东天山四顶黑山层状岩体地质特征及成矿潜力分析

东天山黄山岩带因发育众多镁铁质-超镁铁质岩体和岩浆铜镍硫化物矿床而备受地质学者关注。四顶黑山岩体位于该岩带最东端,具有层状岩体特征;岩石类型有单辉橄榄岩、橄榄辉石岩、橄榄苏长辉长岩、橄榄辉长岩、辉石角闪岩、辉长岩、角闪辉长岩、闪长岩,主要造岩矿物为贵橄榄石、古铜辉石、透辉石、普通角闪石和斜长石,岩体分异较好,蚀变较发育。通过矿物显微结构特征观察以及计算得出:四顶黑山岩体中橄榄石最先结晶,其开始结晶温度大约在1419℃左右;古铜辉石和透辉石在橄榄石之后开始结晶,结晶温度分别在1100℃左右和900～1100℃之间,两矿物相在岩石中可以共存。岩体中橄榄岩相、苏长岩相发育,以及贵橄榄石+古铜辉石的矿物组合特征,表明岩体具有形成铜镍(铂)矿床的有利条件。     

A Study of the Strathcona Mine and Its Bearing on the Origin of the Nickel-Copper Ores of the Sudbury District, Ontario

The Strathcona iron-nickel-copper sulfide ore deposit lies atthe base of the Sudbury Nickel Irruptive along the north rimof the Sudbury basin. In the vicinity of the deposit the mainbody of the Nickel Irruptive consists of an upper unit of 3700ft (1200 m) of granophyre (the ‘micropegmatite’)and a lower unit of 1500 ft (500 m) of augite norite (the ‘felsicnorite’) separated by 300 ft (100 m) of transitional rock(the ‘transition zone’). Two augite norite intrusions(the ‘mafic norite’ and the ‘xenolithic norite’)that are younger than the felsic norite occur along its lowercontact. The xenolithic norite is relatively rich in xenolithsand grades downwards into a unit known as the ‘hanging-wallbreccia’. The breccia resembles the xenolithic noritebut contains a higher proportion of xenoliths. A quartz-plagioclase-augite gneiss (the ‘footwall gneiss’)underlies all units of the Nickel Irruptive. A cataclastic breccia(the ‘footwall breccia’) which formed as a resultof comminution of both gneiss and overlying Irruptive rocksis present in most areas between the gneiss and the Nickel Irruptive.The ore body occurs partly as a dissemination of sulfides inthe matrix of the hanging-wall breccia (‘hanging-wallore’), partly as a fine dissemination and massive stringersof sulfide in the footwall breccia matrix (‘main-zoneore’), and partly as massive stringers of sulfide in thefootwall gneiss (‘deep-zone ore’). Xenoliths in the xenolithic norite and hanging-wall brecciarange from dunite to olivine gabbro. Olivine in the xenoliths(composition estimated by an X-ray method) varies from Fo73to Fo85, and hypersthene and augite (composition estimated byelectron microprobe analysis) vary from Fs25 to Fsi3, and Fsi3to Fs5, respectively. The iron content of the mafic mineralsshows a positive correlation with the proportion of felsic mineralsin the xenoliths, suggesting that the xenoliths have been derivedfrom a cryptically layered body of mafic and ultramafic rock.The wide distribution of xenoliths around the margin of theNickel Irruptive coupled with the absence of any obvious externalsource is strong evidence that the xenoliths are cognate, supportingWilson's (1956) proposal that the Irruptive is a funnel-shapedintrusion with a zone of ultramafic rocks towards its base. Hypersthene ranges from Fs33 to Fs28 in the felsic norite, fromFs28 to Fs22 in the mafic norite, and from Fs28 to Fs20 in thexenolithic norite. Augite ranges from Fsl6 to Fs14 in the felsicnorite and from Fs14 to Fsn in both the mafic and xenolithicnorites. The distribution coefficient for iron and magnesiumbetween coexisting augite and hypersthene ranges from 1-0 insome of the xenoliths to 1-5 in some samples of felsic norite,indicating that the two pyroxenes equilibrated at, or near,magmatic temperature. The composition of plagioclase in thefelsic norite, mafic norite, and xenolithic norite is aroundAn65-70 but decreases to An44 in those Irruptive rocks closestto the footwall breccia. The composition of plagioclase withinthe breccia varies between An32 and An43. Sodium metasomatismappears to have affected the breccia and to have spread outto affect adjacent rocks. The concentration of