Postsedimentary lithogenesis of terrigenous complexes in fold systems: Rock fabric and cleavage

The simplest intergranular cleavage and foliation of clayey rocks are typical of postsedimentary lithogenesis of folded terrigenous complexes at passive continental margins if the rocks do not contain metamorphic minerals. Cleavage zones coincide with metagenesis (anchimetamorphism) zones. Cleavage is often superimposed on the rock fabric formed in the process of subsidence lithogenesis (e.g., in the Verkhoyansk terrigenous complex). In other cases, cleavage in terrigenous rocks is regarded as the final stage of the development of their microfabric formation related to folding (e.g., Jurassic sequence of southern Dagestan).     

The K–Ar and Rb–Sr Isotopic Systems in Rocks from the Jurassic Terrigenous Complex of the Greater Caucasus

The behavior of K–Ar and Rb–Sr isotopic systems in clayey rocks from the Jurassic terrigenouis complex of the Greater Caucasus sampled along the Terek River is discussed. It is shown that the rocks experienced intense postdiagenetic alterations accompanied by substantial changes in mineral composition and K–Ar and Rb–Sr isotopic systems. Lateral stress is the leading factor responsible for secondary mineral and geochemical transformations of rocks in cleavage zones. Rejuvenation of the radiological age of rocks, relative to their stratigraphic age, is 100 Ma and more. The age estimate of approximately 50 Ma obtained for samples from the southern limb of the anticlinorium reflects the Paleocene–Eocene phase of tectonic activity manifested in both the Caucasus and other areas of the Mediterranean foldbelt.     

Stages of the Epigenetic Alteration of Upper Precambrian Rocks from the Central East European Platform: Evidence from Rb–Sr and K–Ar Isotope-Geochemical Investigations

Results of K–Ar measurements in Upper Vendian–Lower Cambrian clayey rocks drilled in the Gavrilov Yam area are considered. Combined with earlier Rb–Sr measurements, they suggest that the examined rocks experienced several stages of epigenetic alteration. One of these stages registered by Rb–Sr and K–Ar geochronometers is related to events that occurred 650 ± 50 Ma ago. Another stage (390 Ma) registered only by the Rb–Sr geochronometer was related to Hercynian activation in the East European Platform. Probable causes responsible for different behaviors of Rb–Sr and K–Ar systems during the epigenetic rock transformation are discussed. The measured age exceeds the value obtained for the same rocks by stratigraphic methods.     

Rb-Sr and K-Ar indicators of the transformation of precambrian clayey rocks in the East European Platform

Rb-Sr and K-Ar characteristics of Vendian and Upper Riphean sections in various structural units of the East European Platform are studied. It is shown that Neoproterozoic clayey rocks of the platform underwent postsedimentary transformations, primarily owing to processes of K accumulation (illitization). Their intensity decreases with depth and isotopic signatures of provenance rocks are partly retained in Riphean rocks. Stages of the most active transformations approximately 400 and 600 Ma ago are manifested in the Vendian clayey rocks. Events of approximately 1000 Ma ago are recorded in Riphean rocks of the East European Platform. The least altered rocks of the Pachelma aulacogen can retain ancient hydrocarbon pools.     

Rb-Sr geochronology of Vendian shales,the Staraya Rechka Formation,Anabar Massif,northern Siberia

Fine-grained clayey subfractions (SF) with particle sizes of 1–2, 0.6–1.0, 0.3–0.6, 0.2–0.3, 0.1–0.2, and <0.1 μm were extracted from shales of the Vendian Staraya Rechka Formation in the Anabar Massif and studied by XRD and Rb-Sr methods. All the clayey subfractions are represented by illite with high crystallinity indices, which are characteristic of the low-temperature diagenesis/catagenesis zone and grow with the decrease of the particle size. The Rb-Sr systematics in clayey subfractions combined with mineralogical data provide grounds for the conclusion that illite from clayey rocks of the Staraya Rechka Formation was forming during two periods: approximately 560 and 391–413 Ma ago. The first illite generation was likely formed in the course of lithostatic subsidence of the Staraya Rechka sediments and the second one, during the Devonian lithogenesis stage. It is assumed that age of the first generation (∼560 Ma) is close to that of the Staraya Rechka Formation. This inference is consistent with biostratigraphic, chemostratigraphic, and geochronological data obtained for both rocks of the Anabar Massif and Vendian sediments from other regions of Siberia.     

