油藻混合水体遥感反射比光谱分析

辐射传输模式HydroLight是研究水体辐射传输特性的有效工具,同时也是进行石油类水体辐射传输特性的有效模型。本文基于2018年8月在辽宁大连港海域实测的石油类污染水体的表观及固有光学量数据,通过设置不同浓度的配比模拟试验,利用HydroLight对油类物质和藻类物质的单一组分和两者混合水体的遥感反射比（remote sensing reflectance,R_rs）光谱进行了模拟。模拟结果表明：（1）在仅含油类物质单一组分的水体中,R_rs随着油浓度C_oil的变化分为两个特征波段：400~480 nm和480~700 nm。在400~480 nm波段范围内R_rs随C_oil的增加而减小,在480~700 nm随C_oil的增大而增大;（2）在仅含藻类物质的单一成分水体中,叶绿素的光谱特性需要其浓度C_chl达到一定值才能表现出来,在低C_chl时的R_rs光谱特性反映为纯水的光谱特性;（3）在油藻混合水体中,随C_oil的增加会增大叶绿素的R_rs,但不会明显改变叶绿素的R_rs随波长的变化趋势,这说明油藻混合水体的光谱形状主要受叶绿素的影响,油类物质的存在只改变光谱的量值。利用HydroLight对石油类污染水体的R_rs展开研究,有助于丰富水色遥感基础研究,对完善各类水体生物光学模型研究具有重要的理论意义。     

养马岛附近海域藻华期间有色溶解有机质的生物可利用性研究

本研究利用吸收光谱和荧光激发-发射矩阵光谱-平行因子分析(EEMs-PARAFAC),研究了养马岛附近海域海水中有色溶解有机质(CDOM)的浓度、组成、来源和生物可利用性,并估算了浮游植物生长繁殖对CDOM及具有生物可利用性CDOM的贡献。结果表明,表、底层海水中CDOM浓度(以吸收系数a₃₅₀计)平均值分别为1.62±0.42 m^-1和1.30±0.47 m^-1,光谱斜率(S_275-295)平均值分别为0.022±0.003 nm^-1和0.023±0.003 nm^-1。利用PARAFAC模型识别出4种荧光组分,分别为陆源类腐殖酸C1、类色氨酸C2、类酪氨酸C3和微生物源类腐殖酸C4。荧光指数(FIX)、腐殖化指数(HIX)和生物指数(BIX)显示,CDOM受陆源输入和海洋自生源的综合影响。降解实验结果显示,表、底层海水中生物可利用性CDOM百分比(%△a₃₅₀)平均值分别为(23.36%±17.94%)和(8.93%±20.30%)。C1、C2和C4组分的荧光强度在培养之后降低,而C3组分的荧光强度上升。各荧光组分生物可利用性依次递减的顺序为:%△C1(23.75%±8.96%)＞%△C4(20.83%±11.71%)＞%△C2(11.67%±38.87%)＞%△C3(-29.61%±39.90%),显示培养之后CDOM的平均分子量和腐殖化程度降低。表层海水中a₃₅₀、%△a350与Chl a之间存在显著线性相关关系,据此可以估算出浮游植物生长繁殖对CDOM的贡献为36.9%,对具有生物可利用性CDOM的贡献为85.0%。     

Assessing temporal variation of coloured dissolved organic matter in the coastal waters of South Eastern Arabian Sea

Coloured dissolved organic matter （CDOM） plays a major role in marine photochemical and biological processes and its optical properties are known to affect the underwater light penetration. This paper highlights in situ optical estimation and satellite retrieval of CDOM in deciphering its temporal variations in coastal waters of the South Eastern Arabian Sea. The study accentuated the source of CDOM as terrigenous origin during monsoon， of in situ productions during pre-monsoon and during post-monsoon of autochthonous-allocthonous origin. The matchup analysis for in situ and MODIS Aqua retrieved A_dg443 exhibited bias which decreased by incorporating the seasonal component. The study also identified degrading bloom of Noctiluca scintillans as the source for exceptionally high CDOM in the area during January and February. The study demands to incorporate seasonal components and phytoplankton abundance while assessing the performance of CDOM algorithms in optically complex coastal waters.     

