银川盆地清水营组咸化湖盆沉积特征与湖盆演化

银川盆地发育厚层新生界,其中清水营组是咸化湖盆发育的时期,也是烃源岩最为发育的层段,因此明确清水营组的沉积特征及湖盆演化具有重要的地质意义和勘探意义.综合利用野外露头、钻井岩心、测井及有机地球化学资料,对银川盆地古近纪晚期清水营组的岩性、岩相类型进行分析总结,明确沉积环境.利用岩电特征、小波变换对清水营组进行沉积旋回识别与划分,在此基础上分析湖盆演化.清水营组岩性主要为灰色泥岩、棕红色泥岩、含石膏泥岩、石膏及薄层细砂岩、粉砂岩等,共有四种岩相组合类型.清水营组可划分3个四级旋回,对应清水营组咸化湖盆的3个演化阶段：SQ1为裂陷初期咸化湖盆的发育阶段;SQ2为强烈裂陷期,湖盆水体深度有所增大,盐湖鼎盛阶段;SQ3期水体变浅,湖盆范围变大,封闭性减弱,由咸水湖演化成淡水湖.     

江西信江盆地罗塘凹陷膏盐微量元素地球化学特征

江西信江盆地罗塘凹陷发育一套晚白垩世周田组暗色泥岩与膏盐岩互层沉积,为了解膏盐岩成因,综合利用钻井资 料和地球化学分析手段进行研究。结果表明,研究区膏盐岩主要发育在周田组二、三、四段,岩性为含钙石膏泥岩和泥质 石膏岩,其次为（硬） 石膏岩。稀土和微量元素地球化学特征揭示了膏盐岩与围岩的物源均来自陆源,而非深部卤水。膏 盐岩具有早期高水位浅水区和晚期低水位深水区两种沉积模式。早期高水位浅水区沉积模式主要分布在盆地边缘,沉积了 紫红色含钙质结核泥岩夹膏盐岩;晚期低水位深水区沉积模式主要分布在盆地中心,发育了膏盐岩与暗色泥岩互层沉积, 并组成多个盐韵律。平面上由盆地边缘到中心依次沉积了碳酸盐岩、膏盐岩类的典型蒸发岩序列。     

中-新生代塔里木与中亚盐湖链蒸发岩沉积及其控制因素初探

全球性的构造运动末期一般伴着海退和干旱的气候环境,而蒸发岩沉积与大地构造条件紧密相关。中亚卡拉库姆盆地、阿富汗_塔吉克盆地、塔里木盆地自晚侏罗世至中新世以来至少发生了3次大规模海侵_海退旋回,每次海侵_海退均受特提斯构造事件控制。卡拉库姆盆地、阿富汗_塔吉克盆地为晚侏罗世—早白垩世蒸发岩沉积、塔里木盆地的莎车次级盆地为晚白垩世—古新世蒸发岩沉积,库车次级盆地为古新世—中新世蒸发岩沉积,形成特提斯构造域自西向东蒸发岩沉积时代逐渐变新的盐湖链。中亚及塔里木盐湖链在海侵_海退旋回的控制下,至少发生5次大规模的蒸发岩沉积,发育2种不同的蒸发岩沉积序列,分别对应3次海退期蒸发岩沉积序列及2次断续海侵期蒸发岩沉积序列,具体为晚侏罗世晚期(海退期)卡拉库姆盆地、阿富汗_塔吉克盆地蒸发岩沉积;早白垩世—晚白垩世早期(断续海侵期)阿富汗_塔吉克盆地蒸发岩沉积;晚白垩世晚期(海退期)莎车次级盆地蒸发岩沉积;古新世—中新世(断续海侵期)莎车次级盆地、库车次级盆地蒸发岩沉积;中新世晚期—上新世早期(海退期)库车次级盆地蒸发岩沉积。塔里木与中亚古盐湖发育受控于特提斯构造事件及海侵_海退旋回,而海侵_海退旋回又控制2种不同的蒸发岩沉积序列。蒸发岩沉积序列、古盐湖演化阶段、蒸发岩物质来源、沉积环境决定了盐类矿物沉积类型(单一化学岩型、陆缘碎屑岩_化学岩型),卡拉库姆盆地、阿富汗_塔吉克盆地盐类矿物与塔里木盆地相比,种类简单,反映了盆地化学岩与陆源碎屑_化学岩沉积的区别及后期构造运动对盐类矿物种类的主控作用。     

