Effect of seasonal changes in bottom water oxygenation on sediment N oxides and N2O cycling in the coastal upwelling regime off central Chile (36.5°S)

An intensive and seasonal coastal upwelling process, which attains maximal expression during late austral spring and summer, drives well-known changes in organic matter production and, therefore, in O₂ content in the water column. These variables have a concomitant effect on N sediment processes over the continental shelf off central Chile (36.5°S), which, in turn, can affect the , , and N₂O content in the bottom water. Hydrographic characteristics, benthic and fluxes, and denitrification rates were measured from 1998 to 2001 (with at least seasonal frequency). In order to elucidate how benthic N₂O recycling responds to different O₂ and nutrient levels and how it affects the bottom water N₂O content, net N₂O cycling was measured in December 2001 in sediment slurry incubations under different manipulated dissolved O₂ levels (anoxic: 0 μM; hypoxic: 22.3 μM; oxic: 44.6 μM) and without (natural) and with the addition of and (enriched experiments). Dissolved O₂ and contents (and also ) showed clear seasonal patterns according to the oceanographic regime, i.e., from hypoxic waters rich in nutrients during the upwelling season to oxic waters with less nutrient contents during the non-upwelling season. The bottom water, on the other hand, was influenced by benthic organic mineralization, which consumes O₂ as well as other electron acceptor N-species such as . Benthic fluxes (2.62-5.08 mmol m⁻² d⁻¹) were always directed into the sediments, whereas denitrification rates varied from 0.6 to 2.9 mmol m⁻² d⁻¹. N₂O was also consumed at rates of 5.53 and 4.56 μmol m⁻² d⁻¹ under anoxia and hypoxia, but N₂O consumption rates were reduced to almost half under oxic conditions in both natural and a -enriched experiments. With the -enriched experiments, however, N₂O consumption was very high (up to 24.25 μmol m⁻² d⁻¹) under anoxic and hypoxic conditions, suggesting that high levels induce more N₂O reduction to N₂ by denitrification. N₂O production rates were only measured when oxic conditions were observed in the -enriched experiment, suggesting some role of nitrification. Thus, N cycling in the sediments seems to affect the observed , NO²⁻, and N₂O content in the bottom water and, therefore, in the entire water column due to vertical advection associated with coastal upwelling.     

Circulation and transport of water masses in the Lazarev Sea, Antarctica, during summer and winter 2006

The distribution and circulation of water masses in the region between 6°W and 3°E and between the Antarctic continental shelf and 60°S are analyzed using hydrographic and shipboard acoustic Doppler current profiler (ADCP) data taken during austral summer 2005/2006 and austral winter 2006. In both seasons two gateways are apparent where Warm Deep Water (WDW) and other water masses enter the Weddell Gyre through the Lazarev Sea: (a) a probably topographically trapped westward, then southwestward circulation around the northwestern edge of Maud Rise with maximum velocities of about 20 cm s⁻¹ and (b) the Antarctic Coastal Current (AntCC), which is confined to the Antarctic continental shelf slope and is associated with maximum velocities of about 25 cm s⁻¹.Along two meridional sections that run close to the top of Maud Rise along 3°E, geostrophic velocity shears were calculated from CTD measurements and referenced to velocity profiles recorded by an ADCP in the upper 300 m. The mean accuracy of the absolute geostrophic velocity is estimated at ±2 cm s⁻¹. The net baroclinic transport across the 3°E section amounts to 20 and 17 Sv westward for the summer and winter season, respectively. The majority of the baroclinic transport, which accounts for ∼60% of the total baroclinic transport during both surveys, occurs north of Maud Rise between 65° and 60°S.However, the comparison between geostrophic estimates and direct velocity measurements shows that the circulation within the study area has a strong barotropic component, so that calculations based on the dynamic method underestimate the transport considerably. Estimation of the net absolute volume transports across 3°E suggests a westward flow of 23.9±19.9 Sv in austral summer and 93.6±20.1 Sv in austral winter. Part of this large seasonal transport variation can be explained by differences in the gyre-scale forcing through wind stress curl.     

