CBD方法对天然样品磁性矿物影响

本研究选择川西高原、天山和西伯利亚Kurtak剖面的黄土古土壤样品及亚热带非风成样品进行CBD处理,系统测量并对比处理前后的磁学参数,包括低频磁化率、频率磁化率、非磁滞剩磁、饱和等温剩磁、剩磁矫顽力和热磁曲线(J-T曲线),分析处理前后磁性矿物种类、含量和磁畴的变化.结果表明,CBD方法对于磁性矿物的溶解并无明显的选择性,在温度与反应时间一定的条件下,磁性矿物的溶出量主要受控于其粒径分布.CBD方法可以非常有效地去除具有更大比表面积的细粒(< 1 μm)磁性矿物,同时溶解粗粒(>1 μm)磁性矿物外缘,使其粒径变细.CBD处理后磁化率变化存在多种可能,对于成土作用较强的古土壤,CBD方法可以较为准确地提取成土成因的磁性信息;而干旱和过度湿润条件下的风积黄土,不宜使用CBD方法区分原生与次生磁性矿物.     

浅议中国黄土磁化率的物理意义

中国的陆相黄土地层连续地记录了第四纪以来的古气候变化。基于中国黄土磁化率曲线与深海氧同位素记录具有可比性这一事实，磁化率作为一种气候替代性指标在黄土研究中得到广泛的应用。但是，磁化率的物理意义仍不清楚。本文作者对陕西榆林蔡家沟剖面末次间冰期以来的风成沉积作了研究，指出黄土、古土壤的磁化率差异不仅与前人提出的碳酸盐淋失、空隙度变化、“就地”新生成磁性矿物等作用有关，而且还可能与有机质有重要关系。有机     

Two pedogenic models for paleoclimatic records of magnetic susceptibility from Chinese and Siberian loess

The magnetic susceptibility (MS) of Chinese loess showing a general proportional relationship to pedogenic grade has been widely recognized and used for reconstruction of paleoclimate by Quaternary scientists. The in-situ pedogenic enhancement of ferrimagnetic content is normally believed to be the main reason for the increase of susceptibility in soil units. However, this pattern of high magnetic susceptibility in palaeosols, and low values in loess, are not replicated in some loess deposits. Siberian loess deposits display a completely opposite susceptibility behavior: high values in loess and low values in palaeosols. This inverse relationship has been explained by the idea that magnetic susceptibility is reflecting the magnitude of an aeolian ferrimagnetic component of consistent mineralogy, the grain size of which is related to average wind velocity. Our magnetic study of Siberian samples in this paper suggests that there are notable differences in magnetic properties between Siberian loess and developed palaeosols, not only in magnetic grain-size and concentration but also in magnetic mineralogy. This evidence is difficult to explain fully through variation in wind strength alone, but implies that the low magnetic susceptibility values in the Siberian paleosol units are a reflection, at least in part, of the alteration of the ferrimagnetic content by post-depositional processes. The Loess Plateau is a very arid area where potential evaporation is always higher than precipitation; pedogenesis occurs under dry oxidising conditions. The Siberian Kurtak region is located on the edge of the tundra where it is always wet and saturation during interglacials will lead to a reducing pedogenic environment. Ferrimagnetic minerals under this condition will be destroyed, resulting in lower magnetic susceptibility. Therefore, great care should be taken when using susceptibility values for paleoclimatic reconstruction.     

