Petrology of ultrahigh-pressure rocks from the southern Su-Lu region, eastern China

Abstract In the Su-Lu ultrahigh- P terrane, eastern China, many coesite-bearing eclogite pods and layers within biotite gneiss occur together with interlayered metasediments now represented by garnet-quartz-jadeite rock and kyanite quartzite. In addition to garnet + omphacite + rutile + coesite, other peak-stage minerals in some eclogites include kyanite, phengite, epidote, zoisite, talc, nyböite and high-Al titanite. The garnet-quartz-jadeite rock and kyanite quartzite contain jadeite + quartz + garnet + rutile ± zoisite ± apatite and quartz + kyanite + garnet + epidote + phengite + rutile ± omphacite assemblages, respectively. Coesite and quartz pseudomorphs after coesite occur as inclusions in garnet, omphacite, jadeite, kyanite and epidote from both eclogites and metasediments. Study of major elements indicates that the protolith of the garnet-quartz jadeite rock and the kyanite quartzite was supracrustal sediments. Most eclogites have basaltic composition; some have experienced variable 'crustal'contamination or metasomatism, and others may have had a basaltic tuff or pyroclastic rock protolith.
The Su-Lu ultrahigh- P rocks have been subjected to multi-stage recrystallization and exhibit a clockwise P-T path. Inclusion assemblages within garnet record a pre-eclogite epidote amphibolite facies metamorphic event. Ultrahigh- P peak metamorphism took place at 700–890° C and P >28 kbar at c . 210–230 Ma. The symplectitic assemblage plagioclase + hornblende ± epidote ± biotite + titanite implies amphibolite facies retrogressive metamorphism during exhumation at c . 180–200 Ma. Metasedimentary and metamafic lithologies have similar P-T paths. Several lines of evidence indicate that the supracrustal rocks were subducted to mantle depths and experienced in-situ ultrahigh- P metamorphism during the Triassic collision between the Sino-Korean and Yangtze cratons.     

Petrochemical constraints for dual origin of garnet peridotites from the Dabie-Sulu UHP terrane, eastern-central China

Garnet peridotites occur as lenses, blocks or layers within granulite–amphibolite facies gneiss in the Dabie-Sulu ultra-high-pressure (UHP) terrane and contain coesite-bearing eclogite. Two distinct types of garnet peridotite were identified based on mode of occurrence and petrochemical characteristics. Type A mantle-derived peridotites originated from either: (1) the mantle wedge above a subduction zone, (2) the footwall mantle of the subducted slab, or (3) were ancient mantle fragments emplaced at crustal depths prior to UHP metamorphism, whereas type B crustal peridotite and pyroxenite are a portion of mafic–ultramafic complexes that were intruded into the continental crust as magmas prior to subduction. Most type A peridotites were derived from a depleted mantle and exhibit petrochemical characteristics of mantle rocks; however, Sr and Nd isotope compositions of some peridotites have been modified by crustal contamination during subduction and/or exhumation. Type B peridotite and pyroxenite show cumulate structure, and some have experienced crustal metasomatism and contamination documented by high ⁸⁷Sr/⁸⁶Sr ratios (0.707–0.708), low ε_Nd( t ) values (−6 to −9) and low δ¹⁸O values of minerals (+2.92 to +4.52). Garnet peridotites of both types experienced multi-stage recrystallization; some of them record prograde histories. High- P–T  estimates (760–970 °C and 4.0–6.5±0.2 GPa) of peak metamorphism indicate that both mantle-derived and crustal ultramafic rocks were subducted to profound depths >100 km (the deepest may be ≥180–200 km) and experienced UHP metamorphism in a subduction zone with an extremely low geothermal gradient of <5 °C km⁻¹.     

New Data Regarding Hotly Debated Topics Concerning UHP Metamorphism of the Dabie-Sulu Belt,East-Central China

Critical but controversial problems in the study of UHP metamorphic rocks from the Dabie-Sulu region include: (1) the possible existence of ophiolitic mélange; (2) the “in situ” versus “foreign” origin of UHP eclogites and their enclosing gneisses; (3) the possible presence and role of fluids during ultrahigh-pressure (UHP) recrystallization; (4) the timing of collision between the Yangtze and Sino-Korean continental blocks; (5) the polarity of syncollisional subduction; and (6) a single-versus multistage exhumation scenario for the UHP rocks. These questions are discussed in light of new geological, geochemical, and isotopic constraints.

