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1.
石宝沟花岗岩体位于华北陆块南缘,主要由似斑状二长花岗岩和中细粒二长花岗岩组成,发育岩浆暗色包体。LA-ICPMS锆石U-Pb定年结果显示,似斑状二长花岗岩和中细粒二长花岗岩的成岩年龄分别为(156±1)Ma(N=15,MSWD=0.34)和(157±1)Ma(N=17,MSWD=0.10)。这些花岗岩的A/CNK=0.82~1.02,Na2O+K2O=7.61%~8.91%,K2O/Na2O=1.02~1.48,属于高钾钙碱性、准铝质-弱过铝质I型花岗岩。稀土和微量元素特征显示其富集LREE、Rb、Ba、K、Pb等大离子亲石元素,亏损HREE、P、Ti等高场强元素,具有弱的负铕异常,个别样品具有正铕异常(δEu=0.81~1.12)。似斑状二长花岗岩的锆石εHf(t)为-22.6~-8.3,tDM2为2.64~1.73Ga;中细粒二长花岗岩εHf(t)为-26.9~-12.4,tDM2为2.91~1.99Ga。岩石地球化学和锆石Hf同位素组成特征表明,石宝沟花岗岩体的源区物质以壳源物质为主,可能为太古宙太华群,但也有年轻幔源组分的参与。  相似文献   

2.
应用LA-ICP-MS对马厂箐岩体中(似)斑状花岗岩的锆石进行了U-Pb定年和微量元素分析。在CL图像上,(似)斑状花岗岩中锆石均发育有典型的振荡环带,锆石的稀土元素配分模式表现为亏损轻稀土,富集重稀土,具有强烈正Ce异常和中度负Eu异常,且呈现出较高的Th/U比值等特征,表明所测锆石均为典型的岩浆锆石。马厂箐岩体(似)斑状花岗岩锆石U-Pb加权平均年龄为(33.78±0.21)Ma(MSWD=0.71),累计概率统计得到正长斑岩锆石U-Th-Pb年龄为(35.6±0.3)Ma、花岗斑岩锆石U-Th-Pb年龄为(35.0±0.2)Ma,宝兴厂矿段铜钼矿辉钼矿Re-Os等时线年龄分别为(35.8±1.6)Ma和(33.9±1.1)Ma,乱硐山矿段接触交代型金矿白云母40Ar/39Ar年龄为(35.25±0.36)Ma,人头箐—金厂箐矿段热液脉型金成矿白云母40Ar/39Ar年龄为(35.35±0.32)Ma,反映斑岩型铜钼矿化、接触交代型金矿化和热液脉型金矿化为同一个构造-岩浆-热液成矿系统的产物,Ⅱ期(33~37Ma)正长斑岩+二长斑岩+花岗斑岩+(似)斑状花岗岩岩性组合是成矿的地质体,为成矿提供了物质、流体和热动力条件,这期斑岩-热液-成矿系统的持续时间约为4Ma,铜、钼、金的成矿主要发生在Ⅱ期岩浆活动的早-中期。  相似文献   

3.
辽宁兴城新立屯地区岩浆杂岩主要由4种不同的岩石单元组成,分别为似斑状黑云母二长花岗岩,中细粒石英闪长岩,花岗细晶岩和花岗伟晶岩,前两者分布广泛且为研究区的主要岩石单元,后两者则呈脉状侵入到前两者中。应用LA-ICP-MS锆石U-Pb定年方法,测得似斑状黑云母二长花岗岩,中细粒石英闪长岩及花岗细晶岩的年龄分别为2 496±18 Ma,2 490±19 Ma,2 479±29 Ma,形成于古元古代早期。结合野外地质特征,侵位顺序由早到晚依次为:似斑状黑云母二长花岗岩,中细粒石英闪长岩,花岗细晶岩,花岗伟晶岩。岩石地球化学特征显示,新立屯地区岩浆杂岩主量元素方面具高硅(SiO2=61.38%~74.99%),富碱(Na2O+K2O=6.86%~9.41%),富Mg#(56~70)特征;A/CNK=0.91~1.18,属准铝质-过铝质岩石;微量元素方面,相对富集轻稀土元素,亏损重稀土元素,具有Eu异常(δEu=0.50~0.96);富集大离子亲石元素,亏损高场强元素;锆石Lu-Hf同位素特征εHf(t)值为-1.12~+6.13;TDM2(Hf)介于2 594~2 937 Ma,显示该套岩浆杂岩可能为地幔物质加入新生地壳再造的产物。  相似文献   

