海斗深渊沉积物组成特征及其物质来源研究进展

海斗深渊是海洋中最深的区域,由水深范围在6000～11000 m范围内的深部海沟组成,以极端的物理化学条件为特征,其沉积物以深海黏土为主。基于目前关于马里亚纳海沟及其沉积物的研究进展,总结了海斗深渊的地貌、物理化学和水动力等方面的特征;归纳了海斗深渊沉积物的粒度特征、矿物组成和古生物特征;探讨了海斗深渊沉积物的物质来源及主要分析方法。海斗深渊沉积物的物质来源具有多源性,综合多种方法示踪是准确揭示其物质物源的关键。     

马里亚纳海沟南部海域沉积物的工程地质特性及其成因

大洋27航次中,在马里亚纳海沟挑战者深渊南翼斜坡上获得了箱式插管和重力柱状样品,并对这些样品现场进行了含水率、湿密度、微型扭力十字板、微型贯入和无侧限抗压强度试验,获得了深海表层沉积物的物理力学性质参数,具有较高的含水率、较低的密度、较大的孔隙比、较低的抗剪强度和贯入阻力,各项参数随深度增加呈现规律性变化。归航后通过对沉积物的粒度、碎屑矿物、黏土矿物、微体古生物的鉴定,进一步从物质组成、物质来源和沉积环境等方面对此特殊工程地质性质沉积物的成因进行分析。     

中太平洋(CP)区全新世沉积环境探讨

笔者利用在中太平洋（CP）区采取的CP9和CP25钻孔柱状样及19个站位的表层沉积物样品,通过对沉积物的成分、类型、古生物化石、常微量元素含量等鉴定测试,从地球化学特征对该区全新世以来沉积物中元素在垂向变化特点及相互之间的亲疏关系进行了详细分析和研究。通过R型因子分析与物源的研究,认为该区沉积物主要受陆源碎屑及生物碎屑沉积的影响较大,晚期火山物质供应比早期要充足,全新世的沉积环境趋于比较稳定。     

马里亚纳海沟挑战者深渊南部7000m水深处发现硅藻化石软泥

在马里亚纳海沟"蛟龙号"载人深潜器海试区约7000m水深的海底,发现了硅藻化石软泥沉积物,为中国首次在此大深度船载采集到硅藻化石软泥。室内硅藻化石分析显示,重力柱状样顶部约10cm厚的软泥为大筛盘藻Ethmodiscus rex硅藻软泥。化石主要由大筛盘藻组成,呈碎片状,数量巨大,并伴生有Azpeitia等热带远洋浮游种类。硅藻化石软泥发育表明,本区曾发生过E.rex勃发事件,具有重要的古海洋学和古生物学研究意义。     

南海东岛湖泊沉积物中的生态环境记录

东岛牛塘为目前在西沙群岛少见的淡水湖泊,发育保存完好的沉积物。文章通过对一根长126cm的沉积柱开展多方面的沉积学分析,包括沉积物的岩性特征,反映碳酸盐含量的白度、CaO和LOI950℃以及反映有机质含量的TOC,TN,TS和LOI550℃等地球化学指标随深度的变化特征,沉积物和环境介质的碳、氮同位素的对比分析,沉积物的稀土元素和Sr,F,P,Se等元素地球化学特征。结果认为:该湖泊沉积剖面自上而下可分成3个具有明显不同沉积学特征的沉积单元,其中25～96cm的沉积层明显地受到了海鸟粪的影响。识别出的海鸟粪土沉积层,为进一步研究历史时期岛屿鸟类生态系统和气候演化提供了良好的信息载体。     