基于Delft 3D模型的感潮河口示踪模拟

为研究感潮河口的水力特征及溶质扩散规律，通过布放仪器监测水文参数，分析研究区的水力特征；采用荧光染色剂罗丹明B作为示踪剂开展现场示踪实验，研究示踪剂的扩散规律；基于Delft 3D模型的水动力模块与示踪模块相耦合，对研究区的动力场和示踪结果进行模拟，获取了小清河口的水平湍流扩散系数。结果表明：调查期间（非汛期）小清河口的水力条件主要受潮汐控制，潮汐对河口下游的作用更明显。由于河流径流量较小，在潮汐作用下，示踪剂从小清河口向海传输的速度较慢，导致示踪剂在河口长时间滞留。相关性分析（R²）和均方根误差（RMSE）结果表明示踪剂迁移模拟结果的可靠性高。基于本研究得到小清河口的水平湍流扩散系数（D_ξ，η）为6t^0.12 m²/s。本研究可为小清河口以及同类河口中水平湍流扩散系数的估值提供参考，对于评价污染物在同类河口中的传输行为具有指导意义。     

Respiration rates of planktonic crustaceans from the Inland Sea of Japan with special reference to the effects of body weight and temperature

A total of 293 measurements of respiration rate were made on planktonic crustaceans collected in different seasons from the Inland Sea of Japan. The relationship between the rate of oxygen consumption (R,μl O₂ indiv.⁻¹ hr⁻¹) and body dry weight (W, mg indiv.⁻¹), as expressed by a power function (R=aW ^b , or logR=loga+b logW), was established as a function of temperature (T, °C). The slope of the regression equation (b) was not significantly affected by seasonal temperature variation, but the intercept of the equation (loga) was strongly influenced by temperature. The equation describing this general relation is logR=(0.0444T−0.333)+0.713 logW.     

夏季长江口南北支溶解有机质的比较

本文以2021年5月长江口南北支采集的表层水为研究对象,通过测定氢、氧同位素,溶解有机碳(DOC)浓度,有色溶解有机质(CDOM)的吸收光谱和荧光光谱参数,探讨了夏季长江口北支、南支(北港、北槽、南槽)水体溶解有机质的组成、分布及其影响因素。沿长江下游到河口近海,南、北支DOC浓度分别为1.68±0.16mg/L和1.46±0.31mg/L,CDOM的吸光系数a₃₅₀分别为2.37±0.61m^-1和1.59±0.24m^-1。南支整体具有“高类腐殖质、低类蛋白”的特征,北支则具有“低类腐殖质、低类蛋白”的特征,这可能与南北支的径流量差异有关。在南北支不同分汊河道(北支、南支北港、南支北槽和南支南槽)中,南槽和北支有类似的海水入侵特征,但南槽具有较强的类蛋白组分输入,而南支北港和北槽样品间无显著差异,均表现为河流有机质为主的特征。对比2011年长江南北支DOC和CDOM数据显示,作为长江主河道的南支在2021年无明显变化,而北支有显著的变化。这些结果综合表明长江口DOM的变化格局可能受水动力条件(径流量)、人类活动因素共同作用的影响。比较全球河口DOC和CDOM浓度数据后发现,不同区域的河口具有明显的差异,这可能是因为不同流域在植被覆盖、工农业生产水平、水利工程强度、以及气候变化对土壤侵蚀作用等方面的差异。     

2012—2016年可见光红外成像辐射仪（VIIRS）海表面温度产品精度检验分析

本研究以2012—2016年5 a间的可见光红外成像辐射仪（VIIRS）海表面温度（SST）产品为研究对象，利用Argo浮标为主要验证数据、MODIS Terra和MODIS Aqua SST为辅助验证数据，从时间尺度和空间尺度进行检验对比分析，结果表明：VIIRS SST与Argo浮标白天的平均偏差为-0.015 5℃，标准偏差为0.514 0℃；夜间平均偏差是-0.221 4℃，标准偏差是0.418 9℃，白天平均偏差较夜间更接近Argo浮标的观测结果；VIIRS SST在白天和夜间偏差均是夏季大于冬季；白天VIIRS SST在近赤道太平洋海域、近赤道印度洋海域要高于浮标观测的海温，夜间这些地区总体要低于浮标值，白天和夜间标准偏差空间分布差异较小；与MODIS Terra和MODIS Aqua SST月平均偏差对比显示，夏季在南半球VIIRS较MODIS Terra SST偏暖强度减弱，冬季VIIRS较MODIS Terra SST在北半球中高纬度海域偏冷；夏季部分海域VIIRS SST较MODIS Aqua偏低，冬季则是大部分海域VIIRS 低于MODIS Aqua SST。     