nickel and copper in the sulfides variessystematically across the ore deposit. The nickel content ofiron-nickel sulfides varies between 2-5 and 3 per cent in thehanging-wall ore but increases regularly from 3 per cent to5 or 5-5 per cent from hanging wall to footwall across the main-zoneore. Copper concentration shows a similar but more erratic variation.The variation is attributed to thermal diffusion of nickel andcopper within the main-zone ore along a gradient induced bythe overlying, hot, Nickel Irruptive. The principal opaque minerals in the ore body are, in the orderof their abundance, pyrrho-tite of at least two types, magnetite,pentlandite, chalcopyrite, and pyrite. All of the sulfides inthe hanging-wall ore are the result of exsolution from a high-temperature,pyrrhotite solid solution. Pyrite started to exsolve below 700C, chalcopyrite below 450 C, and pentlandite below 300 C.Monoclinic pyrrhotite formed from the host hexagonal pyrrhotiteprobably between 300 and 250 C. The temperature of formationof the sulfides in the main-zone ore has been obscured by reworkingof the ore after its first emplacement. The principal ore sulfides, pyrrhotite and pentlandite, arecommon throughout the mafic norite, xenolithic norite, and hanging-wallbreccia, occurring in amounts around 5 per cent in most samples.Pyrrhotite and pentlandite are extremely rare in the overlyingfelsic norite where pyrite is the most common sulfide. It occursin amounts between 01 and 0-5 per cent, commonly together withsecondary amphibole after pyroxene. The sulfides in the maficand xenolithic norites and in the hanging-wall breccia occupyspaces interstitial to the silicates, and little or no replacementof silicates by sulfides has occurred. In the main-zone ore,evidence of small-scale replacement of silicates by sulfidesis common. The high percentage of pyrrhotite and pentlandite in the maficand xenolithic norites in contrast to the felsic norite, texturalrelations between sulfides and silicates, and the high temperaturesindicated by the pyroxene distribution coefficients lead tothe conclusion that the hanging-wall sulfides (including thehanging-wall ore) at Strathcona were introduced with these youngernoritic intrusions. Data on the solubility of sulfides in silicatemagmas rule out the possibility that the bulk of the sulfideswere in solution in the noritic magmas; the data support thehypothesis that during intrusion the sulfides were held in suspensionin the in the magmas as droplets of immiscible sulfide-oxideliquid. Calculations on the rate of settling to be expectedfor such sulfide droplets are consistent with this hypothesis.The manner of emplacement of the main-zone ore is less certain;our explanation is that this ore consists of sulfides that originallysettled out of, or collected along, the base of the hanging-wallbreccia zone and were subsequently incorporated in the brecciationthat gave rise to the footwall breccia. The origin of the sulfides at Strathcona is clearly connectedclosely with the origin of the younger noritic intrusions. Asimilar connexion exists between sulfides and young marginalintrusions at many other Sudbury deposits. Jt is possible thatboth sulfides and intrusions are portions of the Nickel Irruptivemagma that lagged behind the main body of magma and were intrudedat a later stage. Alternatively, the young intrusions may haveassimilated sulfides from a sulfide-rich zone within or at themargin of the deeper layers of the Irruptive.     

Composition and petrogenesis of oxide-, apatite-rich gabbronorites associated with Proterozoic anorthosite massifs: examples from the Adirondack Mountains,New York