长江口水下三角洲表层沉积物有机质分布特征

根据对长江口水下三角洲31个表层样沉积物粒度、总有机碳(TOC)、总氮(TN)的测定,得出了粒度及有机质的分布特征,利用C/N比分析有机质来源及不同来源的贡献率.研究结果表明:1)长江口水下三角洲表层沉积物平均粒径介于3 ～8Φ之间,存在由陆向海变细的趋势;2)TOC含量在0.1％ ～1.2％之间,平均值为0.52％;TN含量介于0.02％ ～0.08％之间,平均值为0.057％.TOC和TN含量的分布特征相似,具有自陆向海、由低至高的变化趋势,这主要是受到沉积物粒径的影响,但是TOC在崇明岛东侧和九段沙东侧有两个高值点,可能与人类活动或局地因素有关;粒度校正之后,TOC含量在0.40％～1.67％之间,平均值为0.68％;TN的含量介于0.05％～0.10％之间,平均值为0.07％.TOC含量在近岸地区略高,TN含量是北部地区略高于南部地区,并且TOC和TN都在崇明岛东侧和九段沙东侧有两个高值点;3)C/N比值在6～16之间,平均值为9.6;利用C/N比值估算得到的陆源有机碳含量在35％ ～ 90％之间,平均值为60％.C/N比和陆源有机碳含量在长江口南支外围邻近海域表层沉积物中较高,表明南支带来了大量的陆源有机质入海,并呈舌状向东北方向凸出;而在长江北支附近其值相对较低,表明北支径流影响相对减弱,潮流作用相对增强.研究表明,长江南支是主要的陆源有机质入海通道,而进入水下三角洲之后陆源有机碳分布受到了河口混合过程的显著影响.     

沉积物不同提取态有机物特征及水文地球化学意义——以河套盆地典型研究区为例

地下水系统中有机物（OM）特征和活性对于地下水化学特征的形成和演化起着十分重要的作用。将内蒙古河套盆地表层湖相沉积物按10 cm间隔采集,并对沉积有机质的性质及来源进行重点分析。测量了不同深度上不同岩性沉积物的色度、水溶性有机物（WEOM）和盐溶性有机物（SEOM）含量及其光谱学特性。结果显示,沉积物的色度（R530-520）与TOC含量呈现相反的变化趋势:色度值较大时,TOC含量反而较小。相对于细砂层,黏土层的色度值较低,但TOC含量较高。相同的沉积物中,SEOM含量高于WEOM,但WEOM更易迁移至地下水中。有机物的光谱指数表明,WEOM以微生物来源为主,而SEOM以陆源为主。通过三维荧光光谱分析发现,荧光强度和沉积物有机碳（SOC）含量呈正相关;黏土层沉积有机物荧光强度更高;WEOM和SEOM均含类腐殖质成分和类蛋白成分,但SEOM中腐殖质成分较高;类腐殖质是所研究的沉积物中OM最主要的存在形式。     

东海赤潮高发区沉积物柱状样中正构烷烃和脂肪醇的分布与来源

选取了东海赤潮高发区4个站位的沉积物柱状样,通过测定δ13C_TOC值,利用δ13C的双端元模型计算了沉积物中TOC的海源和陆源贡献率,并分析了正构烷烃和脂肪醇的组成与分布,探讨了其来源。结果表明,东海赤潮高发区沉积物中,正构烷烃以高碳数烷烃为主,有明显的奇碳优势,且呈双峰群分布;各站位总正构烷烃（T-ALK/μg/g）含量随深度有不同的变化;碳数奇偶优势指数（CPI）、陆源海源优势烷烃比（TAR）、平均链长（ACL）等正构烷分子指标,反映出在调查海区陆源正构烷烃的输入占主导,且以草本植物为主。直链烷基醇主要来源于陆地高等植物,4个站位的植醇经历了相似的生物化学过程,说明沉积环境较一致;菜籽甾醇与甲藻甾醇的比值指示了调查海区浮游植物种群的历史变化,由于水体富营养化的日益加重所导致的赤潮由简单的硅藻赤潮向硅藻甲藻混合型赤潮转变。     

