Atmospheric circulation epochs and climate changes

The atmospheric circulation studies allow climate changes to be diagnosed and forecasted. Variations in occurrence frequencies of the atmospheric circulation forms W, E, and C (by the Vangengeim classification) and Z, M ₁, and M ₂ (by the Girs classification), which characterize climatic conditions in most of the Northern Hemisphere, are analyzed over a period of more than 100 years. It is shown that the occurrence frequency of the forms W, C, and M ₁ continually decreased, while that of the forms E and Z increased, which indicates a significant change in atmospheric circulation in the Northern Hemisphere during the last century. The occurrence frequency of the forms C and Z demonstrates specific features at inter-decade time scales. Correlations are found between accumulated sums of anomalies of occurrence frequencies of the atmospheric circulation forms C, (W + E), Z, and (M ₁ + M ₂) and inter-decade variations of the Earth’s rotation. The causes of these relationships are discussed along with possibilities of their use for diagnosis of climatic variations in the Northern Hemisphere.     

Field Experiments and Numerical Modeling of Wind Speed and Surface Waves in Medium-size Inland Reservoirs

An attempt is made to apply the modern methods of surface wave simulation developed for oceanic conditions to the modeling of waves in medium-size inland reservoirs (10–100 km). The results of field measurements of wind speed and waves are described, and on their basis the parameterization C _D (U ₁₀) is proposed. WAVEWATCH III spectral wave model was adapted to the conditions of a medium-size inl and reservoir. The simulated data are compared with the field data. The use of the new parameterization C _D (U ₁₀) allowed reducing the values of the wind wave growth rate that improved consistency in data from the field experiment and numerical modeling concerning the height of significant waves. Further steps towards improving the quality of prediction of the adapted WAVEWATCH III model are discussed.     

A compact form for the analytic description of temperature dependence of saturation vapor pressure over plane surfaces of water and ice

A possibility is studied of extending the range of action of the simple three-parameter formula (ITS-90 scale) proposed in the previous work of the author [2] for the dependence of saturation vapor pressure E on temperature T within the range of 250 to 490 K. The results demonstrated that the dependence ln[E(T)/E(T _bas)] = (T - T _bas)[A - B(T - T _bas) + C(T - T _bas)²]/T with four sets of coefficients A, B, and C obtained using one base temperature Tbas equal to the temperature of triple point of water T _t = 273.16 K and two additional base values T _bas2 = 473.16 K and T _bas3 = 623.16 K makes it possible to approximate rather accurately the initial experimental and computed data in the temperature range from the point of homogeneous freezing of 235 K to the critical temperature of 647 K for liquid water and from 193 K to T _t for ice. A procedure used for obtaining the inverse function T(E) by solving the third-degree algebraic equation is validated. A hypothesis is proposed for the physical substantiation of additional base points in the form of “a noticeable appearance of dimers at the point T _bas2 and their 100% concentration at the temperature T _bas3.”     

Formulation of stability-dependent empirical relations for turbulent intensities from surface layer turbulence measurements for dispersion parameterization in a lagrangian particle dispersion model

Season- and stability-dependent turbulence intensity (σ _u /u _*, σ _v /u _*, σ _w /u _*) relationships are derived from experimental turbulence measurements following surface layer scaling and local stability at the tropical coastal site Kalpakkam, India for atmospheric dispersion parameterization. Turbulence wind components (u′, v′, w′) measured with fast response UltraSonic Anemometers during an intense observation campaign for wind field modeling called Round Robin Exercise are used to formulate the flux–profile relationships using surface layer similarity theory and Fast Fourier Transform technique. The new relationships (modified Hanna scheme) are incorporated in a Lagrangian Particle Dispersion model FLEXPART-WRF and tested by conducting simulations for a field tracer dispersion experiment at Kalpakkam. Plume dispersion analysis of a ground level hypothetical release indicated that the new turbulent intensity formulations provide slightly higher diffusivity across the plume relative to the original Hanna scheme. The new formulations for σ _u , σ _v , σ _w are found to give better agreement with observed turbulent intensities during both stable and unstable conditions under various seasonal meteorological conditions. The simulated concentrations using the two methods are compared with those obtained from a classical Gaussian model and the observed SF₆ concentration. It has been found that the new relationships provide comparatively higher diffusion across the plume relative to the model default Hanna scheme and provide downwind concentration results in better agreement with observations.     

