额尔古纳地块新元古代岩浆作用与微陆块构造属性:来自侵入岩锆石U-Pb年代学、地球化学和Hf同位素的制约

对额尔古纳地块新元古代花岗岩进行了锆石LA-ICP-MS U-Pb年代学、岩石地球化学和锆石Hf同位素研究,以便对其新元古代岩浆作用历史与微陆块构造属性给予制约.所测花岗质岩石中锆石的CL图像特征和Th/U比值(0.17~1.46) 显示其为岩浆成因.测年结果并结合前人定年结果,可以判定额尔古纳地块上至少存在~929 Ma、~887 Ma、~850 Ma、~819 Ma、~792 Ma、~764 Ma和~738 Ma岩浆事件.岩石地球化学特征显示,~887 Ma花岗岩为一套后碰撞花岗岩类;而850~737 Ma花岗质岩石整体上属于A-型花岗岩,也有部分岩体(漠河、阿木尔、碧水和室韦岩体)显示I-型花岗岩特征.锆石Hf同位素特征反映这些花岗岩的源区既有中-新元古代(T_DM2=884~1 563 Ma)新增生地壳物质的部分熔融,同时伴有少量古老地壳物质的混染,也有残留的古老中基性下地壳物质的部分熔融.综合研究区新元古代侵入岩的地球化学特征,同时对比新元古代全球构造热事件,认为额尔古纳地块上新元古代岩浆活动记录了Rodinia超大陆形成和演化过程中的地壳响应:927~880 Ma的岩浆作用应是Rodinia超大陆汇聚造山的产物;而850~737 Ma的岩浆作用应是对Rodinia超大陆快速裂解的记录.通过岩浆事件对比发现,额尔古纳地块与邻近的西伯利亚南缘微陆块(如中蒙古地块和图瓦地块)具有亲缘性,而与塔里木板块和华南板块至少在新元古代岩浆活动上具有一定的相似性,而明显区别于华北板块和西伯利亚板块.      

大兴安岭中段塔尔气地区早白垩世花岗岩成因及形成构造环境

通过大兴安岭中段塔尔气地区三道桥和桑多尔岩体全岩地球化学、年代学和锆石Lu-Hf同位素资料,探讨了其形成时代、岩石成因、源区性质等方面问题。三道桥和桑多尔岩体分别由正长花岗岩和二长花岗岩组成。LA-ICP-MS锆石U-Pb定年结果表明三道桥和桑多尔岩体均形成于早白垩世,其年龄分别为143 Ma和141 Ma。岩石地球化学分析结果显示,三道桥和桑多尔岩体均为高钾钙碱性的I型花岗岩,具有相似的岩浆源区。上述两岩体的锆石ε_(Hf)(t)值为正值(分别为4.9~9.3和2.1~8.1),具较年轻的二阶段Hf模式年龄(t_(DM2)=598~882 Ma,676~1 062 Ma),暗示其源于新元古代—显生宙期间新增生地壳物质的部分熔融。结合区域研究资料,认为三道桥和桑多尔岩体的形成与蒙古-鄂霍茨克洋闭合后的岩石圈伸展密切相关。     

滇西北贡山地块始新世花岗岩的成因及其构造意义

滇西三江地区发育古近纪花岗岩,记录了印度－欧亚大陆碰撞的岩浆活动信息。对贡山地块福贡花岗岩开展岩石地球化学及锆石U Pb Hf系统研究,结果表明,该花岗岩为钙碱性、过铝质特征的I S型花岗岩。锆石U Pb同位素分析表明,福贡马吉花岗岩侵位于55 Ma,并含有252~77 Ma的继承锆石。锆石Hf同位素分析表明,该区岩浆锆石具有与青藏高原及东其南缘同时代长英质侵入体相似的Hf同位素组成,暗示其相似的岩浆起源。微量元素和同位素组成模拟计算结果表明,马吉花岗岩的原生岩浆是由53%的新生地壳组分和47%古老地壳基底物质混合而成的原岩经 5%~15%(F=005~015)的部分熔融而成。贡山地块福贡马吉花岗岩与冈底斯地块和腾冲地块早始新世岩浆岩(约55 Ma)具相似的年龄及地球化学特征,暗示它们之间可能存在类似的成因机制,均为新特提斯洋俯冲板片断离引起的壳内减压熔融的产物。     

