Environmental evolution of Gongwang Mountains during Holocene in northeastern Yunnan, China

This paper presents the study on two continuous glacio-lacustrine sedimentary deposits, Laotanfang (3 597 m) and Shibantang (3 689 m) located on the southern and northern sides of Hulifang peak in Yunan, China. Environmental change indexes are constructed for each deposit, based on grain size, geochemical and pollen analysis, environmental magnetic susceptibility, and 14C dating. The study of climatic environmental change since the Holocene epoch in this region shows that the climate fluctuated at different stages during the early Holocene, that is, the climate was cool and wet during 8 4-7 7 ka, cold and wet during 7 7-6 5 ka, cold and dry during 6 5-4 7 ka, cool and wet during 4 7-2 1 ka, warm and wet during 2 1-1 0 ka, and warmer and wet since 1 ka. These findings reflect the overlapping influences of the southwest and southeast monsoons in different times during the Holocene in the north part of southwestern China are in accord with other Holocene climate change models in this part of China.     

Volume expansion rates of seismic landslides and influencing factors: A case study of the 2008 Wenchuan earthquake

When a big landside occurs, source material can change into loose deposit during its runout, causing the increase of the total landslide volume to some extent. Such changes can influence the quantification of seismic landslides. The objective of this paper was to study the volume expansion rate of landslides based on the data of 1417 co-seismic landslides triggered by the 2008 Wenchuan, China Mw 7.9 earthquake. We also analyzed the correlations between this rate and landslide geometric parameters(volume, height(H), length-width ratio(L/W), length-height ratio(L/H)), and environmental factors(peak ground acceleration(PGA), lithology, slope angle and aspect). The results show that the total source volume of the 1417 landslides is 1248 million m3, while the total volume of the deposit is 1501 million m3, which means the total volume expanding rate(Et) is 20.3% with the average volume expansion rate(Ea) 22.6%. The analysis indicates that volume expansion rate generally decreases with the increasing volume and height of landslides, while becoming larger with increasing L/H and L/W. Besides, the volume expansion rate is closely related to the landslide type and the volume scale of landslides. This study analyses volume change of co-seismic landslides deeply, permitting to help the correct quantification of the source volume and deposit volume of seismic landslide and a useful reference for the correct quantification of landslide volume.     

STUDY ON THE CORROSION PEAK OF CARBON STEEL IN MARINE SPLASH ZONE

lNTRODUCTI0NSincetheoonceptofrnarinesplashzone(MSZ)wasfirstproposedbyHumble,rnanyresearchesprovedthatthecorrosionofsteelinthesplashzoneisthemostseriousinthemarineenvironninetandthatthisMSZcorrosionhasapeak(Zhu,l995).Howevertheenvironmentalfactorscatisingthecorrosionpeakwasnotkn0wnthen(Niat0,l975,Atsushi,l994)andtherangeoftheMSZwasnotyetdeariydefinedopzkaki,l985).ThispaperexplainsthemaincauseofthecormsionpeakanddefinestheexaCtrangeoftheMSZinsomeofChina'sharbours.MATERIALSANDMET…     

THE RELATIONSHIP BETWEEN THE ENVIRONMENTAL CHANGE OF THE ZHUJIANG RIVER DELTA IN HOLOCENE AND ITS CULTURAL ORIGINS AND PROPAGATION

（翁齐浩）ＴＨＥＲＥＬＡＴＩＯＮＳＨＩＰＢＥＴＷＥＥＮＴＨＥＥＮＶＩＲＯＮＭＥＮＴＡＬＣＨＡＮＧＥＯＦＴＨＥＺＨＵＪＩＡＮＧＲＩＶＥＲＤＥＬＴＡＩＮＨＯＬＯＣＥＮＥＡＮＤＩＴＳＣＵＬＴＵＲＡＬＯＲＩＧＩＮＳＡＮＤＰＲＯＰＡＧＡＴＩＯＮ￥ＷｅｎｇＱｉｈ...     