4.
胶东是我国最重要的金矿集区,也是环太平洋中、新生代金成矿系统的重要组成部分,其内花岗质岩石分布广泛,95%以上的金资源储量赋存在晚侏罗世玲珑型花岗岩和早白垩世早期郭家岭型花岗质岩中。关于花岗岩类的成因,尤其是早白垩世花岗质岩的岩石类型及其源区仍存有争议。新城金矿床位于胶东西北部焦家断裂带北段,是迄今为止在胶东矿集区内发现的赋存在早白垩世花岗质岩中最大的金矿床,其内已探明金资源储量大于200t。该金矿床的赋矿围岩为新城花岗岩体,由中细粒石英二长岩和中粗粒似斑状二长花岗岩组成,形成于127~132Ma。进一步的地质观察表明中粗粒似斑状二长花岗岩两侧的岩石粒度逐渐变细,斑晶逐渐变小,长英质矿物增多,明显不同于中粗粒似斑状二长花岗岩,应为中细粒似斑状二长花岗岩。论文对该中细粒似斑状二长花岗岩进行了系统的岩石地球化学、锆石LA-ICP-MS定年和Lu-Hf同位素组成研究,并进一步探讨了该类岩石的地球化学类型、形成时代、岩浆源区性质及其与新城花岗岩体的关系。岩石地球化学研究表明中细粒似斑状二长花岗岩具有高的SiO2(71.18%~73.72%)、全碱(K2O+Na2O=7.07%~8.64%)、Ba(793×10-6)、Sr(729×10-6)和轻稀土含量(71.14×10-6),低的Al2O3(13.57%~15.73%)、MgO(0.22%~0.39%)、Rb(91.7×10-6)、Th(7.4×10-6)、U(4.51×10-6)、Nb(4.49×10-6)、Ta(0.26×10-6)、Y(3.67×10-6)和重稀土含量(7.47×10-6),无明显的铕异常,明显亏损Nb、Ta、P、Ti等高场强元素,显示出典型的高Ba-Sr花岗岩所具有的地球化学特征,属高BaSr花岗岩。锆石LA-ICP-MS定年结果表明中细粒似斑状二长花岗岩形成于123±1Ma,而石英二长岩和中粗粒似斑状二长花岗岩的锆石LA-ICP-MS年龄为127±2Ma~132±1Ma,3种类型岩石具有相似的主量元素组成及稀土和微量元素分布模式,表明新城花岗岩体的形成时代应为123±1Ma~132±1Ma。Lu-Hf同位素测试结果显示中细粒似斑状二长花岗岩岩浆锆石的εHf(t)为-20.76~-18.66,二阶段模式年龄tDM2为2351~2479Ma;在εHf(t)-锆石U-Pb年龄图解中,所有数据点均落在球粒陨石演化线之下的壳源区域。金矿床已有石英二长岩、中粗粒似斑状二长花岗岩和区域玲珑型花岗岩Hf同位素组成及该中细粒似斑状二长花岗岩中2个太古代(2629±14Ma、2402±18Ma)和3个中生代(150±7Ma、151±1Ma、147±1Ma)的继承锆石年龄,表明新城金矿床内中细粒似斑状二长花岗岩应来源于前寒武纪变质基底岩石,岩浆上升过程中遭受了上地壳(主要是玲珑黑云母花岗岩)的混染。  相似文献   

