鄂尔多斯盆地延长组长7富铀烃源岩铀的赋存状态

鄂尔多斯盆地晚三叠世延长组长7段是一套深湖相富铀烃源岩,铀含量很高,其矿物学特点是富含胶磷矿、草莓状黄铁矿、有机质等.通过光片、扫描电镜、电子探针、能谱分析、α放射性照相等研究方法,分析了长7段富铀烃源岩中铀的赋存状态,结果表明铀除了以类质同象赋存于胶磷矿中,以及以吸附态赋存于黄铁矿和有机质中以外,还在长7富铀烃源岩中...     

国际水文地质学家协会进展

国际水文地质学家协会成立于1956年。1985年资深的中国专家出席了第17届和18届国际水文地质大会,自那时以来,越来越多的中国代表出席了该学会的学术会议。中国分会于1987年建立,并组织相关活动。中国的协会成员近年来不断增加。国际水文地质大会曾在中国举办两次,第21届大会于1988年在桂林市举行,第34届大会于2006年在北京举行。多年来,在我国每年都举行水文地质学和地下水科学学术会议。协会主办的《Hydrogeology Journal》期刊编委会中有很多中国和华裔学者,中国分会负责论文摘要的中文翻译。协会的图书系列在我国广泛传播,促进了中国地下水科学的发展。该协会近期提出了水文地质战略系列,已经发布的九个专题分别是:生态系统与地下水、能源与地下水、粮食安全与地下水、全球变化与地下水、人类健康与地下水、城市与地下水、联合国2030年可持续发展目标、采矿业与地下水,以及气候变化适应地下水,指导了地下水资源和水文地质科学的发展。     

Effect of pretreatment of the electrokinetic properties of quartz

Effects of various commonly used pretreatments such as desliming, ultrasonic scrubbing and leaching with dilute nitric, hydrofluoric and sodium hydroxide solutions on the electrokinetic properties of quartz in aqueous solutions are reported. The study showed that treatments with various reagents often used in mineral processing research in the past to clean minerals can affect, sometimes severly, the electrokinetic properties of quartz. The change in these properties during subsequent aging is also found to be governed by the type of treatment used. This study also shows the need in mineral research for standardization of mineral preparation techniques in order that the discrepancy in data reported for surface properties in literature can be minimized.     

A review of theories of mechanisms of induced seismicity

Theories of the physical processes leading to the stimulation of seismic activity by underground explosions, fluid injection, and reservoir impoundment are summarized. In all cases, the materials must be pre-stressed to a substantial fraction of their breaking strength in order for seismicity to be induced. Stress concentrations due to the presence of old faults or to inhomogeneities in the material properties play an important role in localizing induced seismicity.

For the few cases for which data are available, the stimulation of earthquakes by fluid injection in bore holes is adequately explained by a Coulomb-Mohr failure criterion and the concept of effective pressure in a water-filled porous mechanism. Reservoir-related earthquakes are most likely due to the same mechanism, but, in view of the low injection pressures, additional physical or chemical effects of the water on the materials may play an important role. There may be a weakening of the materials in old fault zones by the introduction of water or static fatigue in silicate rocks due to stress corrosion.     

深基坑边坡支护方式的现状

根据目前国内边坡支护工作中的主要方式,将深基坑边坡支护按其结构的受力状态和支护的作用原理进行分类,详细论述了各种深基坑边坡支护方式的机制和适用条件,对今后岩土工程的实际工作具有一定的参考作用。     

Address of the retiring President of the International Association of Sedimentologists: Differences in size distributions of populations of particles among sands of various origins

This address reminisces and reflects on a subject in which I have been involved for more than twenty years: the effect of depositional processes on various parameters of the size-frequency distribution of sands. Movements of air and water generally separate particles by their sizes; the distribution of sizes relates to (1) the availability of different sizes of particles in a parent material, (2) processes operating where the sediments are deposited, particularly the competency of flow, and (3) concentrations of particles in suspension. Differences in size-frequency distributions among sands correlate with various origins, that is with their terminal depositional environments. Reminiscences in this address express my personal experience, both its up and downs, in advocating the study of this relationship, particularly in applying the method of moments on the basis of the concept that one statistical function expresses the characteristics of the population of particles. This address re-emphasizes some points made in previous studies (Friedman, 1961, 1962b, 1967) on the interrelationship between textural parameters and depositional processes for beach, dune, and river sands and then complements and supplements data which have not been presented before. These new data are grouped on scatter plots for sands of various origins. Finally, this address displays on maps regional trends of process-induced changes in size distributions of populations of particles in sands of four different settings: (1) a beach-dune setting, as exemplified by Padre Island, Texas, on the shores of the Gulf of Mexico; (2) a point-bar setting in the Arkansas River of Oklahoma; (3) a continental shelf-slope setting in the Gulf of Mexico off Louisiana, Mississippi, and Alabama; and (4) a continental shelf setting of the western Atlantic Ocean off New Jersey. This address concludes with the observation that the distribution of particles in sands will be influenced by the conditions that determine what happens in the depositional environment, hence statistical parameters that define the size-frequency distribution may be related to formative process.     