Seasonal cycle of N2O vertical distribution and air-sea fluxes over the continental shelf waters off central Chile (∼36°S)

The continental shelf off central Chile is subject to strong seasonal coastal upwelling and has been recognized as an important outgassing area for, amongst others, N₂O, an important greenhouse gas. Several physical and biogeochemical variables, including N₂O, were measured in the water column from August 2002 to January 2007 at a time series station in order to characterize its temporal variability and elucidate the physical and biogeochemical mechanisms affecting N₂O levels. This 4-year time series of N₂O levels reveals seasonal variability associated basically with hydrographic and oceanographic regimes (i.e., upwelling and non-upwelling). However, a noteworthy temporal evolution of both the vertical distribution and N₂O levels was observed repeatedly throughout the entire study period, allowing us to distinguish three stages: winter/early spring (Stage I), mid-spring/mid-summer (Stage II), and late summer/early autumn (Stage III).Stage I presents low N₂O, the lowest surface saturation ever registered (from 64% saturation) in a period of high O₂, and a homogeneous column driven by strong wind; this distribution is explained by physical and thermodynamic mechanisms. Stage II, with increasing N₂O concentrations, agrees with the appearance of upwelling-favourable wind stress and a strong influence of oxygen-poor, nutrient-rich equatorial subsurface waters (ESSW). The N₂O build-up creates a “hotspot” (up to 2426% N₂O saturation) and enhanced concentrations of (up to 3.97 μM) and (up to 4.6 μM) at the oxycline (4-28 μM) (∼20-40 m depth). Although the dominant N₂O sources could not be determined, denitrification (mainly below the oxycline) appears to be the dominant process in N₂O accumulation. Stage III, with diminishing N₂O concentrations from mid-summer to early autumn, was accompanied by low N/P ratios. During this stage, strong bottom N₂O consumption (from 40% saturation) was suggested to be mainly driven by benthic denitrification.Consistent with the evolution of N₂O in the water column over time, the estimated air-sea N₂O fluxes were low or negative in winter (−9.8 to 20 μmol m⁻² d⁻¹, Stage I) and higher in spring and summer (up to 195 μmol m⁻² d⁻¹, Stage II), after which they declined (Stage III). In spite of the occurrence of ESSW and upwelling events throughout stages II and III, N₂O behaviour should be a response of the biogeochemical evolution associated with biological productivity and concomitant O₂ levels in the water and even in the sediments. The results presented herein confirm that the study area is an important source of N₂O to the atmosphere, with a mean annual N₂O flux of 30.2 μmol m⁻² d⁻¹; however, interannual variability could not yet be properly characterized.     

Regional shape and tectonics of the equatorial East Pacific Rise

The geography of the East Pacific Rise (EPR) between 10°N and 6°S, redetermined by new surface ship surveys, is characterized by long spreading axes orthogonal to infrequent transform faults. Near 2°10N the EPR is intersected by the Cocos-Nazca spreading center at the Galapagos triple junction. The present pattern was established 27-5.5 m.y.b.p. by a complex sequence of rise-crest jumps and reorientations from a section of the Pacific-Farallon plate boundary. Transverse profiles of the rise flanks can be matched by thermal contraction curves for aging lithosphere, except between the triple junction and 4°S, where the east flank is anomalously shallow and almost horizontal. Most sections of spreading axis have the 10–30 km wide, 100–400 m high, axial ridge that is characteristic of fast spreading centers. However, within 60 km of the triple junction the rise crest structure is atypical, with an axial rift valley and elevated rift mountains, despite a spreading rate of 140 mm/yr. With the exception of this atypical section, the bathymetric profile along the spreading axis is remarkably even, with continuous, gentle slopes for hundreds of kilometers between major transform faults, where step-like offsets in axial depths occur. Most of the observations can be accommodated by a model in which the long spreading axes are underlain by continuous crustal magma chambers that allow easy longitudinal flow of magma, and whose size controls the style and dimensions of EPR crestal topography.Contribution of the Scripps Institution of Oceanography, new series.     

