共查询到20条相似文献,搜索用时 894 毫秒
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研究了新合成的1-(2-羟基-3,5-二硝基苯基)-3-「4-(苯基偶氮)苯基」-三氮烯(HDNPAPT)试剂与铜的显色反应。在乳化剂OP存在下,PH11.0的Na2B4O7-NaOH介质中,铜与HDNPAPT形成的红色配合物,其组成比为1:2,λmax=540nm,表观摩尔吸光系数ε540=1.73×10^5L·mol^-1·cm^-1,铜的质量浓度在0 ̄360μg/L符合比尔定律。方法应用于大 相似文献
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研究了新试剂2,4-二溴-6-羧基苯重氮氨基偶氮苯与Tl(Ⅲ)的高灵敏显色反应。在非离子表面活性剂TritonX-100存在下,于pH10.5的NH_3·H_2O-NH_4Cl缓冲介质中,Tl(Ⅲ’)与该试剂生成红色配合物,其配合物的最大吸收波长位于520nm处,摩尔吸光系数为1.83×10 ̄5L·mol ̄-1·cm ̄-1。Tl(Ⅲ’)量在0~0.64μg/ml范围内符合比尔定律。方法用于废水中痕量Tl的测定,结果与其它方法结果相符。测定工业废水及粉煤灰中痕量Tl的RSD(n=6)在1.6%~3.2%范围。 相似文献
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研究结果表明,在混合表面活性剂CTMAB-吐温-60存在下的pH5.7~6.5的缓冲介质中,Sc(Ⅲ)与4,5-二溴苯基荧光酮(DBPF)形成高灵敏的多元配合物,其ε_(590)=2.26×10 ̄5L·mol ̄(-1)·cm ̄(-1),组成比为:Sc:DBPF:CTMAB=1:2:4。采用混合表面活性剂使增溶增敏作用更为显著,并加速了显色反应,增强了配合物的稳定性。而Na_2SO_4的加入能显著地提高体系的灵敏度。Sc量在0~0.36ug/ml范围内遵守比尔定律。方法可直接测定合成混合稀土中的Sc,回收率在98%~105%;结合沉淀分离和PMBP萃取分离,实现了地质试样中痕量Sc的测定。 相似文献
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痕量银与meso-四(对-磺酸基苯基)卟啉显色反应的研究 总被引:4,自引:0,他引:4
研究了Ag(I)与meso-四(对-磺酸基苯基)叶琳的光催化显色反应。在pHl0的缓冲溶液中形成稳定的Ag(I)-TPPS_4-CTMAB三元配合物,其最大吸收波长为426nm,组成为Ag(1)TPPS_4:CTMAB=1:1:2。表观摩尔吸光系数为2.79×l0 ̄5L·mol ̄-1·cm ̄-1,Ag(1)的浓度在0~0.2μg/ml内符合比尔定律。基于此建立的测Ag(I)方法灵敏度高,结合巯基棉分离干扰,可用于矿物中Ag(I)的测定。 相似文献
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研究了在氯化十六烷基吡啶(CPC)和乳化剂OP存在下,Mg与邻氯苯基荧光酮(o-Cl-PF)的显色反应。在pH12的碱性介质中,Mg(Ⅱ)与o-Cl-PF形成1:3的蓝色配合物,其λ_max=612nm,表现摩尔吸光系数ε_612=1.39×10 ̄5L·mol ̄-1·cm ̄-1,Mg(Ⅱ)在0~0.2μg/ml范围内符合比尔定律。方法用于新陶瓷材料氮化硅(Si_3N_4)中微量MgO的测定,其结果与原子吸收光谱法相符。 相似文献
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邻羟基苯基重氮氨基偶氮苯与铜显色反应的研究及应用 总被引:1,自引:0,他引:1
研究了邻羟基苯基重氮氨基偶氮苯与Cu^2+的显色反应。在乳化剂OP存在下及PH10.0-12.0的Na2B4O7-NaOH缓冲介质中,Cu^2+和o-HDAA形成1“3的红色配合物,其最大吸收波长为546nm,表观摩尔吸光系数4.20*10^4L.mol^-3.cm^-1。 相似文献
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5′-硝基水杨基荧光酮胶束增敏分光光度法测定微量钯 总被引:1,自引:0,他引:1
于pH67~76的磷酸盐缓冲介质中,溴化十六烷基三甲铵存在下,Pd(Ⅱ)与5′_硝基水杨基荧光酮30min内反应完全,生成组成比1∶2的紫红色配合物。λmax=582nm,Δλ=56nm,表观ε为104×105L·mol-1·cm-1,配合物至少稳定36h。测Pd(Ⅱ)的线性范围在0~080mg/L。结合丁二酮肟_氯仿萃取分离,方法可用于试样中微量钯的测定,结果与5_Br_PADAB光度法一致,标准加入回收率为932%~1004%,相对标准偏差为17%(n=10)。 相似文献
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Emily Keeble David I. Whiteside Michael J. Benton 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(2):99-119
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco. 相似文献
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Gilles Serge Odin 《Comptes Rendus Geoscience》2002,334(6):409-414
