Production of Drinking Water from Highly Contaminated Surface Waters: Removal of Organic,Inorganic, and Microbial Contaminants Applying Mobile Membrane Filtration Units

In military out of area missions of the Bundeswehr, it can be necessary to produce drinking water even from highly polluted surface waters containing a variety of organic, inorganic, and microbiological contaminants. Thus, mobile drinking water purification systems must be able to remove such contaminants as far as possible to meet the requirements of the German and European drinking water regulation/directive. Presently, two novel drinking water purification units applying membrane filtration undergo intensive long‐term trials carried out by the Bundeswehr. If these trials positively proof the functionality of these units and their ability to remove all possible contaminants they shall substitute so far available devices which use large amounts of chemicals and charcoal filtration for water purification.In the course of a research project, the functionality of the new devices and their efficacy to remove high amounts of algae, microbes, and organic and inorganic pollutants are additionally tested in “worst‐case” field studies. In September 2000, the first mobile drinking water purification unit was tested at the Teltowkanal in Berlin, Germany.This canal was chosen because it carries high burdens of municipal sewage effluents. The results from the fatigue test confirmed the ability of the water purification unit to reduce the concentrations of all contaminants meeting the maximum tolerance levels set by the German/European drinking water regulation.The pre‐filtration device was very effective in removing algae and solid particles to protect the membranes from clogging and to enable an almost maintenance‐free operation. Residues of pharmaceuticals and some other organic contaminants have almost totally been removed from the surface water where they were detected at individual concentrations up to the μg/L‐level.     

Scum in Nutrient Removal Plants: The Role of Carbon Sources in “Microthrix parvicella” Growth

Scum formation is a widespread problem in activated sludge nutrient removal plants. It often comes along with an excessive development of the filamentous bacterium “Microthrix parvicella” stabilizing the flotation process. As “M. parvicella” was found to depend on long‐chain fatty acids (LCFA) as sole carbon source not only in vitro but also in situ, some options of in‐situ substrate supply are discussed. Wastewater concentrations of fatty acids in the range of 2 to 15 mg L^‐1 and homologue concentrations from synthetic surfactant degradation below 10 mg L^‐1 rule out these substrates as source for excessive biomass production. They might, however, well be suitable for start‐up of a “M. parvicella” population. Build‐up of excessive biomass might rely on fatty acid supply originating in cell walls of lysed stationary phase bacteria of long residence time sludge fractions such as scum layers. Moreover, biogenic surfactants such as rhamnolipids have been proved to be an excellent carbon source for excessive biomass production in vitro.     

Determination of subcatchment and watershed boundaries in a complex and highly urbanized landscape

Urban development significantly alters the landscape by introducing widespread impervious surfaces, which quickly convey surface run‐off to streams via stormwater sewer networks, resulting in “flashy” hydrological responses. Here, we present the inadequacies of using raster‐based digital elevation models and flow‐direction algorithms to delineate large and highly urbanized watersheds and propose an alternative approach that accounts for the influence of anthropogenically modified land cover. We use a semi‐automated approach that incorporates conventional drainage networks into overland flow paths and define the maximal run‐off contributing area. In this approach, stormwater pipes are clustered according to their slope attributes, which define flow direction. Land areas drained by each cluster and contributing (or exporting) flow to a topographically delineated catchment were determined. These land masses were subsequently added or removed from the catchment, modifying both the shape and the size. Our results in a highly urbanized Toronto, Canada, area watershed indicate a moderate net increase in the directly connected watershed area by 3% relative to a topographically forced method; however, differences across three smaller scale subcatchments are greater. Compared to topographic delineation, the directly connected watershed areas of both the upper and middle subcatchments decrease by 5% and 8%, respectively, whereas the lower subcatchment area increases by 15%. This is directly related to subsurface storm sewer pipes that cross topographic boundaries. When directly connected subcatchment area is plotted against total streamflow and flashiness indices using this method, the coefficients of variation are greater (0.93 to 0.97) compared to the use of digital elevation model‐derived subcatchment areas (0.78 to 0.85). The accurate identification of watershed and subcatchment boundaries should incorporate ancillary data such as stormwater sewer networks and retention basin drainage areas to reduce water budget errors in urban systems.     