The influence of light on nitrogen cycling and the primary nitrite maximum in a seasonally stratified sea

In the seasonally stratified Gulf of Aqaba Red Sea, both release by phytoplankton and oxidation by nitrifying microbes contributed to the formation of a primary nitrite maximum (PNM) over different seasons and depths in the water column. In the winter and during the days immediately following spring stratification, formation was strongly correlated (R² = 0.99) with decreasing irradiance and chlorophyll, suggesting that incomplete reduction by light limited phytoplankton was a major source of . However, as stratification progressed, continued to be generated below the euphotic depth by microbial oxidation, likely due to differential photoinhibition of and oxidizing populations. Natural abundance stable nitrogen isotope analyses revealed a decoupling of the δ¹⁵N and δ¹⁸O in the combined and pool, suggesting that assimilation and nitrification were co-occurring in surface waters. As stratification progressed, the δ¹⁵N of particulate N below the euphotic depth increased from −5‰ to up to +20‰.N uptake rates were also influenced by light; based on ¹⁵N tracer experiments, assimilation of , , and urea was more rapid in the light (434 ± 24, 94 ± 17, and 1194 ± 48 nmol N L⁻¹ day⁻¹ respectively) than in the dark (58 ± 14, 29 ± 14, and 476 ± 31 nmol N L⁻¹ day⁻¹ respectively). Dark assimilation was 314 ± 31 nmol N L⁻¹ day⁻¹, while light assimilation was much faster, resulting in complete consumption of the ¹⁵N spike in less than 7 h from spike addition. The overall rate of coupled urea mineralization and oxidation (14.1 ± 7.6 nmol N L⁻¹ day⁻¹) was similar to that of oxidation alone (16.4 ± 8.1 nmol N L⁻¹ day⁻¹), suggesting that mineralization of labile dissolved organic N compounds like urea was not a rate limiting step for nitrification. Our results suggest that assimilation and nitrification compete for and that N transformation rates throughout the water column are influenced by light over diel and seasonal cycles, allowing phytoplankton and nitrifying microbes to contribute jointly to PNM formation. We identify important factors that influence the N cycle throughout the year, including light intensity, substrate availability, and microbial community structure. These processes could be relevant to other regions worldwide where seasonal variability in mixing depth and stratification influence the contributions of phytoplankton and non-photosynthetic microbes to the N cycle.     

Evolution of the East Pacific Rise at 16°–19° S since 5 Ma: Bisection of overlapping spreading centers by new,rapidly propagating ridge segments

Nearly complete side-scan, bathymetry and magnetic coverage documents the evolution of the geometry of the East Pacific Rise (EPR) between 16° and 19° S since 5 Ma. Lineaments visible in SeaMARC II, H-MR1 and Sea Beam 2000 side-scan data correspond dominantly to normal fault scarps which have developed in the axial region perpendicular to the least compressive stress. Except near overlapping spreading centers (OSCs), the lineament orientations are taken to represent the perpendicular to the instantaneous Pacific-Nazca spreading direction. Their dominant orientation in the axial region is 012°, in good agreement with the prediction of the current model of relative plate motion (DeMets et al., 1994). However, the variations of the lineament azimuths with age show that there has been a small (3°–5°) clockwise change in the Nazca-Pacific relative motion since 5 Ma. There is also a distinct population of lineaments which strike counterclockwise to the ambient orientation. These discordant lineaments form somewhat coherent patterns on the seafloor and represent the past migration tracks of several left-stepping OSCs. Concurrent analysis of these discordant zones and the magnetic anomalies, reveals that up to 1 Ma, the EPR was offset by a few large, left-stepping OSCs. These OSCs were bisected into smaller OSCs by new spreading segments forming within their overlap basins. The smaller OSCs proceeded to migrate rapidly and were further bisected by newly spawned ridge segments until the present staircase of small, left-stepping OSCs was achieved. By transferring lithosphere from one plate to the other, these migration events account remarkably well for the variable spreading asymmetry in the area. Between 16° and 19° S, the present EPR is magmatically very robust, as evidenced by its inflated morphology, the profuse volcanic and hydrothermal activity observed from submerisbles and towed cameras, the geochemistry of axial basalts, and seismic and gravity data. Since 1 Ma, all the OSCs have migrated away from the shallowest, most robust section of the ridge between 17° and 17°30 S, which was previously offset by a large OSC. We propose that the switch from a presumed starved magmatic regime typically associated with large OSCs to the presently robust magmatic regime occurred when the EPR overrode a melt anomaly during its westward migration relative to the asthenosphere. The resulting increase in melt supply at 17°–17°30 S has fed the migration of axial discontinuities for this section of the southern EPR since 1 Ma.     