基于融合技术的结构性栅格时空数据平台的构建

时空数据融合是当前研究地理现象空间格局的数据存储、处理方法与有效途径。在构建国家资源环境时空数据平台过程中 ,我们设计了基于 1 km栅格单元的土地利用现状与变化数据库。这种时空数据表达方式的优点 :(1 )在保持面积信息不损失情况下明显减少了数据存储量 ,并且满足区域分析的空间尺度要求 ;(2 )便于多时间序列的数据存储与变化分析 ,以及变化专题信息提取与结果显示 ;(3)有利于区域土地利用变化环境背景与驱动力分析 ,可以实现与其他多源数据的有效融合 ;(4 )从小尺度到大尺度的空间尺度转换非常便利 ,在空间聚合的基础上能够快速实现从区域分析扩大至国家尺度、全球尺度的分析。     

Remote Detection of Varying Water Storage in Relation to Surfacial Temperature of Aral Sea

Lake monitoring by remote sensing is of significant importance to understanding the lake and ambient ecological and environmental processes. In particular, whether lake water storage variation could predict lake surfacial temperature or vice versa has long fascinated the research community, in that it would greatly benefit the monitoring missions and scientific interpretation of the lake change processes. This study attempted to remotely detect the dynamics of the Aral Sea and pursue the relationships between varying lake water storage attributes and surface water temperature by using MODIS LST(Moderate-resolution Imaging Spectroradiometer Land Surface Temperature) 8-day composite products, satellite altimeter data, and actual meteorological measurements. Their associations with lake Surface Water Temperatures(SWT) were then analyzed. Results showed the lake water surface areas and elevations of the North Aral Sea tended to increasing trend from 2001(2793.0 km~2, 13.6 m) to 2015(6997.8 km~2, 15.9 m), while those of the South Aral Sea showed a decreasing trend during 2001(20 434.6 km~2, 3.9 m) and 2015(3256.1 km~2, 0.9 m). In addition, the annual daytime and nighttime lake SWT both decreased in the North Aral Sea, while only the daytime SWT in the South Aral Sea exhibited an increase, indicating a rising deviation of diurnal temperatures in the South Aral Sea during the past 15 yr. Moreover, a lower correlation was found between variations in the daytime SWT and storage capacity in the South Aral Sea(R~2 = 0.33; P 0.05), no fair correlations were tested between lake water storage and daytime SWT in the North Aral Sea nor between lake water storage and nighttime SWT in either part of the sea. These results implied that climate change, if any at least during the research period, has no significant effects on lake dynamics over the two sectors of the Aral Sea with anthropogenic disturbances. However, climate change and human activities may overlap to explain complex consequences in the lake storage variations. Our results may provide a reference for monitoring the spatiotemporal variations of lakes, increasing understanding of the lake water storage changes in relation to the lake SWT, which may benefit the ecological management of the Aral Sea region, in the effort to face the likely threats from climate change and human activities to the region.     

ESTARFM模型在西藏色林错湖面积时空变化中的应用分析(1976-2014年)

湖泊（特别是内陆湖）作为全球气候变化的敏感区域,是气候变化与环境变异的指示器,其面积变化在一定程度上可反映区域的气候变化。因此,精确监测湖泊面积的时空变化,对分析区域生态环境变化具有重要的意义。本文基于ESTARFM时空数据融合模型,利用MODIS数据模拟了2000年后无法得到的Landsat数据;利用NDWI和MNDWI 2种水体指数并辅以DEM数据分析了1976-2014年西藏色林错湖湖面面积的时空变化;综合湖区周围6个气象站点的气象数据(1970-2014年),探究了湖面面积变化的原因及其对气候变化的响应。结果表明：(1)利用ESTARFM时空融合模型得到的Landsat-Like数据与真实的Landsat数据在水体信息提取方面具有较高的相关性,R²可达0.93,时空数据融合的结果可用于湖泊水体的信息提取;(2)近40年来（1976-2014年）,色林错湖处于持续扩张状态,面积呈较显著的增长趋势,增加了近711.652 km²,增幅为42.36%,年平均增长速率约为18.728 km²a^-1,增长最快时可达55.954 km²a^-1;湖面面积变化先后经历了平稳变化-迅速变化-平稳变化3个阶段;北部湖区在40年间变化最为明显,向北扩展了约22.812 km;2003-2005年,南部湖区已与雅根错湖连为一体,随后二者共同扩张;(3)气温的持续升高造成的冰雪融水补给增加可能是导致湖泊面积扩张的主要因素,风速的降低为次要因素,湖面的面积变化与降水量、日照时数的变化相关性不明显。     