‘Application of a New Spectral Theory of Stably Stratified Turbulence to the Atmospheric Boundary Layer over Sea Ice’

A new spectral closure model of stably stratified turbulence is used to develop a K–ε model suitable for applications to the atmospheric boundary layer. This K–ε model utilizes vertical viscosity and diffusivity obtained from the spectral theory. In the ε equation, the Coriolis parameter-dependent formulation of the coefficient C ₁ suggested by Detering and Etling is generalized to include the dependence on the Brunt-Väisälä frequency, N. The new K–ε model is tested in simulations of the ABL over sea ice and compared with observations from BASE as simulated in large-eddy simulations by Kosovic and Curry, and observations from SHEBA.     

Parameterization of sheared entrainment in a well-developed CBL. Part I: Evaluation of the scheme through large-eddy simulations

The entrainment flux ratio A _e and the inversion layer (IL) thickness are two key parameters in a mixed layer model. A _e is defined as the ratio of the entrainment heat flux at the mixed layer top to the surface heat flux. The IL is the layer between the mixed layer and the free atmosphere. In this study, a parameterization of A _e is derived from the TKE budget in the firstorder model for a well-developed CBL under the condition of linearly sheared geostrophic velocity with a zero value at the surface. It is also appropriate for a CBL under the condition of geostrophic velocity remaining constant with height. LESs are conducted under the above two conditions to determine the coefficients in the parameterization scheme. Results suggest that about 43% of the shear-produced TKE in the IL is available for entrainment, while the shear-produced TKE in the mixed layer and surface layer have little effect on entrainment. Based on this scheme, a new scale of convective turbulence velocity is proposed and applied to parameterize the IL thickness. The LES outputs for the CBLs under the condition of linearly sheared geostrophic velocity with a non-zero surface value are used to verify the performance of the parameterization scheme. It is found that the parameterized A _e and IL thickness agree well with the LES outputs.     

Uncertainty of global summer precipitation in the CMIP5 models: a comparison between high-resolution and low-resolution models

Worldwide, the majority of rapidly growing neighborhoods are found in the Global South. They often exhibit different building construction and development patterns than the Global North, and urban climate research in many such neighborhoods has to date been sparse. This study presents local-scale observations of net radiation (Q _* ) and sensible heat flux (Q _H ) from a lightweight low-rise neighborhood in the desert climate of Andacollo, Chile, and compares observations with results from a process-based urban energy-balance model (TUF3D) and a local-scale empirical model (LUMPS) for a 14-day period in autumn 2009. This is a unique neighborhood-climate combination in the urban energy-balance literature, and results show good agreement between observations and models for Q _* and Q _H . The unmeasured latent heat flux (Q _E ) is modeled with an updated version of TUF3D and two versions of LUMPS (a forward and inverse application). Both LUMPS implementations predict slightly higher Q _E than TUF3D, which may indicate a bias in LUMPS parameters towards mid-latitude, non-desert climates. Overall, the energy balance is dominated by sensible and storage heat fluxes with mean daytime Bowen ratios of 2.57 (observed Q _H /LUMPS Q _E )–3.46 (TUF3D). Storage heat flux (ΔQ _S ) is modeled with TUF3D, the empirical objective hysteresis model (OHM), and the inverse LUMPS implementation. Agreement between models is generally good; the OHM-predicted diurnal cycle deviates somewhat relative to the other two models, likely because OHM coefficients are not specified for the roof and wall construction materials found in this neighborhood. New facet-scale and local-scale OHM coefficients are developed based on modeled ΔQ _S and observed Q _* . Coefficients in the empirical models OHM and LUMPS are derived from observations in primarily non-desert climates in European/North American neighborhoods and must be updated as measurements in lightweight low-rise (and other) neighborhoods in various climates become available.     

Analysis of photosynthetically active radiation and applied parameterization model for estimating of PAR in the North China Plain

As photosynthetically active radiation (PAR) variability and PAR estimating methods play an important role in climate change and ecological process research, PAR variation trends and broadband global solar radiation (R _s ) ratios (PAR/R _s ) in the North China Plain (NCP) are examined using in situ PAR and R _s observed data for 2005 to 2011. The annual average PAR value found in the NCP is 22.9 mol m^?2 d^?1. The highest and lowest values were recorded at Changwu and Luancheng sites, respectively. The highest PAR/R _s value was found in Jiaozhouwan due to large water vapor volumes present in this area. PAR/R _s levels have increased in the NCP due to a decrease in fine aerosols and increase in water vapor concentration. From these analysis results, a parameterization model that can be applied to all sky conditions was checked. Empirical estimation model comparisons for obtaining PAR values indicate that model was least accurate when R _s was used independently. When the model included R _s, the clearness index (K _s) and the solar zenith angle, the model estimated PAR values with acceptable accuracy. A parameterization model was constructed by considering K _s and attenuation factors of PAR under clear weather conditions (ρ _clear). The improved parameterization model more accurately predicts values for local sites and for various observation sites.     