Mafic dikes and sheets rich in Fe, Ti-oxides and apatite are commonly associated with Proterozoic massif anorthosites and are referred to as oxide-apatite gabbronorites (OAGN). Within the Adirondacks, field evidence indicates that during middle to late stages of anorthositic evolution, these bodies were emplaced as magmas with unspecified liquid-crystal ratios. Sixty whole rock analyses of Adirondack OAGN and related rocks define continuous oxide trends on Harker variation diagrams (SiO₂=37–54%). Similar trends exist for Sr, Y, Nb, Zr, and REE and together suggest a common origin via fractional crystallization. A representative parental magma (plagioclase-rich crystal mush) has been chosen from this suite, and successive daughter magmas have been produced by removal of minerals with compositions corresponding to those determined in actual rocks. Least squares, mass balance calculations of major element trends indicate that removal of intermediate plagioclase (An_40–50) plus lesser amounts of pyroxene account for the compositional variation of this suite and produce very low sums of the squares of the residuals (R² _s>0.25). The extracted mineral phases correspond volumetrically and compositionally to those of the anorthositic suite, and the model succeeds in accounting for the observed OAGN trends. The major element model is utilized to calculate trace elejent concentrations for successive magmas, and these agree closely with observation. We conclude that, beginning with a plagioclase-rich crystal mush, the extraction of intermediate plagioclase (An_40–50) drives residual magmas to increasingly Fe-, Ti-, and P-rich and SiO₂-poor conditions characteristic of Fenner-type fractionation. The crystallization sequence is plagioclaseplagioclase+orthopyroxeneplagioclase+orthopyroxene (pigeonite)+augite. Fe, Ti-oxides begin to crystallize near the end of the sequence and are followed by apatite and fayalitic olivine which appears in place of pigeonite. Augitic pyroxene becomes the dominant ferromagnesian phase in late stages of fractionation. Resultant OAGN magmas are injected into congealed anorthosite by filter pressing of liquid-rich interstitial fractions. Varying compositions of the dikes reflect filter pressing at different stages during fractionation and thereby provide information on the fractionation history of Proterozoic massif anorthosites.     

中天山白石泉镁铁-超镁铁质岩体岩石学与矿物学研究

白石泉地区镁铁一超镁铁质岩体处于塔里木板块前缘活动带与中天山地块接合部位，是中天山地块华力西中期岩浆活动的产物。主要岩石类型有辉石橄榄岩（斜方辉石橄榄岩、斜长二辉橄榄岩）、橄榄辉石岩、橄长岩、辉长岩及角闪辉长岩等，主要造岩矿物为橄榄石、斜方辉石、单斜辉石、角闪石、斜长石及黑云母。橄榄石均为贵橄榄石，其Fo值（78-85）位于含铜镍硫化物矿橄榄石的Fo值范围之内；辉石主要有顽火辉石、古铜辉石、紫苏辉石、透辉石等；斜长石的环带构造较为发育；角闪石的FeO含量随着岩浆的演化逐渐增加。它们与造山带环境中的东疆型镁铁一超镁铁杂岩中的造岩矿物具有相同的特征。这些特征表明了白石泉地区的镁铁一超镁铁质岩体的原始岩浆为高镁的拉斑玄武质岩浆。     

Incomplete high P–T metamorphic transitions within the Kvamsøy pyroxenite complex, west Norway: a case study of disequilibrium

Abstract The Kvamsøy pyroxenite complex consists of olivine websterite, olivine gabbro and leucogabbro-norite which have been subjected to regional high P-T (HPT) metamorphism. The metamorphism has resulted in a range of disequilibrium textures with the development of coronas and pseudomorphism of the igneous phases. Reactions between felsic and mafic mineral domains have been controlled by variable and selective diffusion of elements, resulting in a variety of local plagioclase-breakdown reactions and in significant compositional variations for the product garnet. Restricted diffusion favours transient reaction stages with garnet ± spinel ± corundum ± zoisite after calcic plagioclase in olivine gabbro and olivine websterite and garnet ± spinel ± kyanite ± quartz + sodic plagioclase in leucogabbro-norite. Complete HPT reaction has produced garnet pyroxenite which consists of garnet + diopside + hornblende + zoisite in gabbroic rocks, while amphibolitization continued during the cooling and uplift history. Grt + Ky + Pl + Qtz geobarometry suggests pressures in the range 13-16 kbar for T = 750°C, comparable with the regional eclogite-forming metamorphism.     

Olivine-normative dolerite dikes from western South Carolina: Mineralogy,chemical composition and petrogenesis

