Optimization of enrichment and pretreatment of low-activity radium isotopes in the open ocean

In the open ocean, radium isotopes are useful tracers of residence time and water-mass mixing. However, limited by the measurement resolution of commonly used gamma counters, the low activity of radium in the open ocean makes it necessary to enrich radium from large volumes of seawater and pretreat radium-enriched carriers prior to measurements. The commonly applied method of radium enrichment and pretreatment, however, has limitations of uneven coating of MnO₂ on cartridges, relative...     

夏季台湾海峡水及黑潮次表层涌升水向东海近陆架区营养盐输送通量的估算

According to historical mean ocean current data through the field observations of the Taiwan Ocean Research Institute during 1991–2005 and survey data of nutrients on the continental shelf of the East China Sea(ECS) in the summer of 2006, nutrient fluxes from the Taiwan Strait and Kuroshio subsurface waters are estimated using a grid interpolation method, which both are the sources of the Taiwan Warm Current. The nutrient fluxes of the two water masses are also compared. The results show that phosphate(PO4-P), silicate(SiO3-Si) and nitrate(NO3-N) fluxes to the ECS continental shelf from the Kuroshio upwelling water are slightly higher than those from the Taiwan Strait water in the summer of 2006. In contrast, owing to its lower velocity, the nutrient flux density(i.e., nutrient fluxes divided by the area of the specific section) of the Kuroshio subsurface water is lower than that of the Taiwan Strait water. In addition, the Taiwan Warm Current deep water, which is mainly constituted by the Kuroshio subsurface water, might directly reach the areas of high-frequency harmful alga blooms in the ECS.     

Copper and zinc isotope variations in ferromanganese crusts and their isotopic fractionation mechanism

Ferromanganese(Fe-Mn) crusts are potential archives of the Cu and Zn isotope compositions of seawater through time. In this study, the Cu and Zn isotopes of the top surface of 28 Fe-Mn crusts and 2 Fe-Mn nodules were analysed by MC-ICP-MS using combined sample-standard bracketing for mass bias correction. The Zn isotope compositions of the top surface of Fe-Mn crusts are in the range of 0.71‰ to 1.08‰, with a mean δ~(66) Zn value of 0.94‰±0.21‰(2 SD, n=28). The δ~(65) Cu values of the top surface of Fe-Mn crusts range from 0.33‰ to0.73‰, with a mean value of 0.58‰±0.20‰(2 SD, n=28). The Cu isotope compositions of Fe-Mn crusts are isotopically lighter than that of dissolved Cu in deep seawater(0.58‰ vs. 0.9‰). In contrast, the δ~(66) Zn values of Fe-Mn crusts appear to be isotopically heavy compared to deep seawater(0.94‰±0.21‰ vs. 0.51‰±0.14‰). The isotope fractionation between Fe-Mn crusts and seawater is attributed to equilibrium partitioning between the sorption to crusts and the organic-ligand-bound Cu and Zn in seawater. The Cu and Zn isotopes in the top surface of Fe-Mn crusts are not a direct reflection of the Cu and Zn isotopes, but a function of Cu and Zn isotopes in modern seawater. This study proposes that Fe-Mn crusts have the potential to be archives for paleoceanography through Cu and Zn isotope analysis.     

New Analytical Solutions for Time Fractional Benjamin–Ono Equation Arising Internal Waves in Deep Water

In this article, the author sets up the abundant traveling wave solutions for time fractional Benjamin–Ono equation which was introduced to describe internal waves in stratified fluids by using Jacobi elliptic function expansion method. The traveling wave solutions are expressed in terms of the hyperbolic functions, the trigonometric functions and the rational functions. It can be seen that the obtained results are found to be important for the statement of some physical demonstrations of problems in mathematical physics and ocean engineering. In ocean engineering Benjamin–Ono equations are generally used in computer simulation for the water waves in deep water and open seas.     