A low‐dimensional model of bedrock weathering and lateral flow coevolution in hillslopes: 2. Controls on weathering and permeability profiles,drainage hydraulics,and solute export pathways

The advance of a chemical weathering front into the bedrock of a hillslope is often limited by the rate weathering products that can be carried away, maintaining chemical disequilibrium. If the weathering front is within the saturated zone, groundwater flow downslope may affect the rate of transport and weathering—however, weathering also modifies the rock permeability and the subsurface potential gradient that drives lateral groundwater flow. This feedback may help explain why there tends to be neither “runaway weathering” to great depth nor exposed bedrock covering much of the earth and may provide a mechanism for weathering front advance to keep pace with incision of adjacent streams into bedrock. This is the second of a two‐part paper exploring the coevolution of bedrock weathering and lateral flow in hillslopes using a simple low‐dimensional model based on hydraulic groundwater theory. Here, we show how a simplified kinetic model of 1‐D rock weathering can be extended to consider lateral flow in a 2‐D hillslope. Exact and approximate analytical solutions for the location and thickness of weathering within the hillslope are obtained for a number of cases. A location for the weathering front can be found such that lateral flow is able to export weathering products at the rate required to keep pace with stream incision at steady state. Three pathways of solute export are identified: “diffusing up,” where solutes diffuse up and away from the weathering front into the laterally flowing aquifer; “draining down,” where solutes are advected primarily downward into the unweathered bedrock; and “draining along,” where solutes travel laterally within the weathering zone. For each pathway, a different subsurface topography and overall relief of unweathered bedrock within the hillslope is needed to remove solutes at steady state. The relief each pathway requires depends on the rate of stream incision raised to a different power, such that at a given incision rate, one pathway requires minimal relief and, therefore, likely determines the steady‐state hillslope profile.     

Introducing environmental thresholds into water withdrawal management of mountain streams in the Kura River basin,Azerbaijan

Abstract

The study aims to set and implement environmentally relevant limits for the exploitation of mountain streams in the Kura River basin of Azerbaijan. Such streams represent the preferred spawning grounds for valuable sturgeon of the Caspian Sea, but experience continuously increasing exploitation in the form of water withdrawals for industry and irrigation. Since no detailed environmental flow assessments have been conducted on any of the Kura basin streams, an interim approach is suggested based on minimum flow, referred to as “base environmental minimum”. The latter may be estimated from the unregulated parts of observed or simulated daily flow records. Environmental flow requirements for individual months of an individual year may be calculated using correction factors related to monthly rainfall. Simple relationships are suggested for base environmental flow estimation at ungauged sites, and the implications of river pollution for monthly environmental requirements are examined. Further, definition of environmentally critical periods in a stream is proposed based on a ratio of observed to “environmental” flow as an indicator of environmental stress. It is illustrated that the conjunctive use of several closely located streams for water supply may significantly reduce the duration of, or completely eliminate, environmentally critical periods. The idea of environmentally acceptable areal water withdrawal is formulated, so that the overall approach may be applied for environmentally sustainable water withdrawal management in other small streams.     

Numerical investigation of alternative fracture stiffness measures and their respective scaling behaviours

We study the mechanical deformation of fractures under normal stress, via tangent and specific fracture stiffnesses, for different length scales using numerical simulations and analytical insights. First, we revisit an equivalent elastic layer model that leads to two expressions: the tangent stiffness is the sum of an “intrinsic” stiffness and the normal stress, and the specific stiffness is the tangent stiffness divided by the fracture aperture at current stress. Second, we simulate the deformation of rough fractures using a boundary element method where fracture surfaces represented by elastic asperities on an elastic half‐space follow a self‐affine distribution. A large number of statistically identical “parent” fractures are generated, from which sub‐fractures of smaller dimensions are extracted. The self‐affine distribution implies that the stress‐free fracture aperture increases with fracture length with a power law in agreement with the chosen Hurst exponent. All simulated fractures exhibit an increase in the specific stiffness with stress and an average decrease with increase in length consistent with field observations. The simulated specific and tangent stiffnesses are well described by the equivalent layer model provided the “intrinsic” stiffness slightly decreases with fracture length following a power law. By combining numerical simulations and the analytical model, the effect of scale and stress on fracture stiffness measures can be easily separated using the concept of “intrinsic” stiffness. We learn that the primary reason for the variability in specific stiffness with length comes from the fact that the typical aperture of the self‐affine fractures itself scales with the length of the fractures.     