Relationship Between Fine-Particle Pollution and the Urban Heat Island in Beijing,China: Observational Evidence

Urbanization has led to a significant urban heat island (UHI) effect in Beijing in recent years. At the same time, air pollution caused by a large number of fine particles significantly influences the atmospheric environment, urban climate, and human health. The distribution of fine particulate matter (PM_2.5) concentration and its relationship with the UHI effect in the Beijing area are analyzed based on station-observed hourly data from 2012 to 2016. We conclude that, (1) in the last five years, the surface concentrations of PM_2.5 averaged for urban and rural sites in and around Beijing are 63.2 and 40.7 µg m^?3, respectively, with significant differences between urban and rural sites (ΔPM_2.5) at the seasonal, monthly and daily scales observed; (2) there is a large correlation between ΔPM_2.5 and the UHI intensity defined as the differences in the mean (ΔT_ave), minimum (ΔT_min), and maximum (ΔT_max) temperatures between urban and rural sites. The correlation between ΔPM_2.5 and ΔT_min (ΔT_max) is the highest (lowest); (3) a Granger causality analysis further shows that ΔPM_2.5 and ΔT_min are most correlated for a lag of 1–2 days, while the correlation between ΔPM_2.5 and ΔT_ave is lower; there is no causal relationship between ΔPM_2.5 and ΔT_max; (4) a case analysis shows that downwards shortwave radiation at the surface decreases with an increase in PM_2.5 concentration, leading to a weaker UHI intensity during the daytime. During the night, the outgoing longwave radiation from the surface decreases due to the presence of daytime pollutants, the net effect of which is a slower cooling rate during the night in cities than in the suburbs, leading to a larger ΔT_min.     

Effect of solubility limitation on hygroscopic growth and cloud drop activation of SOA particles produced from traffic exhausts

Hygroscopicity measurements of secondary organic aerosol (SOA) particles often show inconsistent results between the supersaturated and subsaturated regimes, with higher activity as cloud condensation nucleus (CCN) than indicated by hygroscopic growth. In this study, we have investigated the discrepancy between the two regimes in the Lund University (LU) smog chamber. Various anthropogenic SOA were produced from mixtures of different precursors: anthropogenic light aromatic precursors (toluene and m-xylene), exhaust from a diesel passenger vehicle spiked with the light aromatic precursors, and exhaust from two different gasoline-powered passenger vehicles. Three types of seed particles were used: soot aggregates from a diesel vehicle, soot aggregates from a flame soot generator and ammonium sulphate (AS) particles. The hygroscopicity of seed particles with condensed, photochemically produced, anthropogenic SOA was investigated with respect to critical supersaturation (s_c) and hygroscopic growth factor (gf) at 90% relative humidity. The hygroscopicity parameter κ was calculated for the two regimes: κ_sc and κ_gf, from measurements of s_c and gf, respectively. The two κ showed significant discrepancies, with a κ_gf /κ_sc ratio closest to one for the gasoline experiments with ammonium sulphate seed and lower for the soot seed experiments. Empirical observations of s_c and gf were compared to theoretical predictions, using modified Köhler theory where water solubility limitations were taken into account. The results indicate that the inconsistency between measurements in the subsaturated and supersaturated regimes may be explained by part of the organic material in the particles produced from anthropogenic precursors having a limited solubility in water.     

Comprehensive modeling of monthly mean soil temperature using multivariate adaptive regression splines and support vector machine