Our conclusions for the Dabie-Sulu belt are as follows: (1) Mafic-ultramafic blocks are of two distinct origins: one group samples lithosphere of the suprasubductionzone mantle wedge, whereas the second group represents postcollisional magmatic intrusions. Neither lithologic group represents true oceanic crust. (2) Quartzofeldspathic gneisses enveloping the eclogites are of two types— metasedimentary “in situ” and igneous “foreign.” The paragneisses contain UHP garnets + white micas, and are uniformly older (235 ± 5 Ma) than the orthogneisses (210 ± 5 Ma), which are devoid of UHP mineralogic indicators. (3) Fluids were active under UHP conditions and allowed the formation of UHP hydrous phases such as phengite and zoisite. However, the aqueous fluids may have been restricted to certain channels/pathways during exhumation. External fluids were absent until ascent of the UHP rocks to middle-crustal levels. (4) The Yangtze and Sino-Korean continental blocks collided during 230 to 240 Ma, when supracontinental rocks experienced UHP metamorphism. The HP metamorphic event dated as >400 Ma might record a subduction of oceanic crust during the Paleozoic. (5) An ancient mantle wedge is revealed by geochemical characteristics of Mesozoic magmatic rocks developed on the southern margin of the Sino-Korean craton, the hanging wall of the UHP-rock-bearing unit. Seismic tomography images reveal that the Yangtze block extends beneath the Dabie-Sulu orogenic belt. This indicates that both oceanic and continental crust had a northward subduction polarity. (6) Taking petrologic and geochronological data into account, we prefer a multistage exhumation model. The UHP rocks were exhumed rapidly during the first stage (230 to 200 Ma), perhaps reflecting a corner-flow mechanism. Then, buoyancy and mantle upwelling brought the UHP rocks up to middle-crustal levels during the second stage (200 to 170 Ma). Extension and thermal uplift, as well as erosion, eventually exposed the UHP rocks to the surface in the third stage (170 to 120 Ma).     

Subduction of lithospheric upper mantle recorded by solid phase inclusions and compositional zoning in garnet: Example from the Bohemian Massif

This paper presents monomineral and multiphase inclusions in garnet from eclogites and clinopyroxenites, which form layers and boudins in garnet peridotites from two areas in the Moldanubian zone of the Bohemian Massif. The garnet peridotites occur in felsic granulites and reached UHP conditions prior to their granulite facies overprint. In addition to complex compositional zoning, garnets from hosting eclogites and clinopyroxenites preserve inclusions of hydrous phases and alkali silicate minerals including: amphiboles, chlorites, micas and feldspars. Amphibole, biotite and apatite inclusions in garnet have a high concentration of halogens; CO₂ and sulfur are involved in carbonates and sulfide inclusions, respectively. The inclusion patterns and compositional zoning in garnet in combination with textural relations among minerals, suggest that the ultramafic and mafic bodies are derived from lithospheric mantle above the subduction zone and were transformed into garnet pyroxenites and eclogites in the subduction zone. Based on compositional, mineral and textural relations, all of these rocks along with the surrounding crustal material were overprinted by granulite facies metamorphism during their exhumation.     

Ultrahigh-pressure metamorphism and exhumation of garnet peridotite in Pohorje, Eastern Alps