How tides and river flows determine estuarine bathymetries

For strongly tidal, funnel-shaped estuaries, we examine how tides and river flows determine size and shape. We also consider how long it takes for bathymetric adjustment, both to determine whether present-day bathymetry reflects prevailing forcing and how rapidly changes might occur under future forcing scenarios.Starting with the assumption of a 'synchronous' estuary (i.e., where the sea surface slope resulting from the axial gradient in phase of tidal elevation significantly exceeds the gradient in tidal amplitude ), an expression is derived for the slope of the sea bed. Thence, by integration we derive expressions for the axial depth profile and estuarine length, L, as a function of and D, the prescribed depth at the mouth. Calculated values of L are broadly consistent with observations. The synchronous estuary approach enables a number of dynamical parameters to be directly calculated and conveniently illustrated as functions of and D, namely: current amplitude Û, ratio of friction to inertia terms, estuarine length, stratification, saline intrusion length, flushing time, mean suspended sediment concentration and sediment in-fill times.Four separate derivations for the length of saline intrusion, L_I, all indicate a dependency on (U_o is the residual river flow velocity and f is the bed friction coefficient). Likely bathymetries for `mixed' estuaries can be delineated by mapping, against and D, the conditions L<sub>I</sub>/L<1,E<sub>X</sub>/L<1 (E<sub>X</sub> is the tidal excursion) alongside the Simpson-Hunter criteria D/U<sup>3</sup><50 m<sup>−2</sup> s<sup>3</sup>. This zone encompasses 24 out of 25 `randomly' selected UK estuaries.However, the length of saline intrusion in a funnel-shaped estuary is also sensitive to axial location. Observations suggest that this location corresponds to a minimum in landward intrusion of salt. By combining the derived expressions for L and L_I with this latter criterion, an expression is derived relating D_i, the depth at the centre of the intrusion, to the corresponding value of U_o. This expression indicates U_o is always close to 1 cm s⁻¹, as commonly observed. Converting from U_o to river flow, Q, provides a morphological expression linking estuarine depth to Q (with a small dependence on side slope gradients).These dynamical solutions are coupled with further generalised theory related to depth and time-mean, suspended sediment concentrations (as functions of and D). Then, by assuming the transport of fine marine sediments approximates that of a dissolved tracer, the rate of estuarine supply can be determined by combining these derived mean concentrations with estimates of flushing time, F_T, based on L_I. By further assuming that all such sediments are deposited, minimum times for these deposition rates to in-fill estuaries are determined. These times range from a decade for the shortest, shallowest estuaries to upwards of millennia in longer, deeper estuaries with smaller tidal ranges.     

Continental terrace and Deep Plain offshore central California

Seismic-reflection profile investigations of the California continental terrace and Deep Plain, between 35°N and 39°N, support the hypothesis that the continental shelf and slope consist of alternating blocks of Franciscan and granitic-metamorphic basement overlain by varying thicknesses of younger sediments. North of 37°N, the seismic profiles confirm the distribution of turbidites shown by other workers. A significant proportion of the sediments on the middle and lower continental rise, south of 37°N, appears to be unrelated to the present Monterey deep-sea canyon system.Near 39°N the ridge which forms the topographic axis of the Delgada deep-sea fan consists of a thin cover of acoustically-transparent sediment unconformably overlying a thick sequence of turbidites; the southern part of this ridge is composed of well-defined short reflectors of highly variable dip. The ridge is incised by a steep-walled, flat-floored valley which follows a nearly straight course across its eastern flank. Among possible explanations for this pattern is uplift of the sea floor beneath the ridge.Our data and investigations of others indicate that acoustic basement north of 38°40N is at least 0.5 sec (two-way travel time) shoaler than it is south of Pioneer Ridge; when present, the ridge may represent as much as 0.5 sec additional basement relief. This structural pattern probably does not extend east of 127°40W, although the magnetic expression of the ridge persists to 127°W.Disappearance of the distinctive abyssal hills topography from west to east within the area of investigation usually can be attributed to burial by turbidites. Normal pelagic sediments form a veneer, rarely more than 0.15 sec thick, which conforms with the basement topography; some localities are devoid of discernible sediment.     

