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1.
Characterization and identification of na-cl sources in ground water   总被引:6,自引:0,他引:6  
Elevated concentrations of sodium (Na+) and chloride (Cl-) in surface and ground water are common in the United States and other countries, and can serve as indicators of, or may constitute, a water quality problem. We have characterized the most prevalent natural and anthropogenic sources of Na+ and Cl- in ground water, primarily in Illinois, and explored techniques that could be used to identify their source. We considered seven potential sources that included agricultural chemicals, septic effluent, animal waste, municipal landfill leachate, sea water, basin brines, and road deicers. The halides Cl-, bromide (Br), and iodide (I) were useful indicators of the sources of Na+-Cl- contamination. Iodide enrichment (relative to Cl-) was greatest in precipitation, followed by uncontaminated soil water and ground water, and landfill leachate. The mass ratios of the halides among themselves, with total nitrogen (N), and with Na+ provided diagnostic methods for graphically distinguishing among sources of Na+ and Cl- in contaminated water. Cl/Br ratios relative to Cl- revealed a clear, although overlapping, separation of sample groups. Samples of landfill leachate and ground water known to be contaminated by leachate were enriched in I and Br; this provided an excellent fingerprint for identifying leachate contamination. In addition, total N, when plotted against Cl/Br ratios, successfully separated water contaminated by road salt from water contaminated by other sources.  相似文献   

2.
Cosmic-ray produced 36Cl(t1/2 = 3.0 × 105 years) has been measured in four Antarctic meteorites and one sample of Antarctic ice using a tandem Van de Graaff accelerator as an ultrasensitive mass spectrometer with the extremely low background level of 36Cl/Cl< 2 × 10?16. Results from this ion counting technique (applied here to extraterrestrial materals for the first time) are used to support a two-stage irradiation model for the Yamato-7301 and Allan Hills-76008 meteorites and to show a long terrestrial age (0.7 ± 0.1 m.y.) for Allan Hills-77002. Yamato-7304 has a terrestrial age of less than 0.1 m.y. The 36Cl content of the Antarctic ice sample from the Yamato Mountain area implies that the age of the ice cap at this site is less than one 36Cl half-life.  相似文献   

3.
The temporal and spatial distributions of Antarctic sea ice play important roles in both the generation mechanisms and the signal characteristics of microseisms. This link paves the way for seismological investigations of Antarctic sea ice. Here we present an overview of the current state of seismological research about microseisms on Antarctic sea ice. We first briefly review satellite remote-sensing observations of Antarctic sea ice over the past 50 years. We then systematically expound upon the generation mechanisms and source distribution of microseisms in relation to seismic noise investigations of sea ice, and the characteristics of Antarctic microseisms and relationship with sea ice variations are further analyzed. We also analyze the continuous data recorded at seismic station BEAR in West Antarctica from 2011 to 2018 and compare the microseism observations with the corresponding satellite remote-sensing observations of Antarctic sea ice. Our results show that:(1) the microseisms from the coastal regions of West Antarctica exhibit clear seasonal variations, SFM with maximum intensities every April-May and minimum intensities around every October-November; while DFM intensities peak every February-March, and reach the minimum around every October. Comparatively, the strong seasonal periodicity of Antarctic sea ice in better agreement with the observed DFM; and (2) microseism decay is not synchronous with sea ice expansion since the microseism intensity is also linked to the source location, source intensity (e.g., ocean storms, ocean wave field), and other factors. Finally, we discuss the effect of Southern Annular Mode on Antarctic sea ice and microseisms, as well as the current limitations and potential of employing seismological investigations to elucidate Antarctic sea ice variations and climate change.  相似文献   