Soil temperature (T _s) and its thermal regime are the most important factors in plant growth, biological activities, and water movement in soil. Due to scarcity of the T _s data, estimation of soil temperature is an important issue in different fields of sciences. The main objective of the present study is to investigate the accuracy of multivariate adaptive regression splines (MARS) and support vector machine (SVM) methods for estimating the T _s. For this aim, the monthly mean data of the T _s (at depths of 5, 10, 50, and 100 cm) and meteorological parameters of 30 synoptic stations in Iran were utilized. To develop the MARS and SVM models, various combinations of minimum, maximum, and mean air temperatures (T _min, T _max, T); actual and maximum possible sunshine duration; sunshine duration ratio (n, N, n/N); actual, net, and extraterrestrial solar radiation data (R _s, R _n, R _a); precipitation (P); relative humidity (RH); wind speed at 2 m height (u ₂); and water vapor pressure (V_p) were used as input variables. Three error statistics including root-mean-square-error (RMSE), mean absolute error (MAE), and determination coefficient (R ²) were used to check the performance of MARS and SVM models. The results indicated that the MARS was superior to the SVM at different depths. In the test and validation phases, the most accurate estimations for the MARS were obtained at the depth of 10 cm for T _max, T _min, T inputs (RMSE = 0.71 °C, MAE = 0.54 °C, and R ² = 0.995) and for RH, V _p, P, and u ₂ inputs (RMSE = 0.80 °C, MAE = 0.61 °C, and R ² = 0.996), respectively.     

Characteristics of the precipitation recycling ratio and its relationship with regional precipitation in China

A dynamic recycling model (DRM) with an analytical moisture trajectory tracking method, together with Japan Meteorological Agency 25-year reanalysis data, is used to study the regional precipitation recycling process across China, by calculating the regional recycling ratio (ρ _r ) at the daily time scale during 1979–2010. The distribution of ρ _r shows that, in western China, especially the Tibetan Plateau and its surrounding areas, precipitation is strongly dependent on the recycling process associated with regional evaporation. In Southeast China, however, the contribution from the recycling processes is much smaller due to the influence of the summer monsoon. A precipitation threshold value of about 4 mm/day is obtained from detailed analysis of both extreme and all-range ρ _r years. According to this threshold, China is classified into three types of sub-regions: low-precipitation sub-regions (mainly in the northwest), high-precipitation sub-regions (mainly in the south), and medium-precipitation sub-regions (mainly in the northeast). It is found that ρ _r correlates positively with precipitation, as well as convective precipitation (P _CP) and large-scale precipitation (P _LP) in the low-precipitation sub-regions. However, negative ρ _r ?～?P _LP correlations are found in the high-precipitation sub-regions and nonsignificant correlations exist in the medium-precipitation sub-regions. As P _CP is mainly locally generated due to mid-latitude mesoscale systems and the cumulus parameterization used in producing the reanalysis, the recycling ratio positively correlates to the ratio P _CP/P _LP in almost all sub-regions, particularly in the Tibetan Plateau and its surrounding areas. The correlation between radiation flux and ρ _r suggests more net radiation supports more evaporation and higher ρ _r , especially in the high-precipitation sub-regions. The influence of clouds on shortwave radiation is crucial, since evaporation is suppressed when the amount of cloudiness increases, especially in the high-precipitation sub-regions. Together with the consideration of soil moisture, it can be inferred that limited soil moisture inhibits evaporation in the low-precipitation sub-regions, while the energy or radiation is the dominant factor controlling evaporation in the high-precipitation sub-regions.     

Effect of urbanization on the urban meteorology and air pollution in Hangzhou

Urbanization has a substantial effect on urban meteorology. It can alter the atmospheric diffusion capability in urban areas and therefore affect pollutant concentrations. To study the effects of Hangzhou’s urban development in most recent decade on its urban meteorological characteristics and pollutant diffusion, 90 weather cases were simulated, covering 9 weather types, with the Nanjing University City Air Quality Prediction System and high-resolution surface-type data and urban construction data for 2000 and 2010. The results show that the most recent decade of urban development in Hangzhou substantially affected its urban meteorology. Specifically, the average urban wind speed decreased by 1.1 m s ^?1; the average intensity of the heat island increased by 0.5°C; and the average urban relative humidity decreased by 9.7%. Based on one case for each of the nine weather types, the impact of urbanization on air pollution diffusion was investigated, revealing that the changes in the meteorological environment decreased the urban atmosphere’s diffusion capability, and therefore increased urban pollutant concentrations. For instance, the urban nitrogen oxides concentration increased by 2.1 μg m ^?3 on average; the fine particulate matter (diameter of 2.5 μm or less; PM_2.5) pollution concentration increased by 2.3 μg m ^?3 on average; in highly urbanized areas, the PM_2.5 concentration increased by 30 μg m ^?3 and average visibility decreased by 0.2 km, with a maximum decrease of 1 km; the average number of daily hours of haze increased by 0.46 h; and the haze height lifted by 100–300 m. The “self-cleaning time” of pollutants increased by an average of 1.5 h.     