Interpolation of TC02 data on a 1° × 1° grid throughout the water column below 500 m depth in the Atlantic Ocean

We have combined the available total CO₂, temperature, salinity and oxygen data from the TTO, SAVE and WOCE programs in the Atlantic Ocean to parameterize TCO₂ below 500 m depth as a function of potential temperature, salinity and apparent oxygen utilization. We then use the Levitus data set of temperature, salinity and oxygen to compute the TCO₂ profiles at the resolution of the Levitus data set on a 1° × 1° grid with a vertical resolution of 33 layers, more densely spaced in the upper 1500 m than below. Depending on the method used to interpolate the data (along isopycnals or vertically by station), the estimated random uncertainty of the computed TC0₂ values in the Atlantic Ocean throughout the water column below the wintertime mixed layer depth ranges from ± 7.1 μmol kg⁻¹ to t 5.9 μmol kg⁻¹.     

The Rodriguez Triple Junction (Indian Ocean): Structure and evolution for the past one million years

The Rodriguez Triple Junction (RTJ) corresponds to the junction of the three Indian Ocean spreading ridges. A detailed survey of an area of 90 km by 85 km, centered at 25°30 S and 70° E, allows detailed mapping (at a scale of 1/100 000) of the bathymetry (Seabeam) and the magnetic anomalies. The Southeast Indian Ridge, close to the triple junction, is a typical intermediate spreading rate ridge (2.99 cm a^-1 half rate), trending N140°. The Central Indian Ridge rift valley prolongs the Southeast Indian Ridge rift valley with a slight change of orientation (12°). The half spreading rate and trend of this ridge are 2.73 cm a^-1 and N152° respectively. In contrast, the Southwest Indian Ridge close to the triple junction is expressed by two deep-valleys (4300 and 5000 m deep) which abut the southwestcrn flanks of the two other ridges, and appears to be a stretched area without axial neovolcanic zone. The evolution of the RTJ is analysed for the past one million years. The instantaneous velocity triangle formed by the three ridges cannot be closed indicating that the RTJ is unstable. A model is proposed to explain the evolution of the unstable RRF Rodriguez Triple Junction. The model shows that the axis of the Central Indian Ridge is propressively offset from the axis of the Southeast Indian Ridge at a velocity of 0.14 cm a^-1, the RTJ being restored by small jumps. This unstable RRF model explains the directions and offsets which are observed in the vicinity of the triple junction. The structure and evolution of the RTJ is similar to that of the Galapagos Triple Junction located in the East Pacific Ocean and the Azores Triple Junction located in the Central Atlantic Ocean.     

Morphotectonics, Volcanism and Hydrothermal Activity on the East Pacific Rise between 21°12′ S and 22°40′ S

