阿舍勒铜锌矿床地球化学特征

阿舍勒铜锌矿床原生晕和次生晕均受矿体、中泥盆统阿舍勒组第二岩性段地层、近ＳＮ向一断裂控制。阿舍勒铜锌矿床的成矿、成晕作用是多期次的，其成矿、成晕直接（矿体）指示元素为Ｃｕ，Ｐｂ，Ｚｎ，Ａｕ，Ａｇ，Ｂａ等。前晕指示元素为Ａｓ，Ｓｂ，Ｈｇ等；尾晕指示元素为Ｓｎ，Ｍｏ等。利用这些异常元素的地球化学特征，不仅可确定该矿床的矿化类型和矿体剥蚀深度（或埋深），而且也可确定与该矿床相似的成矿靶区（即异常区），并对成矿靶区进行预测评价。     

河南嵩县小南沟金矿床尾晕地球化学特征及其地质意义

河南省嵩县小南沟金矿是产于熊耳群火山岩中的构追蚀变岩型矿床,矿化受控于近南北向断裂构造。系统的矿床地质地球化学研究发现,矿体横刹面和纵剖面上都存在明显的元宋分带。纵投肜剖面的地球化学反映出与金矿化关系密切的元宋Au、Ag、Cu、Pb、Zn、As、Sb、W等均形成向上开口的“U” 形,含量上高下低,向深部晕的规模逐渐减小,强庋减弱,垂向上具有尾晕的地球化学特点,热晕也与此完全相似。这些地球化学特点显示出主要矿化地区集中于11线以北以及55线以南,矿化宦集地段集中于9~12线多组浙裂交汇邯位(主矿段),55线以南也有较好的探矿前景。矿体向北侧伏,侧伏的原因是多组断裂的交汇部位形成一个向北侧伏的有利成矿空间。     

山东金青顶金矿床控矿构造特征及深部预测

金青顶金矿床位于山东牟平-乳山金矿带将军石-曲河庄断裂的南端,矿床围岩为昆嵛山花岗岩,属含金石英脉型金矿。本文通过矿床地质特征、围岩蚀变以及控矿构造特征等方面的研究,认为与成矿有关的构造活动至少划分为4期,基本控制着矿体的定位与分布。深部地球化学原生晕研究表明,矿体在垂向上具有明显的地球化学分带性,且在已知矿体下方出现近矿晕、前缘晕及尾晕特征指示元素构造叠加晕强度升高趋势。结合矿体在断裂中分布的规律以及原生晕特点,对金青顶矿床深部第二富集段进行了预测,推断在-1100m下有第二金富集段存在,且具有很大的经济价值。     

五台山—恒山绿岩带Au-Ag-Cu成矿作用地球化学特征

五台山—恒山绿岩带Ａｕ、Ａｇ、Ｃｕ矿床可分为二大类型：（１）再生型金银铜矿，产在包括岩浆岩在内的各类岩石断裂构造中，与岩浆期后热液有关；（２）变生型金银铜矿，产于各类变质岩中，具有层控特征（即绿岩型金矿）。在地球化学特征上，再生型矿床与变生型矿床相比，矿体及围岩中Ｍｏ、Ａｇ、Ｐｂ、Ｚｎ、Ｃｄ等成矿及伴生元素明显富集；Ｋ２Ｏ、Ｒｂ、Ｓｒ、Ｂａ、Ｔｈ、Ｕ也明显富集，是后期岩浆热液作用的结果；Ｈｇ、Ｆ的明显富集则与后期构造活动有关；Ｚｎ／Ｃｄ比值较低，说明受到后期岩浆侵入影响；Ｔｈ／Ｕ比值低，可能指示富钙的酸性岩环境。再生型Ａｕ矿化的元素组合为Ｃｄ、Ａｓ、Ｎｉ、Ａｇ、Ｓｂ、Ａｕ、Ｈｇ（Ｂｉ），再生型Ａｇ矿化的元素组合为Ａｓ、Ｓｂ、Ａｇ、Ｃｄ、Ｃｕ、Ｎｉ（Ｍｏ、Ｐｂ、Ｚｎ、Ｂｉ），变生型Ａｕ矿化的元素组合较简单，只为Ａｕ、Ｈｇ、Ａｓ或Ａｕ、Ｃｕ。上述地球化学特征不仅可以有效地区分矿化类型，而且可以作为地球化学找矿和评价的指标     