New evidence for ultrahigh‐pressure metamorphism (UHPM) in the Eastern Alps is reported from garnet‐bearing ultramafic rocks from the Pohorje Mountains in Slovenia. The garnet peridotites are closely associated with UHP kyanite eclogites. These rocks belong to the Lower Central Austroalpine basement unit of the Eastern Alps, exposed in the proximity of the Periadriatic fault. Ultramafic rocks have experienced a complex metamorphic history. On the basis of petrochemical data, garnet peridotites could have been derived from depleted mantle rocks that were subsequently metasomatized by melts and/or fluids either in the plagioclase‐peridotite or the spinel‐peridotite field. At least four stages of recrystallization have been identified in the garnet peridotites based on an analysis of reaction textures and mineral compositions. Stage I was most probably a spinel peridotite stage, as inferred from the presence of chromian spinel and aluminous pyroxenes. Stage II is a UHPM stage defined by the assemblage garnet + olivine + low‐Al orthopyroxene + clinopyroxene + Cr‐spinel. Garnet formed as exsolutions from clinopyroxene, coronas around Cr‐spinel, and porphyroblasts. Stage III is a decompression stage, manifested by the formation of kelyphitic rims of high‐Al orthopyroxene, aluminous spinel, diopside and pargasitic hornblende replacing garnet. Stage IV is represented by the formation of tremolitic amphibole, chlorite, serpentine and talc. Geothermobarometric calculations using (i) garnet‐olivine and garnet‐orthopyroxene Fe‐Mg exchange thermometers and (ii) the Al‐in‐orthopyroxene barometer indicate that the peak of metamorphism (stage II) occurred at conditions of around 900 °C and 4 GPa. These results suggest that garnet peridotites in the Pohorje Mountains experienced UHPM during the Cretaceous orogeny. We propose that UHPM resulted from deep subduction of continental crust, which incorporated mantle peridotites from the upper plate, in an intracontinental subduction zone. Sinking of the overlying mantle and lower crustal wedge into the asthenosphere (slab extraction) caused the main stage of unroofing of the UHP rocks during the Upper Cretaceous. Final exhumation was achieved by Miocene extensional core complex formation.     

A crustal origin for eclogites and a mantle origin for garnet peridotites: Strontium isotopic evidence from clinopyroxenes

Strontium isotopic data suggest that the classic eclogite-facies rocks of western south Norway described by Eskola (1921) formed from several parental materials in a variety of environments. Mineral separates from essentially basic, bi-minerallic (clinopyroxene and garnet) eclogites that occur as lens-shaped masses within high grade gneisses (country rock eclogites) have Sr⁸⁷/Sr⁸⁶ values that range from 0.704 for fine-grained varieties to 0.716 for coarse-grained, orthopyroxene-bearing varieties. These high, varied ratios contrast with the very low, restricted ratios (0.701 to 0.704) of similar minerals from ultrabasic, garnet-clinopyroxene-orthopyroxene-olivine assemblages (garnet peridotites) that occur as lenses within large peridotite bodies. The eclogite-facies metamorphism that generated the garnet peridotites may have occurred in the mantle. However, the metamorphism that generated at least the more radiogenic country-rock eclogites must have occurred in the crust. The high Sr⁸⁷/Sr⁸⁶ ratios of these eclogites could be generated either by forming them from crustal parental rocks or by contaminating mantle-derived parental rocks with radiogenic strontium from the country rocks. If this contamination occurred after intrusion and before eclogite-facies metamorphism, a rather contrived history must be postulated that involves intrusion, contamination accompanied by hydration, subsequent dehydration, and finally eclogite-facies metamorphism. These processes could have occurred within the long, complicated history of the enclosing country rocks. Alternatively, if the contamination occurred during eclogite-facies metamorphism, the presence of some hydrous fluid appears to be required to transport the radiogenic strontium from the enclosing country rocks. The eclogites with the highest Sr⁸⁷/Sr⁸⁶ ratios are also the most coarse-grained and it is possible that the presence of some intergranular fluid enabled these eclogites to recrystallize to a much larger grain size than would have been possible in a totally anhydrous environment. The garnet peridotites and fine-grained country rock eclogites may have formed from mantle material in the crust but escaped contamination by radiogenic strontium as a result of their position in a dry environment in the crust.Lamont-Doherty Geological Observatory Contribution No. 2443     

大别—苏鲁超高压变质带内的块状榴辉岩及其构造意义

大别—苏鲁超高压(> 27× 108Pa) 变质带内的榴辉岩, 在大陆深俯冲、碰撞和折返剥露过程中, 大都遭受了强烈的变形和变质作用的重置与再造.但是, 大型榴辉岩体核部以及包裹于大理岩和石榴橄榄岩体内部的块状榴辉岩, 往往保留其初始简单的矿物组合、中-细粒状变晶结构和块状构造.详细地分析了块状榴辉岩的几何学、岩相学及变质作用特征, 指出它们是超高压榴辉岩递进及多期变质变形分解作用的残留体, 位于尺度不同的弱应变域内, 是大陆深俯冲及碰撞作用的真正记录.      