Cretaceous Rocks of the Penzhina Bay: Mineralogy,Petrography, and Geodynamic Sedimentation Conditions

Cretaceous sedimentary and volcanosedimentary rocks from northwestern Kamchatka are considered. The stadial analysis has revealed variable impacts of three major provenances upon the Cretaceous Penzhina sedimentary basin. The provenances were composed of volcanic and volcanosedimentary rocks (Uda–Murgal island arc and Okhotsk–Chukotka volcanic belt) and granitic–metamorphic rocks (the mature Asian continental margin). Sediments were largely accumulated owing to the erosion of island-arc volcanics during reactivation of the Uda–Murgal island arc (Hauterivian–Barremian) or the Okhotsk–Chukotka volcanic belt (middle Albian–Cenomanian). Eroded granitic–metamorphic rocks of the mature Asian continental margin (Berriasian–Valanginian) or Asian metamorphic–volcanic rocks (Santonian–Campanian) were supplied to the basin during tectonically quiet periods (Berriasian–Valanginian and late Cenomanian–Campanian). Compositional changes in provenances were related to active tectonic processes at the continental margin, including evolution and closure of the Uda–Murgal island-arc system and origin of the Okhotsk–Chukotka volcanic belt. The postsedimentary modification of Cretaceous rocks deposited in forearc trough beyond the tectonically active accretionary prism is characterized by a low degree of clastic component alteration.     

Epigenesis of Middle Riphean Rocks in the Bashkir Meganticlinorium,Southern Urals: Timing of Alterations and Geological Implications

The Rb–Sr and K–Ar characteristics of whole-rock argillite samples from the Middle Riphean Yurmatinian Group have been studied. The timing of final rock alteration was estimated at 525 ± 30 Ma by the Rb–Sr geochronometer. In the section near the Bol'shoi Avzhyan Settlement, the rocks experienced alteration up to the stage of deep epigenesis. The K–Ar data indicate that rock alterations continued after the Rb–Sr system conservation and was accompanied by a gradual gain of K. The great temporal gap between alterations of Middle and Lower Riphean rocks was established in the southern Urals. This gap may be explained either by the affiliation of sampled rocks to different tectonic units or by principal errors in stratigraphic correlations.     

Some geochemical aspects of tin mineralization in the Tasman Geosyncline

Differentiation analysis using Köhler-Raaz indices has been applied to 284 granitic rocks from various parts of the Tasman Geosyncline in Queensland, New South Wales, Victoria and Tasmania. It was found that the majority (about 80%) of rocks known to be associated with tin mineralization (mostly leucocratic granites and adamellites) have a well defined range of Köhler-Raaz indices (qz=60–70%, F=20–25%, fm=5–15%) in agreement with findings in other parts of the world. Rocks associated with cassiterite deposits usually have a higher tin content than those not carrying cassiterite — but this information has to be used with caution because the form of tin in the rock (i. e. as an economic mineral e. g. cassiterite or in a host mineral, e. g. in biotite) is determined by several factors. All these factors (geochemical, physicochemical and geological) must be considered in an integrated approach to exploration for new tin deposits.     