陕西交道全新世黄土-黑垆土磁化率的CBD研究

根据黄士高原中部交道剖面全新世黄土－黑垆土剖面的非磁滞磁化率和ＣＢＤ提取前后的磁化率、频率磁化率以及热磁分析结果,分析了磁性矿物的种类和磁畴状态,讨论了古土壤的磁化率增强,指出ＣＢＤ技术强有力的支持古土壤磁化率增强的土壤成因观点．虽然ＣＢＤ能非常有效地溶解土壤成因的磁赤铁矿,但并不是完全选择性地溶解土壤成因的磁铁矿颗粒．此外,通过对样品ＣＢＤ处理前后磁化率数据的分析,从土壤化学角度为黄土的风成说提供了新证据。     

Influence of Quaternary paleoclimate change on the permeability of the loess–paleosol sequence in the Loess Plateau,northern China

Permeability differences in multi-cycle loess–paleosol aeolian sediments, which are still poorly understood, have the potential to significantly improve our understanding of climatic change during the glacial–interglacial periods of the Quaternary. In this study, the permeability of a well-preserved and continuous loess–paleosol sequence in the South Jingyang Plateau was investigated. Weathering intensity was inferred using a series of climate proxies including grain-size distribution, magnetic susceptibility and mineralogy. The results of laboratory tests showed that the average saturated hydraulic conductivity of loess layers is higher than that of paleosol layers. Also, clear differences between loess and paleosol were found in terms of depth variations of the vertical and horizontal saturated hydraulic conductivities. Differences in loess–paleosol were also found for other proxies for pedogenic weathering [i.e. clay content, sand content, Kd value (ratio of coarse silt to clay), magnetic susceptibility, dolomite content and the ratios of hornblende/illite and hornblende/chlorite]. Our results showed a high permeability of loess layers associated with weak pedogenic weathering during cold/dry paleoclimatic conditions in glacial stages. On the contrary, paleosol layers developed in a warm/humid climate during the interglacial stages experienced strong pedogenic weathering that resulted in lower permeability. Based on these results, we construct a connection between Quaternary climate change theory and the modern hydrological system. This provides a scientific basis for investigating the distribution and pollution of groundwater resources in the local region. © 2020 John Wiley & Sons, Ltd.     

天山北麓黄土环境磁学特征及其古气候意义

新疆黄土-古土壤序列环境磁学参数的变化机理及其气候意义仍存在争议.本文选择天山北麓的中梁黄土剖面,系统开展了低温和常温下环境磁学参数的测试与研究,测量包括室温的磁化率与饱和磁化强度,以及磁化率与饱和剩余磁化强度的低温变化.结果发现,该剖面黄土和古土壤样品的磁性矿物主要由磁铁矿与磁赤铁矿组成,不含任何粒级成壤形成的超顺磁矿物颗粒,其磁化率信号主要记录了粉尘磁性矿物含量变化,较高的磁化率指示较强的风动力状况或者较近的风尘源区,新疆黄土的这种环境磁学"风尘输入模式"可用来重建干旱区的风动力强弱变化.     

黄土高原西北缘末次冰期晚期以来黄土沉积物的岩石磁学性质

以黄土高原西北缘的靖远和古浪剖面(包含黄土层L1上部和占土壤层SO)作为研究对象,选取代表性样品进行磁化率、频率磁化率、热磁曲线、等温剩磁获得曲线和磁滞回线等测定.结果表明,靖远和古浪L1黄土和SO古土壤具有相似的岩石磁学特征.磁性矿物含量相对较低,载磁矿物均以磁铁矿为主,同时含有磁赤铁矿和赤铁矿,且SO占土壤中的磁赤...     

Preliminary study on the mineral magnetic properties of sediments from Kůlna Cave (Moravian Karst), Czech Republic