考洲洋牡蛎养殖海域海-气界面CO2交换通量的时空变化

根据2018年7月、11月和2019年1月、4月对广东考洲洋牡蛎养殖海域进行4个季节调查获得的pH、溶解无机碳(DIC)、水温、盐度、溶解氧(DO)及叶绿素a(Chla)等数据,估算该区域表层海水溶解无机碳体系各分量的浓度、初级生产力(P_P)、表层海水CO₂分压[p(CO₂)]和海-气界面CO₂交换通量(F_CO2),分析牡蛎养殖活动对养殖区碳循环的影响。结果表明:牡蛎养殖区表层海水中Chla、DIC、HCO₃^–和P_P显著低于非养殖区;养殖淡季表层海水中pH、DO、DIC、HCO₃^–、和CO₃^2–显著大于养殖旺季,养殖旺季的p(CO₂)和F_CO2显著大于养殖淡季。牡蛎养殖区表层海水夏季、秋季、冬季和春季的海-气界面CO₂交换通量F_CO2平均值分别是(42.04±9.56)、(276.14±52.55)、(–11.59±18.15)和(–13.02±6.71)mmol/(m²·d),冬季各站位F_CO2值离散度较大,其中位数是–10.73mmol/(m²·d)。在全年尺度,表层海水p(CO₂)及F_CO2与水温呈显著正相关,与盐度呈显著负相关。在非养殖区,浮游植物光合作用可能对影响表层海水p(CO₂)及F_CO2起主导作用。养殖牡蛎钙化、呼吸作用等生理因素释放的CO₂对表层海水p(CO₂)及F_CO2未产生显著影响。考洲洋养殖海域养殖旺季为CO₂的源,养殖淡季整体为CO₂的弱汇。     

大辽河口营养物基准推导方法

河口富营养化与流域氮、磷营养物的输入直接相关，制定河口营养物基准，可用于控制河口及其近岸海域富营养化，为环境管理的科学决策提供依据。大辽河是渤海最大的入海河流之一，河口污染较为严重；本文采用频数分布法、非参数分析法和实验室模拟压力响应关系法探讨大辽河口及近岸海域营养物基准的推导，最终得到大辽河口总氮（TN）、总磷（TP）及叶绿素a（Chl-a）推荐基准值分别为1.008 mg/L，0.067 mg/L和1.175 mg/m³，以期为大辽河口及其近岸海域富营养化评估和营养物标准制定提供科学依据。     

秦皇岛外海低氧区颗粒物吸收光谱特征

近年来, 渤海夏季低氧现象频发, 引起了人们的广泛关注。然而对该海域低氧形成的机制还未得到充分认识。研究基于在秦皇岛外海的现场观测, 分析了海水中颗粒物吸收光谱特征及其与不同粒径浮游植物叶绿素a (chl a)组成、环境因子的关系, 评估了夏季底层水体脱氧过程中有机物来源与特征。结果显示,夏季秦皇岛外海微型浮游植物chl a占总量的80%。表层水体中, 总颗粒物吸收光谱[a_p(l)]特征由浮游植物色素吸收光谱[a_ph(l)]主导, 在中、底层水体中则由碎屑颗粒物吸收光谱[a_d(l)]主导。垂向上, a_p(440)和a_d(440)均表现为表层<中层<底层。结果还表明, 浮游植物粒径主导秦皇岛外海chl a的光吸收效率, 即a^*_ph(440)。基于三粒级chl a含量, 可利用多元回归预测a_ph(440)。碎屑颗粒物的吸收光谱同样受浮游植物群落、有机质相对含量等的影响。研究结果表明初级生产产生的微型颗粒有机物是底层水体脱氧的主要底物。     

大洋河河口海域有色溶解性有机物的光学特性及遥感反演模型

有色溶解性有机物(CDOM)在河口混合过程中近似呈保守行为,可作为水团运动的示踪剂.基于2009年5月6日大洋河河口海域水体调查的实测数据,对该区域CDOM光学特性及遥感反演模型进行了研究,结果表明:研究区域CDOM主要来自河流输入,成分相对较稳定,属于典型的近岸二类水体区域;波长275～295 nm的光谱斜率和波长4...     

