内蒙古孟恩陶勒盖岩体的成岩时代——LA-ICP-MS锆石U-Pb同位素年代学

孟恩陶勒盖岩体侵位于兴蒙造山带晚古生代浅变质岩系内,根据岩石类型划分为中细粒英云闪长岩、花岗闪长岩和二长花岗岩3个填图单位,具有典型S型花岗岩的矿物组成和岩石化学特征.花岗闪长岩和二长花岗岩LA-ICP-MS锆石U-Pb同位素年龄测定结果分别为234±1 Ma和230±1 Ma,时代为中三叠世,代表孟恩陶勒盖岩体的侵位时代.     

柴达木盆地北缘西端冷湖花岗岩

冷湖花岗岩体由花岗闪长岩和二长花岗岩组成，岩体中发育较多的辉绿岩墙和花岗闪长斑岩岩墙。岩石的常量、稀土、微量元素地球化学研究表明花岗岩类和脉岩类为同源岩浆分异演化而成，Rb-Sr、Sm-Nd同位素特征反映其源岩来自地幔。地球化学判别图解得出，冷湖花岗岩类属I型花岗岩，早期的花岗闪长岩形成于岛弧环境，与柴达木板块、南祁连板块的碰撞有关；晚期的二长花岗岩形成于板块碰撞隆起环境，与阿尔金大型走滑断裂的活动有关。     

北山北亚带干河梁岩体地质特征

干河梁岩体是中酸性复式岩体,不同岩石类型之间接触关系清楚,由早到晚其侵位顺序为石英闪长岩→英云闪长岩→花岗闪长岩→斑状二长花岗岩→黑云二长花岗岩→钾长花岗岩。岩石地球化学资料表明,该岩体与碰撞后型花岗岩相似。依据同位素测年结果,确定其侵位时代为晚古生代晚期。     

北秦岭商南花岗岩体地质特征及其成因类型

商南花岗岩体位于北秦岭造山带商丹断裂北侧，主体侵位于古元古代秦岭岩群变质杂岩中，属于新元古代花岗岩类，已获单颗粒锆石蒸发Ｐｈ－Ｐｈ年龄８８９±２２Ｍａ．岩石类型包括：英云间长岩、花岗闪长岩、黑云母二长花岗岩、二长花岗岩，以花岗间长岩为主体．岩石学、岩石地球化学特征研究表明，商南岩体的主要岩石类型存在着明显的岩石成分演化关系，并具有Ｉ型和Ｓ型花岗岩的双重特征，以Ｉ型为主，属于Ｃａｓｔｒｏ等的Ｈ型花岗岩，成岩物质来源于壳幔混合源．     

柴达木盆地北缘西端冷湖花岗岩

冷湖花岗岩体由花岗闪长岩和二长花岗岩组成，岩体中发育较多的辉绿岩墙和花岗闪长斑岩岩墙。岩石的常量、稀土、微量元素地球化学研究表明：花岗岩类和脉岩类为同源岩浆分异演化而成，Rb-Sr、Sm-Nd同位素特征反映其源岩来自地幔。地球化学判别图解得出，冷湖花岗岩类属Ⅰ型花岗岩，早期的花岗闪长岩形成于岛弧环境，与柴达木板块、南祁连板块的碰撞有关；晚期的二长花岗岩形成于板块碰撞隆起环境，与阿尔金大型走滑断裂的活动有关。     

大兴安岭东北部哈拉巴奇花岗岩体锆石U-Pb年龄及其成因

哈拉巴奇岩体主要由二长花岗岩钾长花岗岩和花岗闪长岩组成。样品的LAICPMS锆石UPb年龄测定和主量及微量元素的分析结果表明,哈拉巴奇岩体为两次侵位的早古生代花岗岩体,其中二长花岗岩钾长花岗岩的侵位时间较早(500Ma),花岗闪长岩的侵位时间相对较晚(461Ma);岩体具有后造山花岗岩类的岩石组合特征和地球化学特征,为额尔古纳地块与兴安地块碰撞拼贴作用结束后的后造山阶段的产物;二长花岗岩钾长花岗岩和花岗闪长岩起源于相同的岩浆源区,其源区物质可能是中元古代期间地幔中新增生的地壳物质,二者地球化学特征的差别是源岩部份熔融程度不同所致。     

大别山造山带东南部天柱山花岗岩类侵入体的特征及其LA-ICP-MS锆石U-Pb年龄

大别山造山带内广泛发育晚中生代的花岗岩类侵入体,天柱山岩体是其中的一个典型代表,位于分隔南大别超高压变质带与北大别杂岩之间的五河-水吼断裂带附近.该岩体是个由多期次侵位构成的复式岩体,自早到晚依次为闪长岩→石英正长岩/花岗闪长岩→碱长花岗岩.整个杂岩体属高钾钙碱性系列,但碱长花岗岩的地球化学性质与构成杂岩体的其他类型岩...     