Strike-slip fault-propagation cleavage in carbonate rocks: the Mattinata Fault Zone, Southern Apennines, Italy

Disjunctive, spaced solution cleavage in carbonate rocks is genetically associated with the propagation of the left-lateral, strike-slip Mattinata Fault in the Gargano Promontory, Italy. Typical cleavage development is restricted within the 200–300-m wide fault zone, which is bounded by virtually unfractured wall rocks. The cleavage consists of sub-parallel solution surfaces, which are often reactivated as sheared solution planes. Geometrical and kinematic relationships exist between the fault and the associated cleavage planes, thus: (1) cleavage–fault intersection lines lie parallel to the fault and the sheared cleavage rotational axes and (2) the cleavage–fault angle is almost constantly equal to 40°. A model for the development of the Mattinata Fault is proposed in which the cleavage surfaces are interpreted as fault-propagation deformations. Cleavage nucleates as solution planes at the front of the advancing fault as the result of stress concentration in this region. Two distinct, time-sequential processes are shown to operate during the fault propagation: (1) typical millimetre- to centimetre-spaced solution surfaces form in the distal tip zone of the advancing fault plane; (2) as the tip advances, the fault plane breaks through the cleavage as minor shear displacements reactivate some of these nascent surfaces. These observations may prove useful in understanding mechanisms for fault-controlled enhanced/reduced permeability and fluid pathways.     

Along-arc lateral variation of Rb−Sr and K−Ar ages of Cretaceous granitic rocks in Southwest Japan

Cretaceous granitic rocks were emplaced over a distance of 700 km along arc in Southwest Japan. Rb–Sr and K–Ar ages of a major group of these granitic rocks, with ilmenite series ore mineralogy, were examined. Rb–Sr whole rock ages of 92.8±4.0 Ma and Rb–Sr and K–Ar biotite ages of 80–88 Ma were obtained on one group of these granitic rocks from Kamo-Sera area of central Hiroshima Prefecture. The K–Ar ages of various minerals, combined with the Rb–Sr whole-rock age, give a smooth cooling curve, which suggests a 5 to 10 Ma time-lag between intrusion and cooling at 300° C for the Cretaceous granitic rocks. The Rb–Sr whole-rock and Rb–Sr/K–Ar biotite ages of these granitic rocks become younger eastward along the Southwest Japan arc, and the time-lag between the two systems remains constant at 5 to 10 Ma over the entire area. The along-arc age variation does not support the genetical relationship of the Cretaceous granitoids with steady-state subduction. The Cretaceous granitic province at the eastern margin of Eurasian continent was, at least partly, formed by an episodic event such as ridge subduction.     

Isotope Evidences of the Paleozoic Stage of Epigenetic Transformation of Vendian Sediments of the Russian Platform

The Rb–Sr characteristics of whole-rock samples of Upper Vendian clayey rocks recovered by Gavrilov-Yam boreholes are studied. The Rb–Sr age versus sampling depth relationship has been revealed. Three sample assemblages are identified. The errorchron relationship of samples in the first interval (1760–2400 m) fits the age of 390 ± 40 Ma corresponding to the initial Hercynian history characterized by the transformation of platformal sediments. The other two assemblages (2410–2525 and 2528–2560 m) make up isochrons with slopes corresponding to 590 ± 50 and 690 ± 10 Ma, respectively. Their geochronological meaning is unclear.     

Structural-morphological features of kaolinite from clayey rocks subjected to different stages of lithogenesis: Evidence from the Voronezh anteclise

This paper reports the results of precision structural-morphological study of kaolinite from clayey rocks taken in various areas of the Voronezh anteclise subjected to different stages of lithogenesis: primary kaolins of the weathering crust, proluvial-talus and lacustrine secondary kaolins, as well as lacustrine-swampy fireproof and deltaic-lagoonal refractory clays. The clayey material was transported over more than 300 km. The formation of the fireproof and refractory kaolin deposits in the Voronezh anteclise was related to the Devonian and Early Cretaceous stages of the geological evolution of the region. In terms of spatiotemporal and facies features, the studied genetic series of the kaolin clay deposits is unique. It was established that the sequential structural-morphological evolution o kaolinite in the considered deposits was caused by its mechanical disintegration during transport and redeposition. Interrelation between organic and mineral matters in the fireproof clays was revealed for the first time. Experimental studies of the behavior of kaolinite during sequential grinding and heating confirmed the main reasons for its natural degradation. The formation of virtually monomineral kaolin clays was provoked by the “flow-through” diagenesis, which is similar to weathering in trend. Evolution of mineral matter of the considered genetic series in kaolinite clay deposits was accompanied by the increase of δ¹⁸O values and their dispersion. Peculiarities identified in the behavior of kaolinite and related oxygen isotope characteristics of different-aged denudation and redeposition products of the Devonian weathering crust can play an indicator role in studying different stages of the lithogenesis of clayey rocks.     