内蒙古银根盆地下白垩统沉积相

在对盆地周缘大量野外地质剖面详细测量的基础上结合室内分析，研究了银根盆地下白垩统巴音戈壁组的沉积相类型及其分布、演化。银根盆地下白垩统为典型的内陆湖盆沉积，形成了厚度达2000m以上的砂砾岩、泥岩夹碳酸盐岩、中基性火山岩，局部见油页岩和蒸发岩沉积，发育冲积扇、河流（以辫状河为主）、扇三角洲、三角洲、湖泊等沉积相类型。沉积体系的分布及演化主要受区域构造的影响，大致可以划分为三个沉积阶段，反映了断陷湖盆由发生、发展直至萎缩的一个完整旋回。早白垩世早期为湖盆初始断陷阶段，中期为强裂断陷阶段，晚期为湖盆萎缩阶段，每一沉积阶段在湖盆的不同部位发育了特定的沉积相类型及组合。     

泌阳凹陷湖相白云岩层序地层学分析

泌阳凹陷湖盆中心安棚地区核二段和核三段上部发育一套巨厚白云岩层系地层，岩性以泥质白云岩、白云质泥岩、泥岩、纯白云岩和碱层为主，属淡化期和咸化期相互交替的常年碱性盐湖沉积体系。笔者从湖相白云岩层系沉积特征人手，首先从剖面上对长期旋回、中期旋回和短期旋回进行层序分析，然后从沉积成岩角度对该短期旋回和韵律旋回进行高分辨率层系地层分析。     

潜江凹陷古近系潜江组盐间泥岩地球化学特征及地质意义

咸化湖盆盐间泥岩的地球化学特征对咸化烃源岩的形成环境及其共生盐岩的形成条件具有重要指示意义。利用江汉盆地潜江凹陷内潜三下段盐间泥岩的详细地球化学测试结果,并结合岩芯观察,分析了古近系潜江组沉积时湖盆的古盐度、氧化还原环境及古气候背景。该地层较高的Sr丰度、Sr/Ba值及钙芒硝的存在揭示潜江组泥岩沉积时水体盐度较高;氧化还原环境指标及一些敏感元素的含量变化指示潜江组沉积时期水体含氧量较低,处于底层水体中等分层厌氧环境;主量元素化学蚀变指数CIA、Mg/Ca比值及对膏盐层岩芯观察反映潜三下段泥岩沉积于气候相对潮湿期段,而膏盐层则沉积于气候相对干旱期。这种泥岩与膏岩互层出现的变化可能是由我国晚始新世频繁的气候变化导致的。而且,由气候干湿波动造成的淡化-咸化成盐序列,伴随着生物短期的爆发与死亡,将有利于有机质的生成与堆积;潮湿、缺氧的沉积环境有利于有机质的保存,整体上盐间泥岩具备形成较好烃源岩的条件。     