内蒙古乌兰浩特地区二长花岗岩年代学、岩石成因及其构造环境

内蒙古乌兰浩特地区太平山嘎查岩体主要岩石类型为黑云母二长花岗岩。所测得的LA-ICP-MS锆石U-Pb年龄分别为127.4 Ma和125.6 Ma,属于早白垩世。太平山嘎查岩体的地球化学特征表明岩体属于弱过铝质、高钾钙碱性系列的高分异I型花岗岩。样品(P9-48-1)的锆石Hf同位素组成显示黑云母二长花岗岩的ε_(Hf)(t)=+8.60±0.57,两阶段亏损地幔模式年龄为511~748 Ma,说明其岩浆源区主要为新元古代—显生宙期间从亏损地幔新增生地壳的部分熔融。太平山嘎查岩体应形成于伸展构造体制,该伸展构造体制的产生可能与古太平洋板块向欧亚大陆下的俯冲有关。     

大兴安岭中北段早白垩世爱林源花岗岩的成因:锆石U-Pb年代学、地球化学及Hf同位素制约

大兴安岭绰尔地区爱林源岩体锆石U-Pb年代学、地球化学及Lu-Hf同位素分析结果显示,爱林源岩体的岩石类型主要为二长花岗岩,两个样品LA-ICP-MS锆石U-Pb定年结果分别为132 Ma和137 Ma,为早白垩世岩浆作用产物。地球化学数据显示二长花岗岩具有高硅、富钾、贫铁、贫镁的特点,具有中等-弱铕异常(Eu/Eu*)=0.46~1.07,∑REE为54.11×10~(-6)~191.42×10~(-6),LREE/HREE=11.38~18.03,轻重稀土元素分馏作用明显[(La/Yb)_N=12.12~23.52],相对富集大离子亲石元素(Rb、Ba、K),亏损高场强元素(Nb、Ta、Ti)及P元素等。锆石Lu-Hf同位素特征显示样品锆石ε_(Hf)(t)值均为正值(分别为3.9~7.9和2.9~8.0),并且具有较年轻的Hf二阶段模式年龄(t_(DM2)=709~942 Ma,677~1 001 Ma)。结合区域地质研究,笔者认为花岗质岩浆由新生地壳物质的部分熔融形成,可能与古太平洋板块俯冲兴安地块有关。     

桂东大瑶山地区加里东期基性岩的发现及地质意义

思泰岩体位于扬子地块与华夏地块拼合带的西南段,对剖析华南区域构造演化具有重要的地质意义。思泰岩体主要由辉长岩、辉长闪长岩组成。LA-ICP-MS锆石U-Pb年代学分析表明,辉长岩的侵位结晶时限为(445±1)Ma,属于加里东期岩浆活动产物。岩石具有高钾钙碱性特征;其铝饱和指数为0.95~1.99,属准铝质-过铝质岩石;岩石具有中等偏高的Mg#值(0.43~0.51)。锆石的εHf(t)值主要集中在0.39~5.84之间,其一阶段模式年龄为1 181~855 Ma,暗示其源区主要为中-新元古代岩石圈地幔。综合地球化学、锆石Hf同位素组成特征及区域地质资料,认为思泰岩体是在陆内碰撞造山期后伴随岩石圈局部伸展-减薄,软流圈高温地幔物质上涌,从而导致中-新元古代岩石圈地幔物质的部分熔融,随后岩浆发生上升侵位固结成岩,在上升侵位的过程中受到少量的地壳物质的混染而形成。     

兴凯地块伊曼群的形成时代与物源：碎屑锆石与岩浆锆石U-Pb年代学证据

本文对出露在兴凯地块南部伊曼群的变沉积岩和侵入其中的火成岩进行了系统的锆石LA-ICP-MS U-Pb定年和Hf同位素研究,旨在查明伊曼群的形成时代与物源,并讨论侵入岩的成因和构造背景。伊曼群二云母片岩中锆石呈自形-半自形,显示典型的岩浆生长环带,暗示其岩浆成因。定年结果表明:100个碎屑锆石分析点给出了555～1322Ma的年龄区间,主要峰值年龄为555Ma、612Ma、700Ma、739Ma、769Ma、839Ma、936Ma;其中约533Ma的锆石ε_(Hf)(t)值介于-4.1～+3之间,二阶段模式年龄t_(DM2)介于1305～1755Ma之间;700～839Ma的锆石ε_(Hf)(t)值介于-3.7～+7.8之间,二阶段模式年龄t_(DM2)介于1246～1907Ma之间。侵入伊曼群的白云母二长花岗岩的定年结果显示为443±3Ma,此年龄对应ε_(Hf)(t)值介于-17.6～-4.2之间,二阶段模式年龄t_(DM2)介于1688～2529Ma之间。结合二云母片岩中碎屑锆石的最小年龄以及穿切其中花岗岩的形成时代,可以判定伊曼群二云母片岩的形成时代介于443～555Ma之间,应为新元古代晚期至晚奥陶世之间。基于伊曼群中碎屑锆石的年龄众数及与区域岩浆事件的对比,伊曼群的沉积物源主要来自松嫩地块和佳木斯地块的新元古代火成岩。此外,白云母二长花岗岩显示出埃达克岩的地球化学属性,岩浆源于加厚下地壳的部分熔融,暗示晚奥陶世研究区可能发生了陆壳加厚事件。     