Analyzing land-use change in farming-pastoral transitional region using autologistic model and household survey approach

Land change science （LCS） strives to understand and model land-use change, which will further advance the understanding of multiple issues in the socio-ecological systems. Based on GIS/RS techniques, autologistic model, and household survey method, this study investigated major land use changes and their causes from 1978 to 2008 in Uxin Banner （county-level）, Inner Mongolia in China and then developed an understanding of the relationships between household livelihood and land-use pattern. Results showed that cultivated land increased from 1988 to 2000, and leveled offafter 2000. Built-up land increased stably for the period 1978 2008. The change of grassland and bare land differed among the three periods. From 1978 to 1988, grassland increased by 23.3%, and bare land decreased by 20.48%. From 1988 to 2000, bare land expanded by 1.7%, but grassland declined by 1.3%. From 2000 to 2008, an increase in grassland area by 1.8% was observed, but a decrease in bare land area by 9.0% was witnessed. The autologistic models performed better than logistic models as indicated by lower Akaike Information Criterion （AIC） values. Factors associated with human activities significantly correlated with the change of cultivated land, forest land, grassland, and built-up land. The produce prices and extensive cultivated land use are major issues in the farming area. This study suggests that completing land circulation systems and maintaining the stability of price are effective solutions. By contrast, reclamation and overgrazing are major concerns in the pastoral areas. Implementing environmental policies effectively, transferring population out of rural pastoral areas, and developing modem animal husbandry are effective ways to address these issues.     

Effect of contrasting climates on antioxidant and bioactive constituents in five medicinal herbs in Western Himalayas

To understand the effect of climate change on constitutive antioxidant and biochemical metabolites in Western Himalayas, five medicinal herbs were selected and grown at two altitudes in Jammu (305 m) and Srinagar (1730 m) with subtropical and temperate climates, respectively. Significant variations were observed in phenols and flavonoids in Hypericum perforatum L., Matricaria chamomilla L., Thymus vulgaris L., Cynara cardunculus L. and Echinacea purpurea L. growing at two locations. High altitude temperate site show variable (up to 13 fold) increase in their content. Proteins (1.3 – 1.8 times), sugars (2.8 – 4.1 times) and free amino acid (1.04 – 1.22 times) were also higher at Srinagar (1730 m). Within these plants, H. perforatum and M. chamomilla have shown higher accumulation of phenols, xanthophylls and proline even at subtropical environment in Jammu (305 m) suggesting potential for increasing their geographical area. The results demonstrate that changing environmental conditions significantly affect the bioactive constituents, which accumulate as a defence strategy by these temperate plants. Their medicinal significance during climate change scenario has also been discussed.     