长江口吴淞-浏河滨岸带沉积物AVS和SEM含量的空间分布特征

对长江口吴淞-浏河滨岸带37个站位沉积物中酸可挥发性硫化物（AVS）和同时可提取态重金属（SEM）含量及其空间分布特征进行了研究。结果表明,SEM在37个站位沉积物中浓度范围为0．20～1．37μmol／g,平均值为0．74μmol／g;AVS的浓度范围为0．20—0．80μmol／g,平均值为0．23μmol／g;沉积物中AVS含量与总有机碳（TOC）和含水率呈显著正相关关系,而SEM分别与TOC和含水率呈显著正相关关系,与沉积物中值粒径呈显著负相关关系。依据SEM／AVS比值评价方法以及美国EPA（SEM—AVS）差值评价方法对沉积物中重金属的生物有效性的判断表明,除了B2站点无显著生物毒性外,吴淞-浏河滨岸带沉积物中重金属对水生生物均处于中等毒性水平。     

黔中三叠纪地层研究新进展

通过对黔中地区区域地质调查，在二叠系—三叠系过渡层中发现了一系列的韵律层，并通过岩性岩相、矿物学、地球化学和地层古生物学研究，认为过渡层中韵律层是远源火山碎屑重力流沉积产物，并据古生物、沉积学、地层学研究将过渡层归属于三叠系。原安顺组下部“大汪段”之上、下发现大量牙形刺化石，根据岩性及古生物特征，将“大汪段”归入大冶组。黔中—黔南中三叠统陆源碎屑体系的物源来自江南古陆；菊石、双壳类化石层是浊流作用形成的事件沉积层。     

Geology of the Yap Trench: new observations from a transect near 10°N from manned submersible Jiaolong

This paper describes the petrology and geochemistry of rocks from the Yap Trench acquired by three dives of the Jiaolong research submarine. Combining the geophysical data and submersible observations, this paper describes the geomorphology, shallow structures, and sedimentology of the Yap Trench and further discusses the tectonics and activities of this region. Two obvious slope breaks are found on the landward slope, and horsts and grabens with small fault offsets are observed in the ocean-ward slope of the trench. Peridotites sampled from the Yap Trench inner wall are highly depleted subduction-related mantle residues. Volcanic rocks in the northern segment of the trench have subduction-related characteristics that Yap fore-arc rocks underwent metasomatism during Cenozoic subduction. The rocks with remarkable lithologic difference from lithospheric mantle and upper crust sampled in the break slopes suggest that the slope break area may represent a lithologic boundary or transition zone. The landward slope of the Yap Trench was removed by subduction erosion as a result of collision with the Caroline Ridge. The bending of the down-going plate caused normal faults, horsts, and grabens with little or no sediments indicating that the Caroline Ridge is subducting beneath the Yap arc along the trench even though the convergence rate is very slow.     

三江地区北部三叠纪深水沉积及其意义

位于西藏东部的三江地区北部累计厚度达１００００余米的三叠系以海相沉积为主,由碎屑岩、碳酸盐岩和火山岩的一种或两种占优势的组分构成。其以陆源、内源及火山源碎屑流与浊流形成的深水沉积为特色,并分别堆积在不同背景的江达弧内盆地和生达弧后区的沉积盆地中,研究表明这些深水沉积应是活跃的构造作用的响应,对认识三江地区的构造活动具有指示意义。     

马尼拉海沟1.4 ka B.P.以来浊流事件沉积及其成因机制*

浊流是远距离沉积物运输的一种重要方式,海底浊流广泛存在于海底峡谷或海沟。马尼拉海沟位于南海东北部,是一条正在活动的板块汇聚边界。独特的地理位置(亚热带—热带)和气候条件(台风频发),使得马尼拉海沟浊流频发,然而,现今对马尼拉海沟的浊流研究甚少。本研究通过对马尼拉海沟北部水深3747 m处重力柱岩心(GEO6)进行高精度的粒度及沉积学特征分析,探讨马尼拉海沟浊流沉积规律。GEO6岩心底部细颗粒沉积物中浮游有孔虫的¹⁴C的AMS年龄为1405 a B.P.。高精度的粒度分析(0.25 cm)和沉积学特征显示: GEO6岩心记录有至少11次浊流沉积(T1-T11),且这些浊流都有明显的底部粒度最粗(砂质粉砂或砂)、向上粒度逐渐变细的正粒序特征,只有T8沉积体为反粒序特征,可能为异重流沉积。结合区域地质资料,本研究认为1.4 ka B.P.以来,研究区频繁的台风带来了大量陆源松散沉积物堆积在马尼拉海沟上游(高屏峡谷),不稳定的构造环境及地震频发导致这些松散沉积物垮塌并向下游马尼拉海沟输送,在海沟内形成频繁发育的浊流沉积体。     