Organic Carbon versus Major Elements Relationship in Rocks of the Bazhenov Formation,Western Siberia

A close relation of the organic carbon (C_org) content with major has been established for rocks of the Upper Jurassic–Lower Cretaceous Bazhenov Formation. Applying the method of multiple linear regression, it has been demonstrated that the C_orgcontent in rocks of the Bazhenov Formation is stringently controlled by its bulk chemical composition. This inference is consistent with the existing ideas regarding a close interrelation between the following main components of rocks: organic carbon and authigenic quartz formed on remains of Radiolaria; pyrite formed in a highly reducing medium of C_org-rich sediments; and terrigenous clayey material diluting the authigenic siliceous–carbonaceous–pyritic matrix. These components chiefly determine the spectrum of major elements in the Bazhenov Formation. The establishment of the close relation between the C_orgcontent and the group of major elements refutes the suggestion of some authors that siliceous material was supplied to nonlithified sediments of the Bazhenov sea by hydrothermal solutions, because this mechanism would have inevitably upset geochemical relations between elements in the studied rocks.     

Cenozoic lithogenesis in the Baikal rift zone

New data on the geological history and Cenozoic lithogenesis in depressions of the Baikal rift zone are considered with areas adjacent to Lake Baikal as example. In this region, rifting developed during the plain (Late Oligocene?Early Pliocene) and orogenic (Late Pliocene?Holocene) stages and was accompanied by the accumulation of plain coaliferous fan and orogenic molasses formations, respectively. The examination of Quaternary sequences in the Baikal region reveals that deposition and postsedimentary transformations of riftogenic sediments were intensely influenced by deep-seated water sources of the so far undivided stratal?infiltration, elision, and exfiltration types, according to the classification in (Kislyakov and Shchetochkin, 2000). Deep processes in this region determined the elevated heat flow, volcanism, and extensive discharge of hydrothermal solutions and gas fluids. In our opinion, gaseous?hydrothermal activity stimulated the formation of hydrothermal?sedimentary rocks (dolomitic and calcitic travertines, geyserites, aluminosulfates), the accumulation of diatomaceous and carbonaceous oozes in Baikal, and the formation of a large methane gas hydrate deposit.     

Carbon,oxygen, and sulfur isotope compositions and model of the Silurian rock formation in northwestern Belarus

The paper describes the results of study of the Silurian clayey–carbonate rocks ranging from the Telychian Stage (Llandovery) to the Gorstian Stage (Ludlow) recovered by the Borehole Davtyuny 3k in northwestern Belarus. Rocks of the Sheinwoodian Stage demonstrate a positive excursion of δ¹³C with amplitude of 4.7‰, marking the Ireviken biotic event recorded in the global chemostratigraphic curve. Values of δ¹⁸O for the carbonate material in the studied section (25.5–29.2‰ SMOW) are close to those for Silurian rocks from the Baltic region, Scandinavia, Ukraine, Poland, and Canada. The whole section contains postsedimentary gypsum as nodules and the infilling of fissures and fenestrae. Values of δ³⁴S in gypsum (21.3–26.7‰ CDT) are close to those for the Silurian rocks on the Phanerozoic isotope plot. The formation of gypsum was related to a partial development of the supralittoral environment over the sublittoral and littoral clayey–carbonate substrate. The seawater accumulated in lowlands of the supralittoral plain after storms was intensely concentrated during arid conditions and accumulated in the clayey–carbonate sediment. The subsequent underground evaporation promoted the formation of gypsum as nodules in the unlithified sediments and the infilling of fissures and fenestrae in the lithified rocks.     