印尼北苏拉威西海蓝碧海峡水团性质的南北差异

Two field observations were conducted around the Lembeh Strait in September 2015 and 2016, respectively.Evidences indicate that seawater around the Lembeh Strait is consisted of North Pacific Tropical Water(NPTW),North Pacific Intermediate Water(NPIW), North Pacific Tropical Intermediate Water(NPTIW) and Antarctic Intermediate Water(AAIW). Around the Lembeh Strait, there exist some north-south differences in terms of water mass properties. NPTIW is only found in the southern Lembeh Strait. Water mass with the salinity of 34.6 is only detected at 200–240 m between NPTW and NPTIW in the southern Lembeh Strait, and results from the process of mixing between the saltier water transported from the South Pacific Ocean and the lighter water from the North Pacific Ocean and Sulawesi Sea. According to the analysis on mixing layer depth, it is indicated that there exists an onshore surface current in the northern Lembeh Strait and the surface current in the Lembeh Strait is southward.These dramatic differences of water masses demonstrate that the less water exchange has been occurred between the north and south of Lembeh Strait. In 2015, the positive wind stress curl covering the northern Lembeh Strait induces the shoaling of thermocline and deepening of NPIW, which show that the north-south difference of airsea system is possible of inducing north-south differences of seawater properties.     

Study on biological oceanography charateristics of planktonic copepods in waters north of Taiwan Ⅱ. Community characteristics

I~IOWThe area north of Taiwan is a mixing waters with complicate hydrographic features because itis influenced by the pushing and mixing of different water masses such as the Zhejiang -- Fujiancoastal water, the Taiwan Strait water, the Kuroshio surface water, the KurOShio sub-surfacewater and so on. The planktonic copepods in the area are also very complex and various. From research on species compoSition and ~nal variation, diversity and characteristics of copeal community in the area, …     

中国近海潮汐响应峰值估算的数值模拟

A numerical method is designed to examine the response properties of real sea areas to open ocean forcing. The application of this method to modeling the China’s adjacent seas shows that the Bohai Sea has a highest peak response frequency(PRF) of 1.52 d-1; the northern Yellow Sea has a PRF of 1.69 d-1; the Gyeonggi Bay has a high amplitude gain plateau in the frequency band roughly from 1.7 to 2.7 d-1; the Yellow Sea(including the Gyeonggi Bay), the East China Sea shelf and the Taiwan Strait have a common high amplitude gain band with frequencies around 1.76 to 1.78 d-1 and are shown to be a system that responds to the open ocean forcing in favor of amplifying the waves with frequencies in this band; the Beibu Gulf, the Gulf of Thailand and the South China Sea deep basin have PRFs of 0.91, 1.01 and 0.98 d-1 respectively. In addition, the East China Sea has a Poincare mode PRF of 3.91 d-1. The PRFs of the Bohai Sea, the northern Yellow Sea, the Beibu Gulf and the South China Sea can be explained by a classical quarter(half for the Bohai Sea) wavelength resonance theory. The results show that further investigations are needed for the response dynamics of the Yellow Sea-East China Sea-Taiwan Strait system, the East China Sea Poincare mode, the Taiwan Strait, and the Gulf of Thailand.     

BEHAVIOURS OF SUSPENDED PARTICULATE MATERIALS IN CHANGJIANG ESTUARY

The paper deals with the distribution of suspended particulated materials (SPM) in the Changjiang Estuary, the relation of salinity to particulated organic carbon and particulated organic nitrogen, and behaviour of SPM in mixing river-sea water. At the same time, the article shows that the SPM in Changjiang River emptying into the sea contains a large amount of organic matter. The relative concentrations of suspended particulate organic matter and living organic matter gradually increase seaward. In the estuarine environment, there is a linear relationship between log SPM and C/N ratio during the mixing of fresh water with seawater.     

FLOCCULATION OF DISSOLVED Fe, Al, Mn, Si, Cu, Pb AND Zn DURING ESTUARINE MIXING

This is the first study of the flocculation of dissolved Fe, Al, Mn, Si, Cu, Pb and Zn during mixing in Zhujiang Estuary, based on the experiment on a series of solutions of salinities ranging from 0 to 24 by mixing the Zhujiang water near Zhongshan University and the seawater in Wan-shan Archipelago area. The mechanism of flocculation of the 7 elements is explored, and the effects of time, acidity and temperature on flocculation are discussed. The results show that the flocculation rates of Fe and Pb in the Zhujiang water are almost a hundred per cent, while that forCu reaches 76%; for Mn, 51%; for Al, 48%; for Zn, 28%; and for Si, 1.2%, indicating that Si is conservative.     