Urban water systems under climate stress: An isotopic perspective from Berlin,Germany

Large urban areas are typically characterized by a mosaic of different land uses, with contrasting mixes of impermeable and permeable surfaces that alter “green” and “blue” water flux partitioning. Understanding water partitioning in such heterogeneous environments is challenging but crucial for maintaining a sustainable water management during future challenges of increasing urbanization and climate warming. Stable isotopes in water have outstanding potential to trace the partitioning of rainfall along different flow paths and identify surface water sources. While isotope studies are an established method in many experimental catchments, surprisingly few studies have been conducted in urban environments. Here, we performed synoptic sampling of isotopes in precipitation, surface water and groundwater across the complex city landscape of Berlin, Germany, for a large -scale overview of the spatio-temporal dynamics of urban water cycling. By integrating stable isotopes of water with other hydrogeochemical tracers we were able to identify contributions of groundwater, surface runoff during storm events and effluent discharge on streams with variable degrees of urbanization. We could also assess the influence of summer evaporation on the larger Spree and Havel rivers and local wetlands during the exceptionally warm and dry summers of 2018 and 2019. Our results demonstrate that using stable isotopes and hydrogeochemical data in urban areas has great potential to improve our understanding of water partitioning in complex, anthropogenically-affected landscapes. This can help to address research priorities needed to tackle future challenges in cities, including the deterioration of water quality and increasing water scarcity driven by climate warming, by improving the understanding of time-variant rainfall-runoff behaviour of urban streams, incorporating field data into ecohydrological models, and better quantifying urban evapotranspiration and groundwater recharge.     

Retracted and replaced: A modelling study of hyporheic exchange pattern and the sequence,size, and spacing of stream bedforms in mountain stream networks,Oregon, USA

This article has been retracted and replaced. See Retraction and Replacement Notice DOI: 10.1002/hyp.6350 Studies of hyporheic exchange flows have identified physical features of channels that control exchange flow at the channel unit scale, namely slope breaks in the longitudinal profile of streams that generate subsurface head distributions. We recently completed a field study that suggested channel unit spacing in stream longitudinal profiles can be used to predict the spacing between zones of upwelling (flux of hyporheic water into the stream) and downwelling (flux of stream water into the hyporheic zone) in the beds of mountain streams. Here, we use two‐dimensional groundwater flow and particle tracking models to simulate vertical and longitudinal hyporheic exchange along the longitudinal axis of stream flow in second‐, third‐, and fourth‐order mountain stream reaches. Modelling allowed us to (1) represent visually the effect that the shape of the longitudinal profile has on the flow net beneath streambeds; (2) isolate channel unit sequence and spacing as individual factors controlling the depth that stream water penetrates the hyporheic zone and the length of upwelling and downwelling zones; (3) evaluate the degree to which the effects of regular patterns in bedform size and sequence are masked by irregularities in real streams. We simulated hyporheic exchange in two sets of idealized stream reaches and one set of observed stream reaches. Idealized profiles were constructed using regression equations relating channel form to basin area. The size and length of channel units (step size, pool length, etc.) increased with increasing stream order. Simulations of hyporheic exchange flows in these reaches suggested that upwelling lengths increased (from 2·7 m to 7·6 m), and downwelling lengths increased (from 2·9 m to 6·0 m) with increase in stream order from second to fourth order. Step spacing in the idealized reaches increased from 5·3 m to 13·7 m as stream size increased from second to fourth order. Simulated upwelling lengths increased from 4·3 m in second‐order streams to 9·7 m in fourth‐order streams with a POOL–RIFFLE–STEP channel unit sequence, and increased from 2·5 m to 6·1 m from second‐ to fourth‐order streams with a POOL–STEP–RIFFLE channel unit sequence. Downwelling lengths also increased with stream order in these idealized channels. Our results suggest that channel unit spacing, size, and sequence are all important in determining hyporheic exchange patterns of upwelling and downwelling. Though irregularities in the size and spacing of bedforms caused flow nets to be much more complex in surveyed stream reaches than in idealized stream reaches, similar trends emerged relating the average geomorphic wavelength to the average hyporheic wavelength in both surveyed and idealized reaches. Copyright © 2005 John Wiley & Sons, Ltd.     