The morphotectonic setting of the East Pacific Rise (EPR) between21°12 and 22°40 S and its recent and past hydrothermalactivity were the focus of the Russian R/V Geolog Fersmans expeditionin 1987–1988.The EPR axial zone in the study area is comprised of three segmentsseparated by overlapping spreading centers (OSCs) near 21°44 and22°08 S. The northern segment is the shallowest of three and hasa distinct massive axial ridge, trapeziodal in cross-section, toppedby a very wide flat summit surface and cut by a well-developedcentral graben. These features testify to intense magmatism and to avoluminous crustal magmatic chamber underlying the whole segment.Fine-scale segmentation is most clearly revealed in the structure ofthe central graben within which several 4th-order segments can bedistinguished. This scale of segmentation is also reflected on flanks of theaxis by variations in the character and intensity of faulting.According to structural and petrologic data, the magmatism is mostintense in the central part of the segment which is probably locateddirectly over a magmatic diapir supplying the melt to the whole segment.Magma migration at the subcrustal level from the center towards the ends ofthe segment with discrete injection into the crustal magmatic chamber ispresumed.The central segment is broken into two morphologically distinct partsseparated by a deval. In the subsided northern part, the wide summit of theaxial ridge is cut by a well-developed, intensely fractured axialgraben. In the southern part, the axial ridge is relatively elevated, butnarrow with an ephemeral graben along its crest. The character and intensityof faulting on the axial flanks are also considerably different in thenorthern and southern parts of the segment. Thus, the magmatic supply tothese two parts is thought to originate from two different sources. If so,then at present the magma chamber underlying the southern part of thesegment is probably at the stage of replenishment, while in the north it isat the stage of deep cooling.The southern segment is structurally similar to the central one. Howeverthere is considerably less intensive magmatic activity in this region,especially south of 22°30 S where the axial ridge is narrow, andtriangular in cross-section.Both OSCs studied are marked by abrupt narrowing and sharp subsidence ofthe tips of axial ridges within the northern limbs. The southern OSC limbsare morphologically similar to normal sections of axial ridges. In bothcases the flanks are structurally and morphologically disrupted adjacent tothe OSCs and oblique structures can be traced far southward of the OSCflanks. Due to the spatial position of oblique structures on the the flanksit is presumed that the OSC near 22°07 S is migrating northward.The 21°44 S OSC zone has apparently undergone small spatialoscillations. In spite of the small amplitude of lateral displacement, thiszone is marked by prominent bathymetric anomalies.Numerous massive sulfide deposits were discovered atop the axial ridgealong the entire length of the uplifted and hydrothermally active northernsegment. Ore metal concentrations in near-bottom waters are maximumover the southern part of the northern segment, while maximum concentrationsof the same metals in surficial sediments are confined to the central partof the same segment. We surmise that there has been a recentalong-axis shift of the zone of maximum hydrothermal activity fromthe middle of the segment to its present position in the southern part ofthe segment. Considering sedimentation rates, the age of this shift can beapproximately estimated to be 5 to 10 thousand years before the present.The relatively Mg-enriched basalts of the middle part of thenorthern segment represent a tike of a more primitive pattern, while therelatively Fe-rich rocks of its southern part probably reflect alarge degree of fractionation at shallow crustal levels. Considering thistrend, in addition to morphotectonic data we presume that subaxial magmaflow from the middle to the southern part of the segment is responsible forthe along-axis shift of hydrothermal activity.In the central segment of the study area, massive sulfides have only beendiscovered south of the 21°55 S deval, where the axial ridgeshoals and where the existence of a subjacent magma chamber is presumed.The very weak manifestations of recent volcanism within the southernsegment explain the absence of hydrothermal activity and sulfide depositswithin this segment.     

Tectonics of a fast spreading center: A Deep-Tow and sea beam survey on the East Pacific rise at 19°30′ S