含柯石英超高压榴辉岩的早期变形--以苏北东海碱场榴辉岩体为例

以超高压矿物组合的各种后成合晶及冠状体等卸载不平衡结构为参考标志，将含柯石英的超高压榴辉岩的交形序列分成两个部分。后成合晶及冠状体发育之前的变形为早期变形，是在大陆深俯冲和碰撞条件下发育的超高压变质变形组构。后成合晶及冠状体发育之后的变形为晚期变形，是在超高压岩石折返剥露过程中，主要是在角闪岩相甚至绿片岩相条件下发育的。构造上江苏省北部东海县碱场合柯石英榴辉岩体，分为块状榴辉岩和面理化榴辉岩两种类型，分别代表超高压变质岩早期变形的两个构造阶段或世代(D1、D2)。详细描述了它们的矿物组合、中小尺度及显微尺度下的组构特征，讨论了两者的几何关系和区域构造意义，强调指出，只有含柯石英榴辉岩的早期变形组构，才能记录和反映斜向大陆深俯冲及碰撞的动力学过程。     

Genesis of garnet peridotites in the Sulu UHP belt: Examples from the Chinese continental scientific drilling project-main hole, PP1 and PP3 drillholes

The main hole (MH), and pre-pilot holes PP1, and PP3 of the Chinese Continental Scientific Drilling Project (CCSD) penetrated three different garnet peridotite bodies in the Sulu ultrahigh pressure (UHP) metamorphic belt, which are 80 m, 120 m, and 430 m thick, respectively. The bodies occur as tectonic blocks hosted in eclogite (MH peridotite) and gneisses (PP1 and PP3 peridotites). The peridotites in the MH are garnet wehrlites, whose protoliths were ultramafic cumulates based on olivine compositions (Fo_79-89) and other geochemical features. Zoned garnet and omphacite (with 4-5 wt.% Na₂O) are typical metamorphic minerals in these rocks, and, along with P-T estimates based on mineral pairs, suggest that the rocks have undergone UHP metamorphism. SHRIMP U-Pb isotope dating of zircon from the garnet wehrlite yielded a Paleozoic protolith age (ca. 346-461 Ma), and a Mesozoic UHP metamorphic age (ca. 220-240 Ma). The peridotites in PP1 consist of interlayered garnet (Grt)-bearing and garnet-free (GF) peridotite. Both types of peridotite have depleted mantle compositions (Mg# = 90-92) and they display transitional geochemical features. The intercalated layers probably reflect variations in partial melting rather than pressure variations during metamorphism, and the garnets may have been formed by exsolution from orthopyroxene during exhumation. These peridotites were probably part of the mantle wedge above the subduction zone that produced the UHP metamorphism and thus belonged to the North China Block before its tectonic emplacement. The exhumation of the subducted Yangtze Block brought these mantle fragments to shallow crustal levels. The ultramafic rocks in PP3 are dominantly dunite with minor garnet dunite. Their high Mg# (92-93) and relatively uniform chemical compositions indicate that they are part of a depleted mantle sequence. The presence of garnet replacing spinel and enclosing pre-metamorphic minerals such as olivine, clinopyroxene and spinel suggests that these rocks have undergone progressive metamorphism. SHRIMP U-Pb isotope dating of zircon from these rocks yielded two age groups: 726 ± 56 Ma for relic magmatic zircon grains and 240 ± 2.7 Ma for the newly formed metamorphic zircon. The older group is similar in age to granitic intrusions within the Dabie-Sulu belt, suggesting that the PP3 garnet peridotite may record the early emplacement of the peridotite into the crust. The younger dates coincide with the age of UHP metamorphism during continent-continent collision between the Yangtze and North China Blocks, suggesting that these peridotites were subducted to depths equivalent to the coesite facies and later exhumed. Thus, the garnet peridotites in the CCSD cores include both ultramafic rocks that existed originally in the subducted plate and rocks from the mantle wedge above the subducted plate, i.e., part of the North China Block.     