Effects of seasonal variation on soil microbial community structure and enzyme activity in a Masson pine forest in Southwest China

Soil microbial communities and enzyme activities play key roles in soil ecosystems. Both are sensitive to changes in environmental factors,including seasonal temperature, precipitation variations and soil properties. To understand the interactive mechanisms of seasonal changes that affect soil microbial communities and enzyme activities in a subtropical masson pine(Pinus massoniana) forest, we investigated the soil microbial community structure and enzyme activities to identify the effect of seasonal changes on the soil microbial community for two years in Jinyun Mountain National Nature Reserve, Chongqing, China. The soil microbial community structure was investigated using phospholipid fatty acids(PLFAs). The results indicated that a total of 36 different PLFAs were identified, and 16:0 was found in the highest proportions in the four seasons, moreover, the total PLFAs abundance were highest in spring and lowest in winter. Bacteria and actinomycetes were the dominant types in the study area. Seasonal changes also had a significant(P 0.05) influence on the soil enzyme activity. The maximum and minimum values of the invertase and catalase activities were observed in autumn and winter, respectively. However, the maximum and minimum values of the urease and phosphatase acid enzymatic activities were found in spring and winter, respectively. Canonical correspondence analysis(CCA) analysis revealed that the seasonal shifts in soil community composition and enzyme activities were relatively more sensitive to soil moisture and temperature, but the microbial community structure and enzyme activity were not correlated with soil pH in the study region. This study highlights how the seasonal variations affect the microbial community and function(enzyme activity)to better understand and predict microbial responses to future climate regimes in subtropical area.     

A thin cloud removal method from remote sensing image for water body identification

In this paper,a thin cloud removal method was put forward based on the linear relationships between the thin cloud reflectance in the channels from 0.4 μm to 1.0 μm and 1.38 μm.Channels of 0.66 μm,0.86 μm and 1.38 μm were chosen to extract the water body information under the thin cloud.Two study cases were selected to validate the thin cloud removal method.One case was applied with the Earth Observation System Moderate Resolution Imaging Spectroradiometer(EOS/MODIS) data,and the other with the Medium Resolution Spectral Imager(MERSI) and Visible and Infrared Radiometer(VIRR) data from Fengyun-3A(FY-3A).The test results showed that thin cloud removal method did not change the reflectivity of the ground surface under the clear sky.To the area contaminated by the thin cloud,the reflectance decreased to be closer to the reference reflectance under the clear sky after the thin cloud removal.The spatial distribution of the water body area could not be extracted before the thin cloud removal,while water information could be easily identified by using proper near infrared channel threshold after removing the thin cloud.The thin cloud removal method could improve the image quality and water body extraction precision effectively.     

全球250 m反照率产品算法及验证

反照率是反映地表能量平衡的重要参数之一,也被运用于全球变化与天气预测研究中。为了更好地获取反照率产品,学者们在不断地更新反照率产品和提出新算法。本文主要是在1 km分辨率的全球陆表特征参量（GLASS）反照率产品基础上进一步开发250 m反照率产品。算法思路是利用中分辨率成像光谱仪（MODIS）传感器的250 m分辨率波段提供纹理信息,利用成熟的GLASS 1 km反照率产品提供均值信息,进行数据融合,实现GLASS 1 km反照率产品的降尺度。相比于GLASS 1km反照率产品,250 m产品首先展现出更为丰富的空间细节信息,并且在与地面站点观测数据（北美地区站点数据）直接对比中显示出稍高的验证精度,GLASS 1 km产品的验证精度为0.0257,而250 m产品验证精度0.0235。最后,以北京市为例,基于2003—2013年的产品分析了北京市周边反照率及其变化趋势的空间分布,可以看到250 m反照率产品视觉效果更好,相比于1 km产品能够揭示反照率变化趋势的更多空间细节信息。分析表明,在北京城市化进程中,由于加大了城市绿化,主城区反照率总体呈降低趋势。     

Distribution of microbial populations and their relationship with environmental variables in the North Yellow Sea, China

