云南六合正长斑岩中花岗岩包体锆石U-Pb定年及其地质意义

滇西地区沿金沙江-哀牢山断裂带广泛发育新生代富碱斑岩,其中六合富碱斑岩中发现了与镁铁-超镁铁质深源包体紧密共生的花岗岩包体。本文对花岗岩包体中锆石进行了阴极发光图像、LA-ICP-MS微量元素分析和U-Pb定年研究。研究表明,该花岗岩包体中锆石可分为岩浆锆石、老核新壳的复合岩浆锆石和变质交代成因锆石;复合岩浆锆石的新壳206Pb/238U平均加权年龄为39.2±2Ma,代表花岗岩包体的成岩年龄,与寄主富碱斑岩的成岩年龄基本一致;复合岩浆锆石的老核206Pb/238U平均加权年龄为828.1±7.1Ma,代表基底岩石年龄。变质锆石的206Pb/238U平均加权年龄为108.4±4.4Ma,与角闪石化金云石榴透辉岩中角闪石Ar-Ar年龄102.87±1.19Ma基本吻合,代表地幔流体交代矿物的结晶年龄,表明地幔流体交代作用过程可能在白垩纪前后延续一个相当长的时期。结合岩相学研究,认为该花岗岩包体被捕获运移时处于熔融态;花岗质熔浆的形成很可能与地幔流体作用引发的地壳部分熔融与壳幔岩浆混合作用密切相关。     

云南六合富碱斑岩中花岗岩包体锆石U-Pb定年及其地质意义

滇西地区沿金沙江-哀牢山断裂带广泛发育新生代富碱斑岩,其中六合富碱斑岩中发现了与镁铁-超镁铁质深源包体紧密共生的花岗岩包体.本文对花岗岩包体中锆石进行了阴极发光图像、LA-ICP-MS微量元素分析和U-Pb定年研究.研究表明,该花岗岩包体中锆石可分为岩浆锆石、老核新壳的复合岩浆锆石和变质交代成因锆石;复合岩浆锆石的新壳...     

哀牢山-金沙江碱性岩带南段云南金平八一村钾质碱性花岗岩锆石SHRIMP U-Pb年龄

云南省金平县八一村钾质碱性花岗岩中的锆石由岩浆锆石和岩浆复合型锆石(老核新壳锆石)组成，以后者居多。锆石定年结果表明，岩浆锆石和岩浆复合型锆石的新壳SHRIMP U-Pb年龄为37Ma，反映岩浆上侵定位时的结晶时间，相当于始新世晚期。锆石老核获得的最大年龄为510Ma和177Ma，相当于晚寒武世和中侏罗世，表明该岩体保存有寒武纪和侏罗纪地质事件信息，而42～48Ma年龄可能是混合年龄。最后对锆石的成因和花岗岩的成岩机制等进行了初步探讨。     

江苏东海县磨山片麻状碱性花岗岩锆石SHRIMP定年研究

对东海县磨山片麻状碱性花岗岩中变质锆石和变质复合锆石进行SHRIMP UPb定年：①对变质锆石和变质复合锆石的新壳共测定8个点,其206Pb/238U加权平均年龄为212±3.6 Ma（MSWD=7.55）,反映了磨山片麻状碱性花岗岩的变质时间,即成岩时间,属于印支期,相当于晚三叠世;②变质复合锆石的老核（继承锆石）,多为发育有规则韵律环带的岩浆碎屑锆石,对其中3个颗粒进行了测定,UPb年龄分别为866 Ma、378 Ma和370 Ma,暗示其来源是异地多时代的。同时还表明其寄主岩的原岩应是沉积岩,其时代不会早于晚古生代。     

广东罗定龙塘碱性花岗岩锆石SHRIMP定年及地质意义

龙塘碱性花岗岩位于广东云开大山地区,属罗定泗纶混合岩田区,其中的锆石均为具有老核新壳的变质复合型锆石。SHRIMP定年结果,新壳6个测点加权平均年龄为265±1.8Ma,反映该岩体的成岩年龄,相当于中二叠世,属于海西晚期。老核获得最大的U-Pb年龄为1098Ma,相当于中元古代;457Ma和414Ma可能是新壳和老核的混合年龄。根据锆石的成因类型,结合微观所见的岩石结构(反映沉积变质成因的粒状变晶结构和花岗变晶结构等),表明该碱性花岗岩的成因可能是砂泥质沉积物经变质而成。     

滇西桃花花岗斑岩中新太古代-古元古代锆石年龄信息:对扬子板块西缘基底时代的约束

扬子板块西缘滇西地区是否存在古老基底一直存在争议。本文对滇西桃花地区花岗斑岩进行了岩石学、地球化学和锆石SHRIMP U-Pb年代学研究。形成于晚造山-后碰撞背景的桃花花岗斑岩具岛弧花岗岩地球化学特征,其成因可能与:1)俯冲拆离的洋壳俯冲拆离的洋壳或富集地幔重熔作用;2)加厚的地壳部分熔融。花岗斑岩中的继承锆石有两种类型:一类是发育具有密集振荡环带的岩浆锆石;另一类是次浑圆状锆石。测年结果显示,花岗斑岩的岩浆锆石年龄为36.35±0.35Ma,环带发育的继承锆石年龄介于167~891Ma之间;而次浑圆状继承锆石可以分为两组,其207Pb/206Pb加权平均年龄分别为1851±22Ma与2499±32Ma。新的锆石测年结果表明着滇西桃花地区不仅存在古金沙江洋东向俯冲形成的晚古生代弧岩浆记录,还发现新元古代岩浆活动信息,及早古元古代和新太古代的锆石记录。推测1.8Ga与2.5Ga锆石可能是捕获自地壳或围岩(石鼓片岩),表明滇西地区可能存在古老基底。     