内蒙古苏尼特左旗北达布锡勒图岩体主微量元素地球化学特征及成因探讨

达布锡勒图岩体位于华北板块与西伯利亚板块兴蒙造山带中的二连-贺根山缝合线北侧附近.通过对岩体各类岩性样品进行稀土和微量元素含量分析,结果显示,花岗闪长岩类(包括黑云花岗闪长岩和花岗闪长岩)成因类型为I-S过渡型花岗岩,成岩岩浆可能为大洋俯冲板片和上覆陆壳变杂砂岩部分融熔的混合岩浆,花岗岩类(包括二长花岗岩、黑云花岗岩和钾长花岗岩)为S-型花岗岩,原岩为变质泥岩,均产出于大陆弧构造环境,非埃达克质岩石.     

中国不同岩石类型花岗岩类元素丰度及特征

依据采自全国范围内约750个有代表性的大、中型花岗岩类岩体上的768件组合样的实测分析数据,这里计算并提出了碱长花岗岩、正长花岗岩、二长花岗岩、花岗闪长岩、石英二长岩、石英二长闪长岩等中国不同岩石类型的花岗岩类岩石近七十种化学元素或成份的丰度,探讨了中国不同花岗岩类岩石的岩石化学特征和微量元素丰度的特征。     

广西佛子冲铅锌矿田成岩成矿时代研究

广西佛子冲铅锌矿田位于桂东南博白-岑溪多金属成矿带的NE端,区内发育燕山期花岗岩、花岗闪长岩、二长花岗斑岩和英安质凝灰熔岩等;其中花岗闪长岩和二长花岗斑岩与铅锌成矿关系密切,成矿岩体形成时代分别为156Ma和127Ma。     

Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA

Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N₂ in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.     

山西五台山区滹沱群变质玄武岩岩石学、地球化学特征及其成因意义

在野外地质调查的基础上,选取滹沱群豆村亚群底部四集庄组玄武岩、顶部青石村组玄武岩和东冶亚群中下部河边村组玄武岩,进行岩石学和地球化学研究。分析结果表明：玄武岩主量元素高TiO2、TFeO,低MgO,具有演化的基性岩浆的特征。稀土元素含量相对较高,具有弱—中等程度的轻稀土元素富集,中等程度的轻重稀土元素分异,轻微的Eu异常;玄武岩中Cr、Ni含量变化较大,但与Mg#具有很好的正相关性。微量元素配分图解中具有明显的Sr负异常,部分样品具有Nb、Ta和Ti负异常,无Zr、Hf负异常,与岛弧火山岩不同;同时Nb、Ta无分异,Zr/Hf值较高,具有板内玄武岩浆的特征。综合分析认为,滹沱群玄武岩可能形成于板内裂谷环境。在岩浆上升过程中发生橄榄石与尖晶石的分离结晶作用,同时不同程度地受到地壳的混染。     

贵州岑巩羊桥罗家塘杷榔动物群的发现及其后生动物早期演化的意义

岑巩县羊桥乡罗家塘杷榔组仅出露中-上部地层,岩性单一,均为青灰、灰绿色粉砂质泥、页岩.在其上部层位发现了俞氏贵州始海百合(Guizhoueocrinus yui Zhao,Parsley et Peng,2007),计有棘皮动物始海百合、腕足动物、软体动物-软舌螺、节肢动物-三叶虫等8属9种,包括了2个未定名的新种和1...     

深港西部通道填海区地下水铜、钒、铊、镉、钨迁移的实验研究

填海工程使滨海地区的地下水物理化学条件改变,导致该区域地下水中重金属浓度升高。本文以深港西部通道填海区为例,采用实验室模拟填海条件的办法,初步探讨了影响填海区地下水重金属迁移的关键因素。模拟实验结果表明,填海区地下水中钨元素含量升高与地下水淡化、淤泥氧化过程以及填料风化有关;铜元素含量升高则与淤泥氧化过程以及填料风化有关;钒元素含量升高与地下水淡化和淤泥氧化过程有关,而其他元素含量升高则主要与填料风化释放有关。     

扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究

马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。     

Geology, mineralogy, and PGE mineralization of the copper-nickel occurrences of the Kvinum ore field, Sredinny Range, Kamchatka