大兴安岭新林镇岩体的同位素特征及其地质意义

新林镇岩体位于大兴安岭北部,主要由花岗闪长岩、石英二长岩、二长花岗岩、碱长花岗岩组成,局部见到细粒辉长岩和闪长岩包体。岩石地球化学和岩石学特征表明,该杂岩体属于高钾钙碱性I型花岗岩。两个花岗闪长岩的锆石LA-ICP-MS U-Pb定年结果分别为(132±3)Ma和(131±3)Ma,属于早白垩世岩浆活动的产物。样品的Sr-Nd同位素组成比较均一,而Hf同位素特征变化较大,其εHf(t)变化介于1.32~8.32之间,Hf模式年龄与Nd模式年龄一致,表明花岗质岩浆主要起源于元古代增生的地壳物质,在岩石形成过程中有地幔组分的贡献。岩体的同位素特征将额尔古纳地块地壳增生时间限定在新元古代,而兴安地块地壳增生发生在新元古代—显生宙,暗示它们具有不同的地壳演化过程。     

保山地块北部晚白垩世岩浆岩成因及其构造指示：全岩地球化学、锆石U-Pb年代学和Hf同位素制约

滇西保山地块晚白垩世-古近纪岩浆活动代表了新特提斯演化阶段的一次重要岩浆事件,其岩浆岩成因、源区属性及地球动力学背景尚不明确。本文对出露于保山地块北部漕涧地区的花岗岩类进行了全岩地球化学、锆石U-Pb年代学和Hf同位素组成研究。2件样品锆石U-Pb年龄结果分别为73.32±0.19Ma(MSWD=0.68)和73.44±0.20Ma(MSWD=1.3)。岩体具有高硅(SiO2=73.76%~74.74%)、富碱(K2O+Na2O=8.14%~8.62%)、过铝质(A/CNK=1.15~1.23)特征,在SiO2-K2O岩石判别图解上属钾玄岩系列;明显富集Rb、U及Th等大离子亲石元素和Pb,相对亏损Nb、Ta及Ti等高场强元素;具有强烈的轻重稀土分馏(LREE/HREE=8.5~15.1),球粒陨石标准化配分曲线表现出明显的负Eu异常(δEu=0.29~0.43)特征。锆石εHf(t)值十分集中(-5.0~-3.5),对应的Hf同位素地壳模式年龄tC DM为1352~1496Ma。这些地化特征和Hf同位素组成综合表明槽涧岩体属于晚白垩世S型花岗岩,其可能来源于保山地块中元古代地壳基底的深熔作用,物质来源为富黏土的泥质岩。构造环境判别图解中样品均落入同碰撞花岗岩区域。综合研究表明,保山地块发育有85~83Ma、~73Ma和66~60Ma三期过铝质花岗岩类,预示该地区在晚白垩世-古新世存在持续的地壳伸展减压作用。基于区域大地构造背景,本文提出了如下岩浆岩形成构造演化过程:(1)早白垩世中特提斯洋的闭合导致保山地块西侧地壳增厚;(2)晚白垩世新特提斯洋板片北东向俯冲过程中可能发生过海沟回撤作用,导致先存加厚地壳发生减压熔融,岩浆上侵形成漕涧岩体。综合对比西藏冈底斯岩浆带和腾冲地块同一时代花岗岩锆石Hf同位素数据,表明保山地块基底属性明显不同于腾冲地块和拉萨地块南部。     

黑龙江跃进山矽卡岩型铜金矿床花岗闪长岩的年代学和地球化学特征

对跃进山铜金矿床与矽卡岩型矿化有关的花岗闪长岩开展了LA-ICP-MS锆石U-Pb定年、锆石Lu-Hf同位素及岩石地球化学研究。结果表明,花岗闪长岩中26个锆石测点的~(206)Pb/~(238)U加权平均年龄为(118.96±0.77) Ma (MSWD=0.29);岩体中锆石的ε_(Hf)(t)值均为正值(+1.4～+3.2),且具有较年轻的Hf二阶段模式年龄(t_(DM2)=1.09～0.98 Ga);花岗闪长岩表现为富Al、高K和Na以及低Ti、P、Ca的钙碱性I型花岗岩地球化学特征,显示出轻稀土富集、重稀土元素亏损的稀土元素组成特征;样品锆石的ε_(Hf)(t)的值为偏低的正值,表明岩浆物质来源应为壳幔混源。结合岩石地球化学投图以及区域构造背景演化认为,花岗闪长岩和花岗斑岩均属于后碰撞-火山弧花岗岩,研究区的成矿成岩作用与太平洋板块强烈俯冲背景下的下岩石圈地幔拆沉有直接关系。     

Police, politics, and the right to the city

Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA

Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N₂ in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.     

扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究

马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。     

Rb-Sr, K-Ar, H-and O-Isotope systematics of the Middle Riphean shales from the Debengda Formation, the Olenek Uplift, North Sibera

Clay subfractions (SFs) of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2 and 2–5 μm separated from Middle Riphean shales of the Debengda Formation are studied using the TEM, XRD, K-Ar and Rb-Sr isotopic methods. The oxygen and hydrogen isotope compositions in the SFs are studied as well. The low-temperature illite-smectite is dominant mineral in all the SFs except for the coarsest ones. The XRD, chemical and isotopic data imply that two generations of authigenic illite-smectite different in age are mixed in the SFs. The illite crystallinity index decreases in parallel with size diminishing of clay particles. As compared to coarser SFs, illite of fine-grained subfractions is enriched in Al relative to Fe and Mg, contains more K, and reveals higher K/Rb and Rb/Sr ratios. The Rb-Sr age calculated by means of the leachochron (“inner isochron”) method declines gradually from 1254-1272 Ma in the coarsest SFs to 1038-1044 Ma in finest ones, while the K-Ar age decreases simultaneously from 1225–1240 to 1080 Ma. The established positive correlation of δ¹⁸O and δD values with dimensions of clay particles in the SFs seems to be also consistent with the mixing systematics. The isotopic systematics along with data on mineral composition and morphology lead to the conclusion that mixedlayer illite-smectite was formed in the Debengda shales during two periods 1211–1272 and 1038–1080 Ma ago. The first period is likely close to the deposition time of sediments and corresponds to events of burial catagenesis, whereas the second one is correlative with the regional uplift and changes in hydrological regime during the pre-Khaipakh break in sedimentation.     

贵州岑巩羊桥罗家塘杷榔动物群的发现及其后生动物早期演化的意义

岑巩县羊桥乡罗家塘杷榔组仅出露中-上部地层,岩性单一,均为青灰、灰绿色粉砂质泥、页岩.在其上部层位发现了俞氏贵州始海百合(Guizhoueocrinus yui Zhao,Parsley et Peng,2007),计有棘皮动物始海百合、腕足动物、软体动物-软舌螺、节肢动物-三叶虫等8属9种,包括了2个未定名的新种和1...     

Breakthroughs in the biodiversity, biogeography, biostratigraphy, and basin analysis of the Beaufort group

Over the past decade researchers working on the rocks of the Beaufort Group in the main Karoo Basin of South Africa have vastly increased our understanding of this important Permo-Triassic sequence. Many new fossil forms have been discovered, allowing for breakthroughs into the biodiversity, biogeography and biostratigraphy of the group. Taxonomic and phylogenetic advances are many and varied, and cover most of the vertebrate taxa, but with emphasis placed on the temnospondyl amphibians, archosauriforms and non-mammalian synapsids, in particular the anomodontia. Biostratigraphic breakthroughs have centered on the Middle Permian Eodicynodon and Tapinocephalus assemblage zones, the Late Permian Dicynodon Assemblage Zone, and the Triassic Lystrosaurus and Cynognathus assemblage zones. Correlation of these biozones with better dated sequences in Europe, Russia and China has allowed for many chronostratigraphic refinements, which are in turn vital for sequence stratigraphical analysis of the basin fill. Based on fossil data, both the lower (Ecca–Beaufort) and upper (Beaufort–Molteno) contacts of the group have been proved to be highly diachronous. The refined chronostratigraphic framework has also allowed for a better analysis of the basin evolution through time, particularly in terms of the correlation of external stimuli that affect basin sedimentation patterns.     

Delivery of Trace Metals (Al,Fe, Mn,V, Co,Ni, Cu,Cd, Ag,Pb) from the Trinity River Watershed Towards the Ocean

The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological (i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates) controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were <20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is lost to sediments.     

深港西部通道填海区地下水铜、钒、铊、镉、钨迁移的实验研究

填海工程使滨海地区的地下水物理化学条件改变,导致该区域地下水中重金属浓度升高。本文以深港西部通道填海区为例,采用实验室模拟填海条件的办法,初步探讨了影响填海区地下水重金属迁移的关键因素。模拟实验结果表明,填海区地下水中钨元素含量升高与地下水淡化、淤泥氧化过程以及填料风化有关;铜元素含量升高则与淤泥氧化过程以及填料风化有关;钒元素含量升高与地下水淡化和淤泥氧化过程有关,而其他元素含量升高则主要与填料风化释放有关。