A modelling study of hyporheic exchange pattern and the sequence,size, and spacing of stream bedforms in mountain stream networks,Oregon, USA

Studies of hyporheic exchange flows have identified physical features of channels that control exchange flow at the channel unit scale, namely slope breaks in the longitudinal profile of streams that generate subsurface head distributions. We recently completed a field study that suggested channel unit spacing in stream longitudinal profiles can be used to predict the spacing between zones of upwelling (flux of hyporheic water into the stream) and downwelling (flux of stream water into the hyporheic zone) in the beds of mountain streams. Here, we use two‐dimensional groundwater flow and particle tracking models to simulate vertical and longitudinal hyporheic exchange along the longitudinal axis of stream flow in second‐, third‐, and fourth‐order mountain stream reaches. Modelling allowed us to (1) represent visually the effect that the shape of the longitudinal profile has on the flow net beneath streambeds; (2) isolate channel unit sequence and spacing as individual factors controlling the depth that stream water penetrates the hyporheic zone and the length of upwelling and downwelling zones; (3) evaluate the degree to which the effects of regular patterns in bedform size and sequence are masked by irregularities in real streams. We simulated hyporheic exchange in two sets of idealized stream reaches and one set of observed stream reaches. Idealized profiles were constructed using regression equations relating channel form to basin area. The size and length of channel units (step size, pool length, etc.) increased with increasing stream order. Simulations of hyporheic exchange flows in these reaches suggested that upwelling lengths increased (from 2·7 m to 7·6 m), and downwelling lengths increased (from 2·9 m to 6·0 m) with increase in stream order from second to fourth order. Step spacing in the idealized reaches increased from 5·3 m to 13·7 m as stream size increased from second to fourth order. Simulated downwelling lengths increased from 4·3 m in second‐order streams to 9·7 m in fourth‐order streams with a POOL–RIFFLE–STEP channel unit sequence, and increased from 2·5 m to 6·1 m from second‐ to fourth‐order streams with a POOL–STEP–RIFFLE channel unit sequence. Upwelling lengths also increased with stream order in these idealized channels. Our results suggest that channel unit spacing, size, and sequence are all important in determining hyporheic exchange patterns of upwelling and downwelling. Though irregularities in the size and spacing of bedforms caused flow nets to be much more complex in surveyed stream reaches than in idealized stream reaches, similar trends emerged relating the average geomorphic wavelength to the average hyporheic wavelength in both surveyed and idealized reaches. This article replaces a previously published version (Hydrological Processes, 19 (17), 2915–2929 (2005) [ DOI:10.1002/hyp.5790 ]. See also retraction notice DOI:10.1002/hyp.6350 Copyright © 2006 John Wiley & Sons, Ltd.     

Spatial analysis of instream nitrogen loads and factors controlling nitrogen delivery to streams in the southeastern United States using spatially referenced regression on watershed attributes (SPARROW) and regional classification frameworks

Understanding how nitrogen transport across the landscape varies with landscape characteristics is important for developing sound nitrogen management policies. We used a spatially referenced regression analysis (SPARROW) to examine landscape characteristics influencing delivery of nitrogen from sources in a watershed to stream channels. Modelled landscape delivery ratio varies widely (by a factor of 4) among watersheds in the southeastern United States—higher in the western part (Tennessee, Alabama, and Mississippi) than in the eastern part, and the average value for the region is lower compared to other parts of the nation. When we model landscape delivery ratio as a continuous function of local‐scale landscape characteristics, we estimate a spatial pattern that varies as a function of soil and climate characteristics but exhibits spatial structure in residuals (observed load minus predicted load). The spatial pattern of modelled landscape delivery ratio and the spatial pattern of residuals coincide spatially with Level III ecoregions and also with hydrologic landscape regions. Subsequent incorporation into the model of these frameworks as regional scale variables improves estimation of landscape delivery ratio, evidenced by reduced spatial bias in residuals, and suggests that cross‐scale processes affect nitrogen attenuation on the landscape. The model‐fitted coefficient values are logically consistent with the hypothesis that broad‐scale classifications of hydrologic response help to explain differential rates of nitrogen attenuation, controlling for local‐scale landscape characteristics. Negative model coefficients for hydrologic landscape regions where the primary flow path is shallow ground water suggest that a lower fraction of nitrogen mass will be delivered to streams; this relation is reversed for regions where the primary flow path is overland flow. Published in 2009 by John Wiley & Sons, Ltd.     