This investigation describes five Mesozoic dolerite dikes which intrude Paleozoic metamorphic and igneous rocks of the Inner Piedmont of western South Carolina. The dikes are vertical or nearly so and strike approximately N40° W. Three major northeast-trending faults also occur in the study area. Left lateral displacement of one dolerite is documented at a locality near Cleveland, South Carolina. Elsewhere, several of the dolerite dikes appear to terminate at or near the faults. — The dolerite dikes have subophitic to microporphyritic textures and consist principally of plagioclase (generally An_70–80), olivine (dominantly Fo_80–90) and augite with subordinate pigeonite, titanomagnetite, chromite and brown, partly glassy mesostasis. In one dike pyroxene compositions trend from augite to ferroaugite in contrast to an augitesubcalcic augitepigeonite trend characteristic of the other dolerites. The contrasting trends primarily result from differences in SiO₂ abundance in the dolerite magmas. — Major and trace element analyses indicate the presence of two different olivine-normative dolerite magma types. The two magma types are not related by near surface crystal fractionation. Models for genesis of the olivine-normative dolerite magmas by partial melting of a plagioclase peridotite upper mantle source region are presented. The models require that the source region be enriched in LREE and incompatible elements such as Rb, Ba, Hf and Th relative to Cl chondritic abundances. One magma type appears to represent a primary dolerite magma that ascended from the source region with little subsequent compositional change. The second magma type most likely experienced assimilation of clinopyroxene-garnet (eclogite) during ascent, thereby acquiring a REE pattern with a less steep negative slope for the LREE and a slight positive slope in the HREE.     

The Gaojiacun Mafic-Ultramafic Complex （Sichuan, SW China）：Neoproterozoic Magmatic Activity at the Western Margin of the Yangtze Craton

1 Introduction The Gaojiacun intrusive complex is one of the numerous ultramafic-mafic intrusions in Sichuan Province of China. It was mapped during the 1970s and studied mainly by Chinese scientists (e.g. Geological Team 106, 1975; Shen et al., 1986, 1989; CGGJC, 1986; Yang et al., 1993; Li et al., 1995; Shen et al., 2003; Zhu et al., 2004a). Since the year 2000, China has become one of the largest PGE consumers. While the country can produce only less than 1 ton PGE/year, the Chin…     

牛鼻子梁镁铁质-超镁铁质杂岩体岩石特征

牛鼻子梁岩体位于柴达木地块的北缘,出露面积约8 km²,平面形态呈长条状,主要由斜长二辉橄榄岩、斜长单辉橄榄岩、角闪二辉橄榄岩、角闪橄榄岩、角闪橄榄二辉岩、黑云母化二辉岩、角闪辉石岩、橄榄辉石角闪石岩、角闪橄榄辉长岩、细粒辉长岩、似斑状辉长岩、暗色辉长岩、辉长岩、淡色辉长岩、石英闪长岩和英云闪长岩组成。文章通过岩石学、矿物学、地球化学研究,得到锆石U-Pb年龄为（361.5±1.2） Ma,Sm-Nd等时线年龄为（347±26） Ma。研究认为,牛鼻子梁基性-超基性岩体含矿岩石产于大陆边缘环境。岩体形成于泥盆纪晚期。岩浆分异充分,岩石类型丰富,岩浆演化过程中主要发生了橄榄石和斜长石的分离结晶/堆晶作用。岩体的母岩浆应属于拉斑玄武岩质岩浆。从目前发现的矿化情况来看,牛鼻子梁基性-超基性杂岩体为含矿岩体,有很好的找矿前景。     

Simulation of primary phase relations and mineral compositions in the Partridge River intrusion,Duluth Complex,Minnesota: implications for the parent magma composition

In order to describe the composition and crystallinity of the initial (parental) magma of the Partridge River intrusion of the Keweenawan Duluth Complex, and thereby understand the mode of emplacement and solidification of the intrusion, we have applied a numerical simulation technique called geochemical thermometry (Frenkel et al. 1988). The parental magma was a low-alumina, high-Ti-P olivine tholeiite similar to typical Keweenawan low-alumina, high-Ti-P basalts associated with the Duluth Complex and from the nearby Portage Lake area of the Lake Superior region. The parental magma was emplaced as a crystal-liquid suspension, followed by chilling of an evolved, leading edge ferrodioritic liquid in the basal zone of the intrusion. The conditions of emplacement at the present crustal location were 1,150°C, 2 kbar, and f _{O 2} slightly above the wustite-magnetite (WM) buffer. The main differentiation process after emplacement was the sorting and redistribution of plagioclase and olivine crystals on a local scale accompanied by less efficient convection and minor settling of olivine. Calculated crystallization sequence for the parental magma is olivine+plagioclase (1,240°C)olivine+plagioclase+magnetite (1,146°C, WM+0.5)olivine+plagioclase+magnetite+augite (1,140°C, WM+0.5). The calculated compositions of the cumulus olivine and plagioclase in equilibrium with the parent magma at 1,150°C are Fo_66.7±1.1 and An_64.5±2.5, respectively, and are similar to the estimated average composition of primary olivine (Fo_69.1±2.8) and the average composition of plagioclase core (An_66.3±2.8) measured in drill core samples through the intrusion (Chalokwu and Grant 1987).     