个旧老厂钾质煌斑岩矿物学特征及其锆石U-Pb和黑云母~(40)Ar-~(39)Ar年龄

个旧老厂锡铜多金属矿区出露多条钾质煌斑岩脉,是个旧白垩纪岩浆活动的重要组成部分。本文利用电子探针对煌斑岩进行矿物学特征分析,利用锆石TIMS U-Pb和黑云母~(40)Ar-~(39)Ar进行了煌斑岩年代学研究。煌斑岩辉石斑晶和微晶化学成分近一致,均属普通辉石;黑云母斑晶属壳源铁质-镁质黑云母,而黑云母微晶属壳幔混源型镁质黑云母;中长石斑晶偏基性(An25~40),透长石微晶偏酸性(An1~6)。煌斑岩2颗锆石TIMS U-Pb年龄(87.1±1.3)Ma为捕获的围岩(老卡花岗岩体)锆石的年龄。煌斑岩脉的6个黑云母~(40)Ar-~(39)Ar同位素坪年龄集中在75~70 Ma间(平均72.9 Ma),代表煌斑岩侵位时代,稍晚于个旧中酸性岩浆活动的时代(85~78 Ma)。个旧老厂钾质煌斑岩脉代表壳-幔的相互作用,岩浆起源于古特提斯洋壳板块俯冲的残留板片对地幔楔的交代富集作用而形成的地幔源区。煌斑岩浆侵位的构造背景为俯冲-碰撞后的板内拉伸环境。     

北山地区白山堂铜多金属矿区岩浆岩锆石LA-ICP-MS U-Pb年代学及其地质意义

提要：北山地区是中国重要成矿区带之一。白山堂铜多金属矿是北山地区最重要的斑岩铜矿之一。本文采用锆石LA-ICP-MS U-Pb定年法测定了白山堂矿区I矿带两类含矿斑岩的同位素年龄。获得的花岗斑岩锆石加权平均年龄（275.0±3.0）Ma（MSWD=1.17）,代表了花岗斑岩的结晶年龄（早二叠世）。在流纹斑岩中获得两组年龄,一组系结晶较好的岩浆锆石,加权平均年龄为（371.1±2.8）Ma（MSWD=1.7）,表明流纹斑岩的结晶年龄为晚泥盆世;另一组锆石为继承锆石,晶形明显磨圆或包裹于第一组岩浆锆石中,年龄分别为（2627±35）Ma, （2598±35）Ma, （1705±44）Ma, （1722±48）Ma, （1642±51）Ma, （1213±54）Ma,大致分为26亿年、17亿年、12亿年左右的3类。结合地球化学特点,确定流纹斑岩可能与中上地壳在泥盆纪的重熔有关。     

青海省纳日贡玛斑岩钼铜矿床成矿花岗斑岩锆石LA-ICP-MSU-Pb定年及地质意义

对青海省纳日贡玛斑岩钼铜矿床开展了锆石LA-ICP-MS U-Pb同位素定年研究,结果表明,纳日贡玛矿区2个黑云母花岗斑岩样品的锆石206Pb/238U同位素加权平均年龄分别为(43.4±0.4)Ma和(42.9±0.3)Ma,锆石形态、结晶振荡环带结构及元素含量均显示出岩浆成因特点;因此,锆石U-Pb年龄可代表斑岩的岩浆结晶年龄,纳日贡玛含矿斑岩岩浆的侵位年代可精确地限定于新生代喜马拉雅期,相当于中始新世。1件辉钼矿样品Re-Os同位素模式年龄为(40.8±0.4)Ma,结合前人的辉钼矿测试结果,认为在纳日贡玛岩浆活动约2.6 Ma后,岩浆热液成矿流体开始产生成矿作用。三江走滑断裂构造系统控制斑岩矿床的分布,青海三江北段斑岩钼铜矿具有很大的找矿潜力。     

滇西北普朗斑岩铜矿锆石离子探针U-Pb年龄: 成矿时限及地质意义

应用高精度离子探针锆石U-Pb测年方法,获得普朗斑岩铜矿床中3件矿化石英二长斑岩的锆石年龄分别为228±3Ma、226.3±2.8Ma、226±3Ma。锆石形态和铀钍参数均属典型的岩浆锆石特征,年龄值在误差范围内近似一致,表明形成矿化斑岩的中酸性岩浆从岩浆房快速上升侵位。结合前人已发表的矿化斑岩的黑云母Ar-Ar坪年龄及辉钼矿Re-Os同位素年龄等数据,推测普朗斑岩铜矿的岩浆—热液系统从岩浆侵入至矿化阶段的持续时间可能长达10Ma以上,主成矿期约为216~214Ma。从岩浆房分异出的富含成矿物质和挥发份的岩浆流体在相对较晚阶段对普朗复式岩体发生了强烈的蚀变作用并可能进一步萃取了岩体中的成矿物质。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。