Summary Magnetic property variations in marine, lacustrine and loess-paleosol sequences have proved to be useful proxies in climate change studies. However in order to correctly interpret the record of the magnetic property variations it is absolutely necessary to have a good understanding of the cause of the observed variations. Most of the ambiguity in loess-paleosol studies is in distinguishing the role of pedogenesis from other climatic factors. Studying the mineral magnetic properties of the protected cave sediments which have not undergone pedogenesis allows us to determine the degree to which detrital input is climatically driven. These results will help us better understand the variations observed in the surficial loess-paleosol sequences. This study reports mineral magnetic data collected from entrance facies sediments deposited during the early Wurmian glacial stage in the Kůlna Cave. The entrance facies sediments consist of loess-like silts with varying amount of talus. The magnetic susceptibility record from these sediments shows higher values in layers originating in colder climates which is different to that commonly observed in surficial loess deposits. Higher values of magnetic susceptibility in Kůlna sediments are probably due to higher concentrations of ferromagnetic minerals (magnetite and maghemite) and due to an increased proportion of superparamagnetic grains. The magnetic mineralogy and the grainsize distribution (grains larger than superparamagnetic) appear not to change throughout the studied profiles. Higher magnetic susceptibility accompanied by an increase in the superparamagnetic fraction observed in the sediments deposited during colder periods can be explained by an increased input from a pedogenic source when the vegetation cover was reduced and the erosion rate increased.     

塔里木盆地南缘8.5 ka以来的黄土岩石磁学特征及其磁化率变化机制

黄土岩石磁学参数是古气候研究中的重要指标,其中磁化率应用最为广泛,并在黄土高原地区取得重大进展,其受控于成壤作用的变化机制也被普遍接受.然而在黄土高原外缘的新疆地区,磁化率的变化机制仍不明确,导致磁化率的古气候意义在该区存在较大争议.本文选取塔里木盆地南缘具有精确年代控制的典型黄土剖面（羊场剖面）开展岩石磁学和高分辨率磁化率研究,利用交叉小波分析方法并结合剖面粒度、矿物及元素特征对该地区磁化率变化机制进行初步探讨.结果显示,羊场剖面的岩石磁学性质主要由粗颗粒软磁性矿物所控制,同时也表现出一定的顺磁性特征.根据载磁矿物和磁化率变化特征可将剖面进一步划分为两个阶段：阶段Ⅰ（8.5~2.5 ka）,载磁矿物以亚铁磁性的磁铁矿为主,磁化率值整体较高;阶段Ⅱ（2.5~0.2 ka）,亚铁磁性矿物依然占据主导地位,但硬磁性矿物和以黄铁矿为代表的顺磁性矿物相对增多,磁化率值显著降低.相关性研究和交叉小波分析表明：阶段Ⅰ磁化率与粗颗粒组分的变化具有一致性,符合"风速论"模式;阶段Ⅱ磁化率不仅与粗颗粒组分具有明显的正相关关系,而且与指示成壤作用强度的频率磁化率百分含量呈现出显著的负相关关系,暗示了阶段Ⅱ的磁化率变化可能受到"风速论"和"还原性成壤"模式的共同影响.本文拓宽了对新疆地区黄土岩石磁学特征及其磁化率变化机制的深入理解,也为利用磁化率恢复新疆及中亚地区全新世以来的古气候变化历史提供了新的线索.     

毛乌素沙地风沙沉积物磁学特征及其古环境意义

在沙漠沉积环境中,成土作用对磁化率的贡献较小,往往被原生磁信号掩盖,因此分离两种磁组分对气候和粉尘代用指标的提取至关重要.本研究选取位于毛乌素沙地东缘的锦界风沙沉积剖面为研究对象,利用多变量一元线性回归中的"平均值概念"进行磁化率的原生碎屑组分0和次生成土组分Xpedo的分离,并探讨磁学参数所承载的气候和环境意义.结果显示,磁学比值参数(如Xpedo/X0、Xfd/HIRM、Xfd%和XARM/SIRM)彼此之间存在显著线性或指数/对数相关关系,它们对成土强度指示明确,可以在一定程度上减小或避免磁性矿物背景值差异所产生的误差,与磁化率相比更适宜用于该区的古降水量重建.HIRM主要由碎屑赤铁矿含量控制,HIRM与X0存在明显正相关关系,表明碎屑赤铁矿随原生磁性矿物总体含量的增加(减少)而增加(减少),在粉尘成因磁性矿物中所占比例大致稳定,从而HIRM可以指示源区粉尘通量的变化.锦界剖面的原生和次生磁性矿物浓度均明显低于黄土高原黄土,不同地层X0和Xpedo在磁化率中所占的比例存在较大差异,因此磁化率的环境意义比较复杂,在使用其恢复古气候古环境时需慎重.     