Inter-mineral Fe isotope variations in mantle-derived rocks and implications for the Fe geochemical cycle

Iron isotope and major- and minor-element compositions of coexisting olivine, clinopyroxene, and orthopyroxene from eight spinel peridotite mantle xenoliths; olivine, magnetite, amphibole, and biotite from four andesitic volcanic rocks; and garnet and clinopyroxene from seven garnet peridotite and eclogites have been measured to evaluate if inter-mineral Fe isotope fractionation occurs in high-temperature igneous and metamorphic minerals and if isotopic fractionation is related to equilibrium Fe isotope partitioning or a result of open-system behavior. There is no measurable fractionation between silicate minerals and magnetite in andesitic volcanic rocks, nor between olivine and orthopyroxene in spinel peridotite mantle xenoliths. There are some inter-mineral differences (up to 0.2‰ in ⁵⁶Fe/⁵⁴Fe) in the Fe isotope composition of coexisting olivine and clinopyroxene in spinel peridotites. The Fe isotope fractionation observed between clinopyroxene and olivine appears to be a result of open-system behavior based on a positive correlation between the Δ⁵⁶Fe_{clinopyroxene-olivine} fractionation and the δ⁵⁶Fe value of clinopyroxene and olivine. There is also a significant difference in the isotopic compositions of garnet and clinopyroxene in garnet peridotites and eclogites, where the average Δ⁵⁶Fe_{clinopyroxene-garnet} fractionation is +0.32 ± 0.07‰ for six of the seven samples. The one sample that has a lower Δ⁵⁶Fe_{clinopyroxene-garnet} fractionation of 0.08‰ has a low Ca content in garnet, which may reflect some crystal chemical control on Fe isotope fractionation. The Fe isotope variability in mantle-derived minerals is interpreted to reflect subduction of isotopically variable oceanic crust, followed by transport through metasomatic fluids. Isotopic variability in the mantle might also occur during crystal fractionation of basaltic magmas within the mantle if garnet is a liquidus phase. The isotopic variations in the mantle are apparently homogenized during melting processes, producing homogenous Fe isotope compositions during crust formation.     

中国东部上地幔岩石相转变及其意义

中国东部新生代玄武岩和大别-苏鲁超高压变质带中的含石榴石相橄榄岩, 带来了发生在上地幔的尖晶石→石榴石相转变和铝辉石→贫铝辉石+石榴石的重要信息, 为中国东部上地幔岩石结构分层奠定了重要基础.通过岩石学与实验岩石学的研究, 推导出发生相转变的P-T条件, 为建立中国东部大陆上地幔岩石分层结构提供了重要约束.尖晶石二辉橄榄岩向石榴石二辉橄榄岩相转变发生在55~70km, 随着深度增加, 石榴石二辉橄榄岩从富铝石榴石二辉橄榄岩(70~120km) 转变为贫铝石榴石二辉橄榄岩(> 120~150km).      

Deep subduction of mantle-derived garnet peridotites from the Su-Lu UHP metamorphic terrane in China

Garnet peridotites from the southern Su‐Lu ultra‐high‐pressure metamorphic (UHPM) terrane, eastern China, contain porphyroblastic garnet with aligned inclusions comprising a low‐P–T mineral assemblage (chlorite, hornblende, Na‐gedrite, Na‐phlogopite, talc, spinel and pyrite). Orthopyroxene porphyroblasts show fine exsolution lamellae of clinopyroxene and minor chromite. A clinopyroxene inclusion in garnet shows some orthopyroxene exsolution lamellae. Both the rims of porphyroblastic pyroxene and garnet and the matrix pyroxene and garnet crystallized at the expense of olivine. This is interpreted as a result of metasomatism of the peridotites by an SiO₂‐rich melt at UHP conditions. A chromian garnet further overgrew on the rims of the garnet. The X_Mg values (Mg/(Mg+Fe)) of porphyroblastic garnet decrease from core to rim and vary in different peridotite samples, while the compositions of both the porphyroblastic and the matrix pyroxene are similar in terms of Ca–Mg–Fe. The Mg‐rich cores of porphyroblastic garnet and orthopyroxene record high temperatures and pressures (c. 1000 °C, ≥5.1 GPa), whereas the matrix minerals, including the rims of porphyroblasts, record much lower P–T (c. 4.2 GPa, c. 760 °C). Sm–Nd data give apparent isochron ages of c. 380 Ma and negative ε_Nd(0) values (c.?9). These dates are considered meaningless due to isotopic disequilibrium between garnet cores and the rest of the rocks. The isotopic disequilibrium was probably caused by metasomatism of the peridotites by melt/fluids derived from the coevally subducted crustal materials. On the other hand, the Rb–Sr isotopic systems of phlogopite and clinopyroxene appear to have reached equilibrium and record a cooling age of c. 205 Ma. It is suggested that the garnet peridotites were originally emplaced into a low‐P–T environment prior to the c. 220 Ma continental collision, during which they were subducted together with crustal rocks to mantle depth and subjected to UHP metamorphism. An important corollary is that at least some of the coevally subducted crustal rocks in the Su‐Lu terrane have been subjected to peak metamorphism at P–T conditions much higher than presently estimated (≥2.7 GPa, ≤800 °C).     