易门狮子山铜矿床构造岩微量元素特征及构造地球化学异常模式

易门狮子山铜矿床位于昆阳裂谷易门裂陷盆地内,属沉积-改造型中型铜矿床。矿体主要赋存于落雪组白云岩中,并严格受狮子山背斜及北东向压扭性断裂控制。应用构造地球化学方法,重点研究了断裂构造岩微量元素分布特征及其异常分带规律,结果表明:断裂破碎带矿化蚀变强烈,构造岩中Cu、Bi、Mo、Co、Mn、Ag、Pb等成矿元素富集;矿床具有自上而下的轴向分带序列Ba-Mn-Ag-Zn-Cu-Pb-Co-Bi-Mo;横向上Cu-Bi-Mo-Co-Mn为矿体的近矿指示元素,Ag-Pb为远程指示元素;纵向上从矿床东部至西部,矿化强度及异常规模明显减弱,反映了该类型矿床分带明显的特征。根据地球化学找矿标志,3～8号勘探线间近矿晕规模大,是深部隐伏矿的主要靶区。     

内蒙古哈达门沟金矿床13号脉构造叠加晕模式及深部找矿预测

哈达门沟金矿床13号脉受断裂构造控制,具有多期多阶段叠加成矿（晕）的特点.矿床分为4个成矿阶段,各成矿阶段元素含量和地球化学特征参数表明,金成矿与金属硫化物关系密切.第Ⅰ阶段成矿较弱,第Ⅱ、Ⅲ阶段为主成矿阶段,第Ⅳ阶段不成矿.确定矿床的头晕元素为As、Sb、Hg,矿体晕元素为Au、Ag、Cu、Pb、Zn、Bi,尾晕元素为Ni、W、Co、Mo.建立了原生叠加成矿成晕模式,矿脉在垂向上形成串珠状分布的多个富集矿体,各富集矿体上部存在头晕元素异常,中部对应矿体晕元素异常,下部存在尾晕元素异常,富集矿体之间存在头、尾晕元素共存区.总结了应用模式找矿的准则,认为在含矿构造带内,Au品位较低时,如果存在头、尾晕元素共存,则指示深部有矿,当再叠加Cu、Pb、Zn等元素异常时,指示深部矿体还很富.同时,利用构造叠加晕模式和深部预测标志对已知矿体深部进行盲矿体预测,在实践生产中得到了很好的验证.     

内蒙古安家营子金矿床地球化学异常特征

安家营子金矿就位于内蒙东部赤金矿成矿区,主要类型为破碎带交代蚀变岩型。矿脉呈对称为分带。指示元素Ａｇ、Ｃｕ、Ｐｂ、Ｚｎ、Ａｓ、Ｍｏ、Ｗ、Ｎｉ和Ｃｏ与成矿元素Ａｕ呈正相关。聚类分析和指示元素长向分带序列计算结果与金档中的普遍规律不一致,似无可循。这很可能是一个好信息,说明下部矿体的地球化学晕对上部矿体的晕的叠加作用。     

山东蓬莱石家金矿原生晕地球化学特征及深部找矿预测

为预测和评价山东蓬莱石家金矿床的深部找矿远景,延长矿山服务年限,着重论述了该矿床的原生晕地球化学特征,对矿床的深部找矿潜力进行了探讨。原生晕元素组合特征分析表明,石家金矿床的矿体及近矿晕元素组合为Au、Ag、Cu、Pb、Zn、S、Te,前缘晕为Hg、As、Sb、Ba,尾晕为Mo、W、Sn。元素异常形态特征显示,326号矿脉南段以前缘晕和近矿晕为主,北段以前缘晕和尾晕为主,近矿晕元素异常较弱,矿体总体具有向南侧伏的特点。原生晕轴向分带序列在36线和84线均呈现反分带和前缘晕、尾晕共存的特点,结合地球化学参数在垂向上呈振荡波动变化的特征,说明矿体由多期次成矿作用叠加形成,同时预示矿体向深部还有一定延伸或有盲矿体存在。综合分析认为,326号矿脉南段为成矿的有利部位,深部仍有较大的找矿空间;矿体北段深部矿化减弱,但出现了前缘晕、尾晕元素的共存,预示深部可能还有盲矿体存在。     

穆龙套金矿床上的地球化学原生晕

本文论述了穆龙套金矿床Ａｕ、Ｗ、Ａｓ等地生晕特点及与矿化的关系，并通过对其东南侧所作的地球化学研究，对伴生元素进行了垂向和横向的分带。根据原生晕的组成及展布特点确定了矿床成因。     

