首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 15 毫秒
1.
In the Amba Dongar diatreme, “ferrocarbonatite” is not a single unit of late differentiate of calciocarbonatite magma but it is a family with variation on field occurrence, mineralogy and chemistry of each unit. The family includes dikes of ankeritic carbonatites (phase I and II), plugs of ankeritic carbonatite within sövite ring dike, dikes of sideritic carbonatite in ankeritic carbonatite plug and rödberg veins. Their intrusive relations are very clear in the field and each phase has characteristic mineralogy and trace and REE geochemistry. According to the nomenclature suggested by Harmer and Gittins (1997) majority of “ferrocarbonatites” of Amba Dongar plot in field of “ferruginous calciocarbonatite” and only siderite and rödberg plot in the field of “ferrocarbonatite”. Within these family members, their trace and REE show clear increase from early phase to last phase of sideritic carbonatite. The present short communication discusses various aspects of “ferrocarbonatites”.  相似文献   

2.
Wakefieldite-(Ce,La) and vanadinite in coarse-grained calciocarbonatites (sövites) are for the first time reported from the northeastern part of the worldwide largest fluorite deposit at the Amba Dongar carbonatite ring dike, India. Sövite in this part of the carbonatite ring dike is rich in pyrochlore, calcite and magnetite. Pyrochlore makes up almost 50% of some sövite samples and shows core-to-rim compositional changes. The core of pyrochlore consists of primary fluorcalciopyrochlore with high F and Na contents while the margins gained elevated amounts of Pb, La and Ce with the associated loss of F and Na due to circulation of hydrothermal solutions. The presence of wakefieldite-(Ce,La) and vanadinite points to an exceptionally high V abundance in hydrothermal solutions formed towards the end of the carbonatite magma activity. This investigation thus opens new promising areas for Nb and REE prospection in the eastern part of the Amba Dongar carbonatite body.  相似文献   

3.
Pyrochlore is interpreted as a primary magmatic mineral that appeared in early carbonatite phases at Amba Dongar. Later intrusive phases incorporated this early pyrochlore and caused compositional modification, particularly around the rims, in response to changing magma chemistry. Consequently pyrochlore compositions show wide ranges in Nb, Ta, Ca, Ba, Ti and Ce. The final carbonatite phase was ankeritic and rich in hydrothermal fluids, giving rise to extreme compositional zoning and introduction of diverse elements (Si, U, Sr, Th, Fe), in the contained pyrochlore. Enrichment in radioelements such as U lead to metamictization, alteration and A-site vacancy.  相似文献   

4.
Results of different isotopic and trace element studies on three carbonatite–alkaline complexes (Amba Dongar, Mundwara and Sarnu-Dandali) of the Deccan flood basalt province, India, are presented. The Amba Dongar (Ambadungar) complex has been dated precisely to 65.0±0.3 Ma by the 40Ar–39Ar method. The minimum initial Sr isotopic ratio of alkaline rocks of Amba Dongar is found to be same as that of the coexisting carbonatites, suggesting their derivation from a common parent magma, probably through liquid immiscibility. The rare earth element abundance in these rocks also supports the liquid immiscibility hypothesis. Further investigation revealed that the parent magma of this complex has been contaminated (∼5%) by the lower crustal material, which is clearly reflected in the initial 87Sr/86Sr variation of alkaline rocks but not in the carbonatites. Sr study also suggests that the mantle source of Amba Dongar like the other two complexes is a Rb/Sr enriched source. The temporal and spatial relationships of all the three complexes with the Deccan flood basalts support the hypothesis of reunion plume origin for these. Fractional crystallization and subsequent hydrothermal/meteoric alteration are found to have controlled the stable carbon and oxygen isotopic variations in carbonatites. This study suggests that all the complexes have been derived from isotopically average mantle except for a particular batch of parent magma at Amba Dongar, which appears to have incorporated recycled crustal carbon. In a plume origin scenario such incorporation indicates the entrainment of 13C-enriched subcontinental lithospheric mantle by the plume.  相似文献   

