造层。