Reaction of zoning of garnet

Compositional zoning of garnet in metamorphic or igneous rocks preserves evidence of the equilibration history of the sample and can be interpreted in terms of a growth-fractionation, diffusion-exchange, or diffusion-reaction model. Diffusion zoning is usually assumed to result from exchange reactions between garnet and other phases as the partitioning coefficient varies in response to changing environmental conditions, primarily temperature. However, in many natural environments where garnet grew originally in divariant equilibrium with other phases, changing conditions can promote continuous or “divariant” reactions and consequent compositional shifts of phases that can be much greater in some systems showing these reactions than those related to the small changes of partitioning. Diffusional zoning related to overstepping of these continuous reactions must be related to incongruent reaction and necessitates formulation of a kinetic diffusion-reaction model involving moving phase boundaries as well as solid-state diffusion. Three samples containing zoned garnets from the metamorphic aureole around the Ronda ultramafic intrusion in southern Spain are used to illustrate two possible models of diffusion-reaction processes. The examples are particularly informative because the reactions are demonstrably irreversible and evidence of the reaction system is preserved. Partitioning data indicates that compositions of product phases are not in equilibrium with the original garnet and do not vary with extent of reaction; therefore, exchange reactions with garnet were not possible and garnet changed composition only by incongruent reaction. After a small amount of reaction, Mg/Fe of the rim composition approaches a value apparently in equilibrium with product phases, but the garnets are zoned inward to the original garnet composition preserved in the interior. Grossularite content is approximately constant and spessartite content variable but small, thus, the rim composition of pyrope or almandine is assumed to be fixed by the external reaction process and is taken as a boundary condition in the following models. The zoning profile of pyrope or almandine component between the fixed rim and core compositions (assumed to extend to ∞) is described in semiinfinite, half-space models appropriate for large garnets with narrow rims. The first model corresponds to a reaction system in which all garnet compositions are metastable (case 1) and zoning depends on the independent variables of the diffusion constant, velocity of the interface between garnet and matrix, and time. The second model, corresponding to systems in which the initial garnet composition is metastable but an equilibrium composition is stable (case 2), depends on the independent variables diffusion constant, time, and a function of reaction compositions. In case 1 the consumption velocity is assumed constant and a steady state zoning profile is reached at large time, whereas, in case 2, the velocity decreases with the concentration gradient and steady state is not possible. The models were tested using a reaction time estimated from cooling models of the aureole, mass of garnet consumed, determined petrographically, and phase compositions. The two cases are somewhat independent in that different parameters are independent variables. The estimate of the diffusion constant of 10^?18±2 cm²/sec (assumed to be a mutual or binary coefficient for almandine and pyrope) is considered reasonable for the temperature range of reaction (probably 600–900° C), and the two models are consistent considering the probable error and possible real temperature differences. It is obvious that details of the metamorphic reaction system must be known to successfully apply diffusion models. Kinetic models, involving consumption or growth of the phase as well as diffusion are probably necessary when dealing with natural rocks. Several possible and interesting complications, such as cross coupling between components, can be investigated if more data were available. Experimental determination of diffusion constants allow natural reaction rates to be estimated by this method. Diffusion zoning is an important consideration that could increase the efficiency of experimentation with chemically recalcitrant phases.     

Radiogeochemical studies of the features of radionuclide distribution at the sites of dumping of radioactive wastes of the Novaya Zemlya Archipelago