5.
The results of a Sr isotopic study of coexisting alkaline silicate rocks and carbonatites of two Cretaceous alkaline complexes of India, Amba Dongar (Deccan Flood Basalt Province) and Sung Valley (Rajmahal–Bengal–Sylhet Flood Basalt Province) are reported. The overlapping nature of initial Sr isotopic ratios of alkaline rocks and carbonatites of both the complexes is consistent with a magmatic differentiation model. Modelling of initial 87Sr/86Sr variation in alkaline rocks of Amba Dongar is consistent with a process of crustal assimilation by the parent magma undergoing simultaneous fractional crystallization of silicate rocks and silicate–carbonate melt immiscibility. A maximum of ∼5% crustal contamination has been estimated for the parent magma of Amba Dongar, the effect of which is not seen in the Sr isotope ratio of carbonatites generated by liquid immiscibility. A two point Rb–Sr isochron of the Sung Valley carbonatites, pyoxenite and a phlogopite from a carbonatite yielded an age of 106±11 Ma, which is identical to the 40Ar–39Ar age of this complex. The same age for the carbonatites and the alkaline silicate rocks, similar initial Sr ratios and the higher Sr concentration in the former than the latter favour the hypothesis of liquid immiscibility for the generation of the Sung Valley. The higher initial 87Sr/86Sr ratio for these complexes than that of the Bulk Earth indicates their derivation from long-lived Rb/Sr-enriched sources.  相似文献   

6.
A carbon and oxygen isotope survey based on 42 samples from the Amba Dongar carbonatite complex of Gujarat, India, indicates that the magmatic differentiation series sövite → alvikite → ankeritic carbonatite is beset with a distinct isotope trend characterized by a moderate rise in 13C coupled with a sizeable increase in 18O. From an average of −4.6 ± 0.4 ‰ [PDB] for the least differentiated (coarse) sövite member, δ13C values slowly increase in the alvikite (−3.7 ± 0.6 ‰) and ankeritic fractions (−3.0 ± 1.1 ‰), whereas δ18O rises from 10.3 ± 1.7 ‰ [SMOW] to 17.5 ± 5.8 ‰ over the same sequence, reaching extremes between 20 and 28 ‰ in the latest generation of ankeritic carbonatite. While an apparent correlation between δ13C and δ18O over the δ18O range of 7–13 ‰ conforms with similar findings from other carbonatite complexes and probably reflects a Rayleigh fractionation process, the observed upsurge of 18O notably in the ankeritic member is demonstrably related to a late phase of low-temperature hydrothermal activity involving large-scale participation of 18O-depleted groundwaters. As a whole, the Amba Dongar carbonatite province displays the characteristic 13C/12C label of deep-seated (primordial) carbon, reflecting the carbon isotope composition of the subcontinental upper mantle below the Narmada Rift Zone of the Indian subcontinent.  相似文献   

7.
The lens-shaped Miaoya carbonatite complex, located west of the Wudang massif, Hubei Province, consists of several types of carbonatites associated with syenites. According to their composition, the carbonatites can be classified into four types, i. e., sovite, alvikite, carbon-bearing alvikite and ankeritic carbonatite. Their average composition is in agreement with the abundance values for carbonatites compiled by Gold (1966). There are three stages recognizable: the earliest sovite and alvikite followed by carbon-bearing alvikite, with ankeritic carbonatite being the latest. Some rules dominating the distribution of major and rare elements are observed with respect to the evolution of these carbonatites, for example, Nb is essentially enriched in sovite. Except for niobite and ilmenorutile, there are also pyrochlore, nioboeschynite and fersmite. RE are concentrated mainly in ankeritic carbonatite, within which bastnasite, parisite and monazite are found. In general, Ca, Nb, and Sr decrease, while Fe, Mg, Mn, and RE increase from earlier to later stages. It is suggested that the carbonatites are genetically connected with syenitic magma.  相似文献   