5.
闾井岩体是西秦岭"五朵金花"岩体群的成员之一。岩石类型主要为似斑状黑云母二长花岗岩、含斑黑云母二长花岗岩、中细粒黑云母二长花岗岩及粗粒黑云母二长花岗岩。对似斑状黑云母二长花岗岩、粗粒黑云母二长花岗岩和中细粒黑云母二长花岗岩的LA-ICP-MS锆石U_Pb定年分别获得221±1 Ma(N=20,MSWD=0.11)、221±1 Ma(N=24,MSWD=0.04)和218±1 Ma(N=15,MSWD=0.13)的年龄,表明该岩体形成于晚三叠世,其中似斑状黑云母二长花岗岩比中细粒黑云母二长花岗岩形成略早。该花岗岩的A/CNK=1.02~1.16,Na_2O+K_2O=7.65%~8.84%,K_2O/Na_2O=1.37~1.82,属于过铝质-强过铝质、高钾钙碱性-钾玄岩系列,为I型花岗岩。稀土元素配分曲线为右倾型,轻、重稀土元素分馏明显,具有显著的负Eu异常。地球化学上总体富集Rb、Th、K元素,不同程度亏损Sr、Nb、P、Ti元素。锆石饱和温度计算显示,闾井岩体成岩温度为736~818℃。该岩体与"五朵金花"岩体群中的中川岩体具有相似的形成时代及地球化学特征,表明闾井岩体与中川岩体可能具有相似的成岩机制,其外围可能也具有和中川岩体一样的成矿潜力。  相似文献   

6.
泉子沟斑岩钼矿床位于内蒙古丰镇市,地处华北克拉通北缘内蒙古台隆凉城断隆内。矿区出露一套燕山期花岗质杂岩体——红娘山杂岩体,主要由中粗粒花岗岩、似斑状花岗岩和石英斑岩组成,钼矿体主要赋存于似斑状花岗岩中。文章在详细的野外地质调查基础上,对泉子沟矿床的成岩成矿时代进行了详细研究,并探讨了地质意义。5件辉钼矿样品的Re-Os模式年龄介于(158.8±2.2)Ma~(161.5±2.2)Ma之间,其加权平均值为(159.8±1.0)Ma(MSWD=0.92),等时线年龄为(161.7±3.1)Ma(MSWD=1.40)。红娘山杂岩体LA-ICP-MS锆石U-Pb年龄分别为:中粗粒花岗岩结晶年龄为(173±1)Ma(MSWD=0.88),似斑状花岗岩侵位年龄为(162±1)Ma(MSWD=0.40),石英斑岩结晶年龄为(160±2)Ma(MSWD=1.90)。辉钼矿Re-Os和锆石U-Pb定年结果表明,泉子沟钼矿床形成于晚侏罗世早期,成矿与似斑状花岗岩关系密切。泉子沟钼矿床的辉钼矿w(Re)介于16.49×10~(-6)~32.87×10~(-6),暗示成矿物质主要来自下地壳。  相似文献   

7.
报道了鞍山地区东山杂岩带奥长花岗岩和二长花岗岩的锆石SHRIMP U-Pb年龄。中粗粒奥长花岗岩中岩浆锆石的年龄为3329Ma±22Ma(MSWD=9.6),存在年龄为3687~3784Ma的残余锆石。细粒奥长花岗岩和二长花岗岩中岩浆锆石的年龄分别为3141Ma±8Ma(MSWD=1.5)和3142Ma±5Ma(MSWD=0.35)。表明约3.3Ga和3.1Ga是鞍山地区2个重要的地壳演化阶段。  相似文献   

8.
紫金山矿田位于华南褶皱系东部,闽西南凹陷西南部,是我国大型-超大型浅成低温热液铜金矿床,区内发现多个与岩浆活动密切相关的金、银、铜等金属矿床.对紫金山矿田东南矿段与成矿密切相关的细粒黑云母花岗岩开展了详细野外地质调查、岩相学和锆石稀土元素、U-Pb年代学和Hf同位素研究.LA-ICP-MS法获得细粒黑云母花岗岩中岩浆结晶锆石206Pb/238U-207Pb/235U谐和年龄为109.5±1.9 Ma(MSWD=0.74,N=16),206Pb/238U加权平均年龄为107.44±0.94 Ma(MSWD=1.06,N=16),二者在误差范围内结果一致,结合锆石稀土元素和岩浆振荡环带特征及Th/U比值,上述年龄结果可代表岩石的结晶年龄,表明细粒黑云母花岗岩侵位于燕山期早白垩世.细粒黑云母花岗岩锆石Hf同位素初始比值εHf(t)均为负,介于-4.99~-1.06(平均值为-2.99);两阶段Hf模式年龄(tDM2)介于1 233.7~1 485.4 Ma(平均值为1 362.4 Ma).样品的εHf(t)、Hf同位素地壳模式年龄分布范围变化较小,暗示岩体的岩浆来源具有较为均一的锆石Hf同位素组成.紫金山矿田东南矿段早白垩世花岗岩体的锆石U-Pb年龄和Hf同位素特征,反映了闽西南早白垩世的岩浆成矿活动时间和源区特征,其成因与中国东南部岩石圈伸展减薄和壳源物质参与岩浆形成演化密切相关.   相似文献   

