Northern Gulf of Mexico continental slope

The hummocky continental slope in the northwestern Gulf of Mexico is the result of active salt tectonism and accompanying faulting. Fluid and gassy hydrocarbons rise through the sediment column and along faults causing the formation of gas hydrates, gassy sediments, mud volcanoes and mounds, chemosynthetic communities and authigenic carbonates, reefs, and hardgrounds. Salt activity coupled with processes associated with relative sea level fluctuations create a feedback relationship resulting in the above-mentioned phenomena as well as others such as seafloor erosion at great water depths.     

Radiocarbon-derived sedimentation rates in the Gulf of Mexico

Sedimentation rates were determined for the northern Gulf of Mexico margin sediments at water depths ranging from 770 to 3560 m, using radiocarbon determinations of organic matter. Resulting sedimentation rates ranged from 3 to 15 cm/kyr, decreasing with increasing water depth. These rates agree with long-term sedimentation rates estimated previously using stratigraphic methods, and with estimates of sediment delivery rates by the Mississippi River to the northern Gulf of Mexico, but are generally higher by 1–2 orders of magnitude than those estimated by ²¹⁰Pb_xs methods. Near-surface slope sediments from 2737 m water depth in the Mississippi River fan were much older than the rest. They had minimum ¹⁴C ages of 16–27 kyr and δ¹³C values ranging from −24‰ to −26.5‰, indicating a terrestrial origin of organic matter. The sediments from this site were thus likely deposited by episodic mass wasting of slope sediment through the canyon, delineating the previously suggested main pathway of sediment and clay movement to abyssal Gulf sediments.     

Physical and Acoustic Properties of Gas-bearing Sediments in Jinhae Bay,the South Sea of Korea

High-resolution seismic survey and sediment core sampling were conducted to investigate acoustic characteristics of gas-bearing sediments in Jinhae Bay, the southeast of Korea. The sediment in Jinhae Bay is mostly homogenous mud deposited after the Holocene transgression. Along with the 410 km of chirp seismic profiling, five piston core samples were collected on the track lines.

Gassy sediments are common and occur widely in the bay. Core samples were analyzed for sediment texture, physical properties (porosity, water content, bulk density, and grain density), acoustic properties (compressional wave velocity and attenuation), and electrical resistivity. X-radiograph image analysis was also performed to observe the shape of degassing cracks. There is no significant downcore variation on physical and sediment textures regardless of existence of gas bubbles. However, compressional wave velocity dramatically decreases from average 1480 to 1380～739 m/s for the cores that penetrate the gas-bearing zones. This is probably due to degassying cracks that developed by escaping gases and free gas bubbles that are still trapped in the cores. Electrical resistivity is the only geotechnical property that increases in the gas-bearing zone where compressional wave velocity abruptly decreases. This indicates the possibility of using both electrical resistivity as an index variable as well as to compressional wave velocity to identify gassy sediment microstructure because there are little changes in texture and composition of sediment.     

Gulf of Mexico sediment sources and sediment transport trends from magnetic susceptibility measurements of surface samples

The magnetic properties from 200 trigger core-top and Van Veen grab sediment samples recovered from throughout the Gulf of Mexico have been analyzed and used to characterize sediment source and flow pattern distributions. Magnetic parameters included are anhysteretic remanent magnetism (ARM) and magnetic susceptibility (MS) measurements. Results from these measurements are compared to previously determined calcium carbonate percentages, and clay and hematite influx trajectories into the Gulf of Mexico for the same samples reported by Balsam and Beeson [Balsam, W.L. and Beeson, J.P., 2003. Sea-floor sediment distribution in the Gulf of Mexico, Deep-Sea Res. I, 50, 1421–1444.]. The ARM results give an estimate of magnetic grain size distributions, and by analogy, grain size distributions in general, whereas MS patterns show high detrital sediment accumulation zones within the Gulf. The dominant influx of modern high susceptibility sediment into the Gulf of Mexico appears to originate from the Red River, flow into Atchafalaya River Basin and out into the Gulf from Atchafalaya Bay, with significant additional contributions from the Mississippi River through the Southwest Pass of the Mississippi River Delta. This material then moves across the continental shelf and down through the Mississippi Canyon into the deep Gulf where it is redistributed at depths > 3600 m. The eastern shelf margins in the Gulf, offshore from Alabama and Florida, are accumulating calcite- or quartz-rich medium to fine-grained sediment that has a very low or diamagnetic MS signature. From the Louisiana to Texas Gulf coast margins, MS is moderate to high, suggesting a river influx of magnetic constituents from the volcanic fields in New Mexico, and from igneous and metamorphic sources in the Mississippi Basin. Offshore from western Mexico, the MS is high to moderate, but the Yucatan Shelf margin is characterized by low to diamagnetic MS values due to sediment dominated by calcite sands and oozes, a trend that continues to the east onto the West Florida Shelf. Additional measurements of samples collected in association with sites characterized by hydrocarbon seepage exhibit anomalously low MS values. The samples from the lower shelf and slope areas are typified by iron reduction by bacterial organisms in these samples. These results produce anomalous localized lows in the MS trends observed.     