In order to understand the large-scale spatial distribution characteristics of picoplankton,nanophytoplankton and virio-plankton and their relationship with environmental variables in coastal and offshore waters,flow cytometry(FCM) was used to ana-lyze microbial abundance of samples collected in summer from four depths at 36 stations in the North Yellow Sea(NYS).The data revealed spatial heterogeneity in microbial populations in the offshore and near-shore waters of the NYS during the summer.For the surface layer,picoeukaryotes were abundant in the near-shore waters,Synechococcus was abundant in the offshore areas,and bacte-rial and viral abundances were high in the near-shore waters around the Liaodong peninsula.In the near-shore waters,no significant vertical variation of picophytoplankton(0.2-2μm) abundance was found.However,the nanophytoplankton abundance was higher in the upper layers(from the surface to 10 m depth) than in the bottom layer.For the offshore waters,both pico-and nanophytoplankton(2-20μm) abundance decreased sharply with depth in the North Yellow Sea Cold Water Mass(NYSCWM).But,for the vertical dis-tribution of virus and bacteria abundance,no significant variation was observed in both near-shore and offshore waters.Autotrophic microbes were more sensitive to environmental change than heterotrophic microbes and viruses.Viruses showed a positive correla-tion with bacterial abundance,suggesting that the bacteriophage might be prominent for virioplankton(about 0.45μm) in summer in the NYS and that viral abundance might play an important role in microbial loop functions.     

STUDY ON INDEX SYSTEM OF ASSESSMENT OF PUBLIC DISASTER PERCEPTION IN THE WESTERN CHINA

The study on humanity response to global environment change is a new direction in the research of global change science, of which an important aspect is to study the adaptation strategies of human being to environ-mental changes in different regions. One reasonable and scientific adaptation strategy is based on not only scientific assessment of the impact of environmental change on society, but also correct estimation of the public perception of environmental change, whereas the research on the latter is terribly weak. This paper intends to understand the per-sonality difference in public perception of environment in the western China primarily by establishing the assessment index system of nation environmental perception and analyzing the results of questionnaire survey in some regions of Shaanxi Province. The conclusions are as follows: 1) The state of public perception of disaster is one of the founda-tions of constituting and enforcing reasonable adaptation strategy to environmental change. 2) The personality differ-ences of public perception of disaster appear as follows: female disaster perception is stronger than male.the order of disaster perception from strong to weak from the point of age characteristics is 20-30, 0-20, 40-50, 30-40, 50-60,60 year old or over in turns; the order of disaster perception from strong to weak from the point of educational char-acteristics is senior high school, college, illiterate, junior high school, primary school, in turns; the order of disaster perception from strong to weak from the point of occupation characteristics is student, farmer, teacher, worker and functionary, in turns; the order of disaster perception from strong to weak from the point of habitat characteristics is city, countryside, towns, and metrooolis in turns.     

不同格网尺度下的黄山市生境质量差异分析

生境质量格网尺度研究旨在甄别不同格网尺度生境质量评估结果差异,为范围大小不同的区域分析生境质量遴选适宜的空间尺度提供基础,以提高生境质量评估精度。本文以黄山市为例,基于地类斑块构建综合模型对2017年生境质量进行评估,并以30 m为基础尺度,通过尺度转换获得多个格网尺度综合生境质量值,采用弹性系数、空间自相关等方法定量分析格网尺度不同所导致的生境质量评估结果差异。研究结果表明：① 2017年黄山市本底生境质量值为2.02×10¹⁰元,平均值为21 126.1元/hm²,经过修正后的综合生境质量总值为1.84×10¹⁰元,平均值为18 627元/hm²; 随着格网边长增长,黄山市综合生境质量总值呈曲折式减少;② 土地利用分类的格网尺度效应显示,变化尺度为基础研究尺度的奇数倍时生境质量评估结果更精准;高程为0~200 m、200~400 m的区间带格网尺度效应较为明显;③ 以2个相邻的尺度计算生境质量变化弹性系数时,边长由150 m变为180 m、270 m变为300 m及900 m以上的相邻尺度值较高;以基础尺度为参照时,生境质量弹性系数随格网边长的增长呈幂函数式下降,格网边长由30 m变为60 m,生境质量变化最为敏感,由30 m变为210 m时,生境质量变化相对不敏感;④ 黄山市生境质量空间分布呈现显著正自相关,随着尺度格网边长增长,Moran's I指数呈波浪式减小,正态分布Z值呈幂函数式减小。     