4.
利用ICESat数据解算南极冰盖冰雪质量变化   总被引:5,自引:4,他引:1       下载免费PDF全文
南极冰盖冰雪质量变化反映了全球气候变化,并且直接影响着全球海平面变化.ICESat测高卫星的主要任务之一就是要确定南北两极冰盖的质量变化情况并评估其对全球海平面变化的影响.本文利用2003年10月至2008年12月的ICESat测高数据,针对南极DEM分辨率有限的特殊性,通过求解坡度改正值,解决重复轨道地面脚点不重合的问题,计算了南极大陆(86°S以北区域,后文所述南极冰盖均不包括86°S以南区域)在这5年里的冰雪质量变化情况,得到东南极冰盖的质量变化为-18±20Gt/a,西南极-26±6Gt/a,南极冰盖的冰雪质量变化为-44±21Gt/a,对全球海平面上升的影响约为0.12mm·a~(-1).解算结果表明,南极冰盖质量亏损主要集中在西南极阿蒙森海岸附近冰川以及东南极波因塞特角区域.  相似文献   

5.
Magma degassing at Soufrière Hills Volcano (SHV) is characterised by an almost permanent SO2 flux and a HCl production rate which mainly depends on dome growth rate. Degassing processes have been studied through textural, H2O and halogen analyses of clasts collected between 1995 and 2006 on the dome and in pyroclastic flows and vulcanian eruption deposits. Cl, Br and I are strongly depleted in melts during H2O degassing with no significant Cl–Br–I fractionation, whereas F is almost unaffected. All magmas erupted at SHV have followed a multi-step degassing path from the magma chamber up to a shallow depth ( 1 km, P  20 MPa). From that depth, however, effusive and explosive paths are distinct; vulcanian eruptions are the result of closed system degassing (CSD), while effusive dome growth is the result of CSD up to a very shallow depth (≤ 200 m, P  5–2 MPa) followed by open system degassing (OSD). CSD is modelled using the H2O solubility law, the perfect gas law and partition coefficients of halogens between a rhyolitic melt and H2O vapour (dv − li). Gas loss characteristic of OSD is modelled using a Rayleigh law. Degassing induced crystallisation is introduced through the ratio of crystallisation and degassing rates, which ranges from 150–500. dv − lCl for OSD ranges between 50–300, increasing with melt Cl content. For CSD, the lower effective dv − lCl ( 20) is attributed to kinetic effects.

Dome forming activity has a greater impact on atmospheric chemistry than vulcanian eruptions because OSD is much more efficient at extracting halogens. The model shows that HCl flux is a good proxy for the dome forming eruption rate. Comparison between model and measured gas compositions suggests a high HBr–BrO conversion rate (BrO/Total Br  1/3) in the SHV gas plume.

The degassing behaviour of Cl, Br and I implies similar Cl/Br ( 160) and Br/I ( 90) in initial melts, volcanic clasts and high temperature gases. The low Cl/Br at SHV compared to other island arcs ( 250–300) is attributed to a shallow, pre-eruptive Br enrichment. The almost permanent dome extrusion at SHV since 1995 has likely had a significant regional atmospheric impact because of the very efficient effusive degassing and the high conversion rate of halogens into reactive species within the gas plume.  相似文献   


6.
Cosmic-ray-produced53Mn (t1/2 = 3.7 × 106years) has been measured in twenty Antarctic meteorites by neutron activation analysis.36Cl (t1/2 = 3.0 × 105years) has been measured in fourteen of these objects by tandem accelerator mass spectrometry. Cosmic ray exposure ages and terrestrial ages of the meteorites are calculated from these results and from rare gases.14C (t1/2 = 5740years) and26Al (t1/2 = 7.2 × 105years) data. The terrestrial ages range from 3 × 104 to 5 × 105 years. Many of the L3 Allan Hills chrondrites seem to be a single fall based on these results. In addition,10Be (t1/2 = 1.6 × 106years) and36Cl have been measured in six Antarctic ice samples. The first measurements of10Be/36Cl ratios in the ice core samples demonstrate a new dating method for ice.  相似文献   