An optical model for the remote sensing of coloured dissolved organic matter in coastal/ocean waters

An optical model is developed for the remote sensing of coloured dissolved organic matter (CDOM) in a wide range of waters within coastal and open ocean environments. The absorption of CDOM (denoted as a_g) is generally considered as an exponential form model, which has two important parameters – the slope S and absorption of CDOM at a reference wavelength a_g(λ₀). The empirical relationships for deriving these two parameters are established using in-situ bio-optical datasets. These relationships use the spectral remote sensing reflectance (R_rs) ratio at two wavelengths R_rs(670)/R_rs(490), which avoids the known atmospheric correction problems and is sensitive to CDOM absorption and chlorophyll in coastal/ocean waters. This ratio has tight relationships with a_g(412) and a_g(443) yielding correlation coefficients between 0.77 and 0.78. The new model, with the above parameterization applied to independent datasets (NOMAD SeaWiFS match-ups and Carder datasets), shows good retrievals of the a_g(λ) with regression slopes close to unity, little bias and low mean relative and root mean square errors. These statistical estimates improve significantly over other inversion models (e.g., Linear Matrix-LM and Garver-Siegel-Maritorena-GSM semi-analytical models) when applied to the same datasets. These results demonstrate a good performance of the proposed model in both coastal and open ocean waters, which has the potential to improve our knowledge of the biogeochemical cycles and processes in these domains.     

Variability of Particulate Organic Phosphorus in the Northwestern Part of the Black Sea

Based on long-term (1985–1995) monitoring data, the paper considers the peculiarities of seasonal variability in the spatial and vertical distribution of particulate organic phosphorus (Р_POM) in the surface layer and in the photosynthetic zone in the northwestern Black Sea. Regression equations, experimental data, and satellite observations for the chlorophyll a concentration allowed us to evaluate the seasonal longterm (1979–1995) variability in Р_POM in the surface layer and photosynthesis zone. The ratios of the concentrations of particulate organic carbon, nitrogen, phosphorus, and chlorophyll a are calculated and statistical estimates of seasonal changes in the Р_POM in the areas with different degrees of influence of river runoff and water of open seas are obtained. The consistency of intra-annual changes in the concentrations of Р_POM, chlorophyll a, and phytoplankton biomass is shown, which indicates the role of phytoplankton in the formation of Р_POM and in its intra- and interannual variability in the northwestern part of the sea. It is shown that long-term seasonal variations in Р_POM and related changes in the concentration of chlorophyll a depend on the variability of bulk river runoff, the extent of its abundance in the northwestern shelf, and regional hydrometeorological conditions.     

Coloured dissolved organic matter (CDOM) in Southern North Sea waters: Optical characterization and possible origin

The variability and origin of the Coloured Dissolved Organic Matter (CDOM) were studied in the Belgian coastal and adjacent areas including offshore waters and the Scheldt estuary, through the parameters: absorption at 375 nm, a_CDOM(375), and the slope of the absorption curve, S. a_CDOM(375) varied between 0.20 and 1.31 m⁻¹ and between 0.97 and 4.30 m⁻¹ in the marine area and Scheldt estuary, respectively. S fluctuated between 0.0101 and 0.0203 nm⁻¹ in the marine area and between 0.0167 and 0.0191 nm⁻¹ in the Scheldt estuary. The comparative analysis of a_CDOM(375) and S variations evidenced different origins of CDOM in the BCZ. The Scheldt estuarine waters showed decreasing a_CDOM(375) values with increasing salinity but constant S value of ∼0.018 nm⁻¹ suggesting a dominant terrestrial origin of CDOM. On the contrary, samples collected in the marine domain showed a narrow range of a_CDOM(375) but highly variable S suggesting the additional presence of autochthonous sources of CDOM. This source was evidenced based on the sorting of the marine offshore data according to the stage of the phytoplankton bloom when they were collected. A clear distinction was made between CDOM released during the growth stage characterized by high S (∼0.017 nm⁻¹) and low a_CDOM(375) and the decay phase characterized by low S (∼0.013 nm⁻¹) and high a_CDOM(375). This observation was supported by CDOM measurements performed on pure phytoplankton cultures which showed increased CDOM release along the wax and wane of the bloom but decreasing S. We concluded that the high variability of the CDOM signature in offshore waters is explained by the local biological production and processing of CDOM.     