Gas hydrates from the continental slope,offshore Sakhalin Island,Okhotsk Sea

Ten gas-vent fields were discovered in the Okhotsk Sea on the northeast continental slope offshore from Sakhalin Island in water depths of 620—1040 m. At one vent field, estimated to be more than 250 m across, gas hydrates, containing mainly microbial methane (¹³C = –64.3), were recovered from subbottom depths of 0.3–1.2 m. The sediment, having lenses and bedded layers of gas hydrate, contained 30–40% hydrate per volume of wet sediment. Although gas hydrates were not recovered at other fields, geochemical and thermal measurements suggest that gas hydrates are present.     

Preliminary assessment of resources and economic potential of individual gas hydrate accumulations in the Gulf of Mexico continental slope

Some global estimates suggest that gas hydrates represent the largest reservoir of fossil fuel. However, only a few studies of the resource and economic potential of individual gas hydrate accumulations exist. Here we estimate the volume of hydrate-bound gas at GC (Green Canyon) blocks 184/185, GC 234/235, GB (Garden Banks) 388, MC (Mississippi Canyon) 798/842, GC 204, MC 852/853, and AT (Atwater Valley) 425/426 sites in the Gulf of Mexico at water depths ∼500–2000 m. The structural accumulations may contain from 4.7×10⁸ to 1.3×10¹¹ m³ of gas at standard temperature and pressure. The resources in individual gas hydrate accumulations are comparable (by volume) with the reserves in very small to major conventional gas fields. Various geologic, technologic, and economic factors affect the economic potential of studied accumulations. The MC 852/853 appears to be characterized by the most favorable combination of these factors, and thus is suggested to have the highest economic potential. The economic potential of gas hydrate accumulations at GC 204, GB 388, and AT 425/426 sites is ranked as ‘average’. Gas hydrate accumulations at GC 234/235, GC 184/185, and MC 798/842 sites contain only small volumes of hydrate-bound gas, and likely have no economic potential. Future gas hydrate research should focus on the detailed study of large structural gas hydrate accumulations from which gas may be profitably recovered (e.g. the MC 852/853 site).     

Shallow gas depth-contour map of the Skagerrak-western Baltic Sea region

A shallow gas depth-contour map covering the Skagerrak-western Baltic Sea region has been constructed using a relatively dense grid of existing shallow seismic lines. The digital map is stored as an ESRI® shape file in order to facilitate comparison with other data from the region. Free gas usually occurs in mud and sandy mud but is observed only when sediment thickness exceeds a certain threshold value, depending on the water depth of the area in question. Gassy sediments exist at all water depths from approx. 20 m in the coastal waters of the Kattegat to 360 m in the Skagerrak. In spite of the large difference in water depths, the depth of free gas below seabed varies only little within the region, indicating a relatively fast movement of methane in the gas phase towards the seabed compared to the rate of diffusion of dissolved methane. Seeps of old microbial methane occur in the northern Kattegat where a relatively thin cover of sandy sediments exists over shallow, glacially deformed Pleistocene marine sediments. Previous estimates of total methane escape from the area may be correct but the extrapolation of local methane seepage rate data to much larger areas on the continental shelf is probably not justified. Preliminary data on porewater chemistry were compared with the free gas depth contours in the Aarhus Bay area, which occasionally suffers from oxygen deficiency, in order to examine if acoustic gas mapping may be used for monitoring the condition of the bay.     

