喀斯特筑坝河流中生物碳泵效应的碳施肥及对水化学时空变化的影响——以贵州平寨水库及红枫湖为例

耦联水生光合作用的碳酸盐风化碳汇是全球碳循环的重要组成部分,而生物碳泵效应是稳定碳酸盐风化碳汇的关键机制.河流筑坝后,生物碳泵效应的变化、控制因素及对水化学影响的研究甚少.本研究对2个喀斯特筑坝河流平寨水库和红枫湖进行系统采样,以研究河流筑坝后生物碳泵效应的变化、控制因素及对水化学的影响.研究结果表明,入库河流的水化学变化不明显,而2个水库的水化学则表现出显著的季节变化特征,具体表现为水库的水温和pH均呈现出夏季高、冬季低的变化特征,而电导率（EC）、HCO₃^-浓度和pCO₂则表现出夏季低、冬季高的季节变化特征.以叶绿素a（Chl.a）浓度和溶解氧（DO）饱和度指代的生物碳泵效应则是在夏季最强、冬季最弱.生物碳泵效应利用溶解性无机碳（DIC）,形成有机质并释放出氧气,是造成夏季水库pH值和DO饱和度升高,电导率（EC）、HCO₃^-浓度和pCO₂降低的主要因素.空间上,水库的Chl.a浓度及DO饱和度均大于河水,EC、HCO₃^-浓度和pCO₂均小于河水,这表明河流筑坝后,由于水库的“湖泊化”导致水库的生物碳泵效应显著提高.通过对Chl.a与碳、氮和磷浓度及化学计量比的相关性分析发现,平寨水库和红枫湖的生物碳泵效应受到碳施肥的影响.平寨水库和红枫湖水库生物碳泵效应碳施肥机制的发现,表明在喀斯特地区,生物碳泵效应不仅受到氮磷元素的控制,也受到碳元素的控制,因此在富营养化湖泊治理时,也应考虑碳的影响.     

天津于桥水库夏季浮游生物调查及群落结构变化

为了解于桥水库富营养化状况,于2011年7月对于桥水库水质、浮游生物进行了调查.结果表明,于桥水库综合营养状态指数(TLI(∑))为45.8,属于中营养水平.浮游植物共计8门59种,平均丰度为312.40×10⁴cells/L,平均生物量为5.30 mg/L,以蓝、绿藻为主,优势种为铜绿微囊藻(Microcystis aeruginosa)、水华微囊藻(Microcystis flos-aquae)和单角盘星藻具空变种(Pediastrum simplex var.duodenarium).浮游动物共计16种,平均丰度为53.2 ind./L,平均生物量为11.58 mg/L,以长额象鼻蚤(Bosmina longirostris)和近邻剑水蚤(Cyclops vicinus)为优势种.依据多样性指数、均匀度指数和丰富度指数对于桥水库浮游生物进行评价,表明于桥水库处于中~重污染水平,这与采用TLI(∑)的评价结果较为一致.与历史同期调查结果对比得出,于桥水库浮游植物丰度、生物量增加,浮游动物种类减少,而生物量增加,于桥水库由硅-蓝藻型水库过渡为硅-绿藻型水库,最终向蓝-绿藻型水库演变.     