Seasonal dynamics of light absorption by chromophoric dissolved organic matter (CDOM) in the NW Mediterranean Sea (BOUSSOLE site)

We analyze a two-year time-series of chromophoric dissolved organic matter (CDOM) light absorption measurements in the upper 400 m of the water column at the BOUSSOLE site in the NW Mediterranean Sea. The seasonal dynamics of the CDOM light absorption coefficients at 440 nm (a_cdom(440)) is essentially characterized by (i) subsurface maxima forming in spring and progressively reinforcing throughout summer, (ii) impoverishment in the surface layer throughout summer and (iii) vertical homogeneity in winter. Seasonal variations of the spectral dependence of CDOM absorption, as described by the exponential slope value (S_cdom), are characterized by highest values in summer and autumn at the surface and low values at the depths of a_cdom(440) subsurface maxima or just below them. Variations of a_cdom(440) are likely controlled by microbial digestion of phytoplankton cells, which leads to CDOM production, and by photochemical destruction (photobleaching), which leads to CDOM degradation. Photobleaching is also the main driver of S_cdom variations. Consistently with previous observations, a_cdom(440) for a given chlorophyll a concentration is higher than expected from Case I waters bio-optical models. The total non-water light absorption budget shows that surface waters at the BOUSSOLE site are largely dominated by CDOM during all seasons but the algal bloom in March and April. These results improve the knowledge of CDOM absorption dynamics in the Mediterranean Sea, which is scarcely documented. In addition, they open the way to improved algorithms for the retrieval of CDOM absorption from field or satellite radiometric measurements.     

A new formula for saturated water steam pressure within the temperature range −25 to 220°C

Instead of approximation formula ln(E(t)/E(0)) = [(a ? bt)t/(c + T)] commonly used at present for representing dependence of pressure of saturated streams of liquid water E upon temperature we suggested new approximation formula of greater accuracy in the form ln(E(t)/E(0)) = [(A ? Bt + Ct ²)t/T], where t and T are temperature in °C and K respectively. For this formula with parameters A = 19.846, B = 8.97 × 10^?3, C = 1.248 × 10^?5 and E(0) = 6.1121 GPa with ITS-90 temperature scale and for temperature range from 0°C to 110°C relative difference of approximation applying six parameter formula by W. Wagner and A. Pruß 2002, developed for positive temperatures, is less than 0.005%, that is approximately 15 times less than accuracy obtained with the firs formula. Increase of temperature range results in relative difference increasing, but for even temperature range from 0°C to 220°C it does not higher than 0.1%. For negative temperatures relative difference between our formula and a formula of D. M. Murphy and T. Koop, 2005, is less than 0.1% for temperatures higher than ?25°C. This paper also presents values of coefficients for approximation of Goff and Grach formula recommended by IMO. The procedure of finding dew point T _d for known water steam pressure e _n based on our formula adds up to solving an algebraic equation of a third degree, which coefficients are presented in this paper. For simplifying this procedure this paper also includes approximation ratio applying a coefficient A noted above, in the form T _d (e _n ) = \(\frac{{AT_0 }}{{A - \varepsilon }}\) + 0.0866?² + 0.0116?^10/3, where ? = ln(e _n /E(T ₀)). Error of dew point recovery in this ratio is less than 0.005 K within the range from 0 to 50°C.     

Spatial Distribution and Seasonal Dynamics of the Chlorophyll <Emphasis Type="Italic">a</Emphasis> Concentration in the Sea of Azov Based on MERIS Images

The chlorophyll a concentration (Cchl a) in the Sea of Azov is estimated by the two-band NIR-red algorithm [34] from MERIS images for 2002–2012. The sea-truth spectrophotometric measurements and MERIS remote estimates of Cchl a are compared. The monthly average Cchl a values are mapped from MERIS data for its lifetime for the first time. The features of the spatiotemporal distribution of Cchl a are ascertained. Differences between the seasonal dynamics of Cchl a in the Sea of Azov according to the literature data and the dynamics derived from MERIS data are found, namely: the summer–autumn phytoplankton growth period is longer than the spring period and is characterized by higher Cchl a values throughout the water area.     