Lithostratigraphy, physicochemical stratigraphy, biostratigraphy, and geochronology of the 77–70 Ma old series bracketing the Campanian–Maastrichtian boundary have been investigated by 70 experts. For the first time, direct relationships between macro- and microfossils have been established, as well as direct and indirect relationships between chemo-physical and biostratigraphical tools. A combination of criteria for selecting the boundary level, duration estimates, uncertainties on durations and on the location of biohorizons have been considered; new chronostratigraphic units are proposed. The geological site at Tercis is accepted by the Commission on Stratigraphy as the international reference for the stratigraphy of the studied interval. To cite this article: G.S. Odin, C. R. Geoscience 334 (2002) 409–414. 相似文献
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The effect of water on accessory phase solubility in subaluminous and peralkaline granitic melts 总被引:4,自引:0,他引:4
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species. 相似文献
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Muriel Rocher Stéphane Baize Stéphane Jaillet Edward Marc Cushing Yannick Lozach Francis Lemeille 《Comptes Rendus Geoscience》2003,335(8):701-708
Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ1 roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003). 相似文献
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正20141520 Bo Ying(Key Laboratory of Metallogeny and Mineral Assessment,MLR,Beijing 100037,China);Liu Chenglin Saline Spring Hydrochemical Characteristics and Indicators for Potassium Exploration in Southwestern and Northern Tarim Basin,Xinjiang(Acta Geoscientica Sinica,ISSN1006-3021,CN11-3474/P,34(5),2013,p.594-602,5 illus.,3 tables,28 refs.) 相似文献
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正20141243Chen Ge(Hangzhou Research Institute of Petroleum Geology,PetroChina,Hangzhou 310023,China);Si Chunsong Study on Sedimentary Numerical Simulation Method of Fan Delta Sand Body(Journal of Geology, 相似文献
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正20142599Chen Sanming(Guangxi Key Laboratory of Concealed Deposits Exploration,Guilin University of Technology,Guilin541004,China);He Yuzhou Block Model and Reserves Estimation of Panzhihua Iron Deposit Based on 3D Geological Modeling(Journal of Guilin University of Technology,ISSN1674-9057,CN45-1375/N,33(4),2013,p.610-615,9illus.,1table,15refs.) 相似文献
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正20140594 Bai Daoyuan(Hunan Institute of Geology Survey,Changsha 410016,China);Zhong Xiang Faults in the Jingzhou Basin and Their Tectonic Settings(Geotectonica et Metallogenia,ISSN1001-1552,CN44-1595/P,37(2),2013,p.173-183,6illus.,59refs.)Key words:basin evolution,tectonic setting,South China In the Upper Paleozoic and Jurassic se- 相似文献
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正20141912Cao Hui(State Key Laboratory for Continental Tectonics and Dynamics,Institute of Geology,Chinese Academy of Geological Sciences,Beijing 100037,China)Gravitational Collapse and Folding during Orogenesis:A Comparative Study of FIA Trends and Fold Axial Plane Traces(Geology in China,ISSN1000-3657,CN11-1167/P,40(6),2013,p.1818-1828,9illus.,35refs.,with 相似文献