太湖蓝藻水华暴发的氮磷控制阈值分析

藻类生长与营养盐浓度存在藻类几何级数增长的营养盐浓度变化的下限阈值和藻类生长不受氮磷浓度增加影响的上限阈值,但由于蓝藻水华的形成受多种因素的综合影响,不同湖泊、不同区域及不同时段的氮磷浓度对蓝藻水华的影响差别较大,使得蓝藻生长的氮磷控制阈值难以确定.针对控制蓝藻水华暴发的氮磷阈值的研究虽然有所开展,但多集中在实验室研究阶段或对经验值的判断,虽然也有基于野外实测数据的研究,但也限制于某一特定区域,而基于野外长序列实测数据并且覆盖整个湖泊的氮磷阈值研究则是空白.太湖作为具有较高营养背景的富营养化浅水湖泊,蓝藻水华的发生受氮磷影响较大.对太湖总磷(TP)、总氮(TN)和叶绿素a(Chl.a)浓度的时空变化分析发现,太湖西北湖区的TP、TN与Chl.a浓度明显较高,并且TP、TN与Chl.a均呈显著性正相关.为探究太湖蓝藻水华暴发的TP和TN控制阈值,以轻富营养化等级下的Chl.a分级标准(10,26］作为表征水华暴发的条件,采用郑丙辉等的频率分布法,确定了太湖蓝藻水华暴发的TP和TN控制阈值分别为0.05~0.06和1.71~1.72 mg/L;通过空间验证,太湖藻型区TP和TN浓度远高于同级营养水平下全湖区TP和TN控制阈值,表明藻型区高氮磷水平为蓝藻水华发生提供充足营养盐条件,即使氮磷全湖平均浓度控制在蓝藻水华暴发的氮磷阈值水平之下,但在气象水文等因素适宜条件下,藻型区水华发生风险仍然较高;并且在高氮磷背景下,即便在水华发生风险低的季节,水华发生风险仍然较大.近十几年来,虽然太湖经历了大规模的高强度治理,但由于环太湖流域的湖西区入湖负荷占比大,导致太湖藻型区氮磷浓度仍处于高位运行状态,为蓝藻水华的暴发提供了充足的营养盐基础,因此,湖西区的控源减排仍然是太湖富营养化及蓝藻水华防控的重点.     

贵州红枫湖近10年来(2009-2018年)水质变化及影响因素

为更好地研究贵州红枫湖的水质变化情况,本文利用贵阳市两湖一库环境保护监测站2009-2018年对红枫湖7个代表性监测点的营养盐、叶绿素a（Chl.a）浓度和水温、气温、透明度、降雨量等水文气象条件逐月监测数据,分析红枫湖10年间水体营养盐和Chl.a浓度以及部分水文气象条件的变化趋势.运用综合营养状态指数（TLI）对红枫湖营养状态进行评价,采用Pearson相关系数法统计分析10年内Chl.a浓度与总磷（TP）、总氮（TN）等水化学组成及水位、气温等水文气象条件的相关性.结果表明,2009-2018年红枫湖水体逐月TN浓度有较大波动（0.56~2.80 mg/L）,春、夏季高于秋、冬季;水体逐月TP浓度为0.016~0.103 mg/L,夏季略高于冬季;逐月氨氮（NH₃-N）浓度为0.007~0.71 mg/L,春季 > 冬季 > 秋季 > 夏季;水体逐月Chl.a浓度呈季节性波动（0.8~38.9 mg/m³）,夏季 > 春季 > 秋季 > 冬季,年内先上升后下降.TP、NH₃-N、Chl.a浓度整体呈下降趋势,10年间水质有很大改善.经计算红枫湖在这10年间处于中营养状态至轻度富营养状态,且营养状态指数呈逐年下降趋势,夏季TLI明显高于其他季节.统计分析表明,红枫湖水体Chl.a浓度与高锰酸盐指数、NH₃-N、TP浓度均呈显著正相关,与氮磷比呈显著负相关,与水温、pH、降雨量、气温、日照时数呈显著正相关,与透明度、气压呈显著负相关,与水位、湿度、风速无显著相关关系.表明这10年来红枫湖水体Chl.a浓度不仅受营养盐浓度控制,很大程度上还受控于气象和水文条件.     

贵州高原百花水库浮游植物功能群的动态变化及驱动因子

为了解贵州高原百花水库浮游植物功能群的动态变化与环境因子的关系,于2020年1—12月(除2月份)对浮游植物与水环境指标进行逐月采样,利用RDA和相关性分析,结合群落更替指数(BC)对百花水库浮游植物功能群进行分析.结果表明:1)2020年百花水库共鉴定出浮游植物7门64种,其中绿藻门物种数最多为27种,其次为硅藻门和蓝藻门,浮游植物总生物量的范围为124.8~2235.4 μg/L;2)百花水库浮游植物共归类为26个功能群,其中S1、L_M、J、B、P、D、MP、Y和W1为优势功能群,多数适宜生存在中营养的水体.功能群B、D和L_M是长期处于优势地位的功能群,以梅尼小环藻(Meneghiniana cyclotella)、尖针杆藻(Synedra acus)和飞燕角甲藻(Ceratium hirundinella)为主;3)综合营养状态指数(TLI(Σ))为36.90~50.20,生态状态指数(Q)值为0.73~3.46,说明百花水库处于中营养状态.4)分析结果表明,水温和pH共同影响浮游植物优势功能群的动态变化.     