Comparison of marine gas hydrates in sediments of an active and passive continental margin

Two sites of the Deep Sea Drilling Project in contrasting geologic settings provide a basis for comparison of the geochemical conditions associated with marine gas hydrates in continental margin sediments. Site 533 is located at 3191 m water depth on a spit-like extension of the continental rise on a passive margin in the Atlantic Ocean. Site 568, at 2031 m water depth, is in upper slope sediment of an active accretionary margin in the Pacific Ocean. Both sites are characterized by high rates of sedimentation, and the organic carbon contents of these sediments generally exceed 0.5%. Anomalous seismic reflections that transgress sedimentary structures and parallel the seafloor, suggested the presence of gas hydrates at both sites, and, during coring, small samples of gas hydrate were recovered at subbottom depths of 238m (Site 533) and 404 m (Site 568). The principal gaseous components of the gas hydrates wer methane, ethane, and CO₂. Residual methane in sediments at both sites usually exceeded 10 mll^?1 of wet sediment. Carbon isotopic compositions of methane, CO₂, and ΣCO₂ followed parallel trends with depth, suggesting that methane formed mainly as a result of biological reduction of oxidized carbon. Salinity of pore waters decreased with depth, a likely result of gas hydrate formation. These geochemical characteristics define some of the conditions associated with the occurrence of gas hydrates formed by in situ processes in continental margin sediments.     

Geochemical constraints on the distribution of gas hydrates in the Gulf of Mexico

Gas hydrates are common within near-seafloor sediments immediately surrounding fluid and gas venting sites on the continental slope of the northern Gulf of Mexico. However, the distribution of gas hydrates within sediments away from the vents is poorly documented, yet critical for gas hydrate assessments. Porewater chloride and sulfate concentrations, hydrocarbon gas compositions, and geothermal gradients obtained during a porewater geochemical survey of the northern Gulf of Mexico suggest that the lack of bottom simulating reflectors in gas-rich areas of the gulf may be the consequence of elevated porewater salinity, geothermal gradients, and microbial gas compositions in sediments away from fault conduits.     

Acoustic wave attenuation in the gas hydrate-bearing sediments of Well GC955H,Gulf of Mexico

A better understanding of wave attenuation in hydrate-bearing sediments is necessary for the improved geophysical quantification of marine gas hydrates. Here we compare the attenuation behavior of hydrate-saturated vs water-saturated sediments at site GC955H, in the Gulf of Mexico, which was surveyed during the JIP Leg II expedition. We compute the P-wave attenuation of the gas hydrate bearing sediments using the median frequency shift method on the monopole waveforms. The results show that P-wave attenuation due to low saturation (<?0.4) in hydrate-filled fractures of fine-grained sediment is comparable to that of the water-filled fracture case. On the contrary, P-wave attenuation due to high saturation (>?0.4) in the hydrate-filled pores of coarse-grained sediments can be up to as much as three times more than that of the water-saturated case. The correlation analysis shows that the P-wave attenuation increases with the increasing gas hydrate saturation for the highly saturated gas hydrate-bearing sand interval while the correlation of the P-wave attenuation and hydrate saturation is weak for low saturated gas hydrate-bearing shale interval. The results show that P-wave attenuation is more likely to be used as a geophysical proxy for gas hydrate quantification of highly concentrated coarse-grained sediment rather than for that of fine-grained sediment. To examine the P-wave behavior in sand, we use the improved LCAM model, which accounts for physical factors such as grain boundary roughness and squirt flow to explain the observed differences in P-wave attenuation between hydrate and water-saturated coarse-grained sediment. Our results provide further geophysical evidences for P-wave behavior in the gas hydrate-bearing sediments in the field.     