Long-term variation of rainfall erosivity in Calabria (Southern Italy)

The changes in rainfall erosivity have been investigated using the rainfall erosivity factor (R) proposed for USLE by Wischmeier and Smith (R _W-S ) and some simplified indexes (the Fournier index modified by Arnoldus, F, a regional index spatial independent, R _Fr , and a regional index spatial dependent, R _Fs ) estimated by indirect approaches. The analysis has been carried out over 48 rainfall stations located in Calabria (Southern Italy) using data collected in the period 1936–2012 and divided in three sub-periods. The series of the erosivity indexes and of some precipitation variables have been analyzed for evidence of trends using standard methods. The simplified indexes suggested a general underestimation of the rainfall erosivity with respect to R _W-S . The mean underestimation ranged between 23 and 54 % for R _Fr and from 10 to 15 % for R _Fs . Both the sign and the magnitude of the trends were different for the different stations depending on the variable and sub-period considered. In general, the erosivity increased during the period 1936–1955 (1^st sub-period) and during the more recent sub-period (1992–2012, 3^rd sub-period), whereas it decreased during 1958–1977 (2^nd sub-period). The evidence of trends was generally higher for R _W-S than for R _Fr and R _Fs . Focusing on the most recent sub-period (3^rd sub-period), all the variables analyzed showed mainly increasing trends but with different magnitude. More particularly, R _W-S showed a mean increment of 29 %; F, R _Fr and R _Fs increased by 11, 15 and 18 %, respectively; the maximum intensity of 0.5-h precipitation increased by 5 %; and the annual precipitation increased by 22 %. Consequently, it remains difficult to define which precipitation variable plays the dominant role in the temporal variation of rainfall erosivity in the region. However, the overall results suggest that the indexes estimated by indirect procedures (F, R _Fr , and R _Fs ) should be used with caution for climate change analysis, despite they are used for practical purposes considering they are based on easily available information.     

Multivariate drought frequency estimation using copula method in Southwest China

This study reveals the impacts of climatic variable trends on drought severity in Xinjiang, China. Four drought indices, including the self-calibrating Palmer drought severity index (sc-PDSI), Erinç’s index (I _m), Sahin’s index (I _sh), and UNEP aridity index (AI), were used to compare drought severity. The ensemble empirical mode decomposition and the modified Mann-Kendall trend test were applied to analyze the nonlinear components and trends of the climatic variable and drought indices. Four and six climatic scenarios were generated in sc-PDSI, I _m, I _sh, and AI with different combinations of the observed and detrended climatic variables, respectively. In Xinjiang, generally increasing trends in minimal, average, and maximal air temperature (T _min, T _ave, T _max) and precipitation (P) were found, whereas a decreasing trend in wind speed at 2 m height (U ₂) was observed. There were significantly increasing trends in all of the four studied drought indices. Drought relief was more obvious in northern Xinjiang than in southern Xinjiang. The strong influences of increased P on drought relief and the weak influences of increased T _min, T _ave, and T _max on drought aggravation were shown by comparing four drought indices under different climate scenarios. Decreased U ₂ had a weak influence on drought, as shown by the AI in different climate scenarios. The weak influences of T and U ₂ were considered to be masked by the strong influences of P on droughts. Droughts were expected to be more severe if P did not increase, but were likely milder without an increase in air temperature and with a decrease in U ₂.     

Sources of Biological Aerosols in Winter Precipitation in the South of Western Siberia

The results of studying biological aerosols (pollen spectra) in precipitation registered in the south of Western Siberia in the winter of 2014/15 are presented. Pollen grains of birch (Betula sp.), willow (Salix sp.), pine (Pinus sp.), and poplar (Populus sp.) were identified in the three of 28 analyzed precipitation samples. The comprehensive analysis of synoptic conditions during precipitation, back trajectories of air masses calculated with the HYSPLIT model as well as the analysis of the Northern Hemisphere snow cover dynamics and the area of distribution of the identified taxa were carried out. The results allowed determining the Euro-Scandinavian region as the main source of pollen grains inflow with precipitation to the south of Western Siberia in March 2015.     