SIMULTANEOUS DETERMINATION OF TRACES OF URANIUM AND THORIUM IN SEAWATER BY ISOTOPE DILUTION MASS SPECTRO-METRIC ANALYSIS METHOD(IDMS)

The separation and simultaneous determination of the traces of U and Th in seawater by IDMS is described. The detection limits of this method are 2.4×10-9 g for Th and 1.1×10-8 g for U. The concentrations of U and Th in seawater nearby Xiamen were measured, which are 3.20 ppb and 7.73 ppt respectively. The precisions fo the method are ±1.7% for U and ±3.6% for Th respectively.     

“海参-对虾”混养海水池塘的食物网结构及营养层级研究

The food sources of aquacultured Apostichopus japonicus and the trophic levels of organisms in a sea cucumber(A. japonicus) and prawn(Penaeus japonica) polyculture system in a saltwater pond in Zhuanghe, Liaoning Province were examined using carbon and nitrogen stable isotopes. Across organisms, δ13C ranged from(–25.47±0.20)‰ to(–16.48±0.17)‰(mean±SD), and δ15N ranged from(4.23±0.49)‰ to(12.44±0.09)‰. The δ13C and δ15N contents of A. japonicus, P. japonica and Fenneropenaeus chinensis were comparatively higher than those of other organisms. Values of δ13C and δ15N revealed that P. japonica, Hemigrapsus sanguineus and Neomysis japonica comprised the largest component of the diet of A. japonicus. The mean trophic level of the organisms in this saltwater pond polyculture system was(2.75±0.08). P. japonica, A. japonicus, F. chinensis,Synechogobius hasta and Neomysis japonica were in the 3rd trophic level(2–3); jellyfish, H. sanguineus and zooplankton were in the 2nd trophic level(1–2); and Enteromorpha prolifera, benthic microalgae, periphyton and suspended matter primarily consisting of phytoplankton, bacteria and humus were in the primary trophic level(0–1).     

棉兰老流和棉兰老潜流在季节尺度上的关系研究

The ocean general circulation model for the earth simulator(OFES) products is applied to estimate the transports of the Mindanao Current(MC) and the Mindanao undercurrent(MUC) and explore the relation between them on seasonal scale. In general, the MUC is composed of the lower part of the Southern Pacific Tropical Water(SPTW)and Antarctic Intermediate Water(AAIW). While the deep northward core below 1 500 m is regarded as a portion of MUC. Both salinity and potential density restrictions become more reasonable to estimate the transports of MC/MUC as the properties of water mass having been taken into consideration. The climatological annual mean transport of MC is(37.4±5.81)×10~6 m~3/s while that of MUC is(23.92±6.47)×10~6 m~3/s integrated between 26.5 σ_θ and 27.7 σ_θ, and(17.53±5.45)×10~6 m~3/s integrated between 26.5 σ_θ and 27.5 σ_θ in the OFES. The variations of MC and MUC have good positive correlation with each other on the seasonal scale: The MC is stronger in spring and weaker in fall, which corresponds well with the MUC, and the correlation coefficient of them is 0.67 in the OFES.The same variations are also appeared in hybrid coordinate ocean model(HYCOM) results. Two sensitive experiments based on HYCOM are conducted to explore the relation between MC and MUC. The MUC(26.5σ_θ27.7) is strengthening as the MC increases with the enhancement of zonal wind field. It is shown,however, that the main part of the increasement is the deeper northward high potential density water(HPDW),while the AAIW almost remains stable, SPTW decreases, and vice versa.     

