Background deduction of the Chang’E-1 gamma-ray spectrometer data

Gamma-ray spectrometer(GRS) is used to detect the elemental abundances and distributions on the lunar surface.To derive the elemental abundances,it is vital to acquire background gamma rays except lunar gamma rays.So GRS would observe background spectra in the course of earth-moon transfer on schedule.But in fact,GRS was not switched on in the course of flying toward the moon.After the CE-1 probe finished one-year mission,GRS car-ried out a test on background data on November 21?22,2008.The authors did conduct research on the methods of background deduction using 2105 hours of usable gamma-ray spectra acquired at the 200-km orbital height by the GRS and more than 5 hours of gamma-ray spectra acquired in the GRS background test.The final research results showed that the method of deducting the background using the minimum counts in the CE-1 GRS pixels is optimal for the elements,U,K and Th.The method applies to such a case that the elemental abundances in the pixel with the minimum counting rate are 0 μg/g and the continuum background counts are constant over the Moon.Based on the method of background deduction,the full energy peak counts of U,K,and Th are calculated.     

Research on the inversion of elemental abundances from Chang’E-2 X-ray spectrometry data

The elemental abundances of lunar surface are the important clues to study the formation and evolution history of the Moon. In 2010, China＇s Chang＇E-2 （CE-2） lunar orbiter carried a set of X-ray spectrometer （XRS） to investigate the elemental abundances of the lunar surface. During CE-2＇s life span around the Moon, the XRS ex- perienced several events of solar flare. The X-ray solar monitor onboard recorded the spectra of solar X-rays at the same time. In this paper, we introduced the XRS instrument and data product. We analyzed the characteristics of the XRS data. Using the data obtained during an M solar flare event which had occurred on Feb. 16, 201 l, we derived the elemental abundances ofMg, A1, Si, Ca and Fe of the lunar surface in the Oceanus Procellarum. Finally, we dis- cussed the factors that influence the accuracy of the inversion.     

Correlation analysis and partial least square modeling to quantify typical minerals with Chang＇E-3 visible and near-infrared imaging spectrometer＇s ground validation data

In 2013, Chang＇E-3 program will develop lunar mineral resources in-situ detection. A Visible and Near-infrared Imaging Spectrometer （VNIS） has been selected as one payload of CE-3 lunar rover to achieve this goal. It is critical and urgent to evaluate VNIS＇ spectrum data quality and validate quantification methods for mineral composition before its launch. Ground validation experiment of VNIS was carried out to complete the two goals, by simulating CE-3 lunar rover＇s detection environment on lunar surface in the laboratory. Based on the hyperspectral reflectance data derived, Correlation Analysis and Partial Least Square （CA-PLS） algorithm is applied to predict abundance of four lunar typical minerals （pyroxene, plagioclase, ilmenite and olivine） in their mixture. We firstly selected a set of VNIS＇ spectral parameters which highly correlated with minerals＇ abundance by correlation analysis （CA）, and then stepwise regression method was used to find out spectral parameters which make the largest contri- butions to the mineral contents. At last, functions were derived to link minerals＇ abundance and spectral parameters by partial least square （PLS） algorithm. Not considering the effect of maturity, agglutinate and Fe~, we found that there are wonderful correlations between these four minerals and VNIS＇ spectral parameters, e.g. the abundance of pyroxene correlates positively with the mixture＇s absorption depth, the value of absorption depth added as the in- creasing of pyroxene＇s abundance. But the abundance of plagioclase correlates negatively with the spectral parame- ters of band ratio, the value of band ratio would decrease when the abundance of plagioclase increased. Similar to plagioclase, the abundance of ilmenite and olivine has a negative correlation with the mixture＇s reflectance data, if the abundance of ilmenite or olivine increase, the reflectance values of the mixture will decrease. Through model validation, better estimates of pyroxene, plagioclase and ilmenite＇s abundances are given. It is concluded that VNIS has the capability to be applied on lunar minerals＇ identification, and CA-PLS algorithm has the potential to be used on lunar surface＇s in-situ detection for minerals＇ abundance prediction.     