天山黄土区与黄土高原表土磁性特征对比及环境意义

本文对黄土高原和天山黄土区表土进行系统的岩石磁学和粒度测试分析,探讨了表土磁性特征及其环境意义,结果表明表土中的强磁性矿物均为磁铁矿和磁赤铁矿,弱磁性矿物为赤铁矿和纤铁矿或针铁矿,黄土高原黄土地层中的磁赤铁矿至少有部分属于风积成因.黄土高原表土中磁化率与频率磁化率呈良好的正相关,气候作用是主导黄土高原表上磁化率增强的主...     

Magnetic iron oxides occurring in chernozem soil from Ukraine and Poland as indicators of pedogenic processes

The paper concerns the complex study of pedogenic and magnetic characteristics of unpolluted soil profiles from Ukraine (3 profiles, of which two represent chernozem and one kastanozem) and Poland (1 profile of chernozem), all with loess parent material. Two of the profiles were situated further south than the other two. The “southern” zone is characterized by lower precipitation rate and higher annual temperatures than the “northern” zone. Depth variations of magnetic properties obtained with various methods were compared with pedogenic characteristics. The common characteristic of all profiles is enhancement of susceptibility in their upper parts related to the presence of superparamagnetic/ single-domain grains of maghemite/oxidized magnetite of pedogenic origin. However, variations of magnetic characteristics measured down depth profiles differ between profiles probably due to differences in climatic conditions and, perhaps, parent loess.     

轨道调谐建立洛川黄土地层的时间标尺

对黄土高原中部洛川厚140m黄土剖面进行了黄土层间隔5cm、古土壤层间隔3cm的采样,在室内测量了全部样品的磁化率．以磁化率变化作为东亚夏季风气候变化的替代性指标,利用轨道调谐方法建立了黄土－古土壤序列的时间标尺．结果表明,B／M界线处的年龄是772KaB．P,午城黄土与离石黄土分界线的年龄为1348KaB．P,黄土堆积底界的年龄为2471KaB．P．．通过和古地磁场倒转点绝对年龄对比以及与太阳辐射量变化时间序列进行交叉谱分析,证明了新时间标尺的可信性．     

巴基斯坦Bahawalpur黄土岩石磁学特征及磁化率变化机制研究

风成黄土是陆地上分布最广泛的沉积物之一,记载了各种古气候演化信息.目前巴基斯坦的黄土研究甚少,磁化率与气候对应的变化机制研究尚未开展.本文对位于巴基斯坦印度河平原Bahawalpur地区新发现的黄土-古土壤剖面进行系统的岩石磁学研究,结合粒度和漫反射光谱(DRS)数据,讨论巴基斯坦黄土的磁化率变化机制.实验结果显示:Bahawalpur(BH)剖面黄土层主要的载磁矿物为磁铁矿,同时含有少量磁赤铁矿和针铁矿,磁性颗粒以原生的MD和PSD颗粒为主.相对于黄土层,古土壤层则是以针铁矿为主,含有顺磁性矿物和少量磁铁矿.BH剖面磁化率与成土作用关系和中国黄土高原典型剖面相反,磁化率的变化可能存在一个阈值12.8×10^-8 m³·kg^-1,在阈值之上,强磁性矿物(磁铁矿、磁赤铁矿)占主导;阈值之下,以弱磁性矿物(主要是针铁矿)为主,这种磁性矿物的转变可能导致磁化率降低.本文可为今后利用磁化率解读该地区地层蕴含的古气候信息提供新线索.     