7.
The Antarctic meteorite collection has proved to be a source of many important discoveries, including a number of previously unknown or very rare meteorite types. A thermoluminescence (TL) survey of meteorite samples recovered by the 1988/89 European expedition and pre-1988 American expeditions to the Allan Hills Main blue ice field resulted in the discovery of 15 meteorites with very high TL levels ( > 100 krad at 250°C in the glow curvc). It is likely that these samples are fragments of a single meteoroid body which: (1) fell very recently and (2) experienced a decrease in orbital perihelia from 1.1 AU to 1 AU within the last 105 yr. Carbon-14 data for two of the samples confirm their young terrestrial age compared to most Antarctic meteorites. Studies of the cosmogenic isotopes in at least one non-Antarctic meteorite which also has very high natural TL, Jilin, indicate that the meteorite experienced a multi-stage irradiation history, the most recent stage being 0.4 Ma in duration following a major break-up of the object. These meteorites, and the few equivalent modern falls, are the only documented samples from bodies which were recently in Earth-approaching (Amor) orbits (i.e., with perihelion > 1.0 AU), as opposed to the Earth-crossing (Apollo) orbits which are the source of most other meteorites. Their rarity indicates that such rapid orbit changes are unusual for meteoroid bodies and may be the result of isolated, large break-up events.  相似文献   

8.
Minerals that occur as incrustations in cooling lavas are formed by fractional condensation of volatile halides. Sulfates are of secondary origin formed during oxidation of the degassing volatiles. The trace metal compositions of the incrustations are controlled by the F/Cl ratio of the transporting gas phase rather than by element abundances in the silicate melt. The F/Cl ratio of the gas phase, inferred from incrustation mineral equilibria, indicates regional differences in the halogen contents of Icelandic magmas. The rift zone volcanism (tholeiites) is distinguished by low halogen content and very low F/Cl ratios, while the off-rift volcanism (alkaline rocks) is associated with high halogen content and high F/Cl ratios.  相似文献   

9.
We have used satellite solutions to the low degree zonal harmonics of the Earth's gravitational potential, and rates of surface accumulation to partially constrain, by means of repeated forward solution, the time rates of thickness change over the Antarctic and Greenland Ice Sheets (dTA and dTG respectively). In addition to the observed zonal coefficients j2 through j5 we impose only one other constraint: That dTA and dTG are proportional to surface accumulation. The lagged response of the Earth to secular changes in ice thickness spanning recent time periods (up to 2000 years before present) and the late Pleistocene is accounted for by means of two viscoelastic rebound models. The sea level contributions from the ice sheets, calculated from dTA and dTG, lower mantle viscosity, and the start time of present-day thickness change are all variables subject to the constraints. For a given set of post glacial rebound inputs, a family of solutions that have similar characteristics and that agree well with observation are obtained from the large number of forward solutions. The off axis position of the Greenland ice sheet makes its contribution to the low degree zonal coefficients less sensitive to the spatial details of the mass balance than to the overall sea level contribution. dTG is therefore modeled as surface mass balance offset by a uniform and constant mass loss. Though dTA varies widely with choices of input parameters, the combined sea level contribution from both ice sheets is reasonably well constrained by the gravity coefficients, and is predicted to range from -0.9 to +1.6 mm yr-1. The sign of the slope of the low degree zonal coefficients versus sea level contribution for Greenland is positive, but for Antarctica, the sign of the slope is positive for even degree and negative for odd degree harmonics. By using this property of the zonal coefficients, it is possible to determine the individual sea level contributions for Greenland and Antarctica. They vary from -0.6 to +0.3 mm yr-1 for the Greenland Ice Sheet, and from -0.3 to +1.3 mm yr-1 for the Antarctic Ice Sheet.  相似文献   

10.
Sea ice has been reported to contain contaminants from atmospheric and nearshore sediment resuspension processes. In this study successive passive microwave images from the 85.5 GHz channels on the Special Sensor Microwave Imager (SSM/I) were merged with drifting buoy trajectories from the International Arctic Buoy Program to compute Arctic sea ice motion in the Russian Arctic between 1988 and 1994. Smooth daily motion fields were averaged to prepare monthly maps making it possible to compute the 7-year mean and mean seasonal ice motions as well as principal components of directional variability of sea ice motion for the entire Arctic and surrounding basins. These mean motion vectors are used to simulate the advection of contaminants deposited on or contained within the sea ice and subsequently transported into the Arctic Ocean in order to predict both their mean trajectories and dispersal over time. The 3-year displacement of contaminants from a number of Russian sites and one American site display various behaviours from substantial displacement and dispersal to almost no movement. This computational procedure could be applied to realtime SSM/I and ice buoy data to provide detailed, all-weather, vector motion maps of ice circulation to predict the path and dispersal of any new substance introduced to the sea ice and transported into the Arctic or Antarctic ocean surface.  相似文献   