Metasomatism of garnet peridotite from Jiangzhuang,southern Sulu UHP belt: constraints on the interactions between crust and mantle rocks during subduction of continental lithosphere

The Jiangzhuang ultrahigh‐pressure (UHP) metamorphic peridotite from south Sulu, eastern China occurs as a layer within gneiss with eclogite blocks, and consists of coarse‐grained garnet porphyroblasts and a fine‐grained matrix assemblage of garnet + forsterite + enstatite + diopside ± phlogopite ± Ti‐clinohumite ± magnesite. Both types of garnet are characterized by high MgO content and depletion of light rare earth element (LREE) and enrichment of heavy rare earth element, but the matrix garnet has lower MgO, TiO₂ and higher Cr₂O₃ and REE contents. Diopside displays LREE enrichment, and has low but variable large‐ion lithophile element (LILE) contents. Phlogopite is a major carrier of LILE. Ti‐clinohumite contains high Nb, Ta, Cr, Ni, V and Co contents. The P–T conditions of 4.5–6.0 GPa and 850–950 °C were estimated for matrix mineral assemblages. Most peridotites are depleted in Al₂O₃, CaO and TiO₂, and enriched in SiO₂, K₂O, REE and LILE. In contrast to phlogopite‐free peridotites, the phlogopite‐bearing peridotites have higher K₂O, Zr, REE and LILE contents. Zircon occurs only in the phlogopite‐bearing peridotites, shows no zoning, with low REE contents and Th/U ratios, and yields tight U–Pb ages of 225–220 Ma, indicating the peridotites experienced consistent Triassic UHP metamorphism with subducted supercrustal rocks. These data demonstrate that the Jiangzhuang peridotites were derived from the depleted mantle wedge of the North China Craton, and experienced various degrees of metasomatism. The phlogopite‐free peridotites may have been subjected to an early cryptic metasomatism at UHP conditions of the mantle wedge, whereas the phlogopite‐bearing peridotites were subjected to a subsequent strong metasomatism, characterized by distinctly enrichment in LILE, LREE, Zr and K as well as the growth of zircon and volatile‐bearing minerals at UHP subduction conditions. The related metasomatism may have resulted from the filtration of fluids sourced mainly from deeply subducted supracrustal rocks.     

中国大陆科学钻探主孔(CCSD-MH)石榴石橄榄岩:一个经历了深俯冲作用的古生代超镁铁质侵入体

中国大陆科学钻探主孔中的超镁铁岩主要产在603.20～683.53m深度之间。超镁铁岩的上部直接围岩为高Ti-Fe型榴辉岩;内部夹有薄层状含柯石英高镁榴辉岩和厚层状多硅白云母榴辉岩;下部直接围岩为石英榴辉岩和普通榴辉岩。超镁铁岩的主体岩性为石榴石单辉橄榄岩,主要由橄榄石(60%～70%),石榴石(10%～25%),单斜辉石(5%～15%),斜方辉石(1%～5%)和少量金云母和钛铁矿或钛斜硅镁石组成。橄榄石Fo 79～89,其中一些以包裹体形式出现的高MgO橄榄石可能形成较早,主体橄榄石属变质重结晶阶段形成;石榴石以低CaO、高MgO和Cr_2O_3含量高(达3%)为特征,保留较好的进变质成分环带;单斜辉石Na_2O含量达到4%～5%,分为绿辉石和普通辉石类,属变质成因,结合矿物对的温压估算,岩石已经经历超高压变质作用。岩石成分研究表明,石榴石单辉橄榄岩与其顶、底板榴辉岩及其中的榴辉岩夹层有一较大的成分间断,其中MgO含量约相差10%左右,认为超镁铁岩与榴辉岩的原岩不属同一岩浆演化产物。锆石SHRIMP定年表明石榴石单辉橄榄岩原岩时代为古生代346～461Ma,超高压变质作用时代为早中生代220～240Ma。认为CCSD主孔石榴石橄榄岩为古生代的超镁铁质侵入体,在印支期的中国南北板块俯冲折返过程中经历了超高压变质作用。     