卫星热红外亮温异常与深水海域天然气水合物藏区分布——以墨西哥湾地区为例

以墨西哥湾西北部陆坡区为研究区,利用NOAA/AVHRR热红外影像,通过分析1999年Central Mexico 7.0级地震、1999年Oaxaco 7.5级地震和2003年Colima 7.6级地震3次地震期间与墨西哥湾西北部陆坡区海底天然气水合物藏区对应的海表面上方卫星热红外亮温异常的变化,研究了卫星热红外亮温异常与深水海域天然气水合物藏区分布的关系.研究发现,与墨西哥湾西北部陆坡区海底天然气水合物藏区对应的海表面上方,临震前频繁出现孤立的、带状的、强度较大的卫星热红外亮温异常,该研究结果表明,同次和多次地震临震前,该地区频繁出现孤立、带状、强度较大的卫星热红外亮温异常可能与海底蕴藏着天然气水合物藏有关.     

Investigation of microbial influences on seafloor gas-hydrate formations

Microbial communities flourish at gas hydrate occurrences in ocean sediments. Studies are reported in this paper on the laboratory production, separation, characterization and hydrate catalysis of biosurfactants from cultures of the Bacillus subtilis bacterium associated with Gulf of Mexico gas-hydrate accumulations. The B. subtilis bacterium from ATCC 21332 species was cultured anaerobically with glucose as carbon-source to produce surfactin, one of the more potent surface active agents known. The surface-active agent was removed from the broth in foam created by bubbling inert gas through the mixture, and biosurfactant was then recovered from the collapsed-foam distilled water solution by acid precipitation and dichloromethane extraction. According to HPLC spectra, five surfactin isomers were identified in the sample of laboratory-generated biosurfactant. Recovered surfactin was then used to perform gas-hydrate formation studies in porous media saturated with the surfactin-water solution. Gas-hydrate induction time and formation rate determinations showed that the anaerobically-produced biosurfactants catalyzed hydrate formation markedly. The tests suggest prolific surfactin production by the B. subtilis bacterium and of other species under prevailing anaerobic conditions around seafloor gas hydrates that promotes hydrate formation and the propensity of the bioproduct to be dispersed in the porous media by natural gas vents.     

Gas accumulations and their association with particle size distribution patterns in the Ría de Arousa seabed (Galicia, NW Spain): an application of discriminant analysis

Gassy sediments in the Ría de Arousa are preferentially distributed in areas of muddy seabed sediments. The close relationship between seabed sediment parameters and gas distribution is here studied in detail to establish better constraints on the presence of gas. Discriminant analysis was applied to the textural and compositional characteristics of 303 seabed sediment samples to classify gas-related and gas-free areas in the Ría de Arousa. The parameters considered in the classification were: particle size data (percentages of clay, silt, sand and gravel), the total inorganic carbon and the total organic carbon contents of the samples. The samples were initially classified in two groups according to the presence or absence of acoustic turbidity in the seismic profiles, shallower than 150 cm below seabed. Of the total known cases, 85.5% were correctly classified using these variables. Applying the Wilks’ lambda criterion, the most influential textural discriminating variables were the percentage of clay and the percentage of coarse fraction (gravel and sand) in the sediment sample. Discriminant analysis has achieved good differentiation between gas-related and gas-free sediments using near-seabed sediment information. The application of the discriminant method has enabled the estimation of the total area covered by gassy sediments in the Ría de Arousa. The area calculated based on the seismic data (30 km²) is a minimum estimate that is constrained by the limits of the existing seismic data. Based on the sediment information obtained from seabed samples, the statistical method estimates a total area of gassy sediments of 39 km². The new gassy areas recognized are located around the gas field at the inner ría, and the gas field west of Arousa Island, which increase in area by 8.3 and 0.4 km² respectively.     

Mapping the resistivity structure of Walker Ridge 313 in the Gulf of Mexico using the marine CSEM method