11.
As an important component of the cryosphere, sea ice is very sensitive to climate change. The study of sea ice physics needs accurate sea ice thickness. This paper presents an electromagnetic induction (EM) technique which can be used to measure the sea ice thickness distribution efficiently and its successful application in the Antarctic Neila Fjord. Based on the electrical properties of sea ice and seawater and the application of electromagnetic field theory, this technique can accurately detect the distance between the EM instrument and the ice/water interface to measure the sea ice thickness. Analyzing the apparent conductivity data obtained by the electromagnetic induction technique and drill-hole measurements at same location allows the construction of a transform equation for the apparent conductivity and sea ice thickness. The verification of the calculated sea ice thickness using this equation indicates that the electromagnetic induction technique is able to determine reliable sea ice thickness with an average relative error of only 5.5%. The ice thickness profiles show the sea ice distribution in Neila Fjord is basically level with a thickness of 0.8 - 1.4 m.  相似文献   

12.
鉴于卫星测高技术在南极周边海域会受到海面浮冰影响,且在利用测高序列分析海平面周期性动态变化时还会受到潮汐周期混叠效应的影响,为此,本文开展了基于GPS和验潮数据联合的南极大陆附近海域从1994-2014年间海平面的绝对变化研究.研究结果显示:在围绕南极大陆及附近海域的15个验潮站中,海平面绝对变化速度最大的是Diego Ramirez验潮站,达到11.10±0.04 mm·a-1;在西南极南极半岛的德雷克海峡,海平面变化最为活跃,变化均值在8.31±0.05 mm·a-1;在东南极,从Syowa站依次到Casey站,海平面的绝对变化速度相对平稳,四个潮位站海平面变化均值为3.35±0.04 mm·a-1;在罗斯冰架右下侧的罗斯岛附近,由于冰川崩解入海导致Scott Base站处的海平面上升速度较快,达到了9.61±0.07 mm·a-1.综合15个验潮站计算结果可得南极半岛德雷克海峡和罗斯岛附近海域,海平面绝对变化速度要高于同期南大洋海平面绝对变化速度,而东南极4个潮位站海平面绝对变化均值则与其相当.这也进一步反映了南极不同海域间海平面变化的差异性,相比较于对南大洋海平面变化的一个整体研究,分区研究海平面变化更具针对性,能更好地了解南极不同区域冰盖、冰架崩解和消融的情况.  相似文献   

13.
It has been well known by oceanographers that the World Ocean Circulation originates inNorth Atlantic near the Greenland, where in wintertime the cooled surface water descends to form North Atlantic Deep Waters (NADW). The NADW, when passing the Antarctic…  相似文献   

14.
In 2001, a small H4 chondrite, Frontier Mountain (FRO) 01149, was found on a glacially eroded surface near the top of Frontier Mountain, Antarctica, about 600 m above the present ice level. The metal and sulphides are almost completely oxidized due to terrestrial weathering. We used a chemical leaching procedure to remove weathering products, which contained atmospheric 10Be and 36Cl in a ratio similar to that found in Antarctic ice. The FRO 01149 meteorite has a terrestrial age of 3.0 ± 0.3 Myr based on the concentrations of the cosmogenic radionuclides 10Be, 26Al and 36Cl. This age implies that FRO 01149 is the oldest stony meteorite (fossil meteorites excluded) discovered on Earth. The noble gas cosmic ray exposure age of FRO 01149 is ~ 30 Myr. The meteorite thus belongs to the 33 Myr exposure age peak of H-chondrites.The bedrock surface on which FRO 01149 was found has wet-based glacial erosional features recording a former high-stand of the East Antarctic ice sheet. This ice sheet evidently overrode the highest peaks (> 2800 m a.s.l.) of the inland sector of the Transantarctic Mountains in northern Victoria Land. We argue that FRO 01149 was a local fall and that its survival on a glacially eroded bedrock surface constrains the age of the last overriding event to be older than ~ 3 Myr. The concentrations of in-situ produced cosmogenic 10Be, 26Al and 21Ne in a glacially eroded bedrock sample taken from near the summit of Frontier Mountain yield a surface exposure age of 4.4 Myr and indicate that the bedrock was covered by several meters of snow. The exposure age is also consistent with bedrock exposure ages of other summit plateaus in northern Victoria Land.  相似文献   