This paper presents the results of the studies performed from aboard the R/V Akademik Boris Petrov of the Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, in 2002–2004 aimed at surveying the sites of dumping of potentially dangerous objects in Stepovoy, Abrosimov, and Tsivol’ka bays of the Kara Sea. These studies coupled the instrumental facilities of acoustic survey with the visual examination of the objects recovered and also included sampling of the bottom sediments and near-bottom water in the vicinity of the objects and away from them. Subsequently, the samples collected were analyzed using direct gamma spectrometry and radiochemical concentrating selected radionuclides. This allowed us to obtain a statistically reliable database on the specific concentrations of radionuclides (cesium, strontium, cobalt, and plutonium) in the water column and in the bottom sediments. In selected parts of Stepovoy and Abrosimov bays, at the sites where containers were located, local areas with contaminated bottom sediments were registered in the immediate vicinity of the objects, in which significant concentrations of Cs-137 were detected. We also carried out experiments with the samples of the collected bottom sediments on the determination of the kinetic parameters of sorption in the sediment-solution system using the method of radioactive indicators. Taking into account the hydrological conditions, the results obtained allow one to explain particular features of radioactivity distribution in selected aquatic areas. Based on a comparison between the results of the studies performed in 1992–1994 and 2002–2004, we estimated the dynamics of the changes in the mean level of specific concentrations of radionuclides in the regions of the location of sunken objects in shallow-water bays of the Novaya Zemlya Archipelago. The registration of elevated concentrations of corrosive elements in the surface layers of the bottom sediments in these zones suggests a necessity of a multidisciplinary study consisting of regular repeated measurements at reference points in different areas aimed at before-the-fact prevention of possible leakages of radioactive substances from the sunken objects, which might result in a significant contamination of the environment. Original Russian Text ? O.V. Stepanets, L.A. Kodina, A.N. Ligaev, A.P. Borisov. G.Yu. Solov’eva, 2006, published in Geokhimiya, 2006, No. 12, pp. 1315–1324.     

Causes of salinization of the Gulf of Taganrog

Using the database of automatic hydrometeorological stations, installed in the Don RIver delta and Taganrog Bay seashore, the sources of the anomalois scale water negative surge and salinization of the Azov Sea under conditions of low river flow in 2015–2016 are studied. The new schemes of stratification and advection of salty sea waters in the Don River mouth under different weather conditions, water discharge and levels are given.     

青藏高原新生代构造岩相古地理演化及其对构造隆升的响应

在系统分析青藏高原新生代98个残留盆地类型、形成构造背景、岩石地层序列的基础上, 对青藏高原古新世—始新世、渐新世、中新世及上新世构造岩相古地理演化特征进行了讨论: (1)古新世—始新世: 松潘—甘孜和冈底斯带为大面积构造隆起蚀源区.塔里木东部、柴达木、羌塘、可可西里地区主体表现为大面积的构造压陷湖盆-冲泛平原沉积.高原西部和南部为新特提斯海.(2)渐新世: 冈底斯—喜马拉雅和喀喇昆仑大范围沉积缺失, 指示上述地区大面积隆升.沿雅江自东向西古河形成(大竹卡砾岩).西昆仑和松潘—甘孜地区仍为隆起蚀源区.塔里木、柴达木、羌塘、可可西里地区主体表现为大面积构造压陷湖盆沉积.塔里木西南部为压陷盆地滨浅海沉积.渐新世末塔里木海相沉积结束.(3)中新世: 约23 Ma时高原及周边不整合面广布, 标志高原整体隆升.塔里木、柴达木及西宁—兰州、羌塘、可可西里等地区主体表现为大面积的构造压陷湖盆沉积; 约18~13 Ma高原及周边出现中新世最大湖泊扩张期.约13~10 Ma期间, 藏南南北向断陷盆地形成, 是高原隆升到足够高度开始垮塌的标志.(4)上新世: 除可可西里—羌塘、塔里木、柴达木等少数大型湖盆外, 大部分地区为隆起剥蚀区.由于上新世的持续隆升和强烈的断裂活动, 使大型盆地的基底抬升被分割为小盆地, 湖相沉积显著萎缩, 进入巨砾岩堆积期, 是高原整体隆升的响应.高原从古近纪的东高西低格局, 经历了新近纪全区的不均衡隆升和坳陷, 最终铸就了西高东低的地貌格局, 青藏作为一个统一的高原发生了重大的地貌反转事件.      

济阳坳陷车镇凹陷古近系沙河街组遗迹化石Macaronichnus(通心粉管迹)及其沉积环境

济阳坳陷车镇凹陷古近系沙河街组发现的Macaronichnus segregatis(分离通心粉管迹)是一种直到微弯曲形状的层内进食潜穴,个体较小,不分枝,长一般7～8 mm,直径1～3 mm,与前人发现的化石在个体大小上存在着差异。它主要出现于四类环境：①三角洲平原河道间低地,②三角洲、扇三角洲前缘远端砂坝和浊积扇的中扇到外扇,③潮湿气候条件下的浅湖,④周期性干旱气候条件下的滨浅湖。不同沉积环境中产出的Msegregatis都分布于粉砂质泥岩中。通过分析各沉积环境的水动力条件和水体化学性质以及Msegregatis的形成过程,可得出以下结论：①Msegregatis出现的水动力条件中等,水体能量过高或过低,都不适宜其生成;②Msegregatis出现的水体化学性质介于贫氧与富氧之间;③Msegregatis是在沉积物沉积后还未固结时由食沉积物生物活动造成的,衬壁的出现反映了软基底性质。     