A marine controlled source electromagnetic (CSEM) campaign was carried out in the Gulf of Mexico to further develop marine electromagnetic techniques in order to aid the detection and mapping of gas hydrate deposits. Marine CSEM methods are used to obtain an electrical resistivity structure of the subsurface which can indicate the type of substance filling the pore space, such as gas hydrates which are more resistive. Results from the Walker Ridge 313 study (WR 313) are presented in this paper and compared with the Gulf of Mexico Gas Hydrate Joint Industry Project II (JIP2) logging while drilling (LWD) results and available seismic data. The hydrate, known to exist within sheeted sand deposits, is mapped as a resistive region in the two dimensional (2D) CSEM inversion models. This is consistent with the JIP2 LWD resistivity results. CSEM inversions that use seismic horizons provide more realistic results compared to the unconstrained inversions by providing sharp boundaries and architectural control on the location of the resistive and conductive regions in the CSEM model. The seismic horizons include: 1) the base of the gas hydrate stability zone (BGHSZ), 2) the top of salt, and 3) the top and bottom of a fine grained marine mud interval with near vertical hydrate filled fractures, to constrain the CSEM inversion model. The top of salt provides improved location for brines, water saturated salt, and resistive salt. Inversions of the CSEM data map the occurrence of a ‘halo’ of conductive brines above salt. The use of the BGHSZ as a constraint on the inversion helps distinguish between free gas and gas hydrate as well as gas hydrate and water saturated sediments.     

In situ hydrocarbon concentrations from pressurized cores in surface sediments, Northern Gulf of Mexico

Two newly developed coring devices, the Multi-Autoclave-Corer and the Dynamic Autoclave Piston Corer were deployed in shallow gas hydrate-bearing sediments in the northern Gulf of Mexico during research cruise SO174 (Oct–Nov 2003). For the first time, they enable the retrieval of near-surface sediment cores under ambient pressure. This enables the determination of in situ methane concentrations and amounts of gas hydrate in sediment depths where bottom water temperature and pressure changes most strongly influence gas/hydrate relationships. At seep sites of GC185 (Bush Hill) and the newly discovered sites at GC415, we determined the volume of low-weight hydrocarbons (C₁ through C₅) from nine pressurized cores via controlled degassing. The resulting in situ methane concentrations vary by two orders of magnitudes between 0.031 and 0.985 mol kg^− 1 pore water below the zone of sulfate depletion. This includes dissolved, free, and hydrate-bound CH₄. Combined with results from conventional cores, this establishes a variability of methane concentrations in close proximity to seep sites of five orders of magnitude. In total four out of nine pressure cores had CH₄ concentrations above equilibrium with gas hydrates. Two of them contain gas hydrate volumes of 15% (GC185) and 18% (GC415) of pore space. The measurements prove that the highest methane concentrations are not necessarily related to the highest advection rates. Brine advection inhibits gas hydrate stability a few centimeters below the sediment surface at the depth of anaerobic oxidation of methane and thus inhibits the storage of enhanced methane volumes. Here, computerized tomography (CT) of the pressure cores detected small amounts of free gas. This finding has major implications for methane distribution, possible consumption, and escape into the bottom water in fluid flow systems related to halokinesis.     

Predicting saturation of gas hydrates using pre-stack seismic data, Gulf of Mexico

A promising method for gas hydrates exploration incorporates pre-stack seismic inversion data, elastic properties modeling, and seismic interpretation to predict saturation of gas hydrates (Sgh). The technology can be modified slightly and used for predicting hydrate concentrations in shallow arctic locations as well. Examples from Gulf of Mexico Walker Ridge (WR) and Green Canyon (GC) protraction areas illustrate how Sgh was derived and used to support the selection of well locations to be drilled for gas hydrates in sand reservoirs by the Chevron-led Joint Industry Project (JIP) Leg II cruise in 2009. Concentrations of hydrates were estimated through the integration of seismic inversion of carefully conditioned pre-stack data, seismic stratigraphic interpretation, and shallow rock property modeling. Rock property trends were established by applying principles of rock physics and shallow sediment compaction, constrained by regional geological knowledge. No nearby sonic or density logs were available to define the elastic property trends in the zone of interest. Sgh volumes were generated by inverting pre-stack data to acoustic and shear impedance (PI and SI) volumes, and then analyzing deviations from modeled impedance trends. In order to enhance the quality of the inversion, we stress the importance of maximizing the signal to noise ratio of the offset data by conditioning seismic angle gathers prior to inversion. Seismic interpretation further plays an important role by identifying false anomalies such as hard, compact strata, which can produce apparent high Sgh values, and by identifying the more promising strata and structures for containing the hydrates. This integrated workflow presents a highly promising methodology, appropriate for the exploration of gas hydrates.     