15.
In order to better support Antarctic inland ice sheet expedition from Zhongshan Station to Dome A, the topographic data are necessary. At present, although the entire Antarctic DEM provided by RAMP (Radarsat Antarctic Mapping Project) was estimated at the highest horizontal (spatial) resolution of about 200 m, the real horizontal resolution of the DEM varies from place to place depending on the density and scale of the original source data. For ice shelves and the inland ice sheet, the horizontal resolution is about 5 km; the vertical accuracy is estimated to be ±50 m in interior East Antarctic ice sheet and away from the mountain ranges. Therefore, more accurate topographic data are unavailable in Antarctica. In order to meet the requirements of high-accuracy topographic information for further researches, this paper mainly addresses a fusion study of ASTER stereo pairs and ICESat/GLAS altimetry data for extraction of high-accuracy DEM in East Antarctica, based on the high horizontal resolution (15 m) of ASTER and vertical accuracy (13.8 cm) of ICESat/GLAS. First, some altimetry data were selected as vertical control points to reduce errors of image correlation matching during the extraction of ASTER-based DEM. Second, ice sheet altimetry data derived from ICESat were used to generate DEM ranging from 75° to 81°S because existing ASTER data do not cover this area and high density of the coverage of ICESat altimetry data. Finally, the DEM in coverage of the expedition route was produced. The analysis of result reveals that the DEM accuracy is improved significantly. The absolute vertical accuracy of DEM is higher than 15 m in some cases and higher than 30 m for all the areas along the expedition route except from the 009-001 scene; the interior accuracy is higher than 15 m and higher than 7 m in some cases. It can meet the requirements of topographic map at 1:50000 scale, which is an economic and advantageous method to produce the topographic products. Supported by National Natural Science Foundation (Grant No. 40606002), Surveying and Mapping in Chinese Antarctic Expedition Area (Grant No. 1469990711109-1), National Key Technology R & D Program (Grant No. 2006BAD18B01), and GLA12 dataset of ICESat/GLAS in National Snow and Ice Data Center (NSIDC)  相似文献   

16.
Calculations were performed with the Earth system model of intermediate complexity LOVECLIM to study the response of the Greenland and Antarctic ice sheets to sustained multi-millennial greenhouse warming. Use was made of fully dynamic 3D thermomechanical ice-sheet models bidirectionally coupled to an atmosphere and an ocean model. Two 3,000-year experiments were evaluated following forcing scenarios with atmospheric CO2 concentration increased to two and four times the pre-industrial value, and held constant thereafter. In the high concentration scenario the model shows a sustained mean annual warming of up to 10°C in both polar regions. This leads to an almost complete disintegration of the Greenland ice sheet after 3,000 years, almost entirely caused by increased surface melting. Significant volume loss of the Antarctic ice sheet takes many centuries to initiate due to the thermal inertia of the Southern Ocean but is equivalent to more than 4 m of global sea-level rise by the end of simulation period. By that time, surface conditions along the East Antarctic ice sheet margin take on characteristics of the present-day Greenland ice sheet. West Antarctic ice shelves have thinned considerably from subshelf melting and grounding lines have retreated over distances of several 100 km, especially for the Ross ice shelf. In the low concentration scenario, corresponding to a local warming of 3?C4°C, polar ice-sheet melting proceeds at a much lower rate. For the first 1,200 years, the Antarctic ice sheet is even slightly larger than today on account of increased accumulation rates but contributes positively to sea-level rise after that. The Greenland ice sheet loses mass at a rate equivalent to 35 cm of global sea level rise during the first 1,000 years increasing to 150 cm during the last 1,000 years. For both scenarios, ice loss from the Antarctic ice sheet is still accelerating after 3,000 years despite a constant greenhouse gas forcing after the first 70?C140 years of the simulation.  相似文献   