Hydrology of channelized and natural headwater streams / Hydrologie de cours d'eau recalibrés et naturels de tête de bassin

Abstract

Understanding hydrology of channelized and natural headwater streams is paramount for maintaining ecosystem function and natural flow regimes. Two channelized and two natural headwater streams located in Upper Big Walnut Creek (UBWC) watershed in Ohio, USA, were instrumented to facilitate measurement, characterization and comparison of hydrology to the accepted paradigm for headwater hydrology. Data were collected at 10-min intervals from 1 January 2005 to 31 December 2006. Differences in flow magnitudes (average, low and high) were generally greater (P < 0.05) in the channelized streams. Frequency of zero discharge and out-of-bank discharge was significantly greater in the natural streams. Zero discharge occurred in summer and out-of-bank flows occurred in winter. Rate of change variables indicated that channelized streams respond more quickly to rainfall, have significantly greater peak flows, and have slower recession times. In contrast, natural streams tend to be more “flashy”. The findings were generally consistent with the accepted paradigm for headwater hydrology and attributed to stream type, presence of subsurface drainage, potential connection to groundwater, and differences in riparian vegetation. The design and installation of management practices that influence hydrology should consider the potential impacts of altering stream hydrology. Management practices such as water-table management have the potential and show promise in altering the hydrology of channelized streams to resemble the hydrology of natural streams.     

Trophieindikation in Fließgewässern mit Hilfe des TIM (Trophie‐Index Makrophyten) – Erprobung eines neu entwickelten Index im Inninger Bach

Indicating the Trophic State of Running Waters by Using TIM (Trophic Index of Macrophytes) – Exemplary Implementation of a New Index in the River Inninger Bach The river Inninger Bach represents the outflow of the lake Wörthsee (Bavaria). The mean pH of the calcareous river has a value of ca. 8 during the vegetation period, the mean conductivity is about 350 to 400 μS/cm. The macrophyte vegetation of the river course was mapped and the nutrient concentrations of both the water body and the sediment were measured. In every mapping section the Trophic Index of Macrophytes (TIM) was calculated. By cluster analysis the mapping sections were grouped into three zones which differed in macrophyte vegetation. These differences are not associated with varying nutrient concentrations but are mainly due to differences in the degree of shading. In spite of the characterisation of the lake Wörthsee as oligo‐mesotrophic the river Inninger Bach, which represents the outflow of the lake Wörthsee, is classified as meso‐eutrophic by the Trophic Index of Macrophytes TIM. The increased trophic state of the river compared to the lake is caused by the river Krebsbach, a small tributary flowing into the river Inninger Bach only a short stretch downstream of its outflow of the lake Wörthsee. The river Krebsbach shows a total phosphorus concentration of about 56 μg/L P. The input of diaspores of submerged macrophytes both from the oligo‐mesotrophic lake Wörthsee and the eutrophic river Krebsbach leads to a submerged vegetation comprising species with different optima in regard to the trophic situation. This is one of the main reasons why many values of the TIM have to be labeled as “not sure”.     

Ecological and environmental instream flow requirements for the Wei River—the largest tributary of the Yellow River

Instream flows are essential determinants of channel morphology, riparian and aquatic flora and fauna, water quality estuarine inflow and stream load transport. The ecological and environmental instream flow requirements (EEIFR) should be estimated to make the exploitation and utilization of water resources in a highly efficient and sustainable way and maintain the river ecosystem good health. As the largest tributary of the Yellow River, the Wei River is the ‘Mother River’ of Guanzhong region in Shaanxi province. It plays a great role in the development of West China and the health of the ecosystem of the Yellow River. The objective of this study is to estimate the EEIFR for improving the Wei River's ecological and environmental condition and develop the river healthily. Concerning the main ecological and environmental functions of the Wei River in Shaanxi Province, the EEIFR for each section of the Wei River including minimum instream flow requirements (IFR) for aquicolous biotopes maintenance, IFR for channel seepage, channel evaporation, stream self‐purification and sediment transportation were estimated in this paper. The methods to estimate the instream flow requirements for stream self‐purification and instream flow requirements for sediment transportation were proposed. The temporal scale of typical years include the year with the probability 25% of occurrence (high‐flow year), the year with the probability 50% (normal‐flow year) and the year with the probability 75% (low‐flow year). The results show that the EEIFR for the Wei River mainly include instream flow requirements for self‐purification and sediment transportation in each typical year. From high‐flow year to low‐flow year, the annual EEIFR for each reach decrease, except those for the reach from Linjiacun to Weijiabao, and from Linjiacun at the upper reaches to Huaxian at the lower reaches, and the annual reach EEIFR decrease in a sequence. Copyright © 2007 John Wiley & Sons, Ltd.     