Inversion of the Main Mineral Compositions and Subdivision of Tectonic Units on Lunar LQ-4 based on Chang’e Data

Spectra are sensitive in detecting main minerals on the lunar surface from visible light to infrared light. Since spectral characteristics of minerals are closely related to their compositions and the maturity level of soil on the Moon, studying the compositions and distribution of elements and minerals on the lunar surface can help to understand the evolution of the Moon through remote sensing technology. The correlation between the spectral characteristics of Chang’e-1 interference imaging spectrometry (IIM) reflectance images and the mineral contents of LSCC (Lunar Soil Characterization Consortium) lunar surface mineral samples was discussed and the spatial distributions of FeO and Al2O3 contained in both pyroxene and plagioclase on LQ-4 were studied using the improved angle parameter method, MNF, and band ratio statistics. A comparison of the mapping results of the optical models by Lucey, Shkuractov and other researchers on Clementine and the gamma ray spectrometry data shows that the content error is within 0.6% for lunar mare areas and close to 1% for the highland areas. The tectonic framework on the lunar surface was also investigated. And based on integrated analysis of previous findings on topography of the lunar surface, Chang’e LAM, CCD and LOLA images and the gravity anomalies data (Clementine GLGM-2), the tectonic unit subdivision was established for LQ-4, the idea of subdividing the lunar tectonic units was proposed, and this will provide a good foundation for studying the lunar tectonic evolution.     

Space weathering simulation and spectrum decoding

Visible and near-infrared spectra are routinely used to achieve mineral abundances and mineral chemistry of the global surfaces of the Moon and asteroids.However,these spectra can be significantly modified by space weathering,including micrometeorite impacting,solar wind implanting and cosmic ray irradiation.In this paper we report results of laser-bombarding experiments on the Jilin ordinary chondrite,simulating micrometeorite impacting on the surface of asteroids.After laser bombardment,the spectra became significantly redder and moderately darker. With the Modified Gaussian Model(MGM)method,the absorption band positions of olivine can be decoded from the modified spectra,which are correlated with their fayalite contents.In addition,a continuum of the modified spectra can be decoded,and its slope may be used to depict the degree of space weathering.However,relative strengths of the absorption sub-bands of olivine and pyroxenes show significant variant after the bombardment, hence they cannot be used to estimate the relative abundances of high-Ca to low-Ca pyroxenes of the lunar surface and other matured surfaces of asteroids.     

最大熵谱分析法及其在物探中的应用

Maximum entropy spectral analysis is a method of estimating spectrum which has higher resolution than usual methods of calculating power spectra. Its wide application will provide more useful information for geophysical prospecting. This paper systematically presents the theory and algorithm of the method and the simple case of its application in geophysical data processing. Also, it gives examples to show how maximum entropy spectral analysis method was first used in aeromagnetic data processing.     

Analysis on the sources of mercury in soils in the Chengdu Basin, China

Mercury is a pollutant of concern due to its toxic and bioaccumulative properties. Studies on the distribution and hazard of mercury in the environment are mainly focused on its forms, toxicity and the environment standard, and progresses and results have been achieved. But these studies in the past were concentrated on the scales of laboratory or smaller districts merely, such as a small unit of mineral area, vegetable base, paddy field, lake, etc. Multi-target regional geochemical survey carried out by China Geological Survey from the 1990s to now is a fundamental and commonweal geological survey, large-scale and systematical inquisition and research were conducted in 19 provinces （or municipalities directly under the Central Government） in the eastern overlay region of China, and the purpose is to provide the basic geochemical data for national economic construction, adjustment of industrial and agricultural structures and sustainable social development. Geochemical studies aim at investigating soils in these regions and 52 elements have been tested, producing a great amount of data at the same time. Methods： based on the data from 3061 samples of surface soil and 832 samples of deep soil from the project of multi-purpose geochemical survey in the Chengdu Basin, Sichuan, China, this paper describes the correlation relationship between Hg and other 48 elements and their spatial distribution in surface and deep soils of these areas by applying the method of linear regression and factor analysis.     