17.
Antarctic tabular icebergs are important active components in the ice sheet-ice shelf-ocean system. Seafloor topography is the key factor that affects the drifting and grounding of icebergs, but it has not been fully investigated. This study analyzes the impact of seafloor topography on the drifting and grounding of Antarctic tabular icebergs using Bedmap-2 datasets and iceberg route tracking data from Brigham Young University. The results highlight the following points. (1) The quantitative distributions of iceberg grounding events and the tracking points of grounded icebergs are mainly affected by iceberg draft and reach their peak values in sea water with depths between 200 m and 300 m. The peak tracking point number and linear velocity of free-drifting icebergs are found in the Antarctic Slope Front (water depth of approximately 500 m). (2) The area of possible grounding regions of small-scale icebergs calved from ice shelf fronts accounts for 28% of the sea area at water depths less than 2000 m outside the Antarctic coastline periphery (3.62 million km2). Their spatial distribution is mainly around East Antarctica and the Antarctic Peninsula. The area of possible grounding regions of large tabular icebergs with long axes larger than 18.5 km (in water depths of less than 800 m) accounts for 74% of the sea area. (3) The iceberg drifting velocity is positively correlated with ocean depth in areas where the depth is less than 2000 m (R=0.85, P<0.01). This result confirms the effect of water depth variations induced by seafloor topography fluctuations on iceberg drifting velocity.  相似文献   

18.
Lambert冰川-Amery冰架系统是南极冰盖最大的冰流系统之一,对南极冰盖物质平衡研究有着重要的作用.数字高程模型(DEM)是进行南极冰盖研究的基础.本文基于CryoSat-2 L1b波形数据,研究建立了Lambert冰川流域高分辨率DEM.测高卫星返回波形在冰盖区域存在变形,需进行波形重跟踪处理.利用交叉点分析方法对重心偏移法(OCOG)、阈值法和β参数法等常用的波形重跟踪方法对不同类型的CryoSat-2波形的适用性进行了研究.最后,利用克里金插值方法建立了500 m分辨率的Lambert冰川流域DEM——LAS DEM (Lambert Glacier-Amery Ice Shelf system DEM).利用ICESat卫星测高数据和GPS地面实测数据对LAS DEM进行精度验证,并与另外两种基于CryoSat-2数据的南极DEM进行了对比.结果表明:LAS DEM的整体精度约为0.295±2.7 m,优于另外两种CryoSat-2 DEM;在冰盖内陆地区,LAS DEM的高程误差在2 m之内;在Amery冰架上,LAS DEM的精度优于1 m.  相似文献   

19.
Abstract

Sudden rapid advances or surges of glaciers and sections of smail ice caps are well known. After remaining dormant or in retreat over long periods of time these ice masses suddenly move forward rapidly with speeds about 2 orders of magnitude greater than usual. If such surges were to occur in large sections of the Antarctic ice sheet serious consequences could result. These include a significant rise of sea level, a substantial increase in the high-albedo ice cover around the continent especially in summer, and a cooling of the Antarctic ocean by the additional ice melting.

A numerical model has now been developed which simulates surging in certain glaciers and ice sheets in an apparently realistic manner. This model has been found to give close representations to a number of existing real surging temperate ice masses from small mountain glaciers to large sectors of ice caps. The model reproduces realistically many features of these ice masses such as the period of the surge, the duration, the velocity of advance, the magnitude of the advance, and the changes in ice thickness.

The application of the model to the Antarctic ice sheet is made more difficult by the problem caused by the temperature dependence of the flow properties of ice. This means that for a complete study the interaction with the environment needs to be considered. However, at this stage preliminary calculations indicate a number of features that are relevant to the effect of Antarctic ice surges on the global climate. These include the period between surges, the duration of the surge, the amount of ice advanced and the changes in thickness of the ice sheet.  相似文献   

20.
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