温度、盐度和光照对浒苔生长和光合作用的影响

Intensive Pyropia aquaculture in the coast of southwestern Yellow Sea and its subsequent waste, including disposed Ulva prolifera, was speculated to be one of the major sources for the large-scale green tide proceeding in the Yellow Sea since 2007. It was, however, unclear how the detached U. prolifera responded and resumed growing after they detached from its original habitat. In this study, we investigated the growth and photosynthetic response of the detached U. prolifera to various temperature, salinity and irradiance in the laboratory. The photosynthetic rate of the detached U. prolifera was significantly higher at moderate temperature levels(14–27°C)and high salinity(26–32), with optimum at 23°C and 32. Both low(14°C) and highest temperature(40°C), as well as low salinity(8) had adverse effects on the photosynthesis. Compared with the other Ulva species, U. prolifera showed higher saturated irradiance and no significant photoinhibition at high irradiance, indicating the great tolerance of U. prolifera to the high irradiance. The dense branch and complex structure of floating mats could help protect the thalli and reduce photoinhibition in field. Furthermore, temperature exerted a stronger influence on the growth rate of the detached U. prolifera compared to salinity. Overall, the high growth rate of this detached U. prolifera(10.6%–16.7% d~(–1)) at a wide range of temperature(5–32°C) and salinity(14–32) implied its blooming tendency with fluctuated salinity and temperature during floating. The environmental parameters in the southwestern Yellow Sea at the beginning of green tide were coincident with the optimal conditions for the detached U. prolifera.     

Features of the atmospheric boundary layer block for three versions of the WAM wind wave model

The estimated characteristics of the atmospheric boundary layer, obtained by the simulation of wind wave fields using three versions of the WAM numerical model are compared with the well-known empirical dependences of drag coefficient C _d on wind speed U ₁₀ and wave age A, as well as with the dependence of dimensionless roughness height z _n on inverse wave age u*/с р. Calculations carried out for several years in the areas of the Pacific and Indian oceans, based on the ERA-interim and CFSR wind reanalyses have shown good agreement between the model and empirical dependences C _d (U ₁₀) and C _d (A). The range of estimated variability for z _n (u*/с _р ) has been found to be significantly less than empirical. It has been also found that estimated values of wind speed U _10W (t) are overestimated from 5 to 10% in all versions of WAM models compared with the input wind reanalysis U _10R (t) at the moments of appearance maximum values of wind U _10R (t). The reasons for the established features of the WAM model and their dependence on the model version are discussed.     

南极西北威德尔海上层海洋湍流混合研究

Turbulent mixing in the upper ocean(30-200 m) of the northwestern Weddell Sea is investigated based on profiles of temperature,salinity and microstructure data obtained during February 2014.Vertical thermohaline structures are distinct due to geographic features and sea ice distribution,resulting in that turbulent dissipation rates(ε) and turbulent diffusivity(K) are vertically and spatially non-uniform.On the shelf north of Antarctic Peninsula and Philip Ridge,with a relatively homogeneous vertical structure of temperature and salinity through the entire water column in the upper 200 m,both ε and K show significantly enhanced values in the order of O(10~(-7))-O(10~(-6)) W/kg and O(10~(-3))-O(10~(-2)) m~2/s respectively,about two or three orders of magnitude higher than those in the open ocean.Mixing intensities tend to be mild due to strong stratification in the Powell Basin and South Orkney Plateau,where s decreases with depth from O(10~(-8)) to O(10~(-9)) W/kg,while K changes vertically in an inverse direction relative to s from O(10~(-6)) to O(10~(-5)) m~2/s.In the marginal ice zone,K is vertically stable with the order of10~(-4) m~2/s although both intense dissipation and strong stratification occur at depth of 50-100 m below a cold freshened mixed layer.Though previous studies indentify wind work and tides as the primary energy sources for turbulent mixing in coastal regions,our results indicate weak relationship between K and wind stress or tidal kinetic energy.Instead,intensified mixing occurs with large bottom roughness,demonstrating that only when internal waves generated by wind and tide impinge on steep topography can the energy dissipate to support mixing.In addition,geostrophic current flowing out of the Weddell Sea through the gap west of Philip Passage is another energy source contributing to the local intense mixing.     