蓝藻生消对巢湖沉积物phoD碱性磷酸酶基因细菌群落结构的影响

phoD基因编码的碱性磷酸酶驱动沉积物有机磷矿化并释放生物可利用磷,促进了富营养化湖泊蓝藻的生长与暴发,但对富营养化湖泊蓝藻生消周期phoD基因细菌群落动态变化的认识依然有限.本文研究了中国典型富营养化湖泊巢湖蓝藻生消过程沉积物碱性磷酸酶活性（APA）、phoD基因细菌多样性和群落结构的动态变化及其与环境的关系.结果显示：巢湖沉积物APA活性在蓝藻生长与暴发阶段显著升高,且与水温、pH、溶解氧（DO）等环境因子显著相关.蓝藻生消各阶段沉积物phoD基因细菌群落的优势菌属均由Pseudonocardia和Friedmanniella构成;与蓝藻潜伏期和衰亡期相比,生长初期与暴发期大多数样点沉积物Pseudonocardia的丰度显著降低而Friedmanniella显著升高.携带phoD基因的菌属丰度呈显著的时空变化,其中菌属丰度的空间异质性较高.蓝藻生长初期与暴发期的phoD基因细菌群落的Ace指数与Shannon多样性指数显著大于潜伏期与衰亡期.研究表明,携带phoD基因细菌群落结构的变化主要受APA、DO、叶绿素a、水温、总磷以及无机磷的驱动;春季蓝藻的生长消耗大量上覆水溶解性无机磷,激发了沉积物APA活性并诱发Friedmanniella生长从而缓解水体磷限制.     

热带水库浮游植物形态性状的季节变化及影响因子分析——以高州水库为例

体积、比表面积和最大轴性长度是浮游植物主要的形态性状,反映浮游植物资源竞争和反牧食能力.群落中物种的性状分布会随着环境条件的季节改变而变化,热带水库环境条件的季节性变化小,可能导致群落形态性状变化不显著.本文以热带大型水库——高州水库为研究对象,分析浮游植物形态性状季节动态及关键影响因子.高州水库浮游植物以丝状和单细胞藻类为主,群落水平的平均细胞体积在108.52~753.25 μm³之间,平均比表面积在0.93~2.08 μm^-1之间,平均最大轴性长度在5.21~17.44 μm之间,均有明显的季节特征.浮游植物群落平均细胞体积、最大轴性长度与总氮浓度呈负相关,与水温呈正相关;平均比表面积与硝态氮浓度呈负相关.粘质长孢藻（Dolichospermum mucosa）和光角星鼓藻（Staurastrum muticum）是高州水库浮游植物优势种,其形态性状均具有明显的时空差异,表现出明显的形态可塑性.粘质长孢藻的平均细胞体积、最大轴性长度与总氮浓度呈正相关,与水温呈负相关;平均比表面积与总氮浓度呈负相关,与水温呈正相关.光角星鼓藻的平均细胞体积、最大轴性长度与正磷酸盐浓度呈正相关.总体上高州水库浮游植物在群落和种群水平形态性状均有明显的季节差异,夏季以大细胞为主,其他季节以小细胞种类为主,水温、氮和磷的可利用性是导致浮游植物形态性状季节差异的关键因子.     

广东长潭水库富营养化与浮游植物分布特征

为掌握梅州市长潭水库富营养化状态与浮游植物分布特征,为控制藻类水华暴发提供科学依据,2011年10月至2012年7月,在长潭水库关键断面选取10个监测点,测定水体理化特征、浮游植物种类、丰度等指标,采用营养状态指数(TLI)和Shannon-Wiener多样性指数法对水质污染现状进行评价,并分析浮游植物类群分布特征.结果表明:长潭水库水体富营养状态在4、10和12月处于中营养级,7月份处于富营养级,营养指数从库区中游上游逐渐降低;观测期间共检出浮游植物4门11科16属,通过丰度比较,发现长潭水库以蓝绿藻为优势种,并且季节变化明显,总体表现为7月 >4月 >10月 >12月;藻类多样性指数分析显示,水库水体污染水平为中度,中游和库区(除7月)为轻度污染,与综合营养指数结果一致;长潭水库污染源调查分析结果表明,该水库主要为氮、磷污染,污染源主要为上游禽畜养殖废水.     