东天山云海铜镍矿地球化学特征及成因分析

云海铜镍矿位于觉罗塔格构造带西段,成矿岩体为多期次侵入的杂岩体,岩体分异演化充分,镁铁质和超镁铁质岩石均有发育,主要岩石类型为角闪辉石岩、橄榄苏长岩、辉长岩、闪长岩。主量元素化学组成表明,该杂岩体属拉斑玄武岩系列,岩石具同源演化特征,显示高铁、高镁、低钛、低铝特征,富集大离子亲石元素Rb,Ba,亏损Nb,Ta,轻稀土富集。岩浆源区有部分熔融而交代的岩石圈地幔,岩浆在上升过程中受到地壳物质混染,发生橄榄石、斜方辉石、斜长石的分离结晶。岩体形成于早二叠世,为构造活动和地幔柱双重作用下的产物。     

Petrology of mafic-ultramafic rocks along North Puruliya Shear zone,West Bengal

The North Puruliya Shear zone (NPSZ) is characterized by occurrence of mafic-ultramafic rocks aligned parallel to the shear zone, intruding the high grade Proterozoic rocks of Chhotanagpur Gneissic Complex. The ultramafic rocks occur as small lenses, pockets, veins, thin dykes and are intimately associated with mafic (gabbro, norite) rocks. Pyroxenites (viz. olivine websterite, websterite, plagioclase websterite) and hornblendite are the two important members of the ultramafic rocks containing clinopyroxene, orthopyroxene, olivine, plagioclase, amphibole, phlogopite and ilmenite. The mafic-ultramafic rocks show evidence of shearing and retrogressive metamorphism. Linear correlation of chemical attributes suggests fractionation-controlled magmatic differentiation. Enrichment of LILE and LREE in the mafic-ultramafic suite suggests an enriched mantle source and pronounced negative Eu-anomalies in all the rock types except hornblendite suggest fractionation of plagioclase under low f_O2 condition. Progressive iron enrichment trend in rocks of the mafic-ultramafic suite also indicate magmatic differentiation under low f_O2 condition. Early fractionation and accumulation of clinopyroxene and plagioclase from a basaltic magma may have given rise to the ultramafic rocks of the area. Little change in the Nb/Zr and Ce/Zr ratios of ultramafic and mafic rocks (except alkali norite) strongly support low crustal contamination. A few samples of norite and gabbro-norites appeared to be variably contaminated by a crustal component or affected by late granitic intrusion resulting in enrichment of alkali in the former.     

Origin of biotite-hornblende-garnet coronas between oxides and plagioclase in olivine metagabbros,Adirondack region,New York

Complex multivariant reactions involving Fe-Ti oxide minerals, plagioclase and olivine have produced coronas of biotite, hornblende and garnet between ilmenite and plagioclase in Adirondack olivine metagabbros. Both the biotite (6–10% TiO₂) and the hornblende (3–6% TiO₂) are exceptionally Titanium-rich. The garnet is nearly identical in composition to the garnet in coronas around olivine in the same rocks. The coronas form in two stages:

1. Plagioclase+Fe-Ti Oxides+Olivine+water =Hornblende+Spinel+Orthopyroxene±Biotite +more-sodic Plagioclase
2. Hornblende+Orthopyroxene±Spinel+Plagioclase =Garnet+Clinopyroxene+more-sodic Plagioclase

The Orthopyroxene and part of the clinopyroxene form adjacent to olivine. Both reactions are linked by exchange of Mg²⁺ and Fe²⁺ with the reactions forming pyroxene and garnet coronas around olivine in the same rocks. The reactions occur under granulite fades metamorphic conditions, either during isobaric cooling or with increasing pressure at high temperature.     