Seasonal variations in the nitrogen isotopic composition of settling particles at station K2 in the western subarctic North Pacific

Intensive observations using hydrographical cruises and moored sediment trap deployments during 2010 and 2012 at station K2 in the North Pacific Western Subarctic Gyre (WSG) revealed seasonal changes in δ ¹⁵N of both suspended and settling particles. Suspended particles (SUS) were collected from depths between the surface and 200 m; settling particles by drifting sediment traps (DST; 100–200 m) and moored sediment traps (MST; 200 and 500 m). All particles showed higher δ ¹⁵N values in winter and lower in summer, contrary to the expected by isotopic fractionation during phytoplankton nitrate consumption. We suggest that these observed isotopic patterns are due to ammonium consumption via light-controlled nitrification, which could induce variations in δ ¹⁵N(SUS) of 0.4–3.1 ‰ in the euphotic zone (EZ). The δ ¹⁵N(SUS) signature was reflected by δ ¹⁵N(DST) despite modifications during biogenic transformation from suspended particles in the EZ. δ ¹⁵N enrichment (average: 3.6 ‰) and the increase in C:N ratio (by 1.6) in settling particles suggests year-round contributions of metabolites from herbivorous zooplankton as well as TEPs produced by diatoms. Accordingly, seasonal δ ¹⁵N(DST) variations of 2.4–7.0 ‰ showed a significant correlation with primary productivity (PP) at K2. By applying the observed δ ¹⁵N(DST) vs. PP regression to δ ¹⁵N(MST) of 1.9–8.0 ‰, we constructed the first annual time-series of PP changes in the WSG. This new approach to estimate productivity can be a powerful tool for further understanding of the biological pump in the WSG, even though its validity needs to be examined carefully.     

Determination of the chlorophyll <Emphasis Type="Italic">a</Emphasis> concentration by MODIS-Aqua and VIIRS satellite radiometers in Eastern Arctic and Bering Sea

The waters of the Bering and Chukchi seas, as well as the De Long Strait, are investigated based on the data obtained in August 2013 during the scientific expedition of the Far Eastern Floating University on the research vessel Professor Khlyustin. Chlorophyll a concentrations calculated from MODIS-Aqua and VIIRS satellite data by ocean color and obtained by means of shipboard flow-through fluorometric measurements are comparatively analyzed. Vessel data are corrected for standard spectrophotometric measurements and the vertical depth distribution of phytoplankton. It has been found that, in the waters of the Eastern Arctic, satellite radiometers showed overestimated chlorophyll a concentrations in the upper seawater layer visible from the satellite. This is associated with the additional contribution of colored dissolved organic matter in the sea surface color. In the De Long Strait, satellite measurements incorrectly estimate the depth integrated chlorophyll a concentration, since the bulk of phytoplankton cells at a chlorophyll a concentration of 10–20 g/L is at depths of 25–30 m with luminosity of 5%.     

Growth dynamics of the deep-water Asian eelgrass, <Emphasis Type="Italic">Zostera asiatica</Emphasis>, in the eastern coastal waters of Korea