Labile and stabile soil organic carbon fractions in surface horizons of mountain soils–relationships with vegetation and altitude

Global and local climate changes could disturb carbon sequestration and carbon stocks in forest soils. Thus, it is important to characterize the stability of soil organic matter and the dynamics of soil organic carbon (SOC) fractions in forest ecosystems. This study had two aims: (1) to evaluate the effects of altitude and vegetation on the content of labile and stabile forms of organic carbon in the mountain soils; and (2) to assess the impact of the properties of soil organic matter on the SOC pools under changing environmental conditions. The studies were conducted in the Karkonosze Mountains (SW Poland, Central Europe). The content of the most labile fraction of carbon (dissolved organic carbon, DOC) decreases with altitude, but the content of fulvic acids (FA), clearly increases in the zone above 1000 m asl, while the stabile fraction (humins, non-hydrolyzing carbon) significantly decreases. A higher contribution of stabile forms was found in soils under coniferous forests (Norway spruce), while a smaller - under deciduous forests (European beech) and on grasslands. The expected climate change and the ongoing land use transformations in the zone above 1000 m asl may lead to a substantial increase in the stable humus fraction (mainly of a non-hydrolyzing carbon) and an increase in the SOC pools, even if humus acids are characterized by a lower maturity and greater mobility favorable to soil podzolization. In the lower zone (below 1000 m asl), a decrease in the most stable humus forms can be expected, accompanied by an increase of DOC contribution, which will result in a reduction in SOC pools. Overall, the expected prevailing (spatial) effect is a decreasing contribution of the most stable humus fractions, which will be associated with a reduction in the SOC pools in medium-high mountains of temperate zone of Central Europe.     

Elevation change of the Urumqi Glacier No.1 derived from Sentinel-1A data

Accurate measurements of glacier elevation changes play a crucial role in various glaciological studies related to glacier dynamics and mass balance. In this paper, glacier elevation changes of Urumqi Glacier No.1 between August 2015 and August 2017 were investigated using Sentinel-1 A data and DInSAR technology. Meanwhile, the atmospheric delay error was corrected with the MODIS MOD05_L2 products. The weight selection iteration method was applied to calibrate the glacier elevation changes in the mass balance years 2015-2016 and 2016-2017. Finally, the geodetic method was employed to calculate the elevation change values of individual stakes of Urumqi Glacier No.1. Moreover, the elevation change values corrected by the weight selection iteration method were verified. Results showed as follows:(1) the elevation of Urumqi Glacier No.1 glacier affected by atmospheric delay was 1.270 cm from 2015 to 2016. The glacier elevation affected by atmospheric delay from 2016 to 2017 was 1.071 cm.(2) The elevation change value of Urumqi Glacier No.1 was-1.101 m from 2015 to 2016, and the elevation of Urumqi Glacier No.1 decreased by 1.299 m from 2016 to 2017. The overall thickness of Urumqi Glacier No. 1 was thinning.(3) By comparing the elevation change results of individual stakes with corresponding points corrected by the weight selection iteration method, the mean squared errors of difference were 0.343 m and 0.280 m between the two mass balance years, respectively.(4) The accuracy of elevation change in non-glaciated areas was 0.039 m from 2015 to 2016 and 0.034 m from 2016 to 2017. Therefore, it is reliable to use Sentinel-1 A data and the study method proposed in this paper to calculate the elevation change of mountain glaciers with very low horizontal movement.     