陕西大西沟重晶石菱铁矿——银硐子银铜铅多金属特大型矿？…

大西沟－银硐子银多金属矿床由同生断裂－热水流体－地球化学动力学的多重主和形成。矿床在区域上处于柞山镇Ｐｂ、Ａｓ、Ｃｕ地球化学省,ＮＷＷ向富Ｃｕ、Ｍｎ、Ｂａ、Ｐｂ、Ａｇ和ＮＷ向低Ｐｂ高Ｃｕ、Ａｓ及ＮＥ向富Ｐｂ、Ｚｎ、Ｃｕ的地球化学带３者交汇部位。矿床原生异常组合由西向东为Ｆｅ、Ｃｕ、ＭｎＢａ→Ｃｕ、Ａｇ、Ｐｂ、Ｚｎ、Ｂａ、Ｍｎ、→Ｐｂ、Ｚｎ、Ｂａ。成矿成晕具有热水同生沉积－交代→热水混合同生沉积→热     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

Roles of xenomelts,xenoliths, xenocrysts,xenovolatiles, residues,and skarns in the genesis,transport, and localization of magmatic Fe-Ni-Cu-PGE sulfides and chromite

Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).     

Petrographic, mineralogy, and geochemistry of coals of Pabedana, Kerman Province, Central Iran

This paper discusses the result of the detailed investigations carried out on the coal characteristics, including coal petrography and its geochemistry of the Pabedana region. A total of 16 samples were collected from four coal seams d2, d4, d5, and d6 of the Pabedana underground mine which is located in the central part of the Central-East Iranian Microcontinent. These samples were reduced to four samples through composite sampling of each seam and were analyzed for their petrographic, mineralogical, and geochemical compositions. Proximate analysis data of the Pabedana coals indicate no major variations in the moisture, ash, volatile matter, and fixed carbon contents in the coals of different seams. Based on sulfur content, the Pabedana coals may be classified as low-sulfur coals. The low-sulfur contents in the Pabedana coal and relatively low proportion of pyritic sulfur suggest a possible fresh water environment during the deposition of the peat of the Pabedana coal. X-ray diffraction and petrographic analyses indicate the presence of pyrite in coal samples. The Pabedana coals have been classified as a high volatile, bituminous coal in accordance with the vitrinite reflectance values (58.75–74.32 %) and other rank parameters (carbon, calorific value, and volatile matter content). The maceral analysis and reflectance study suggest that the coals in all the four seams are of good quality with low maceral matter association. Mineralogical investigations indicate that the inorganic fraction in the Pabedana coal samples is dominated by carbonates; thus, constituting the major inorganic fraction of the coal samples. Illite, kaolinite, muscovite, quartz, feldspar, apatite, and hematite occur as minor or trace phases. The variation in major elements content is relatively narrow between different coal seams. Elements Sc,, Zr, Ga, Ge, La, As, W, Ce, Sb, Nb, Th, Pb, Se, Tl, Bi, Hg, Re, Li, Zn, Mo, and Ba show varying negative correlation with ash yield. These elements possibly have an organic affinity and may be present as primary biological concentrations either with tissues in living condition and/or through sorption and formation of organometallic compounds.     

Alkaline rocks of Samchampi-Samteran, District Karbi-Anglong, Assam, India

The Samchampi-Samteran alkaline igneous complex (SAC) is a near circular, plug-like body approximately 12 km² area and is emplaced into the Precambrian gneissic terrain of the Karbi Anglong district of Assam. The host rocks, which are exposed in immediate vicinity of the intrusion, comprise granite gneiss, migmatite, granodiorite, amphibolite, pegmatite and quartz veins. The SAC is composed of a wide variety of lithologies identified as syenitic fenite, magnetite ± perovskite ± apatite rock, alkali pyroxenite, ijolite-melteigite, carbonatite, nepheline syenite with leucocratic and mesocratic variants, phonolite, volcanic tuff, phosphatic rock and chert breccia. The magnetite ± perovskite ± apatite rock was generated as a cumulus phase owing to the partitioning of Ti, Fe at a shallow level magma chamber (not evolved DI = O1). The highly alkaline hydrous fluid activity indicated by the presence of strongly alkalic minerals in carbonatites and associated alkaline rocks suggests that the composition of original melt was more alkalic than those now found and represent a silica undersaturated ultramafic rock of carbonated olivine-poor nephelinite which splits with falling temperature into two immiscible fractions—one ultimately crystallises as alkali pyroxenite/ijolite and the other as carbonatite. The spatial distribution of varied lithotypes of SAC and their genetic relationships suggests that the silicate and carbonate melts, produced through liquid immiscibility, during ascent generated into an array of lithotypes and also reaction with the country rocks by alkali emanations produced fenitic aureoles (nephelinisation process). Isotopic studies (δ¹⁸O and δ¹³C) on carbonatites of Samchampi have indicated that the δ¹³C of the source magma is related to contamination from recycled carbon.