Among the seagrasses that occur along the coast of Korea, Zostera asiatica inhabits the deepest depth; however, to date, there is limited information on its ecology. This study presents the first quantitative data on the seasonal growth dynamics of Z. asiatica in Korea. We measured seasonal growth and morphological characteristics, as well as environmental factors, including underwater irradiance, water temperature, salinity and nutrient concentrations of the water column and sediment pore water, bimonthly from July 2012 to May 2015. Underwater irradiance showed clear seasonal trends, increasing in the spring and summer and decreasing in the fall and winter, ranging from 2.4 ± 0.2 mol photons m^-2 d^-1 in November 2012 to 12.8 ± 1.3 mol photons m^-2 d^-1 in July 2014. Water temperature also followed a strong seasonal trend similar to underwater irradiance, ranging from 9.8 ± 0.1°C in January 2013 to 20.5 ± 0.2°C in September 2013. Nutrient availability fluctuated substantially, but there was no evidence of distinct seasonal variations. Shoot density, biomass, leaf productivity, and morphological characteristics of Z. asiatica exhibited significant seasonal variations: maximum values of these variables occurred in summer, and the minima were recorded in winter. Total shoot density was highest (218.8 ± 18.8 shoots m^-2) in July 2012 and lowest (106.3 ± 6.3 shoots m^-2) in January 2013. Total biomass ranged from 182.6 ± 16.9 g dry weight (DW) m^-2 in January 2015 to 310.9 ± 6.4 g DW m^-2 in July 2014.Areal leaf production was highest (4.9 ± 0.0 g DW m^-2 d^-1) in July 2012 and lowest (1.4 ± 0.2 g DW m^-2 d^-1) in January 2013. The optimum water temperature for the growth of Z. asiatica was between 16-19°C. Growth of Z. asiatica was more strongly correlated with underwater irradiance than water temperature, suggesting that light is the most important factor determining seasonality of Z. asiatica at the study site.     

Temporal changes in the geographic distribution of two clam species <Emphasis Type="Italic">Meretrix lusoria</Emphasis> and <Emphasis Type="Italic">M. petechialis</Emphasis> along the coast of Japan and South Korea

The objectives of this study were to distinguish fossil specimens of Meretrix (Bivalvia, Veneridae) using discriminant score and multivariate analysis, and to examine temporal changes in the geographical distributions of M. lusoria and M. petechialis in Japan and South Korea. Fossil shells of Meretrix were collected from Miyagi, Fukui, Aichi and Kumamoto in Japan, and Gimhae, Seosan, Siheung and Ganghwa-do in South Korea. The outside of the right valve was photographed with a digital camera, and ten characteristics of the shell morphology, such as shell height and shell length, were measured using image analysis software and a digital slide caliper. The discriminant score and multivariate analysis of the shell morphology identified all of the examined fossils as M. lusoria, while living individuals collected from the western coast of South Korea were identified as M. petechialis. These results suggest that the fossil shells excavated from the western coast of South Korea are a different species from the living individuals collected from the same areas. Radioactive carbon isotopic results revealed that the ages of the four fossil shells collected from tidal flats in Ganghwa-do ranged between 3,270 ± 30 and 1,830 ± 30 Cal BP. These results suggest that M. lusoria inhabited the western coast of South Korea until at least 2,000 years ago, but was replaced by M. petechialis during the last 2,000 years. Therefore, we propose that either M. petechialis spats were introduced artificially, or planktonic larvae migrated naturally from China to the western coast of South Korea during the last 2,000 years.     

Effects of temperature on growth,photophysiology, Rubisco gene expression in <Emphasis Type="Italic">Prorocentrum donghaiense</Emphasis> and <Emphasis Type="Italic">Karenia mikimotoi</Emphasis>

To explore the effects of temperature changes on dinoflagellate bloom succession in the coastal waters of the East China Sea, changes in the growth, photophysiology, and Rubisco gene expression of Prorocentrum donghaiense and Karenia mikimotoi, two harmful algal species, were investigated at different temperatures (16 to 28°C). The maximal specific growth rate and the maximal mRNA expression of Rubisco gene in P. donghaiense and K. mikimotoi occurred at 20 and 24°C, respectively. The photosynthetic activity of P. donghaiense was generally stable, but K. mikimotoi photosynthesis increased when temperatures rose from 16 to 28°C. The effective photochemical efficiency (F _q ^′ /F _m ^′ ) and the maximal relative electron transfer rate (rETR_max) of K. mikimotoi increased significantly with increasing temperature, and the lowest and highest values occurred at 16 and 28°C, respectively. It seems that P. donghaiense has higher photosynthetic capacity than K. mikimotoi due to its higher F _q ^′ /F _m ^′ , rETR_max, and photosynthetic efficiency (α). However, K. mikimotoi has a higher growth rate than P. donghaiense. These results suggest that the photosynthetic activity and genetic responses of dinoflagellates are species-dependent. It is likely that temperature changes affect species composition during blooms, leading to the observed patterns of bloom succession.