青藏高原东北缘宁南盆地晚古近纪气候变化及其驱动机制

宁南盆地咸化湖相清水营组沉积记录,是研究青藏高原东北缘地区晚古近纪气候变化及其驱动机制的绝佳选择。以宁南盆地古近系清水营组为研究对象,通过野外地质调查、样品采集、石膏主量元素和锶同位素的测试,分析沉积地层记录的化学风化和古气候的变化;并通过与全球气候变化和青藏高原隆升过程的对比分析,研究青藏高原东北缘宁南盆地气候变化的驱动机制。结果表明:宁南盆地清水营组石膏中Al₂O₃/SiO₂、Al₂O₃/Ti₂O、K₂O/Na₂O和87Sr/86Sr等指标可以很好地反映晚古近纪气候变化,在38~36 Ma、34.5~33 Ma、32~31 Ma、30~27 Ma、26~23 Ma这5个时期,化学风化减弱,气候干旱化;在36~34.5 Ma、33~32 Ma、31~30 Ma、27~26 Ma这4个时期,化学风化增强,气候湿润化。晚古近纪38~26 Ma,青藏高原东北缘宁南盆地古气候变化主要受到全球气候变化的驱动;但在26~23 Ma之间,宁南盆地古气候变化受到了青藏高原隆升的重要影响。     

孙吴—嘉荫盆地太平林场组烃源岩海侵特征研究

太平林场组作为孙吴—嘉荫盆地最重要的生烃层位,与松辽盆地海侵层位嫩江组具有很好的可比性。对该盆地萝北剖面和黑龙江剖面的常量元素、微量元素、同位素以及有机地球化学分析表明,太平林场组底部沉积时为高盐度强还原的水体环境,这与嫩江组早期的海侵咸化水体特征一致,且向上具有水体盐度及还原性降低趋势。综合前人研究中的古气候,古生物等方面证据,认为在早白垩世,孙吴—嘉荫盆地为松辽古湖盆一部分,太平林场组与嫩江组为同一湖盆沉积,且遭受了海侵。太平林场组烃源岩地球化学特征反映其沉积保存环境有利于有机质的富集、保存及转化成烃,可为该区油气生成提供物质基础。     

柴达木盆地英西地区下干柴沟组上段高频旋回与古地貌特征

受区域性构造运动和古近纪特殊气候的共同影响,在英西地区沉积了一套陆相咸化湖盆混积岩,其特殊的相序组合对研究陆相咸化湖盆高频层序划分及古地理演化具有重要意义。英西地区下干柴沟组上段地层主要为暗色细粒混积岩,矿物成分复杂,主要由陆源碎屑、碳酸盐矿物和蒸发盐矿物组成,可以划分为碎屑岩、碳酸盐岩和蒸发岩三大岩石类型,分别为湖盆演化的淡化阶段、初始咸化阶段和咸化阶段产物。研究区目的层段识别出7个四级层序（Psq1~Psq7）,除Psq1和Psq2不发育区域性盐岩层外,其他四级层序都由碎屑岩段、碳酸盐岩段、混积型蒸发岩段和区域性盐岩层组成,这也反映出气候及湖盆性质的逐渐演化。在四级层序约束下,根据盐岩层相对厚度,对英西地区下干柴沟组上段的古地貌特征进行了恢复。Psq1和Psq2发育于湖盆演化的相对早期阶段,咸水湖范围非常有限。Psq3至Psq5沉积期间,湖水咸化程度逐渐增加,咸水湖范围不断扩大,在几个洼陷区沉积了大套厚层盐岩。Psq6沉积期间,经过前几个阶段的填洼补平,研究区地貌总体趋于平坦,高差幅度明显减小。至Psq7沉积期间,研究区西部逐渐退出深洼区,沉积中心开始向东发生迁移。     

广西陶圩盆地蒸发岩系特征及其地质时代

广西横县陶圩盆地系一中生代小型断陷盆地。盆地内发育一套红色陆源碎屑－化学岩型沉积。蒸发岩系主要由钙芒硝岩、（硬）石膏岩、泥质白云岩及泥岩、粉砂岩组成，厚达５００多ｍ，从下至上组成一个淡－咸－淡的成盐旋回。该蒸发岩系的孢粉组合属晚白垩世上仑期－赛诺期，其所在地层应属上白垩统，而非前所惯称之下白垩统新隆组     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。