马尼拉海沟1.4 ka B.P.以来浊流事件沉积及其成因机制*

浊流是远距离沉积物运输的一种重要方式,海底浊流广泛存在于海底峡谷或海沟。马尼拉海沟位于南海东北部,是一条正在活动的板块汇聚边界。独特的地理位置(亚热带—热带)和气候条件(台风频发),使得马尼拉海沟浊流频发,然而,现今对马尼拉海沟的浊流研究甚少。本研究通过对马尼拉海沟北部水深3747 m处重力柱岩心(GEO6)进行高精度的粒度及沉积学特征分析,探讨马尼拉海沟浊流沉积规律。GEO6岩心底部细颗粒沉积物中浮游有孔虫的¹⁴C的AMS年龄为1405 a B.P.。高精度的粒度分析(0.25 cm)和沉积学特征显示: GEO6岩心记录有至少11次浊流沉积(T1-T11),且这些浊流都有明显的底部粒度最粗(砂质粉砂或砂)、向上粒度逐渐变细的正粒序特征,只有T8沉积体为反粒序特征,可能为异重流沉积。结合区域地质资料,本研究认为1.4 ka B.P.以来,研究区频繁的台风带来了大量陆源松散沉积物堆积在马尼拉海沟上游(高屏峡谷),不稳定的构造环境及地震频发导致这些松散沉积物垮塌并向下游马尼拉海沟输送,在海沟内形成频繁发育的浊流沉积体。     

Geotechnical properties of lower trench inner-slope sediments

Geotechnical property analyses on sediments recovered by DSDP drilling within select convergent margins were integrated to determine the variability in these properties along the trench inner-slope and to delineate the effects of convergence on these properties. Consolidation states range from very underconsolidated to highly overconsolidated, with preconsolidation pressures exceeding 46,000 kPa in Quaternary sediments. Underconsolidated sediments are attributed to:

1. (1) high sedimentation rates.

2. (2) low sediment permeability relative to the length of the drainage path; (3) laterally applied stresses; and (4) induced pore water pressures resulting from the subduction of pelagic sediments with high water content. Factors contributing to the state of overconsolidation include: (1) tectonically induced overpressures; (2) removal of overburden by mass movement processes.

3. (3) low sediment accumulation rates.

4. (4) age.

Vertical gradients of index properties also vary greatly with the maximum gradient associated with overconsolidated sediments. Values of porosity generally exceed 30% at all margins studied, suggesting this porosity represents the minimum attainable solely by the effects of convergence.Geotechnical property results and site-specific parameters suggest two end members should be considered in the general geotechnical property model for convergent margin sediments. Clastic dominated margins form the basis for the initial geotechnical property model. These margins are characterized by thick trench sediment sequences which are folded and faulted and become progressively more deformed upslope. Convergence rates are low, and no well-developed faults or hrst and graben structures are evident on the downbending oceanic plate. Highly overconsolidated sediments and index property values which change rapidly with depth result from the slow progressive deformation of trench and lower slope sediments. Examples of clastic-dominated margins include the Nankai Trough, Aleutian Trench, and Washington continental margin.Pelagic-dominated margins have significantly different geotechnical properties and site-specific parameters. These margins are characterized by thin clastic trench sediment sequences overlying pelagic sediments on a rapidly converging oceanic plate. Well-developed faults and/or hrst and graben structures are evident on the downbending oceanic plate. Sediment deformation along the trench and lower slope appears limited. These sediments are underconsolidated and index property values change gradually but often irregularly with depth. Japan Trench and Middle America Trench-Guatemala margins are considered pelagic-dominated. Middle America Trench-Mexico appears to represent an intermediate case having characteristics of both margin types.     