8.
The only significant silicate intrusive rock type in the Dicker Willem carbonatite complex is trachyte, forming, in places, an anastomosing array of minor intrusions cutting basement gneiss close to the carbonatite contact. Bodies are predominantly composite breccias, composed of trachyte clasts, commonly in the form of ellipsoidal pellets, enclosed within, and sharply delineated from, a matrix of carbonatite. Despite close temporal and spatial relationships to carbonatite magmatism, the ultrapotassic, quartz-normative composition and isotope systematics of the trachytes preclude any genetic derivation from the carbonatitic and ijolitic rocks of the central complex. Sr, Nd and Pb isotope ratios of trachytes strongly resemble those of the highest grade, potassic fenites, whose metasomatic trend converges from the unaltered basement gneiss towards the homogeneous signature of the nepheline sövite–sövite–ijolite suite. Trachytes are interpreted as forming by melting of a cupola of high-grade fenite in response to the advective heat flux from rising carbonatite magma or fluid. Mixed carbonatite and trachyte were emplaced in a fluidised system as contemporaneous, but genetically unrelated, immiscible magmas.  相似文献   

9.
The Newania carbonatite complex of Rajasthan, India is one of the few dolomite carbonatites of the world, and oddly, does not contain alkaline silicate rocks thus providing a unique opportunity to study the origin and evolution of a primary carbonatite magma. In an attempt to characterize the mantle source, the source of carbon, and the magmatic and post-magmatic evolution of Newania carbonatites, we have carried out a detailed stable carbon and oxygen isotopic study of the complex. Our results reveal that, in spite of being located in a metamorphic terrain, these rocks remarkably have preserved their magmatic signatures in stable C and O isotopic compositions. The δ13C and δ18O variations in the complex are found to be results of fractional crystallization and low temperature post-magmatic alteration suggesting that like other carbonatites, dolomite carbonatites too fractionate isotopes of both elements in a similar fashion. The major difference is that the fractional crystallization of dolomite carbonatites fractionates oxygen isotopes to a larger extent. The modes of δ13C and δ18O variations in the complex, ?4.5?±?1‰ and 7?±?1‰, respectively, clearly indicate its mantle origin. Application of a multi-component Rayleigh isotopic fractionation model to the correlated δ13C versus δ18O variations in unaltered carbonatites suggests that these rocks have crystallized from a CO2 + H2O fluid rich magma, and that the primary magma comes from a mantle source that had isotopic compositions of δ13C ~ ?4.6‰ and δ18O ~ 6.3‰. Such a mantle source appears to be a common peridotite mantle (δ13C = ?5.0?±?1‰) whose carbon reservoir has insignificant contribution from recycled crustal carbon. Other Indian carbonatites, except for Amba Dongar and Sung Valley that are genetically linked to Reunion and Kerguelen plumes respectively, also appear to have been derived from similar mantle sources. Through this study we establish that dolomite carbonatites are generated from similar mantle source like other carbonatites, have comparable evolutionary history irrespective of their association with alkaline silicate rocks, and may remain resistant to metamorphism.  相似文献   

10.
are-earth (REE) and yttrium abundances were determined, by an ion-exchange-X-ray fluorescence procedure, for whole-rock (14) and mineral (87) samples from the Oka carbonatite complex. Whole-rock and mineral data indicate a trend of total REE + Y enrichment, and relative enrichment in light REE, in the order: ultrafenites < ijolites < okaites. The sövites may show wide variations in total REE + Y concentrations, but relative REE abundance patterns will be similar. The greatest REE and Y concentrations occur in apatite, niocalite, perovskite and pyrochlore. Many of the minerals show europium anomalies (both positive and negative), and these are believed to be the result of closed system competition between the various minerals for divalent Eu. The partition coefficients for mineral pairs are quite variable, indicating that the Oka rocks were emplaced through a wide-range of physicochemical and/or nonequilibrium conditions. A reasonable model for the origin of the complex involves a limited partial melting of mantle material, emplacement of the melt in a magma chamber, crystallization of mafic minerals resulting in a residual liquid which produced ijolite and subsequently okaite, and crystallization of the carbonatites from a volatile-rich, possibly immiscible, phase.  相似文献   