Multiple resolution seismic imaging of a shallow hydrocarbon plumbing system,Woolsey Mound,Northern Gulf of Mexico

The northern Gulf of Mexico is dominated by salt tectonics, resulting fracturing and numerous seafloor seeps and vents. Woolsey Mound, site of the Gulf of Mexico Hydrates Research Consortium's seafloor observatory, has been investigated extensively via surveys, direct sampling and seafloor instrument systems. This study presents an innovative approach to seismic data interpretation, integrating three different resolution datasets and maximizing seismic coverage of the complex natural hydrocarbon plumbing system at Woolsey Mound.3D industry seismic data reveal the presence of a salt body at in the shallow subsurface that has generated an extended network of faults, some extending from the salt body to the seafloor (master faults). Higher resolution seismic data show acoustic wipe-out zones along the master faults with expulsion features – seafloor pockmarks and craters – located immediately above them and associated, in the subsurface, with high-amplitude, negative anomalies at constant depth of 0.2 s TWTT b.s.f., interpreted as free gas. Since pockmarks and craters provide pathways for hydrocarbons to escape from depth into the water column, related sub-surface seismic anomalies may indicate free gas at the base of the gas hydrates stability zone (GHSZ). Fluid flow and gas hydrates formation are segmented laterally along faults. Gas hydrates formation and dissociation vary temporally in the vicinity of active faults, and can temporarily seal them as conduits for thermogenic fluids. Periodic migrations of gases and other fluids may perturb the GHSZ in terms of temperature and pressure, producing the observed lack of classical BSRs.     

Estimation of Geoacoustic Properties of Marine Sediment Using a Hybrid Differential Evolution Inversion Method

This paper reports the inversion of midfrequency (1500–4500 Hz) chirps from a short-range transmission experiment conducted on the New Jersey Continental Shelf during the 2006 Shallow Water Experiment (SW06). The source was held at different depths and the sound signals were recorded at a vertical line array to investigate the interactions with the sea bottom at various grazing angles. Strong reflections from the sediment layer were seen in the data for all of the sources. Due to the presence of complex microstructures in the thermocline of the oceanic sound-speed profile, fluctuations both in amplitude and arrival time of the direct path arrivals were observed. Time variation of the water-column environment was also evident during the source transmissions. To mitigate the effects of the ocean environment on the seabed property estimation, a multistage optimization inversion was employed. The sound speed and the experimental geometry were inverted first using only the travel times of the water-column arrivals. The bottom sound speed and the sediment layer thickness were then inverted by matching the travel times of the bottom and sub-bottom reflections. The average of the estimated values for the sediment sound speed is 1598 m/s, consistent with in situ measurements from other experiments in the vicinity.      

Dissolved inorganic carbon (DIC) and its carbon isotopic composition in sediment pore waters from the Shenhu area,northern South China Sea

The Shenhu area is one of the most favorable places for the occurrence of gas hydrates in the northern continental slope of the South China Sea. Pore water samples were collected in two piston cores (SH-A and SH-B) from this area, and the concentrations of sulfate and dissolved inorganic carbon (DIC) and its carbon isotopic composition were measured. The data revealed large DIC variations and very negative δ ¹³C-DIC values. Two reaction zones, 0–3 mbsf and below 3 mbsf, are identified in the sediment system. At site SH-A, the upper zone (0–3 mbsf) shows relatively constant sulfate and DIC concentrations and δ ¹³C-DIC values, possibly due to bioturbation and fluid advection. The lower zone (below 3 mbsf) displays good linear gradients for sulfate and DIC concentrations, and δ ¹³C-DIC values. At site SH-B, both zones show linear gradients, but the decreasing gradients for δ ¹³C-DIC and SO₄ ²⁻ in the lower zone below 3 mbsf are greater than those from the upper zone, 0–3 mbsf. The calculated sulfate-methane interface (SMI) depths of the two cores are 10.0 m and 11.1 m, respectively. The depth profiles of both DIC and δ ¹³C-DIC showed similar characteristics as those in other gas hydrate locations in the world oceans, such as the Blake Ridge. Overall, our results indicate an anaerobic methane oxidation (AMO) process in the sediments with large methane flux from depth in the studied area, which might be linked to the formation of gas hydrates in this area.