Diagenesis of organic matter in suspended particles and sediments in the Cariaco Trench

Suspended particulate materials and bottom sediments from the Cariaco Trench were analysed for lipid content to investigate the diagenesis of organic matter in an anoxic water column and sediment. Distributions of fatty acids, sterols, and the acyclic isoprenoid hydrocarbons, lycopane and 2,6,10,15,19-pentamethyleicosane, support the hypothesis that alteration of organic matter usually attributed to sedimentary diagenesis occurs in the water column. Typical indicators of diagenetic processes, including preferential loss of unsaturated fatty acids, increased abundances of branched fatty acids, stenol-to-stanol conversion, and abundant acyclic isoprenoids, were observed in the water column across the oxic/anoxic interface in the Cariaco Trench. Lipid distributions in the sediment were remarkably uniform with depth. We conclude that organic material delivered to the sediment has been extensively altered in the water column, but that which is buried is preserved without much additional alteration.     

西太暖池区生物组分对海底表层沉积物物理力学性质的影响

西太平洋暖池区是指位于热带西太平洋及印度洋东部海表温度常年在28 ℃以上的海域,是全球海表温度最高的深海区,构造环境与沉积环境复杂,沉积物中的生物组分含量差异较大,生物组分会对深海沉积物物理力学性质产生显著影响,但目前对沉积物中生物组分含量和沉积物物理力学性质之间的相关性关系尚不明确。本文对西太平洋暖池区核心部位的表层沉积物样品进行现场物理力学性质测试和室内涂片鉴定,研究深海表层沉积物的物理力学性质与生物组分之间的关系。结果表明:研究区表层沉积物含水率范围为61.1%~435.1%,天然密度范围为1.04~1.76 g/cm³,贯入阻力范围为0~100 kPa,十字板剪切强度范围为0~8.6 kPa,整体具有高含水率、低密度、低强度等典型的深海沉积物物理力学性质特点。西加洛林海脊、海山等CCD以浅的区域为钙质生物组分>50%的钙质沉积区;西加洛林海槽西南部及其周边的深水沟槽地区一般为硅质生物组分>50%的硅质沉积;西加洛林海盆内部则主要为黏土沉积区。随钙质生物组分减少和硅质生物组分增多,表层沉积物类型分别为钙质沉积物、黏土沉积物和硅质沉积物,天然含水率变高,天然密度、贯入阻力和十字板剪切强度降低,表明深海表层沉积物的物理力学性质与生物组分含量密切相关:贯入阻力、十字板剪切强度、天然密度与钙质生物组分含量呈正相关,与硅质生物组分含量呈负相关;而天然含水率正好相反,与钙质生物组分含量呈负相关,与硅质生物组分含量呈正相关。本文建立了深海沉积物中生物组分与物理力学性质之间的相关关系,提出了沉积物生物组分含量与物理力学性质之间的拟合公式,可以为深海沉积物工程性质的评价提供参考。     

Biogeochemistry of Ethanol and Acetaldehyde in Freshwater Sediments

This study reports the first ethanol and acetaldehyde measurements in sediment porewaters collected at multiple freshwater locations. Ethanol concentrations ranged from 11 to 2535 nM and acetaldehyde concentrations ranged from 6 to 320 nM. A significant positive correlation (p < 0.001) was observed between ethanol concentrations and the percent organic carbon content of sediments (TOC). Porewater depth profiles at two sites within the same lake indicated potential diffusion of ethanol into sediments from the overlying water at a lower TOC site and upwards diffusion from sediment into the water column at a higher TOC site. Diffusion of water column ethanol into sediments was observed at individual sites from October to January, whereas the opposite was true from June to August indicating the seasonal variability of ethanol flux from sediments. Changes in ethanol concentrations during a long-term sediment incubation experiment showed an inverse relation with acetaldehyde concentrations. The lack of a quantitative conversion was likely due to other sources and sinks that control their abundance. Our study provided new information on the biogeochemistry of ethanol in freshwater sediments and shed light on the potential role of ethanol in the global carbon cycle.