Coevolution of hydrology and topography on a basalt landscape in the Oregon Cascade Range,USA

Young basalt terrains offer an exceptional opportunity to study landscape and hydrologic evolution through time, since the age of the landscape itself can be determined by dating lava flows. These constructional terrains are also highly permeable, allowing one to examine timescales and process of geomorphic evolution as they relate to the partitioning of hydrologic flowpaths between surface and sub‐surface flow. The western slopes of the Cascade Range in Oregon, USA are composed of a thick sequence of lava flows ranging from Holocene to Oligocene in age, and the landscape receives abundant precipitation of between 2000 and 3500 mm per year. On Holocene and late Pleistocene lava landscapes, groundwater systems transmit most of the recharge to large springs (≥0·85 m³ s^?1) with very steady hydrographs. In watersheds >1 million years old, springs are absent, and well‐developed drainage networks fed by shallow subsurface stormflow produce flashy hydrographs. Drainage density slowly increases with time in this basalt landscape, requiring a million years to double in density. Progressive hillslope steepening and fluvial incision also occur on this timescale. Springs and groundwater‐fed streams transport little sediment and hence are largely ineffective in incising river valleys, so fluvial landscape dissection appears to occur only after springs are replaced by shallow subsurface stormflow as the dominant streamflow generation mechanism. It is proposed that landscape evolution in basalt terrains is constrained by the time required for permeability to be reduced sufficiently for surface flow to replace groundwater flow. Copyright © 2010 John Wiley & Sons, Ltd.     

Classifying the flow regimes of Mediterranean streams using multivariate analysis

Rivers in the Mediterranean region often exhibit an intermittent character. An understanding and classification of the flow regimes of these rivers is needed, as flow patterns control both physicochemical and biological processes. This paper reports an attempt to classify flow regimes in Mediterranean rivers based on hydrological variables extracted from discharge time series. Long‐term discharge records from 60 rivers within the Mediterranean region were analysed in order to classify the streams into different flow regime groups. Hydrological indices (HIs) were derived for each stream and principal component analysis (PCA) and then applied to these indices to identify subsets of HIs describing the major sources of variations, while simultaneously minimizing redundancy. PCA was performed for two groups of streams (perennial and temporary) and for all streams combined. The results show that whereas perennial streams are mainly described by high‐flow indices, temporary streams are described by duration, variability and predictability indices. Agglomerative cluster analysis based on HIs identified six groups of rivers classified according to differences in intermittency and variability. A methodology allowing such a classification for ungauged catchments was also tested. Broad‐scale catchment characteristics based on digital elevation, climate, soil and land use data were derived for each long‐term station where these data were available. By using stepwise multiple regression analysis, statistically significant relationships were fitted, linking the three selected hydrological variables (mean annual number of zero‐flow days, predictability and flashiness) to the catchment characteristics. The method provides a means of simplifying the complexity of river systems and is thus useful for river basin management. Copyright © 2015 John Wiley & Sons, Ltd.     

Quantifying groundwater dependency of riparian surface hydrologic features using the exit gradient

Numerical groundwater flow models necessarily are limited to subsurface flow evaluation. It is of interest, however, to examine the possibility that, for unconfined aquifer systems, they could be used to proportionately measure the magnitude of seepage they estimate when these aquifers intersect the landscape surface. Our goal in this study was to determine the degree to which an unconfined groundwater model can estimate run‐off or seepage at the land surface during winter time wet season conditions, as well as in the dry season, when evapotranspiration is a major part of the water balance, using a lowland basin‐fill example study area in the Pacific Northwest. The exit gradient is a metric describing the potential for vertical seepage at the landscape surface. We investigated the spatial relationship of mapped surface features, such as wetlands, streams and ponds, to the model‐predicted mapped exit gradient. We found that areas mapped as wetlands had positive exit gradients. During the wet season, modelled exit gradients predicted seepage throughout extensive areas of the groundwater shed, extending far beyond mapped wetland areas (355% increase), associated with previously observed increases in nitrate‐nitrogen in streams in wet season. During the dry season, exit gradients spatially corresponded with wetland areas. The increase in in‐stream nitrogen corresponds with shorter residence times in carbon‐rich wetland zones because of the onset of saturation overland flow. We present results that suggest that the exit gradient could be a useful concept in examining the groundwater–surface water linkage that is often under represented physically in watershed flow models. Published 2015. This article is a U.S. Government work and is in the public domain in the USA.     