11.
Carbonatites that are hosted in metamorphosed ultramafic massifs in the roof of miaskite intrusions of the Il’mensky-Vishnevogorsky alkaline complex are considered. Carbonatites have been revealed in the Buldym, Khaldikha, Spirikha, and Kagan massifs. The geological setting, structure of carbonatite bodies, distribution of accessory rare-metal mineralization, typomorphism of rock-forming minerals, geochemistry, and Sr and Nd isotopic compositions are discussed. Dolomite-calcite carbonatites hosted in ultramafic rocks contain tetraferriphlogopite, richterite, accessory zircon, apatite, magnetite, ilmenite, pyrrhotite, pyrite, and pyrochlore. According to geothermometric data and the composition of rock-forming minerals, the dolomite-calcite carbonatites were formed under K-feldspar-calcite, albite-calcite, and amphibole-dolomite-calcite facies conditions at 575–300°C. The Buldym pyrochlore deposit is related to carbonatites of these facies. In addition, dolomite carbonatites with accessory Nb and REE mineralization (monazite, aeschynite, allanite, REE-pyrochlore, and columbite) are hosted in ultramafic massifs. The dolomite carbonatites were formed under chlorite-sericite-ankerite facies conditions at 300–200°C. The Spirikha REE deposit is related to dolomite carbonatite and alkaline metasomatic rocks. It has been established that carbonatites hosted in ultramafic rocks are characterized by high Sr, Ba, and LREE contents and variable Nb, Zr, Ti, V, and Th contents similar to the geochemical attributes of calcio-and magnesiocarbonatites. The low initial 87Sr/86Sr = 0.7044?0.7045 and εNd ranging from 0.65 to ?3.3 testify to their derivation from a deep mantle source of EM1 type.  相似文献   

12.
Carbonatites, metasomatised country rocks, and carbonatitic calcite and magnetite have been analysed from two carbonatite complexes, Homa and Wasaki, W. Kenya.The carbonatites are all greatly Ce-earth enriched, contain abundant ‘carbonatitic’ trace elements (Sr, Ba, Nb and REE), and generally low concentrations of Cr, Co, Ni, Pb, Ga, Ge, Sn, Bi, Li and Mo. At both complexes early søvite is rich in Sr, and impoverished in other trace elements relative to the alvikites. The late-intruded melacarbonatites contain the greatest concentrations of Ba, REE, Fe and Mn.It is concluded that the accumulation of these elements in the later carbonatites is mainly due to fractionation of carbonates from carbonatite magma which was initially rich in ‘carbonatitic’ trace elements.  相似文献   

13.
The main types of spherulitic and orbicular structures in carbonatites of Sokli (Finland) and Vuorijärvi (U.S.S.R.) are described. The structures have small-scale morphological differences although generally they show fairly similar characteristic features. All the rocks investigated are composed of two structurally different portions: regular ellipsoidal and spherical segregations containing forsterite, magnetite, phlogopite and sometimes calcite and apatite, and a substantially calcitic matrix containing some apatite, silicate and opaque components. These two portions correspond to phoscorite and sövite fractions separated during the crystallization of an initial melt of mixed composition. The structures described are regarded as evidence of liquid immiscibility processes in the formation of sövite and phoscorite rock series which were promoted by limited solubility of ore-silicate and carbonate fractions. Crystallization differentiation by early settling of apatite, silicate and ore minerals plays a leading role in the fractionation of substantially sövitic solutions that contain comparatively small amounts of silicate, ore and phosphate components.  相似文献   