Glauconite at Different Stages of Lithogenesis in Lower Cambrian Rocks of Western Lithuania

It is shown that glauconite was mainly formed under diagenetic conditions in terrigenous–clayey rocks (Rausven Unit) of the Lower Cambrian Virbalis Formation in western Lithuania. This was preceded by bioturbation at some levels of geological column and local short-term reworking at other levels. Different forms of glauconite and its interrelation with ambient minerals in diagenesis and epigenesis are considered. A two-phase micaceous (glauconite–illite) composition of globules has been revealed and crystallochemical characteristics of each phase is presented.     

Nanodiamond Formation at the Lithogenesis and Low-Stages of Regional Metamorphism

Samples of gilsonite from Adzharia, anthraxolite and graphite of coal from Taimyr, shungite from Karelia, and anthracite from Donbass are studied using Raman spectroscopy. Peaks at 1600 cm^?1, indicating the presence of nanographite, are recorded in all samples. The anthracite sample from Donbass, 1330 cm^?1, corresponds to the sp³-line of carbon hybridization conforming to a nanodiamond. It is concluded that in nature diamonds can be formed at late stages of lithogenesis (catagensis, metagenesis), and for coals, it can occur at the zeolite stage of regional metamorphism of rocks, before the green schist stage.     

K-Ar ages of the metamorphic sole of the Semail Ophiolite: implications for ophiolite cooling history

K–Ar ages have been determined on micas and hornblendes in the basal metamorphic sequence and in metamorphic rocks squeezed into the mantle sequence of the Semail Ophiolite. The hornblende ages of 99±0.5 and 102±0.8 Ma and the 90 Ma ages of coexisting micas from the high-grade metamorphic portion of the sequence are interpreted as cooling stages following the peak of metamorphism (T 800–850° C, P 6.5–9 kbar). The new pressure estimates are based on findings of kyanite in garnet-amphibolite and cordierite in quartzitic rocks. These data indicate a cooling rate of 10–30° C/Ma. The oldest mica ages of 95±1 Ma are observed in the lowest-grade greenschists. These also largely represent cooling ages, but might in part also include formation ages. The pattern of the muscovite ages across the metamorphic sole indicates that the cooling front moved from the low-grade metamorphic zone, through the high-grade rocks and into the base of the overlying ophiolite. Radiometric ages of hornblendes (92.3±0.5 and 94.8±0.6 Ma) indicate that the crustal gabbro sequence cooled below 500° C later than the base of the ophiolite sequence. Metamorphism of the sole rocks occurred during subduction of oceanic sediments and volcanic or gabbroic rocks as they progressively came into contact with hotter zones at the base of the overriding plate. The peak of metamorphism must have been contemporaneous with the main magmatism in the Semail Ophiolite. One of the dated muscovites yields an age of 81.3±0.8 Ma, but this is related to discrete deformation zones that were active during late-stage emplacement of the ophiolite.     

Caledonian Cyclic Unit in the Vendian–Lower Paleozoic Succession of the Ishim–Karatau Lithostructural Zone (Kazakhstan)

The lithofacial study of Vendian–Lower Paleozoic sedimentary sequences of the Greater Karatau and Baikonur synclinorium, which are the constituents of the Ishim–Karatau lithostructural zone, revealed that Vendian, Cambrian, and Ordovician rocks form a continuous succession composing the Caledonian cyclic unit. In duration (220–240 Ma), the latter corresponds to a megacycle. The cyclic unit consists of the transgressive and regressive parts. The upper part of the transgressive succession includes facies of the continental slope, slope foot, near-continental area, and transitional zone between the near-continental and pelagic areas of the abyssal plain. It is shown that an avalanche sedimentation of the second global level occurred twice during the transgressive and regressive phases. The formation of transgressive facies was related to the extension regime during the basin opening, whereas regressive facies accumulated under the compression regime. The Ishim–Karatau zone is located in the western, outer part of Caledoninian structures in Kazakhstan. The Caledonian cyclic unit formed on the Vendian–Early Paleozoic Atlantic-type margin of the Kazakhstan microcontinent. Specific features of the cyclic development of mobile areas are outlined.