辽宁永宁地区含金刚石闪长质岩石显微特征及金刚石来源探讨

辽宁永宁地区发育一套闪长质火山岩，该岩石中曾选获金刚石及其指示矿物，因此成为辽宁省金刚石第Ⅳ成矿带。通过对该岩石矿物组成及其显微结构构造特征研究，表明：(1)闪长质岩石中的斑晶斜长石具有环带结构；(2)橄榄石及金云母具有多世代性，且目估橄榄石+金云母含量在10%以上，局部更为富集；(3)出现“橄榄石+金云母+石榴石”与“斜长石+辉石+角闪石”不平衡的矿物组合；(4)发现橄榄石有碎斑结构和金伯利岩角砾。初步认为，永宁地区的闪长质岩浆在上升过程中捕获了早先已形成的金伯利岩并与之发生熔融混合作用，金刚石来自于深部的金伯利岩。这一认识对该地区寻找金刚石原生矿具有启示意义。     

东天山地区黄山东与香山镁铁质- 超镁铁质杂岩体对比

黄山东与香山镁铁质-超镁铁质杂岩体隶属于东天山北部黄山-镜儿泉镁铁质-超镁铁质岩带, 受北东东走向的黄山-镜儿泉韧性剪切带控制, 二者岩石组成差异较大, 黄山东杂岩主要由辉石橄榄岩和辉长岩组成, 主量元素化学组成属钙碱性-拉斑玄武系列, 而香山杂岩主要由辉石橄榄岩、橄榄辉石岩、角闪辉长岩、辉绿岩组成, 属拉斑玄武系列.微量元素地球化学特征显示二者相对富集大离子亲石元素(K、Sr、Ba), 高场强元素(Pb、U), 而相对亏损高场强元素(Nb、P), 适度亏损(Zr、Hf), 但其稀土配分模式不同, 黄山东杂岩显示轻稀土弱富集, 具OIB型的特征, 而香山岩体为平坦型.二者均为尖晶石稳定域不同熔融程度的产物, 侵位过程中主要发生了橄榄石、辉石、斜长石的分离结晶和不同程度的地壳混染.采用LA-ICP-MS法获得黄山东辉长岩与香山角闪辉长岩锆石U-Pb年龄分别为277±1.1 Ma、285±1.1 Ma.二者形成于相同的构造背景下, 是岩石圈地幔根部发生拆沉, 软流圈地幔物质底侵并导致岩石圈地幔发生部分熔融的产物, 构造环境为后碰撞向板内阶段转变的岩石圈间歇性伸展期.      

Metasomatic crystallization of muscovite in granite and tourmaline in schist related to pegmatite emplacement near Yellowknife,Canada

Numerous pegmatite dikes occur in the Sparrow pluton (muscovite-biotite granite) and in the adjacent cordierite-zone schist-hornfels of the Yellowknife Supergroup. Where pegmatite dikes cut granite, the adjacent granite is enriched in muscovite and apatite, and depleted in K-feldspar. Mass transfer calculations, based on rock, mineral, and modal analyses, indicate that H, P, and locally B, Ti, Fe, and Ca were added, and K, Sr, Ba, and locally Na were removed (hydrogen metasomatism). In one alteration zone (8 cm wide) the calculated change (in terms of mols/gram of unaltered granite) is, 600 K-feldspar+24 biotite+190 plagioclase +[770 H+36 P+3 Ti+13 Fe+13 Ca] 400 muscovite+1100 quartz +11 apatite+[240 Na+260 K]. Where pegmatite dikes cut schist-hornfels (biotite-plagioclase-quartz), the adjacent rock is, in places, enriched in tourmaline, apatite, and quartz, and depleted in biotite and plagioclase. These alteration zones are variable in width; most are less than 20 cm wide. Mass transfer calculations, based on rock, mineral, and modal analyses, indicate that B, P, Zn, and locally Ca, Fe, and Al were added, and that Na, K, Fe, Rb, Sr, Ba, and locally Mg and Si were removed (boron metasomatism). In one zone, 2 cm wide, the calculated reaction (in units of mols/gram of unaltered schist) is, 730 biotite+1530 plagioclase +[1080 B+600 H+430 P+360 Ca] 480 tourmaline+480 quartz+115 apatite +[3630 Si+870 Na+590 K+110 Fe]. Changes in the volume fraction of muscovite, K-feldspar, tourmaline, and biotite, relative to distance from pegmatite, are progressive, and in most alteration zones may be expressed by use of an error-function equation. Some tourmaline zones are more complex. Zone formation is considered in terms of a steady-state reaction model in which grainboundary diffusion is the transport mechanism.     