The origin and geological significance of lunar ridges

Lunar ridges are a kind of familiar linear structures developed on the lunar surface. The distribution pattern, formation mechanism and research significance of lunar ridges are discussed in this paper. Single lunar ridges are usually distributed in the form of broken lineation, and, as whole, lunar ridges are trapezoidal or annular in shape around the maria. As to the formation mechanism, only volcanism or tectonism was emphasized in the past, but the two processes are seldom taken into combined consideration. On the basis of detailed analyses, the authors thought that tectonism is a prerequisite for the formation of lunar ridges, while volcanism is the key factor controlling their particular shapes. Finally, the authors pointed out that it is very significant in the study of lunar ridges to link the course of lunar structure evolution with the stress state in the lunar crust.     

Precambrian Geochronology, Chronotectonic Framework and Model of Chronocrustal Structure of the Zhongtiao Mountains

The Zhongtiao Mountains, a typical exposure area of Precambrian rocks, are a concentration area of vari-ous types of copper deposit. The rocks were dated using several dating methods. Based on the age data ob-tained by means of three methods, several aspects are dealt with: (1) the dating results obtained by differentmethods and their geological implications have been compared; (2) a chronotectonic framework has been con-structed by means of these reliable ages, which indicates that the ages of the rocks of the Proterozoic mobilebelt fall in a time span of 2400 to 2000 Ma during which global magmatic records are lacking and reflects theages of important events in the mobile belt; (3) according to the ages of inherited zircons, neodymium modelage of the depleted mantle sources (T_(DM)) and geochemical and geological data, a model of Precambrianchronocrustal structure has been constructed, representing a typical for the North China craton.     

Simulation of surface runoff in theWujiang River watershed based on GIS

Surface runoff in the Wujiang River watershed was simulated by a GIS-based method using precipitation, hydrology data, and land-use data. The volume of surface runoff is chiefly controlled by climates, topographical characteristics and types of land use at the watershed. Five subwatersheds that can represent the whole watershed were chosen and their average annual precipitation, average annual surface runoff and current land use were calculated respectively in the grid model of the Wujiang River watershed based on the climate and hydrology data from 1965 to 2000 and the land-use data acquired in the year of 2000. Surface runoff is assumed to be a function of precipitation and land use and the multiple regression tool is used to determine the relationship between surface runoff, precipitation and present land use. Thus, the rainfall-runoff model for each land-use type has been established. When calibrating these models, the results show that the percent errors are all below 7%, which indicates that the accuracy of this simulation is high.     

Reflectance spectrophotometry extended to u.v. for terrestrial,lunar and meteoritic samples

Extension of remote sensing of planetary bodies to the ultraviolet is now feasiable up to 2000 Å from earth-orbiting telescopes and spacecraft. The benefits of this extension is analysed on the basis of laboratory spectra taken on a large variety of terrestrial, lunar and meteoritic samples. Knowledge of the albedo for two wavelengths at 2300 and 6500 Å permits classification of a surface into one of the following types: lunar, carbonaceous chondrites, ordinary chondrites, achondrites or acidic rocks, basaltic rocks, irons. For lunar-type surfaces, a simple albedo measurement at 6500 Å can be converted into quantitative abundance determinations of silicate, aluminium oxide and iron; a large amount of telescopic lunar photometry data is available for mapping these abundances. Extension of the photometry to 2300 Å permits quantitative measurement of TiO₂ abundances. For asteroids and non-icy satellites, rock-type classification and constraints in chemical abundances of Si, Al, Fe and Ti can be derived from photometry at 2300 and 6500 Å. The IUE telescope already orbiting the earth, the Space Telescope to come, the lunar polar orbiter and other spacecraft under prospect are potentially available to provide the photometric observations at 6500 and 2300 Å required.     