Magnetic Characteristics of Different Soil Types from Bulgaria

Magnetic studies of different soil types can provide valuable information about palaeoenvironmental conditions at the time they were formed. Results of investigations of rock-magnetism of genetically different soil types, which developed over varying time intervals (Meadow Chernozem - formed during the last 6000 years BP; Leached Cinnamonic soil - formed since the 3rd-2nd century BC and Pellic Vertisoil - the oldest, formed since the Late Pliocene) are presented. The soil profiles of the Leached Cinnamonic and Pellic Vertisoil are characterized by lower values of magnetic susceptibility, as compared to that of the parent materials. It is shown that using percentage frequency-dependent susceptibility (Xfd%) and viscous remanent magnetization (VRM), pedogenic alteration could be detected even in such circumstances. The variations of the parameters measured along the depth of the studied Meadow Chernozem soil profile are characterized by gradual smooth magnetic enhancement, pointing to the absence of secondary redistribution of pedogenic magnetites. In contrast to this case, the two other profiles (Leached Cinnamonic and Pellic Vertisoil) show magnetically enhanced lower (illuvial) horizons due to processes of acid destruction and re-precipitation of the original pedogenic ferromagnetic minerals down the profiles. These specific magnetic properties are of particular importance in using susceptibility variations as a palaeoclimatic proxy record.     

甘肃西山坪遗址岩石磁学性质及其研究意义探讨

对甘肃西山坪遗址剖面样品进行磁化率、频率磁化率、热磁分析、非磁滞剩磁和等温剩磁等一系列岩石磁学实验测试,分析环境磁学参数特征变化,试图探讨西山坪遗址研究意义,为今后深入研究该沉积序列蕴含的古环境记录提供了岩石磁学基础.结果表明：西山坪遗址剖面沉积物中磁性矿物主要以低矫顽力的磁铁矿和磁赤铁矿为主,高矫顽力磁性矿物赤铁矿含量极其有限,越向剖面表层,强磁性矿物含量逐渐增加.磁性矿物颗粒表现出黄土的典型特征,以单畴、准单畴为主,含有一定量的超顺磁颗粒,颗粒度越向剖面表层越细.从物源上看,遗址沉积物主要来自近源的黄土风尘堆积,主要是风成堆积,并混合大量人类活动信息,给今后综合研究岩石磁学与人类活动特征的关系有一定借鉴意义.     

Detrital and pedogenic magnetic mineral phases in the loess/palaeosol sequence at Lingtai (Central Chinese Loess Plateau)

A detailed rock magnetic investigation of loess/palaeosol samples from the section at Lingtai on the central Chinese Loess Plateau (CLP) is presented. Thermal demagnetisation of isothermal remanent magnetisation (IRM) and Curie temperature measurements suggest the presence of magnetite, maghemite and hematite as remanence carrying components. Bulk and grain size fractionated samples have been analysed using coercivity spectra of remanence acquisition/demagnetisation curves, which identify four main remanence carriers in different grain size fractions of loesses and palaeosols. A linear source mixing model quantifies the contribution of the four components which have been experimentally derived as dominating endmembers in specific grain size fractions. Up to two thirds of the total IRM of the palaeosols are due to slightly oxidised pedogenic magnetite. Two detrital components dominate up to 90% of the IRM of the loess samples and are ascribed to maghemite of different oxidation degree. Detrital hematite is present in all samples and contributes up to 10% of the IRM. The iron content of the grain size fractions gives evidence that iron in pedogenically grown remanence carriers does not originate from the detrital iron oxides, but rather from iron-bearing clays and mafic silicates. The contribution of pedogenic magnetite to the bulk IRM increases with the increasing degree of pedogenesis, which depends in turn on climate change.     