The value of measurements of density in the study of dolerites

The value of density measurements in the study of differentiated dolerite sills is discussed. It is shown that density measurements correspond closely with the results of chemical and modal analyses. There is a considerable statistical fluctuation in measured values of the density from relatively close specimens, and a similar fluctuation is to be expected in the results of chemical or modal analyses. Because of their speed, it is possible to make a large number of density measurements and take mean values over fifty foot intervals to indicate trends.

The density in a moderately thick tholeiite sheet normally increases linearly from the lower contact to a maximum several hundred feet above it, and then decreases to a minimum at the most silicic region which usually occurs several hundred feet below the upper contact. For a sheet of uniform thickness, the variation of density with depth appears to be roughly the same at all points. The density remained constant in a horizontal tunnel at a constant height above the lower contact, but irregular changes in density, possibly associated with changes in level of the roof or flow can occur, and a remarkable case of a rapid horizontal variation in density is discussed in some detail.     

Geochemical indicators of the evolution of the ultrabasic-alkaline series of Paleozoic massifs of the Fennoscandian shield

Rare-earth element distribution in the rocks and minerals of the olivinite-clinopyroxenitemelilitolite-melteigite-ijolite-nepheline syenite series was analyzed to study the evolution trends of the alkaline-ultrabasic series of the Kola province. The contents of REE and some other trace elements were determined in olivine, melilite, clinopyroxene, nepheline, apatite, perovskite, titanite, and magnetite. It was established that distribution of most elements in the rocks of the Kovdor, Afrikanda, Vuoriyarvi, and other massifs differ from that in the Khibiny ultrabasic-alkaline series, being controlled by perovskite crystallization. Primary olivine-melanephelinite melts of the minor ultrabasic-alkaline massifs are characterized by the early crystallization of perovskite, the main REE-Nb-Ta-Th-U depository. Precipitation of perovskite simultaneously with olivine and clinopyroxene results in the depletion of residual magma in rare-earth elements and formation of low-REE- and HFSE ijolite and nepheline syenite derivatives. In contrast, the formation of the Khibiny ultrabasic-alkaline series was complicated by mixing of olivine melanephelinite magma with small batches of phonolitic melt. This led to a change in crystallization order of REE-bearing titanates and Ti-silicates and accumulation of the most incompatible elements in the late batches of the melt. As a result, the Khibiny ijolites have the highest REE contents, which are accommodated by high-REE apatite and titanite.     

Possible origins of the diversity of types of Active Galactic Nuclei

The observed variety of types of Active Galactic Nuclei (AGN) in galaxies with various masses and morphologies is considered. It is proposed that this diversity is related to the evolutionary development of their host galaxies and central regions, including their bulges, massive black holes, and accretion disks. A possible evolutionary scenario explaining the relationship between various types of AGN is proposed, in which, in addition to differences in the accretion states of the circumnuclear disks, the type of host galaxy is also taken into consideration. Special attention is given to the qualitative similarity of the accretion and radiative processes occurring in active objects with stellar-mass black holes (microquasars) and in AGN, in spite of the huge differences in the masses of their black holes. Studies of variability of the emission of microquasars taking this similarity into account can be used to make predictions about the behavior of the emission of AGN (with scaling in accordance with the black-hole mass).     

采场底板突水机理的跨层拱结构模型

开采华北型煤田受底板承压水威胁的煤炭资源,必须对底板围岩的破坏规律有所认识。为了弄清底板岩层的活动规律,利用实验室大型非线性三维计算机数值模拟,对煤层底板应力分布特征进行了研究。发现采场底板存在跨层拱结构,并指出跨层拱是承载地应力和水压的承载结构;通过理论计算,得出了跨层拱最大主应力的计算公式,据此可以得出底板岩层裂隙产生的位置,该成果可对华北型煤田受承压水威胁矿井的回采工作面宽度设计提供参考。      

恩施渔塘坝富硒碳质岩中硒的赋存状态

在渔塘坝富硒碳质岩中发现了自然硒及其系列硒矿物的组合.这些硒矿物有自然硒、方硒铜矿、硒铜蓝、水硒铁石、硒银矿、含硒黄铁矿、含硒黄铜矿和难以确定名称的Fe-Se矿物.其中自然硒、方硒铜矿和硒铜蓝的矿物组合主要分布在断层面附近的碳质硅质岩中,自然硒与方硒铜矿的矿物组合主要分布在高碳质泥岩中,水硒铁石及未确定的Fe-Se矿物主要赋存于露头处的富硒碳质岩中.硒矿物中除自然硒较普遍地存在外,其他矿物并不是均匀地分布于富硒碳质岩中,而是局部性地出现.Cu-Se矿物的大量发育表明铜可能在硒的表生迁移转化中起着某种重要的作用.     