The trace of the Pacific‐Cocos‐Nazca triple junction in the Central Pacific and the formation of an overlapping spreading centre

The `plate tectonic mirror image' to the region of the Cocos and Nazca plates, which are currently being subducted beneath Central America, is preserved in the Central Pacific around 120°W just south of the equator. Cruise SO‐180 investigated this remote area during project CENTRAL and acquired new magnetic and bathymetric data. A plate tectonic model for the ‘mirror image’ is presented based on the newly acquired as well as reprocessed existing data. Discordant magnetic anomaly patterns and bathymetric structures indicate at least two major reorganization events (19.5 and 14.7 Myr), which can be detected both in the Cocos‐Nazca spreading system and in the East Pacific Rise. Irregularities in the anomaly pattern and curvilinear structures on the sea floor of the survey area are interpreted in terms of a fossil overlapping spreading centre at the location where the Farallon break‐up originated.     

Calibration of AGRS System Using Transportable Pads in India: An Application to AGRS Data of Aravalli Basin,Banswada Block,South Rajasthan

Calibration of airborne gamma ray spectrometric system (AGRS) over standard radioactive sources of known elemental abundances is essential before carrying out airborne surveys. In India, fixed calibration pads were constructed in 1985. Since then calibration of AGRS system was carried out over the fixed pads. However the fixed pads are expensive to build and maintain. Also the large pads are subject to variations in radiation output due to variable moisture content and radon loss. Alternate approach is to construct transportable calibration pads which are discussed in this paper.Atomic Minerals Directorate for Exploration & Research (AMD) under Department of Atomic Energy has recently constructed five transportable calibration pads. Three pads i.e. K, U and Th have been spiked with the respective radioelements while keeping the minor radioelements to the least in order to obtain pure spectra. A composite pad has been constructed which contains all the three radioelements. This helps in cross verifying the obtained calibration results. A background pad has also been constructed which is helpful to obtain the background values during calibration.Analysis of the data acquired over the transportable pads with airborne gamma ray spectrometer (16.8 ltr) has been carried out and presented in this paper. A comparison with the data acquired over the fixed calibration pads is also included. There is a good agreement of results which suggests the use of transportable pads in future.     

月海盆地线性构造展布及其成因分析

综合多源遥感数据识别提取月球正面南北纬50°之间的线性构造,重点分析月岭和月溪的影像特征、分布规律和时空关系,结合月海沉降模型分析两者的成因机制,结合地形和重力场数据预测影响月岭类型的因素。研究表明,在质量瘤盆地,月岭和月溪存在明显的时空关系和构造成因联系,两者主要由月海沉降产生的局部应力引起,前月海时期盆地的均衡状态和月海充填的几何形状可能影响了月岭的分布类型。     

Meso‐Cenozoic Tectonothermal History of Permian Strata,Southwestern Weibei Uplift: Insights from Thermochronology and Geothermometry