Determining the influence of wind-wave breaking on the dissipation of the turbulent kinetic energy in the upper ocean and on the dependence of the turbulent kinetic energy on the stage of wind-wave development

New experimental data that make it possible to explain and predict the observed variability of turbulent-energy dissipation in the upper ocean are discussed. For this purpose, the dependence of the energy dissipation rate of breaking wind waves on their propagation velocity (see [1]) is used. The turbulent-energy dissipation values obtained earlier in [2, 3] by a direct method are compared to the results of radar measurements of individual breaking events presented in [1]. On the basis of this comparison, a strong dependence of the turbulent-energy dissipation value on the stage of wind-wave development, which is characterized by the ratio U _a /c _p (U _a is the wind speed and c _p is the phase speed of the peak of the wind-wave spectrum) is confirmed. This dependence was found earlier purely empirically. Moreover, it is shown that the theoretically obtained dependence (c _p /U _a )⁴, does not contradict the available empirical data. The results of this study opens possibilities for scientifically substantiated calculations of greenhouse-gas exchange (specifically, CO₂ exchange between the ocean and the atmosphere).     

Characterization of dissolved organic matter fluorescence in the South Atlantic Bight with use of PARAFAC model: Relationships between fluorescence and its components,absorption coefficients and organic carbon concentrations

In this study, the CDOM absorption coefficient at 350 nm [a_CDOM(350)] and CDOM excitation emission matrix (EEM) fluorescence were used to estimate annual fluxes of dissolved organic carbon (DOC) from the Cape Fear River to Long Bay in the South Atlantic Bight. Water samples were collected during a 3.5 year period, from October 2001 through March 2005, in the vicinity of the Cape Fear River (CFR) outlet and adjacent Onslow Bay (OB). Parallel factor analysis (PARAFAC) of CDOM EEM spectra identified six components: three terrestrial humic-like, one marine humic-like and two protein-like. Empirical relationships were derived from the PARAFAC model between DOC concentration and a_CDOM(350), total fluorescence intensity and the intensities of respective EEM components. DOC concentration and CDOM optical parameters were very well correlated and R² values ranged from 0.77 to 0.90. Regression analyses revealed that the non-absorbing DOC fraction, in DOC concentration estimated from CDOM optical parameters, varied with the qualitative composition of the CDOM. DOC concentration and intensity of the humic-like CDOM components characterized by excitation maxima at longer wavelengths have significantly higher estimated non-absorbing DOC compared to the analogous relationships between DOC and intensity of the humic-like CDOM components characterized by excitation maxima at shorter wavelengths. The relationships between DOC concentration and intensity of one of the protein-like components resulted in significantly reduced non-absorbing DOC fraction in DOC concentration estimation. Results of regression analyses between fluorescence intensities of specific EEM components and CDOM-specific absorption coefficients suggest that the relative proportion of humic-like CDOM components (characterized by excitation maximum at longer wavelengths) and the main protein-like component have the most impact on the values of a?_CDOM(350). Based on the relationships between a_CDOM(350), Cape Fear River flow, and DOC concentrations, DOC fluxes were estimated for 2002, 2003 and 2004. DOC fluxes varied from 1.5 to 6.2 × 10¹⁰ g C yr^? 1, depending on river flow.     

Parametrization of turbulent fluxes over inhomogeneous landscapes

Reasons for the nonclosure of the heat balance in the atmospheric boundary layers over natural land surfaces are analyzed. Results of measuring the heat-balance components over different land surfaces are used. The Cabauw (Netherlands) data (obtained throughout 1996 over a grass surface with intermittent shrubs and single trees) and the data from the Anchor station in Germany (measured over coniferous forest in 2000–2001) are analyzed. In all, the analysis involves about fifty thousand independent values of the heat-balance components measured in the experiments, which should be indicative of the reliability of the results obtained in the paper. The data have shown that the heat balance is not closed and the imbalance is 50–250 W/m². The sum of the latent and sensible heat fluxes λE + H = STF is found to be systematically smaller than the difference between the net radiation and the heat flux into the ground R _n ? G. It is shown that the main cause of a systematic heat imbalance in the atmospheric boundary layers over inhomogeneous land surfaces is that the methods of surface-flux measurement and estimation are based on the theory that requires the hypothesis of stationarity and horizontal homogeneity. Direct data analysis has shown that the heat imbalance increases with landscape inhomogeneity. In the paper, a parametrization of the heat imbalance is carried out and the coefficient k _f (z ₀ ^ef /L ^ef ) is introduced as a measure of inhomogeneity. For this, data from the experiments FIFE, KUREX, TARTEX, SADE, etc., are also used. Empirical formulas are presented to refine the results of direct measurements and calculations of surface fluxes over natural (inhomogeneous) land surfaces from profile and standard (using bulk parametrizations) data. These formulas can also be used to determine surface fluxes over inhomogeneous underlying land surfaces in order to take into account so-called subgrid-scale effects in constructing prediction models.