胶东海阳所堆积辉长岩的变质反应结构、石榴石形成及P—T演化

海阳所堆积辉长岩由橄长岩、橄榄辉长岩和辉长岩组成。在橄长岩和橄榄辉长岩中发育有典型的变质反应结构：主要为橄榄石与斜长石之间形成由斜方辉石、尖晶石、角闪石和石榴石等矿物组成的多期次次变边，并有三个不同世代变质矿物，早期Cpx＋Opx＋Spl，中期Amp，晚期Grt；期次是钛铁矿与斜长石之间形成石榴石次变边，相对比较简单，只有一个世代变质矿物，为Grt＋Amp＋Rut或Grt＋Rut岩中石榴石是通过斜长石与角闪石或斜长石与钛铁矿之间的变质反应形成的，虽为峰值变质作用的产物，但变质反应的期次及类型不同导致了所形成石榴石的温度和压力有所不同。堆积辉长岩形成演化的温压计算表明，堆积辉长岩在经过近等压降温的岩浆作用之后的变质作用早期，仍为近等压降温，而晚期则表现为近等温升压。这一特殊的P－T演化可能反映了堆积辉长冷侵位与深俯冲特征。     

Crystallization Orders and Phase Chemistry of Glassy Lavas from the Pillow Sequences, Troodos Ophiolite, Cyprus

Three genetically unrelated magma suites are found in the extrusivesequences of the Troodos ophiolite, Cyprus. A stratigraphicallylower pillow lava suite contains andesite and dacite glassesand shows the crystallization order plagioclase; augite, orthopyroxene;titanomagnetite (with the pyroxenes appearing almost simultaneously).These lavas can in part be correlated chemically and mineralogicallywith the sheeted dikes and the upper part of the gabbro complexof the ophiolite. The second magma suite is represented in astratigraphically upper extrusive suite and contains basalticandesite and andesite glasses with the crystallizaton orderchromite; olivine; Ca-rich pyroxene; plagioclase. This magmasuite can be correlated chemically and mineralogically withparts of the ophiolitic ultramafic and mafic cumulate sequence,which has the crystallization order olivine; Ca-rich pyroxene;orthopyroxene; plagioclase. The third magma suite is representedby basaltic andesite lavas along the Arakapas fault zone andshows a boninitic crystallization order olivine; orthopyroxene;Ca-rich pyroxene; plagioclase. One-atmosphere, anhydrous phaseequilibria experiments on a lava from the second suite indicateplagioclase crystallization from 1225?C, pigeonite from 1200?C,and augite from 1165?C. These experimental data contrast withthe crystallization order suggested by the lavas and the associatedcumulates. The observed crystallization orders and the presenceof magmatic water in the fresh glasses of all suites are consistentwith evolution under relatively high partial water pressures.In particular, high P_H2O (1–3 kb) can explain the lateappearances of plagioclase and Ca-poor pyroxene in the majorityof the basaltic andesite lavas as the effects of suppressedcrystallization temperatures and shifting of cotectic relations.The detailed crystallization orders are probably controlledby relatively minor differences in the normative compositionsof the parental magmas. The basaltic andesite lavas are likelyto reach augite saturation before Ca-poor pyroxene saturation,whereas the Arakapas fault zone lavas, which have relativelyless normative diopside and more quartz, reached the Ca-poorpyroxene-olivine reaction surface and crystallized Ca-poor pyroxeneafter olivine.     