中国科学院地质研究所的成立与中央地质调查所的传承

1913年成立的中央地质调查所(成立时称农商部地质调查所)是中国建立的第一个国家级科研机构,代表了中国现代科学的起始,在中国现代科学发展史上具有举足轻重的地位。在它成立后的几十年间,中央地质调查所在区域地质调查、矿产资源勘查、大地构造学、地震学、土壤学、古生物与古人类学等众多领域,取得了一系列举世瞩目的学术成就,是民国时期我国最享有国际声誉的研究单位。1951年,中央地质调查所被正式改组为中国科学院地质研究所。根据当时新中国地质工作"一元化"的要求,原中央研究院地质研究所和原国民政府资源委员会矿产测勘处的部分地质研究人员也一同并入该研究所,使其成为当时我国最大的地质研究机构。1952年6月开始,刚成立不久的中国科学院地质研究所的科技人员开始分流。首先是研究所的古生物研究人员分流到新成立的中国科学院古生物研究所(即现在的中国科学院南京地质古生物研究所),它是在原中央研究院地质研究所基础上成立的。1952年9月,研究所土壤研究室扩充建设为中国科学院土壤研究所。1952年底左右,因新中国大规模经济建设的需求,大批科技人员分流到刚成立的地质部及所属的地质勘探队。从这一脉络可以看出,中国科学院地质研究所是中央地质调查所的传承和延续,而学术界大多认为中央地质调查所已于解放初期解体或撤销的观点与史实并不相符。     

Thermodynamic problems of distribution of cations in superlattices of minerals

Physical methods (infrared spectroscopy, X-ray, Mössbauer spectroscopy) afford exact ratings of ferruginousness of the subphases (sublattices) in the superstructures of minerals. This provides opportunity for studies of the distribution of Fe²⁺ between the subphases in a mineral or in several coexisting minerals, as influenced by P and T. The distribution analysis, in the case of rhombic pyroxenes and amphiboles of the cummingtonite-grünerite series, shows the fruitfulness of this type of approach. A substantial effect of T on the Fe²⁺ distribution in superstructures of these minerals appears indicated. Efficient geothermometers and geomanometers may be developed on that basis. On the other hand, a possibility presents itself for appraisal of sequences of the hydration reactions, as influenced by T, other things being equal. Experimental and theoretical studies will let us arrive at a closer appraisal of the effects of T and P on stability of chemical bonds in minerals, on the basis of endocrystalline ionic equilibria of superstructures in solid solutions. — Authors.     

Problem of lateritic bauxites of Siberia

On paleoclimatic-geological premises and by available indications in the field, prospecting for bauxites of the platformal type is recommended in certain Siberian districts in which conditions were favorable for bauxitization at the end of the Triassic, in the Barremian-Aptian, the Turonian, and the Eocene. -- V.P. Sokoloff.     

震后沟道泥石流启动条件——松散堆积体雨中失稳的水力学机制分析

5.12地震导致大规模的松散崩滑物质堆积于沟道,极大的增加了震后降雨型沟道泥石流爆发的概率。然而,灾后特殊的物源条件和成灾环境改变了传统沟道泥石流的形成机制,给震后沟道泥石流的防治工作带来了巨大的困难。为此,以水文学为基础,在构建松散堆积体潜水位变化水文学模型的前提下,借助水力学理论,分析了沟道堆积体内水力随潜水位变化的规律和特征,研究作用在单元条块堆积体上静水压力和动水压力的计算方法。在合理分段沟道松散堆积体的前提下,基于无限边坡理论完成了对各段堆积体下滑力、基底抗滑力及剩余下滑力的表达构建。结合算例解析了震后降雨条件下堆积体失稳的力学机制。分析表明,震后沟道松散堆积体失稳启动并泥石流化是流域降雨作用下堆积体内潜水位不断抬升、水力环境不断劣化的结果。流域大、沟道窄、堆积深、导水系数小、沟床缓的堆积体因较高的潜水位更易在降雨中失稳,且失稳模式因条块间剩余下滑力差异而分为整体推移启动及解体牵引启动两类。