14.
The carbonatites of the Ilmeny-Vishnevogorsky Alkaline Complex (IVAC) are specific in geological and geochemical aspects and differ by some characteristics from classic carbonatites of the zoned alkaline-ultramafic complexes. Geological, geochemical and isotopic data and comparison with relevant experimental systems show that the IVAC carbonatites are genetically related to miaskites, and seem to be formed as a result of separation of carbonatite liquid from a miaskitic magma. Appreciable role of a carbonate fluid is established at the later stages of carbonatite formation. The trace element contents in the IVAC carbonatites are similar to carbonatites of the ultramafic-alkaline complexes. The characteristic signatures of the IVAC carbonatites are a high Sr content, a slight depletion in Ba, Nb, Та, Ti, Zr, and Hf, and enrichment in HREE in comparison with carbonatites of ultramafic-alkaline complexes. This testifies a specific nature of the IVAC carbonatites related to the fractionation of a miaskitic magma and to further Late Paleozoic metamorphism. Isotope data suggest a mantle source for IVAC carbonatites and indicate that moderately depleted mantle and enriched EMI-type components participated in magma generation. The lower crust could have been involved in the generation of the IVAC magma.  相似文献   

15.
H.v. Maravic  G. Morteani 《Lithos》1980,13(2):159-170
The Lueshe carbonatite is intruded into schists which probably belong to the ßurundian-system. These schists show a weak fenitisation at the contact to the carbonatite complex. Petrographical and chemical investigations show that the different types of syenite of the alkaline complex belong mainly to the miaskitic group. Pyrochlore contents up to 1 vol.% are typical. The carbonatites of the Luesche alkaline complex are mainly sövites with some alvikites and beforsites. Calcite and apatite from the sövites and from the silico-sövites show a wide range of light REE contents. From a Yb/CaYb/La diagram it can be supposed that some of the carbonatites at the contact to the country schists show hydrothermal remobilisation.  相似文献   

16.
Associated rocks from the Seabrook Lake, carbonatite complex in Ontario show an increase in total REE (rare earth element) content and in light REE enrichment in the following order: fenite quartz monzohite 2 and H2O-rich fluids.  相似文献   

17.
The brevity of carbonatite sources in the mantle: evidence from Hf isotopes   总被引:5,自引:0,他引:5  
Hf, Zr and Ti in carbonatites primarily reside in their non-carbonate fraction while the carbonate fraction dominates the Nd and Sr elemental budget of the whole rock. A detailed investigation of the Hf, Nd and Sr isotopic compositions shows frequent isotopic disequilibrium between the carbonate and non-carbonate fractions. We suggest that the trace element and isotopic composition of the carbonate fraction better represents that of the carbonatite magma, which in turn better reflects the composition of the carbonatitic source. Experimental partitioning data between carbonatite melt and peridotitic mineralogy suggest that the Lu/Hf ratio of the carbonatite source will be equal to or greater than the Lu/Hf ratio of the carbonatite. This, combined with the Hf isotope systematics of carbonatites, suggests that, if carbonatites are primary mantle melts, then their sources must be short-lived features in the mantle (maximum age of 10–30 Ma), otherwise they would develop extremely radiogenic Hf compositions. Alternatively, if carbonatites are products of extreme crystal fractionation or liquid immiscibility then the lack of radiogenic initial Hf isotope compositions also suggests that their sources do not have long-lived Hf depletions. We present a model in which the carbonatite source is created in the sublithospheric mantle by the crystallization of earlier carbonatitic melts from a mantle plume. This new source melts shortly after its formation by the excess heat provided by the approaching hotter center of the plume and/or the subsequent ascending silicate melts. This model explains the HIMU-EMI isotope characteristics of the East African carbonatites, their high LREE/HREE ratios as well as the rarity of carbonatites in the oceanic lithosphere.  相似文献   

18.
The study of radioactive element distribution in the rocks of the Guli Complex revealed an increase of uranium and thorium contents in the final products of magmatic differentiation. In the carbonatite complex, the radioactive elements are mainly accumulated in the early rocks—phoscorites, while their contents in the late phases, dolomitic carbonatites, decrease. The Th/U ratio increases from near-chondritic values in the weakly differentiated highly-magnesian primary magmas to the late rocks—phoscorites, calcitic carbonatites, and dolomitic carbonatites. The majority of radioactive elements are hosted in rare-metal accessory minerals: perovskite, pyrochlore, calzirtite, and apatite. Rock-forming minerals are characterized by extremely low contents of radioactive elements.  相似文献   