新疆东天山黄山东岩体橄榄石成因意义探讨

黄山东岩体位于新疆东天山造山带中段,由四次岩浆侵入形成:第一次侵入形成了岩体上部的橄榄辉长岩、角闪辉长岩和闪长岩,构成岩体的主体;第二次侵入形成辉长苏长岩,呈岩墙状分布于岩体西端和西北部;第三次侵入岩石为斜长二辉橄榄岩,位于岩体下部,为主要的赋矿岩石;第四次侵入岩石为底部角闪辉长岩。橄榄石为第三次侵入的斜长二辉橄榄岩和第一次侵入的橄榄辉长岩主要造岩矿物之一,橄榄石的镁橄榄石牌号(Fo)值介于68.5～82.5之间。其中含硫化物斜长二辉橄榄岩中的橄榄石具有较高的Fo值(79.7～82.5);斜长二辉橄榄岩中橄榄石的Fo值为78.3～79.9;而基性程度较低的橄榄辉长岩中橄榄石具有较低的Fo值(68.5～72.2)。利用橄榄石矿物成分计算得出黄山东岩体母岩浆Mg#(Mg2+/(Mg2++Fe2+))为0.59,为原生玄武质岩浆经历结晶分异作用形成。模拟计算结果显示黄山东岩体不含矿岩石中橄榄石是母岩浆经过2%的橄榄石结晶分异且硫达到饱和后,在硫化物熔离的同时岩浆发生橄榄石结晶而形成,并且橄榄石︰硫化物≈50︰1,部分橄榄石成分投点在橄榄石结晶和硫化物熔离的模拟曲线右下侧,指示它们可能受到晶间硅酸盐熔浆作用的影响。含硫化物斜长二辉橄榄岩中Fo值与Ni含量呈负相关关系,说明橄榄石与硫化物熔体之间发生了Fe-Ni交换反应。     

The influence of primary magma composition,H2O and pressure on mid-ocean ridge basalt differentiation

MORB suites display variations in their chemical differentiation trends which are closely related to the incompatible element enrichment of the basalts. We examine suites of primitive to evolved basalts from the Pacific-Nazca Ridge at 28° S (mostly depleted); from the Juan Fernandez microplate region (depleted) and from the Explorer Ridge, northeast Pacific (mostly enriched). Trends for incompatible element enriched MORBs consistently show less depletion of Al₂O₃ and less enrichment of FeO when plotted on MgO variation diagrams.Least squares modeling indicates that enriched basalts have undergone less plagioclase crystallization than depleted basalts especially in the early stages of differentiation. Using thermodynamic modelling, we show that variations between MORB differentiation trends result largely from differences in the major element chemistry and H₂O content of primary magmas. Our chosen enriched and depleted near-primary magmas are similar in major element chemistry but the enriched near-primary magma has higher H₂O and lower Al₂O₃ than the depleted near-primary magma. The MORB crystallization sequence is: olivineolivine+plagioclase olivine+plagioclase+high-Ca pyroxene; and the separate and combined effects of lower Al₂O₃ and higher H₂O are to cause plagioclase to crystallize later (lower temperature), and to make the interval of olivine+plagioclase crystallization shorter. As a result, enriched differentiates have higher Al₂O₃ and lower FeO than depleted MORBs at a given MgO content, even though their parents' Al₂O₃ is lower. Crystallization of enriched basalts at higher pressure than depleted basalts is not able to account for differences between the differentiation trends because the proportion of plagioclase is higher during three-phase crystallization at high pressure.The variations in trends do not depend on geographic location and thus are superimposed on any regional variations in MORB chemistry or mantle source. Nor are they related to spreading rate. Depleted basalts from the fast-spreading 28° S and Juan Fernandez ridges have differentiation trends similar to depleted basalts from the medium-spreading Galapagos Spreading Center, whereas differentiation trends for enriched basalts from the medium-spreading Explorer Ridge are quite different. Fe³⁺/Fe_total is similar (and quite low) for enriched and depleted basalts, indicating that neither oxidation state nor early magnetite crystallization are important.     

Feldspathic hornblende and garnet granulites and associated anorthosite pegmatites from Doubtful Sound,Fiordland, New Zealand

Feldspathic hornblende granulites from Doubtful Sound, New Zealand with the assemblage plagioclase+hornblende+clinopyroxene+orthopy-roxene +oxide+apatite are criss-crossed by a network of garnetiferous anorthosite veins and pegmatites. The feldspathic gneiss in contact with anorthosite has a reaction zone containing the assemblage plagioclase +garnet+clinopyroxene+quartz+rutile+apatite. The garnet forms distinctive coronas around clinopyroxene. The origin of these rocks is discussed in the light of mineral and whole rock chemical analyses and published experimental work.It is thought that under conditions leading up to 750 °C, 8 kb load pressure and 5 kb H₂O pressure, partial melting occured in feldspathic hornblende granulites. The melt migrated into extensional fractures and eventually crystallised as anorthosite pegmatites and veins. The gneisses adjacent to the pegmatites from which the melt was extracted changed composition slightly, by the loss of H₂O and Na₂O, so that plagioclase reacted simultaneously with hornblende, orthopyroxene, and oxide to form garnet, clinopyroxene, quartz and rutile.