Magnetic susceptibility of cambisol profiles in the vicinity of the Vír dam,Czech Republic

Magnetic susceptibility of 72 cambisol profiles from the vicinity of the Vír dam, NW Moravia was measured. The enhanced susceptibility of topsoil, particularly of the horizon O, was assessed from the aspect of vegetation setting and magnetic mineralogy. Magnetic susceptibility variations with field and temperature as well as frequency dependent susceptibility were applied to indicate magnetic carriers. It was found that the enhanced magnetic susceptibility is caused very likely by the presence of maghemite and magnetite of various grain sizes. Magnetic minerals are pedogenic in origin in all three horizons, while in the O and A horizons they are mostly anthropogenic in origin. Magnetic susceptibility was correlated with contents of trace elements Mo, Cu, Pb, Zn, Ag, As, Cd, Sb, Bi, Hg, Se, furthermore with TOT/C, TOT/S, and ¹³⁷C. The close association of susceptibility with Pb, Sb and Hg, or also with Mo, As, Se and their similar depth variations suggest a slight anthropogenic input in soils from a long-distant source. The same is valid for ¹³⁷C, its strong correlation with magnetic susceptibility has been found.     

Vertical variations of luminescence sensitivity of quartz grains from loess/paleosol of Luochuan section in the central Chinese Loess Plateau since the last interglacial

The provenance of loess in Chinese Loess Plateau, including origin, transport pathways and source areas, has long been one of the most important questions. In this study, the vertical variations of the luminescence sensitivity of quartz grains from the central Chinese Loess Plateau were investigated by using optically stimulated luminescence (OSL) techniques. Our results indicate that the luminescence sensitivity of quartz grains of paleosols can be much higher than that of loess beds. In addition, the quartz grains from the loess-paleosol sequence exhibit a temporal trend in the strength of luminescence sensitivity, characterized by higher values in soils and lower values in loess beds. The OSL sensitivity of quartz grains of the loess-paleosol sequence also shows very similar trend to the magnetic susceptibility and particle size fluctuations, implying that the luminescence sensitivity might be climatic dependent. The possible factors affecting the variations of luminescence sensitivity were discussed including particle size, natural radioactivity, and the provenance of eolian deposits. We suggest that the temporal variations of luminescence sensitivity can be attributed to the retreat-advance of deserts, the different contributions of glacial origin quartz particles associated with mountain processes, and wind patterns during glacial/interglacial cycles. Therefore, the secular variations of luminescence sensitivity of quartz grains are ultimately influenced by past climatic change through its controlling on sediment provenance changes.     

Use of variograms for field magnetometry analysis in Upper Silesia Industrial Region

Measurements of topsoil magnetic susceptibility are often used for quick assessment of soil contamination of anthropogenic origin, with heavy metals or other pollutants. However, because of complicated correlations between low-field magnetic susceptibility (shortened to magnetic susceptibility) of topsoil and soil pollution, the outcome of a field magnetometry survey can not be related directly to soil pollution. For each case study, the results should be interpreted on their own taking into account not only the type of pollution but also pedogenic, biogenic and environmental factors. In practice, it is very difficult to measure and consider all these factors. Here we illustrate the merit of geostatistical methods, which are focused on the spatial variability of a phenomenon, in the interpretation of soil magnetometry results. This article presents the analysis of spatial variability of top soil layers magnetic susceptibility-within the Upper Silesia Industrial Region (USIR)-using semivariance analysis. It also explains how to adjust the sampling density of field magnetometry measurements to spatial variability of the soil pollution as well as to the spatial scale of the investigated area. For this purpose, the values of magnetic susceptibility have been measured by using various sampling densities at areas of different size located within USIR. This enabled to determine the main scales of magnetic susceptibility spatial variability of soils within USIR using semivariance. A few distinct scales of variability were found from the site scale to a more regional scale. Variability ranges of 30 km, 12 km, and 5 km refer to the large regional scale, whereas smaller ranges of few hundreds down to a few tens of meters, can be attributed to the local (site) scale. In addition, the precision of the measuring campaigns, performed within USIR with different sampling densities, was compared through the analysis of the spatial variability of the soil magnetic susceptibility signal by using ordinary kriging. jarek97@yahoo.com, piotr.fabijanczyk@is.pw.edu.pl