Sm-Nd Isotope Tracer Study of UHP Metamorphic Rocks: Implications for Continental Subduction and Collisional Tectonics

Sm-Nd isotope tracer techniques are powerful tools in identification of the protolith nature of UHP and HP rocks and can be used to constrain modeling of tectonic processes of continental collision. UHP rocks may have diverse origins, and not all of them carry the same significance for subduction of continental blocks. In this paper, Sm-Nd isotopic data are compiled for UHP and HP rocks, mostly represented by eclogites and garnet peridotites, from the Alpine, Hercynian (Variscan), and Caledonian belts of western Europe; the Pan-African belts of northern Africa; and the Ross belt of Antarctica. These data then are compared with the isotopic characteristics of the UHP rocks from the Dabie orogen of central China. Except for the coesite-bearing quartzitic metasediments of Dora-Maira (Western Alps), which are clearly of continental origin, all HP and UHP rocks (eclogites and ultramafic rocks) from the Alpine, Hercynian, and Pan-African belts have oceanic affinities with the characteristic positive ε_Nd(T) values (= metamorphic initial ¹⁴³Nd/¹⁴⁴Nd ratios). They represent segments of oceanic lithosphere that were subducted, underwent eclogite-facies metamorphism, and later were tectonically transported into orogenic zones during continental collisions. By contrast, the majority of UHP rocks from the European Caledonide and the Dabie orogen have negative ε_ND(T) values, indicating continental affinity. This suggests that these mafic and ultramafic rocks have had a long crustal residence time and that their UHP metamorphism is indicative of subduction of ancient and cold continental blocks, as represented by some Precambrian gneiss terranes containing mafic components including greenschists, amphibolites, or basic granulites.

In the Dabie orogen, none of the UHP eclogites analyzed thus far have shown oceanic affinity; thus they do not represent subducted Tethys Ocean crust. The preservation of ultrahigh ε_ND(0) values (+170 to +260) in eclogites of very low Nd concentrations (average 0.5 ppm) from the Weihai region and of the extraordinarily low δ¹⁸O in many eclogites and gneisses, the general absence of syntectonic granites in the Dabie Shan, and the available age data obtained by different techniques all point to a rapid rate of exhumation and the absence of a pervasive aqueous fluid phase during the entire process of subduction and exhumation of the Dabie UHP terrane.     

苏鲁-大别山超高压变质带迟家店和碧溪岭石榴二辉橄榄岩橄榄石组构

大别山碧溪岭和山东荣成分别发育壳源和幔源的石榴二辉橄榄岩。它们在扬子板块向华北板块的俯冲过程中与俯冲板片一起经历了超高压变质作用。这两种原岩来源不同的石榴橄榄岩中的橄榄石具有相似的结晶学优选方位(LPO):[100]轴主板密垂直于面理面,[010]轴主极密平行于线理,这种橄榄石结晶学优选方位明显不同于高温地幔橄榄岩包体中的橄榄石组构,也不同于最近在超高压变质地体中发现的水导致的橄榄石组构。我们认为碧溪岭和荣成石榴二辉橄榄岩中的这种橄榄石组构可能是在相对较干的超高压变质条件下形成的。本研究为大陆深俯冲超高压变质石榴橄榄岩橄榄石组构特征提供了第一手资料。     

浅变质岩在示踪大别—苏鲁造山带大陆板块俯冲与折返过程中的意义

中国大别-苏鲁造山带为大陆板块俯冲形成的碰撞造山带,该带北缘和内部产有原岩时代为新元古代-晚古生代的浅变质岩。这些浅变质岩对应于扬子板块北缘前寒武变质基底和扬子板块北缘古生代大陆架沉积物,形成过程于印支期扬子板块向北俯冲过程中的刮削作用密切相关,与大洋板块俯冲过程中刮削形成的加积楔具有类似的动力学过程。对大别-苏鲁造山带浅变质岩的深入研究,不仅有助于揭示大陆板块俯冲过程中高压-超高压岩石形成与折返过程,而且确定了扬子板块与华北板块之间的缝合线位置位于大别造山带北淮阳带的北部和苏鲁造山带的五莲-蓬莱群的北侧。     