19.
Alkaline lamprophyre dykes from Taourirt (North Morocco) containnumerous xenoliths, ranging from alkaline pyroxenites, kaersutitites,gabbros and nepheline syenites to a calcite carbonatite. Thesilicate xenoliths and the host rocks consist of Al- and Ti-richdiopside–salite, mica or kaersutitite, ± nepheline,± plagioclase and K-feldspar, and ubiquitous apatite.Both the xenoliths and the lamprophyres are enriched in incompatibleelements. The chemical composition of the lamprophyres cannotbe accounted for by fractional crystallization alone. Moreover,the clinopyroxenes exhibit complex zoning, which requires repeatedmixing of pulses of more or less fractionated melts. The carbonatiteis a sövite cumulate with Sr-rich calcite, pyrochlore,fluorapatite, and rare salite. The Sr–Nd isotopic compositionsof the Taourirt rocks indicate a depleted mantle source, thecarbonatite having the most depleted composition, and definea linear trend similar to that of the East African carbonatites.The different rocks thus represent unrelated magmas, and thetrend is interpreted as mixing between two components with HIMUand EM1 mantle end-member signatures. An EM2 mantle componentcould also be involved for a few samples; it may correspondto hydrous metasomatized mantle of the PP–PKP (phlogopiteand phlogopite K-richterite peridotite) and MARID (mica, amphibole,rutile, ilmenite and diopside) type. KEY WORDS: alkaline magmatism; carbonatite; Morocco; REE; Sr–Nd isotopes  相似文献   

20.
The Alnö alkaline-carbonatite complex consists in its northernmost part at Laångarsholmen of a ring-type intrusion composed of pyroxenite, sövite and ijolite, emplaced in that order. The intrusion is surrounded by a breccia zone. The petrography, mineral chemistry and fluid/solid inclusion studies suggest that the ring complex and the main intrusion at Alnö have had a somewhat different magmatic evolution, implying different evolution of fluid phases also. At Laångarsholmen, a mafic silicate magma started to crystallize Al-diopside of 0.11 CaTs (Tschermak’s) content during a mid-crustal stage of evolution (ca. 5–6?kbar and 1175°?C). At that stage, the mafic magma was coexisting with a Mg-bearing calcitic melt, recorded in the abundant inclusions, trapped by the crystallizing Al-diopside. The two immiscible melts appear to have separated at ca. 5?kbar and 1150°?C, in good agreement with recent experimental studies. The silicate magma crystallized di+ap+magnetite during its ascent, and was in contact with a saline hydro-carbonic fluid trapped as inclusions in diopside (di) and apatite (ap) (type B2 inclusions reluctant to dissolution up to 550°?C). As PH2O started to increase, Fe-pargasite began to replace the pyroxene. It appears that the fluid present at that stage was aqueous and contained ca. 40%?NaCl. With decreasing PT, the fluid separated into two immiscible phases of high- and low-salinity (type B1 of 65%?NaCl and Cl of 7%?NaCl), respectively. At the shallow depths of the final emplacement, the composition of the fluid phase was most probably controlled by supply of meteoric water as indicated by the dilution trend of some B1 type inclusions. After separation, the carbonatite magma fractionated calcite+ap+dol (as shown by dolomite inclusions in early crystallizing apatite). Around 4?kbar, a CO2-bearing aqueous fluid of low salinity (d=0.85) was coexisting with the melt, and became trapped in the apatite formed during the mid-crustal stage (type A1 fluid inclusions). The residual melt was emplaced into the shallow crust and gave rise to phlogopite-bearing sövite. Fluid inclusions (type A2) trapped in calcite and in recrystallized apatite indicate that the fluid phase evolved towards a late (Na+K) hydro-carbonic fluid during cooling at the shallow depths of the final emplacement. The ijolite does not show signs of liquid immiscibility with the sövite at Laångarsholmen, and exhibits mostly post-magmatic activity of fluid phases.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号