Patterns in stream longitudinal profiles and implications for hyporheic exchange flow at the H.J. Andrews Experimental Forest,Oregon, USA

There is a need to identify measurable characteristics of stream channel morphology that vary predictably throughout stream networks and that influence patterns of hyporheic exchange flow in mountain streams. In this paper we characterize stream longitudinal profiles according to channel unit spacing and the concavity of the water surface profile. We demonstrate that: (1) the spacing between zones of upwelling and downwelling in the beds of mountain streams is closely related to channel unit spacing; (2) the magnitude of the vertical hydraulic gradients (VHGs) driving hyporheic exchange flow increase with increasing water surface concavity, measured at specific points along the longitudinal profile; (3) channel unit spacing and water surface concavity are useful metrics for predicting how patterns in hyporheic exchange vary amongst headwater and mid‐order streams. We use regression models to describe changes in channel unit spacing and concavity in longitudinal profiles for 12 randomly selected stream reaches spanning 62 km² in the H.J. Andrews Experimental Forest in Oregon. Channel unit spacing increased significantly, whereas average water surface concavity (AWSC) decreased significantly with increasing basin area. Piezometer transects installed longitudinally in a subset of stream reaches were used to measure VHG in the hyporheic zone, and to determine the location of upwelling and downwelling zones. Predictions for median pool length and median distance between steps in piezometer reaches bracketed the median distance separating zones of upwelling in the stream bed. VHG in individual piezometers increased with increasing water surface concavity at individual points in the longitudinal profile along piezometer transects. Absolute values of VHG, averaged throughout piezometer transects, increased with increasing AWSC, indicating increased potential for hyporheic exchange flow. These findings suggest that average hyporheic flow path lengths increase—and the potential for hyporheic exchange flow in stream reaches decreases—along the continuum from headwater to mid‐order mountain streams. Copyright © 2005 John Wiley & Sons, Ltd.     

Die EG‐Wasserrahmenrichtlinie: Ausweisung und Bewertung künstlicher und erheblich veränderter Gewässer

Designation and Assessment of Artificial and Heavily Modified Water Bodies under the EC Water Framework Directive The EC Water Framework Directive allows the Member States to designate artificial and heavily modified water bodies under specific conditions. For those water bodies the ecological assessment and the resulting programmes of measures will be based on the “maximum ecological potential” as reference conditions and not on the “high ecological status”, which has to be used for natural water bodies. Such designation is possible only, if the hydromorphology of the water bodies concerned has been substantially changed in character to maintain specified uses. The criteria for the designation are fulfilled, if restoration measures needed to meet the high ecological status would have significant adverse effects on the uses and if no other better environmental options would exist to maintain the specified uses. In late 1999 the EC‐Working Group on Heavily Modified Water Bodies (HMWB) has been established to develop criteria for the designation of artificial and heavily modified water bodies as well as for the determination of the maximum ecological potential. The working group has produced the guidance document “Identification and Designation of Artificial and Heavily Modified Water Bodies” in November 2002, which has been agreed by the European Water Directors on 21 November 2002 in Copenhagen. The guidance document is focusing on two time borders, the provisional identification of heavily modified water bodies until 2004 and the legally binding designation as artificial and heavily modified in the first river basin management plan in 2009 at the latest. The guidance document considered the main findings of 34 case studies for rivers, lakes, transitional and coastal waters carried out in 11 European countries. The results of the case studies as well as a summarizing synthesis were used as a fundamental basis to produce the guidance document. The practical examples given by the case studies were compiled as a toolbox which supplements the guidance for the purpose of its better application.     

On the Problem of Sample Preservation by Freezing

During routine analysis of running water samples differences of the analytical results of water‐soluble anions were observed between analysis carried out immediately after sampling and after storage of the cooled/frozen sample. This phenomenon was investigated for some years with the “model ion” chloride. A high number of samples (ca. 210) were analysed over three years with different analytical methods, and by alteration of the sample containers the discrete physical influence of the wall effect of the sample vessel could be worked out definitely. No significant differences occur with the mean value of the year but the single values have high differences in the positive or negative direction. Assuming a similar behaviour of other water constituents when preserved by freezing the analytical values had to be looked at very critically.