大别-苏鲁区超高压(UHP)变质岩的多阶段构造折返过程

追溯和重塑超高压变质岩由100多千米地幔深度折返至上地壳及地表的过程,对理解会聚板块边缘及大陆碰撞带的运动学和动力学是极为重要的.主要依据构造学、岩石学、地球化学和可利用的地质年代学资料,结合区域多期变形分析,大别-苏鲁区超高压变质岩的折返过程至少可分解出4个大的阶段.块状榴辉岩记录了三叠纪(约250~230 Ma)大陆壳岩石的深俯冲/碰撞作用.超高压变质岩早期迅速折返发生于超高压峰期变质作用(P＞3.1~4.0 GPa,T≈800±50 ℃)之后,处于地幔深度和柯石英稳定域,相当于区域D₂变形期阶段.分别与区域变形期D₃、D₄和D₅对应的折返过程,以及后成合晶、冠状体等卸载不平衡结构发育和减压部分熔融作用2个中间性构造热事件,均发生在地壳层次. 网络状剪切带在折返过程的不同阶段和不同层次均有发育,标志着在超高压变质带内的变质和变形分解作用曾重复进行.着重指出,超高压变质岩的折返,主要是由大陆壳的深俯冲/碰撞和伸展作用控制的构造过程,且受到俯冲带内、带外诸多因素的约束,其中水流体就起关键作用.      

变质地质学新领域─—超高压变质作用与地球动力学

简要总结了近年在欧亚大陆发现的超高压变质岩地质产状、岩石类型、结晶条件和构造位置等基本特征，对超高压变质作用及其地球动力学机制的研究现状及存在的问题进行了评述。基于对大别－苏鲁超高压变质带的研究成果，认为超高压变质作用可能是一种新型的区域变质作用，而目前所建立的任何一种地球动力学模型都不完善。建议今后在岩石学和矿物学研究基础上，加强对超高压变质杂岩的地球化学、构造地质学、实验岩石学及地球物理学等方面的研究。     

柴北缘鱼卡含硬柱石假象榴辉岩的发现、P-T-t轨迹及控制硬柱石形成的主要因素

硬柱石是大洋冷俯冲带的代表性矿物之一,富含水和Sr、Pb及稀土等微量元素,其形成和分解对于俯冲带流体活动、壳幔水和微量元素循环、地幔楔交代和熔融及岛弧岩浆作用等具有重要影响.但由于硬柱石对温度和压力的改变非常敏感,在板片折返过程中很容易分解,因此目前全球出露的硬柱石榴辉岩极为稀少.总结了榴辉岩中早期硬柱石存在的识别标志,并据此确定柴北缘超高压带西段鱼卡地区的含蓝晶石榴辉岩和斜黝帘石榴辉岩是峰期硬柱石榴辉岩退变质改造的结果.该发现说明柴北缘成为继大别造山带之后全球第二例出露硬柱石榴辉岩的大陆俯冲型造山带.利用相平衡计算方法恢复了这两种榴辉岩的变质演化过程,其中含蓝晶石榴辉岩的P-T轨迹和峰期变质条件均与区内大陆俯冲型含柯石英多硅白云母榴辉岩相似,而斜黝帘石榴辉岩峰期变质温压则略低.锆石定年获得含蓝晶石榴辉岩和斜黝帘石榴辉岩的变质时代分别为437 Ma和436 Ma,与带内已有超高压榴辉岩相变质时代相同,同时获得含蓝晶石榴辉岩的原岩结晶时代为1 273 Ma.相似的变质P-T轨迹和变质时代表明含蓝晶石榴辉岩与同剖面含柯石英多硅白云母榴辉岩共同经历了大陆深俯冲作用.这一结果表明,硬柱石榴辉岩并非大洋冷俯冲带特有,决定榴辉岩中是否出现硬柱石的主要因素是原岩成分和变质条件.在鱼卡地区,榴辉岩的矿物组合中能否出现硬柱石的最主要控制因素是原岩中的Mg含量,由高Mg#的基性岩变质形成的榴辉岩峰期矿物组合中易出现硬柱石.