2002-2017年千岛湖浮游植物群落结构变化及其影响因素

为认识大型水库中浮游植物群落结构的演替特征及其驱动机制,以钱塘江流域新安江水库（下称"千岛湖"）为例,基于2002-2017年16年的水库浮游植物数据,结合同期千岛湖水质与水文气象资料,分析了千岛湖浮游植物结构及优势属的长期变化特征,探讨了影响浮游植物群落结构变化的主要因素.结果表明：2002-2017年千岛湖共鉴定出浮游植物7门93属,主要由硅藻门、绿藻门、蓝藻门及隐藻门种类组成.16年间,浮游植物年均丰度和群落结构经历了4个阶段：2008年前丰度持续低值且蓝藻不是主要类群,2009-2012年丰度较高且蓝藻成为主要类群,及2013-2015丰度降低且蓝藻占比降低,2016-2017年丰度增加且蓝藻再次成为主要类群.浮游植物门类变化的同时伴随着优势属的变化：浮游植物年优势属从2002-2008年的小环藻属（Cyclotella）、隐藻属（Cryptomonas）和蓝隐藻属（Chroomonas）转变为2009-2012年的颤藻属（Oscillatoria）、小球藻属（Chlorella）、小环藻属和蓝隐藻属,2013-2017年又转变为鱼腥藻属（Anabaena）、束丝藻属（Aphanizomenon）、小环藻属、针杆藻属（Synedra）、直链藻属（Melosira）、栅藻属（Scenedesmus）和蓝隐藻属.冗余分析表明,气温、风速、水位、入库流量等气象水文因子和总氮浓度、电导率、氮磷比、透明度等水质因子与浮游植物群落结构变化关系密切.研究结果表明,在千岛湖这种大型贫-中营养水库,浮游植物群落结构不仅受来水营养盐负荷的影响,还在很大程度上受水文、气象条件的影响,给水库藻类水华等生态风险的预测以及水库水质管理带来了挑战.     

基于结构方程模型的三峡库区汉丰湖叶绿素a与其关键影响因子关系识别

为明确三峡水库汉丰湖叶绿素a(Chl.a)的主要影响因素,分析了汉丰湖2018—2021年的Chl.a、pH、水温、透明度以及氮、磷营养盐等水质指标的变化情况,探讨了Chl.a与其余水质指标的相关性,并应用结构方程模型解析了Chl.a的关键影响因素。结果表明,汉丰湖水体Chl.a浓度在0.04~68.58 μg/L之间变化,水温在9.62~32.10℃之间,pH在6.75~9.81之间,总氮、溶解性氮、总磷、溶解性磷的变化范围分别为0.58~4.68、0.25~3.99、0.02~0.76、0.01~0.44 mg/L。Chl.a浓度与水温、pH、总磷和总固体悬浮物呈显著正相关,与透明度、溶解性氮、碱度、亚硝态氮、硝态氮呈极显著负相关。结构方程模型结果显示,影响Chl.a浓度的因子中理化因子的路径系数为0.68,营养物质的路径系数为0.16,这表明影响Chl.a浓度的因子以理化因子为主,营养物质的作用相对较小。同时,理化因子通过营养盐间接影响Chl.a浓度(路径系数为-0.04)。各理化因子中,水温和pH的路径系数分别为0.51和0.41,水温是理化因子的主要表征指标;在营养盐指标中,总磷和溶解性磷的路径系数分别为0.82和0.71,而总氮的路径系数为0.36,说明磷是汉丰湖的限制性营养元素。     

2006年台湾屏东海外7.2级地震前福建漳州汰内井水氡异常分析

通过对福建华安县汰内井2005年以来的水氡测值进行分析,提取了中期及短期异常,认为这些异常与2006年12月26日台湾屏东海外7.2级地震有关。     

Comparison of liquefaction potential of loess in Lanzhou, China, and Memphis, USA

This paper presents an evaluation of the liquefaction potential of loess in Lanzhou, China, and Memphis, USA. The topography, stratigraphy, and genesis of loess in these two areas were investigated and compared. Several loess samples in each study area were taken and their physical indices were determined. In addition, the microstructures of these loess samples were investigated using an electron microscope, and dynamic triaxial tests were performed using an artificial seismic wave. The results of this investigation indicated that both Lanzhou loess and Memphis loess have a potential for liquefaction, but Memphis loess is less susceptible to liquefaction. Furthermore, Lanzhou loess and Memphis loess behave differently during ground shaking.     