Estimation of changes in energy consumption for heat supply due to interannual temperature variability in the south of the Ukraine

The influence of low-frequency variability of average over the heating season air temperature on population demands in heat supply is considered. Based on monthly mean temperature values for the period from 1882 to 1999, standard deviations σ _e in distributions of energy consumption probability for heating in relative units were estimated; frequency of realization of different values of energy consumption for standard intervals was calculated. It is shown that values of σ _e = 9.5% are characteristic of the Ukrainian south. In the last ten-year periods, the required energy consumption for energy supply more than once exceeded the mean values by more than 2σ _e . A conclusion is made that designed power-generating units of the HPP (heat and power plant) and required fuel reserves for the region should be calculated based on the possible load that is 20% above average demands in fuel.     

Improving Representation of Tropical Cloud Overlap in GCMs Based on Cloud-Resolving Model Data

The decorrelation length (L_cf) has been widely used to describe the behavior of vertical overlap of clouds in general circulation models (GCMs); however, it has been a challenge to associate L_cf with the large-scale meteorological conditions during cloud evolution. This study explored the relationship between L_cf and the strength of atmospheric convection in the tropics based on output from a global cloud-resolving model. L_cf tends to increase with vertical velocity in the mid-troposphere (w₅₀₀) at locations of ascent, but shows little or no dependency on w₅₀₀ at locations of descent. A representation of L_cf as a function of vertical velocity is obtained, with a linear regression in ascending regions and a constant value in descending regions. This simple and dynamic-related representation of L_cf leads to a significant improvement in simulation of both cloud cover and radiation fields compared with traditional overlap treatments. This work presents a physically justifiable approach to depicting cloud overlap in the tropics in GCMs.     

Statistical modelling of the main features of the <Emphasis Type="Italic">Artemisia</Emphasis> pollen season in Wrocław,Poland, during the 2002–2011 time period

The aim of this article is to present statistical forecasting models concerning the dynamics of Artemisia pollen seasons in Wroc?aw, including the start and end, the date of maximum pollen concentration and seasonal pollen index (SPI). For statistical evaluation, use was made of aerobiological and meteorological data from the last 10 years (2002–2011). Based on this data, agroclimatic indicators, i.e. crop heat units (CHUs), were determined for various averaging periods. The beginning of the Artemisia pollen season in the studied time period, on average, took place on 23 June. Its length usually varied between 26 and 45 days, and maximum daily concentrations occurred between 31 July and 18 August. It was found that the beginning of the pollen season depends, above all, on the values of CHUs and photothermal unit (PTU) (p?<?0.05) in the period from March to June, for various thermal thresholds. The date of maximum daily concentration correlates with sunshine duration, PTU and air temperature for June and July (p?<?0.05). On the other hand, SPI is connected with thermal variables, i.e. average, maximum and minimum air temperatures and CHUs and heliothermal unit (HTU) for July (p?<?0.05) and the beginning of spring. Based on the correlation analysis and the chosen variables, regression models for the beginning date of Artemisia pollen season and SPI were prepared, which were then verified by using leave-one-out cross-validation. A better fit between modelled and actual values was found for the analysis concerning the season start date than for the SPI.     

Effect of temperature on the methyl chloride production rate in a marine phytoplankton, <Emphasis Type="Italic">Phaeodactylum tricornutum</Emphasis>

Methyl halides such as methyl chloride (CH₃Cl) are known to be important carriers of halogen from the ocean to the atmosphere, and the halogens they release into the stratosphere by photolysis catalyze ozone depletion. Marine phytoplankton have been reported as a source of CH₃Cl, but the effects of environmental temperature on the CH₃Cl production by phytoplankton have not been investigated. In this study, we investigated the effects of temperature on the production of CH₃Cl in the culture of a marine diatom, Phaeodactylum tricornutum CCMP 630, incubated at 10, 15, 20, 25, and 30 °C. CH₃Cl concentrations in cultured samples were determined using purge and trap gas chromatograph–mass spectrometry. Phytoplankton growth was monitored by measuring the chlorophyll a concentrations. CH₃Cl production was observed for several weeks at four different temperatures ranging from 10 to 25 °C. The CH₃Cl production from P. tricornutum was increased with increasing temperature from 10 to 25 °C, and the maximum production rate for CH₃Cl was 0.21~0.26 μmol (g chlorophyll a)^?1 d^?1 at 25 °C, which was several times higher than that at 10 °C (~0.03 μmol (g chlorophyll a)^?1 d^?1). The Arrhenius equation was successfully used to characterize the effects of temperature on the production rates of CH₃Cl in the culture of P. tricornutum. Our results suggest that water temperature directly affects CH₃Cl production derived from P. tricornutum and that water temperature would be a significant factor for estimating the emissions of CH₃Cl from marine environments.