Sea Beam and Deep-Tow were used in a tectonic investigation of the fast-spreading (151 mm yr^-1) East Pacific Rise (EPR) at 19°30 S. Detailed surveys were conducted at the EPR axis and at the Brunhes/Matuyama magnetic reversal boundary, while four long traverses (the longest 96 km) surveyed the rise flanks. Faulting accounts for the vast majority of the relief. Both inward and outward facing fault scarps appear in almost equal numbers, and they form the horsts and grabens which compose the abyssal hills. This mechanism for abyssal hill formation differs from that observed at slow and intermediate spreading rates where abyssal hills are formed by back-tilted inward facing normal faults or by volcanic bow-forms. At 19°30 S, systematic back tilting of fault blocks is not observed, and volcanic constructional relief is a short wavelength signal (less than a few hundred meters) superimposed upon the dominant faulted structure (wavelength 2–8 km). Active faulting is confined to within approximately 5–8 km of the rise axis. In terms of frequency, more faulting occurs at fast spreading rates than at slow. The half extension rate due to faulting is 4.1 mm yr^-1 at 19°30 S versus 1.6 mm yr^-1 in the FAMOUS area on the Mid-Atlantic Ridge (MAR). Both spreading and horizontal extension are asymmetric at 19°30 S, and both are greater on the east flank of the rise axis. The fault density observed at 19°30 S is not constant, and zones with very high fault density follow zones with very little faulting. Three mechanisms are proposed which might account for these observations. In the first, faults are buried episodically by massive eruptions which flow more than 5–8 km from the spreading axis, beyond the outer boundary of the active fault zone. This is the least favored mechanism as there is no evidence that lavas which flow that far off axis are sufficiently thick to bury 50–150 m high fault scarps. In the second mechanism, the rate of faulting is reduced during major episodes of volcanism due to changes in the near axis thermal structure associated with swelling of the axial magma chamber. Thus the variation in fault spacing is caused by alternate episodes of faulting and volcanism. In the third mechanism, the rate of faulting may be constant (down to a time scale of decades), but the locus of faulting shifts relative to the axis. A master fault forms near the axis and takes up most of the strain release until the fault or fault set is transported into lithosphere which is sufficiently thick so that the faults become locked. At this point, the locus of faulting shifts to the thinnest, weakest lithosphere near the axis, and the cycle repeats.     

Anthropogenic carbon in the East Greenland Current

Sections of dissolved inorganic anthropogenic carbon () based on 2002 data in the East Greenland Current (EGC) are presented. The has been estimated using a model based on optimum multiparameter analysis with predefined source water types. Values of have been assigned to the source water types through age estimations based on the transit time distribution (TTD) technique. The validity of this approach is discussed and compared to other methods. The results indicated that the EGC had rather high levels of in the whole water column, and the anthropogenic signal of the different source areas were detected along the southward transit. We estimated an annual transport of with the Denmark Strait overflow (σ_θ > 27.8 kg m⁻³) of ∼0.036 ± 0.005 Gt C y⁻¹. The mean concentration in this density range was ∼30 μmol kg⁻¹. The main contribution was from Atlantic derived waters, the Polar Intermediate Water and the Greenland Sea Arctic Intermediate Water.     

Structure and topography of the Siqueiros transform fault system: Evidence for the development of intra-transform spreading centers

The Siqueiros transform fault system, which offsets the East Pacific Rise between 8°20N–8°30N, has been mapped with the Sea MARC II sonar system and is found to consist of four intra-transform spreading centers and five strike-slip faults. The bathymetric and side-looking sonar data define the total width of the transform domain to be 20km. The transform domain includes prominent topographic features that are related to either seafloor spreading processes at the short spreading centers or shearing along the bounding faults. The spreading axes and the seafloor on the flanks of each small spreading center comprise morphological and structural features which suggest that the two western spreading centers are older than the eastern spreading centers. Structural data for the Clipperton, Orozco and Siqueiros transforms, indicate that the relative plate motion geometry of the Pacific-Cocos plate boundary has been stable for the past 1.5 Ma. Because the seafloor spreading fabric on the flanks of the western spreading centers is 500 000 years old and parallels the present EPR abyssal hill trend (350°) we conclude that a small change in plate motion was not the cause for intra-transform spreading center development in Siqueiros. We suggest that the impetus for the development of intra-transform spreading centers along the Siqueiros transform system was provided by the interaction of small melt anomalies in the mantle (SMAM) with deepseated, throughgoing lithospheric fractures within the shear zone. Initially, eruption sites may have been preferentially located along strike-slip faults and/or along cross-faults that eventually developed into pull-apart basins. Spreading centers C and D in the eastern portion of Siqueiros are in this initial pull-apart stage. Continued intrusion and volcanism along a short ridge within a pull-apart basin may lead to the formation of a stable, small intra-transform spreading center that creates a narrow swath of ridge-parallel structures within the transform domain. The morphology and structure of the axes and flanks of spreading centers A and B in the western and central portion of Siqueiros reflect this type of evolution and suggest that magmatism associated with these intra-transform spreading centers has been active for the past 0.5–1.0 Ma.