This study provides an integrated interpretation for the Mesozoic-Cenozoic tectonothermal evolutionary history of the Permian strata in the Qishan area of the southwestern Weibei Uplift, Ordos Basin. Apatite fission-track and apatite/zircon(U-Th)/He thermochronometry, bitumen reflectance, thermal conductivity of rocks, paleotemperature recovery, and basin modeling were used to restore the Meso-Cenozoic tectonothermal history of the Permian Strata. The Triassic AFT data have a pooled age of ～180±7 Ma with one age peak and P(χ2)=86%. The average value of corrected apatite(U-Th)/He age of two Permian sandstones is ～168±4 Ma and a zircon(U-Th)/He age from the Cambrian strata is ～231±14 Ma. Bitumen reflectance and maximum paleotemperature of two Ordovician mudstones are 1.81%, 1.57% and ～210°C, ～196°C respectively. After undergoing a rapid subsidence and increasing temperature in Triassic influenced by intrusive rocks in some areas, the Permian strata experienced four cooling-uplift stages after the time when the maximum paleotemperature reached in late Jurassic:(1) A cooling stage(～163 Ma to ～140 Ma) with temperatures ranging from ～132°C to ～53°C and a cooling rate of ～3°C/Ma, an erosion thickness of ～1900 m and an uplift rate of ～82 m/Ma;(2) A cooling stage(～140 Ma to ～52 Ma) with temperatures ranging from ～53°C to ～47°C and a cooling rate less than ～0.1°C/Ma, an erosion thickness of ～300 m and an uplift rate of ～3 m/Ma;(3)(～52 Ma to ～8 Ma) with ～47°C to ～43°C and ～0.1°C/Ma, an erosion thickness of ～500 m and an uplift rate of ～11 m/Ma;(3)(～8 Ma to present) with ～43°C to ～20°C and ～3°C/Ma, an erosion thickness of ～650 m and an uplift rate of ～81 m/Ma. The tectonothermal evolutionary history of the Qishan area in Triassic was influenced by the interaction of the Qinling Orogeny and the Weibei Uplift, and the south Qishan area had the earliest uplift-cooling time compared to other parts within the Weibei Uplift. The early Eocene at ～52 Ma and the late Miocene at ～8 Ma, as two significant turning points after which both the rate of uplift and the rate of temperature changed rapidly, were two key time for the uplift-cooling history of the Permian strata in the Qishan area of the southwestern Weibei Uplift, Ordos Basin.     

Accurate Measurement of Rare Earth Elements by ICP‐MS after Ion‐Exchange Separation: Application to Ultra‐Depleted Samples

This study reports precise and accurate data for rare earth elements (REE) measured on eight geological reference materials, five enriched in REE (BE‐N, BHVO‐2, BR, BR‐24 and RGM‐1) and three very depleted in REE (BIR‐1, UB‐N and DTS‐2). Data were acquired by quadrupole ICP‐MS after isolation of the REE using an ion‐exchange chromatography procedure. All the measured REE abundances were similar within ≈ 5% (10% for the most REE‐depleted sample DTS‐2) to the high‐quality measurements previously published in the literature. We also show that by using an internal Tm spike, the reproducibility of the data was improved to ～ 1%. Applying this technique to the analysis of ultra‐depleted rock samples (sub ng g^?1), we show that significant improvements were obtained relative to the routine trace element measurement method. The chondrite‐normalised patterns were smooth instead of displaying irregularities. Although the classical method gives excellent results on REE‐rich samples, we believe that our technique improves the precision and accuracy of measurements for highly REE‐depleted rocks.     

Determination of Gold in e‐Waste Dust Samples and Geological Matrices by ICP‐MS after Extraction by an HClO4‐HBr‐HI‐Aqua Regia Mixture

This study describes two methods (Procedures‐1 and ‐2) for the direct extraction of Au by an inorganic acid mixture (HClO₄‐HBr‐HI‐aqua regia) from complex sample matrices. Standard PTFE jars at 200 °C were used to decompose test portions of 0.5–1 g, with subsequent precise and accurate analysis by ICP‐MS without any other preconcentration or separation. Procedure‐1 decomposed samples effectively without the necessity of leaching with HF and was developed for dust samples from e‐waste (electronic waste) processing; however, testing on geological reference materials showed very good results. The analyses of replicate decompositions (n = 5) from both procedures yielded very good precision (< 5% RSD) for most of the reference materials. The accuracy achieved was better than ± 10%, with the exception of NIST SRM 2782 data from Procedure‐1. Two unknown samples of dust from e‐waste processing (P‐1 and VM‐1) exhibited elevated concentrations of Au (21.31–61.64 μg g^?1) with precision better than 10% (n = 5). The proposed techniques are simple, sensitive and sparing in the use of chemicals, and are designed for a variety of e‐waste dust samples. No significant influences were observed for the predicted spectral interferences on mass ¹⁹⁷Au.