Attenuation of P,S, and coda waves in Koyna region,India

The attenuation properties of the crust in the Koyna region of the Indian shield have been investigated using 164 seismograms from 37 local earthquakes that occurred in the region. The extended coda normalization method has been used to estimate the quality factors for P waves and S waves , and the single back-scattering model has been used to determine the quality factor for coda waves (Q _c). The earthquakes used in the present study have the focal depth in the range of 1–9 km, and the epicentral distance vary from 11 to 55 km. The values of and Q _c show a dependence on frequency in the Koyna region. The average frequency dependent relationships (Q = Q ₀ f ⁿ) estimated for the region are , and . The ratio is found to be greater than one for the frequency range considered here (1.5–18 Hz). This ratio, along with the frequency dependence of quality factors, indicates that scattering is an important factor contributing to the attenuation of body waves in the region. A comparison of Q _c and in the present study shows that for frequencies below 4 Hz and for the frequencies greater than 4 Hz. This may be due to the multiple scattering effect of the medium. The outcome of this study is expected to be useful for the estimation of source parameters and near-source simulation of earthquake ground motion, which in turn are required in the seismic hazard assessment of a region.     

甘肃岷县两次中强地震震源机制研究

利用地震震中周围7个台站的数字记录反演了甘肃岷县2003年11月13日ML5．5和2004年9月7日ML5．2地震的矩张量,得出了震源机制。将所得结果与用P波初动符号的结果进行了比较,二者具有较好的一致性。结合该地区的地震分布,对可能的发震断层进行了讨论。     

Comments on the use of Ti,Zr, Y,Sr, K,P and Nb in classification of basaltic magmas

The distribution of Ti, Zr, Y, Sr, K, P and Nb has been investigated at 55 sample sites within a single basaltic flow, the Cliefden Outcrop, which has adjusted to low-grade metamorphism of the prehnite-pumpellyite facies. The cluster of points in the plot of Ti, Zr and Y as proposed by Pearce and Cann shows that the ratio of these elements has remained relatively constant after metamorphism and would therefore have significance in attempts at classification of magma type. Likewise a plot involving Nb, Y, Zr and P as proposed by Floyd and Winchester shows only restricted scatter and appears useful. However, plots involving Sr or K show a scatter that is clearly related to metamorphic processes. Consequently, plots involving these two elements are likely to be of little use in classification in this case.Low-grade metamorphism is common, variable and not always recognized. The study concerned one style of alteration and revealed problems in the application of some classification schemes. Consequently it is apparent that much more rigorous testing is needed before classification schemes can be generally applied to sequences of basaltic rocks.     

Sources of variability in springwater chemistry in Fool Creek,a high-elevation catchment of the Rocky Mountains,Colorado, USA

Springs are the point of origin for most headwater streams and are important regulators of their chemical composition. We analysed solute concentrations of water emerging from 57 springs within the 3 km² Fool Creek catchment at the Fraser Experimental Forest and considered sources of spatial variation among them and their influence on the chemical composition of downstream water. On average, calcium and acid neutralizing capacity (bicarbonate-ANC) comprised 50 and 90% of the cation and anion charge respectively, in both spring and stream water. Variation in inorganic chemical composition among springs reflected distinct groundwater sources and catchment geology. Springs emerging through glacial deposits in the upper portion of the catchment were the most dilute and similar to snowmelt, whereas lower elevation springs were more concentrated in cations and ANC. Water emerging from a handful of springs in a geologically faulted portion of the catchment were more concentrated than all others and had a predominant effect on downstream ion concentrations. Chemical similarity indicated that these springs were linked along surface and subsurface flowpaths. This survey shows that springwater chemistry is influenced at nested spatial scales including broad geologic conditions, elevational and spatial attributes and isolated local features. Our results highlight the role of overlapping factors on solute export from headwater catchments.     