Implications of tree species–environment relationships for the responsiveness of Himalayan krummholz treelines to climate change

Climate warming is expected to advance treelines to higher elevations. However, empirical studies in diverse mountain ranges give evidence of both advancing alpine treelines as well as rather insignificant responses. In this context, we aim at investigating the sensitivity and responsiveness of the near-natural treeline ecotone in Rolwaling Himal, Nepal, to climate warming. We analysed population densities of tree species along the treeline ecotone from closed forest stands via the krummholz belt to alpine dwarf shrub heaths (3700-4200 m) at 50 plots in 2013 and 2014. We quantified species - environment relationships, i.e. the change of environmental conditions (e.g., nutrient and thermal deficits, plant interactions) across the ecotone by means of redundancy analyses, variation partitioning and distance-based Moran's eigenvector maps. In particular, we focus on explaining the high competitiveness of Rhododendron campanulatum forming a dense krummholz belt and on the implications for the responsiveness of Himalayan krummholz treelines to climate change. Results indicate that treeline trees in the ecotone show species-specific responses to the influence of environmental parameters, and that juvenile and adult tree responses are modulated by environmental constraints in differing intensity. Moreover, the species - environment relationships suggest that the investigated krummholz belt will largely prevent the upward migration of other tree species and thus constrain the future response of Himalayan krummholz treelines to climate warming.     

矿山废石淋溶对水环境的影响

为了研究废石堆砌对水环境的影响,通过对废石做淋溶实验,分析了出入水的水质变化规律,对废石衍生环境效应的过程、机制、影响因素方面进行讨论,揭示了人们容易忽视的酸性水中硫酸根、总硬度、微量金属离子的动力学变化机理,指出矿山废石对水环境的污染不至限于使水质酸化,硫酸根、总硬度也会大幅度提高,废石堆放应充分考虑当地的地理气候及水文条件,合理堆放,减少污染。     

pH值和氧化剂对硫化锑氧化溶解的影响机制

矿山开采活动影响下辉锑矿的氧化溶解是影响岩-土-水环境介质中锑的迁移转化及其环境效应的重要过程。目前对于辉锑矿溶解的研究主要关注动力学特征,对于它氧化溶解的途径、环境因素的影响、锑的释放规律等重要问题的认识还不明确。为探究碳酸盐岩矿区地下水中锑释放过程,选取重要环境因素pH值和Fe（Ⅲ）,采用单因素控制条件下的批实验方法,精细刻画避光条件下辉锑矿（Sb₂S₃）氧化溶解速率及Sb和S氧化产物的组成特征。研究结果表明,Sb₂S₃的氧化溶解是一个产酸的过程,Sb和S的释放速率、途径和产物特征受pH值和Fe（Ⅲ）的显著影响。Sb₂S₃的氧化溶解速率由快变慢后趋于平衡,初始反应速率的量级为10-8 mol/（m2·s）,平衡反应速率的量级为10-10 mol/（m2·s）。Sb的释放氧化速率随pH值的增加而增加,强碱条件下最有利于Sb的释放和氧化。强酸条件下,H₂S、SO₂气体逸出和S（0）的沉淀促进了Sb₂S₃的溶解,Sb（Ⅲ）和S（0）为主要产物。中性条件下,溶解形成的HS-经逐步氧化生成SO₄2-和少量S₂O₃2-,Sb（Ⅲ）和Sb（Ⅴ）含量相近。强碱条件下,SbS₃3-和S_x-的生成显著提升了Sb₂S₃的氧化溶解速率,Sb（Ⅴ）和S₂O₃2-是主要产物。Fe（Ⅲ）单独氧化作用时,Sb（Ⅴ）和S（0）是主要产物,锑释放的表观速率无显著提升,可能与SbOCl和S（0）的生成有关。研究表明,O₂能够协同Fe（Ⅲ）氧化Sb₂S₃,但以Fe（Ⅲ）的作用为主导。本研究揭示了Sb₂S₃在不同pH值及氧化剂条件下氧化溶解的产物组成特征,提出了不同环境因素影响下的氧化溶解途径,证明碳酸盐岩天然缓冲地层更有利于锑的释放与氧化,岩溶地下水中锑诱发的环境效应会更为严重。