The geology and mineralogy of host metamorphic rocks, the mineralogy of sulfide ores, and the distribution of PGE mineralization were studied in detail for the Kvinum-1 and Kvinum-2 copper-nickel occurrences of the Kvinum ore field, which are the most promising targets for the copper-nickel-PGE mineralization of the Sredinny Range of Kamchatka. It was established that stringer-disseminated and massive copper-nickel ores are localized in amphibole peridotites, cortlandites, and form ore bodies varying from tens of centimeters to 5–20 m thick among the layered cortlandite-gabbroid massifs. The massive sulfide ores were found only at the bottom of cortlandite bodies and upsection grade into stringer-disseminated and disseminated ores. Pyrrhotite, chalcopyrite, and pentlandite are the major ore minerals with a sharply subordinate amount of pyrite, sphalerite, galena, arsenopyrite, and löllingite. Besides pentlandite, the Ni-bearing minerals include sulforasenides (gersdorffite), arsenides (nickeline), and tellurides (melonite) of nickel. It was found that PGE mineralization represented by antimonides (sudburyite) and tellurobismuthides (michenerite) of Pd with sharply subordinate platinum arsenide (sperrylite) is confined to the apical parts of massive sulfide zones and the transition zone to the stringer-disseminated ores. Ore intervals enriched in arsenides and tellurides of Ni, Pd, and Bi contain high-purity gold. In the central parts of the orebodies, the contents of PGE and native gold are insignificant. It is suggested that the contents of major sulfide minerals and the productivity of PGE mineralization in the cortlandites are defined by combined differentiation and sulfurization of ultramafic derivatives under the effect of fluids, which are accumulated at the crystallization front and cause layering of parental magmas with different sulfur contents. The fluid-assisted layering of mafic-ultramafic massifs resulted in the contrasting distribution of PGM in response to uneven distribution of sulfur (as well as As, Te, and Bi) during liquid immiscibility. The productivity of PGE mineralization significantly increases with increasing contents of S, As, Te, and Bi (elements to which Pt and, especially, Pd have high affinity) in fluids.     

Depth of the base of the Jackson aquifer, based on geophysical exploration, southern Jackson Hole, Wyoming, USA

 A geophysical survey was conducted to determine the depth of the base of the water-table aquifer in the southern part of Jackson Hole, Wyoming, USA. Audio-magnetotellurics (AMT) measurements at 77 sites in the study area yielded electrical-resistivity logs of the subsurface, and these were used to infer lithologic changes with depth. A 100–600 ohm-m geoelectric layer, designated the Jackson aquifer, was used to represent surficial saturated, unconsolidated deposits of Quaternary age. The median depth of the base of the Jackson aquifer is estimated to be 200 ft (61 m), based on 62 sites that had sufficient resistivity data. AMT-measured values were kriged to predict the depth to the base of the aquifer throughout the southern part of Jackson Hole. Contour maps of the kriging predictions indicate that the depth of the base of the Jackson aquifer is shallow in the central part of the study area near the East and West Gros Ventre Buttes, deeper in the west near the Teton fault system, and shallow at the southern edge of Jackson Hole. Predicted, contoured depths range from 100 ft (30 m) in the south, near the confluences of Spring Creek and Flat Creek with the Snake River, to 700 ft (210 m) in the west, near the town of Wilson, Wyoming. Received, May 1997 · Revised, February 1998 · Accepted, April 1998     

西藏南木林县秦马弄地区二长花岗岩体岩石成因

以出露在西藏南木林县秦马弄地区二长花岗岩体为研究对象,从野外地质调查、岩石学、LA-ICP-MS锆石U-Pb定年、元素和Lu-Hf同位素地球化学等方面对其进行了分析研究。结果显示：秦马弄地区二长花岗岩体类似于A型花岗岩,形成于古近纪(E1),其LA-ICP-MS锆石U-Pb年龄为(62.0±0.5)~(63.0±0.5) Ma;岩体形成的温度较高(锆石饱和温度为745~805 ℃,平均766 ℃);岩石富SiO2(72.6%~75.0%)、Na2O(2.86%~3.59%)和K2O(4.12%~5.25%),贫CaO(0.72%~1.39%)和MgO(0.26%~0.36%),高FeOT/MgO值(7.26~10.3),属高钾钙碱性系列,弱过铝质;岩石具明显的负Eu异常(Eu/Eu*=0.40~0.70),普遍表现出Ba、Sr、P、Ti元素的亏损和Rb、Th、K、Zr、Hf元素的富集。εHf(t)值为-4.7~-1.8,其两阶段地壳Hf模式年龄tDM2为(1.1~1.3) Ga。秦马弄A型花岗岩体是冈底斯基底地壳物质部分熔融的岩浆产物,形成于古近纪印度板块与欧亚板块俯冲碰撞引起的总体为岛弧背景下的局部拉张构造环境。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.