Quench rates in air, water, and liquid nitrogen, and inference of temperature in volcanic eruption columns

We apply a geospeedometer previously developed in this lab to investigate cooling rate profiles of rhyolitic samples initially held at 720–750°C and quenched in water, liquid nitrogen, and air. For quench of mm-size samples in liquid nitrogen and in air, the cooling rate is uniform and is controlled by heat transfer in the quench medium instead of heat conduction in the sample. The heat transfer coefficient in ‘static’ air decreases with increasing sample size. For quench of mm-size samples in water, heat transfer in water is rapid and the cooling rate is largely controlled by heat conduction in the sample. Our experimental results are roughly consistent with previous calculations for cooling in air and in water (although constant heat transfer coefficients were used in these calculations), but cooling rate in liquid nitrogen is only 1.8–2.3 times that in ‘static’ air, and slower by a factor of 2 than calculated by previous authors. Cooling rate in compressed airflow is about the same as that in liquid nitrogen. The experimental results are applied to interpret cooling rates of pyroclasts in ash beds of the most recent eruptions of the Mono Craters. Cooling rates of pyroclasts are inversely correlated with sample size and slower than those in air. The results indicate that the hydrous species concentrations of the pyroclasts were frozen in the eruption column, rather than inside ash beds or in flight in ambient air. From the cooling rates, we infer eruption column temperature in a region where and at a time when hydrous species concentrations in a pyroclast were locked in. The temperature ranges from 260 to 570°C for the most recent eruptions of Mono Craters. These are the first estimates of temperatures in volcanic eruption columns. The ability to estimate cooling rates and eruption column temperatures from eruptive products will provide constraints to dynamic models for the eruption columns.     

Mining,Environmental, Petroleum,and Engineering Industry Applications of Electromagnetic Techniques in Geophysics

Electromagnetic (EM) techniques are extremely important as a direct detection geophysical tool utilized in the base metal industry. They were developed in countries such as Canada, whose thin conductive weathering overburden did not hamper the penetration of EM signals and enabled exploration to depths on the order of 300 m. As a result, EM techniques were used widely in North America and Scandinavia for many years before they became common in countries with a thick conductive overburden, such as Australia. The 1980s and 1990s have seen the use of EM methods move from anomaly finding to mapping, as well as the development of better, faster and more accurate computer modelling algorithms. A review of EM papers, for the years 1998 to 2002, showed that most dealt with EM techniques as mapping tools. Airborne, ground and marine EM techniques are still being developed, as are data processing and interpretation software. The advent of robust 2-D and 3-D computer modelling and inversion algorithms has led to the acceptance of EM methods as a mapping tool for many environmental and petroleum industry applications, a trend which is expected to increase.     

Acoustic properties of deformed rocks in the Nobeoka thrust,in the Shimanto Belt,Kyushu, Southwest Japan

Laboratory measurements for compressional and shear wave velocities (Vp and Vs, respectively) and porosity were conducted with core samples from the Nobeoka Thrust Drilling Project (NOBELL) under controlled effective pressure (5–65 MPa at 5 MPa intervals) and wet conditions. Samples were classified according to deformation texture as phyllite, foliated cataclasite, or non‐foliated cataclasite. Measured values of Vp, Vs, and porosity are within a range of 5.17–5.57 km/s, 2.60–2.71 km/s, and 2.75–3.10 %, respectively, for phyllite; 4.89–5.23 km/s, 2.46–2.57 km/s, and 3.58–4.53 %, respectively, for foliated cataclasite; and 4.90–5.32 km/s, 2.51–2.63 km/s, and 3.79–4.60 %, respectively, for non‐foliated cataclasite, which are all consistent with the previous laboratory experiments conducted with outcrop samples under dry conditions. However, our results also indicate higher Vp and Vs and lower porosity than those measured by the previous studies that adopted the wire‐line logging methods. The variations in Vp, Vs, and porosity are controlled by deformation structure and are greater for phyllite and foliated cataclasite than for non‐foliated cataclasite.