9.
内蒙古东乌旗索纳嘎铅锌银矿区赋矿侵入岩为一由中粗粒花岗岩、细粒黑云母花岗岩和似斑状钾长花岗岩组成的杂岩体.三种岩石的锆石U-Pb同位素年龄依次为(319.6±4.1)Ma、(172.5±1.4)Ma和(165.5±1.8)Ma.三者均以高钾、富碱、贫镁为特征,均属钙碱性、准铝质-弱过铝质岩石,分异程度较高.岩石稀土总量较高,轻稀土相对富集,均具负铕异常;均富集U、Th,Rb/Sr值大于壳源Rb/Sr值,应属S型花岗岩.根据花岗岩地球化学和区域地质特征分析认为,中粗粒花岗岩形成于晚石炭世后碰撞伸展构造环境;中侏罗世细粒黑云母花岗岩和似斑状钾长花岗岩产于板内伸展构造环境,为同源岩浆演化不同阶段的产物.似斑状钾长花岗岩富含成矿元素Pb和Zn,而且其成岩年龄与辉钼矿(163.4±2.4) Ma~(166.6±2.4) Ma的Re-Os同位素年龄基本一致,可能为成矿母岩.  相似文献   

10.
内蒙古西沙德盖钼矿是华北地台北缘成矿带上的一处中型斑岩钼矿床。采用锆石LA-ICP-MS铀-铅同位素测年技术,针对其含矿钾长花岗岩和矿石进行的成岩成矿年代学测定。获得西沙德盖似斑状钾长花岗岩体的成岩年龄为245 Ma±10 Ma;通过对7件辉钼矿样品进行Re-Os同位素分析,获得同位素模式年龄介于223.2 Ma~232.6 Ma,等时线年龄为225.4 Ma±2.6 Ma(MSWD=0.30);两种方法获得的年龄相近(成矿年龄略小于成岩年龄),成岩与成矿作用均发生于中三叠世末,属印支期碰撞后伸展环境下构造?岩浆活动的产物。结合对已有年龄资料的归纳和分析,认为区内在印支期曾发生过重要的岩浆-(金钼)成矿事件,该事件虽可能遭受了燕山期构造-岩浆活动的改造或破坏,但在一定区域和一定程度上仍有记录或保留。  相似文献   

11.
Police, politics, and the right to the city   总被引:1,自引:0,他引:1  
Mustafa Dikeç 《GeoJournal》2002,58(2-3):91-98
Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.  相似文献   

12.
13.
14.
Humboldt, Arago, and the temperature of groundwater   总被引:1,自引:0,他引:1  
  相似文献   

15.
Mercury contamination in aquatic environments is of worldwide concern because of its high biomagnification factor in food chains and long-range transport. The rivers, estuary and the bay along the northwestern Bohai Sea coast, northeastern China have been heavily contaminated by Hg due to long-term Zn smelting and chlor-alkali production. This work investigated the distributions of total Hg (THg) and monomethylmercury (MMHg) in the water, sediment and hydrophytes from this area. Concentrations of THg in sediment (0.5–64 mg kg−1) and water (39–2700 ng L−1) were elevated by 1–3 orders of magnitude compared to background concentrations, which induced high concentrations of MMHg in these media. The highest concentration of MMHg in sediment reached 35 μg kg−1, which was comparable to that in the Hg mining area, Wanshan, China, and the highest MMHg concentration of 3.0 ng L−1 in the water sample exceeded the MMHg Chinese drinking water guideline of 1.0 ng L−1. Concentrations of THg in a sediment profile from Jinzhou Bay were found to be consistent with annual Hg emission flux from a local Zn smelter (r = 0.74, p < 0.01), indicating that Hg contamination was mainly caused by Zn smelting locally. For some freshwater hydrophytes, concentrations of THg and MMHg ranged from 5.2 to 100 μg kg−1 and 0.15 to 12 μg kg−1, respectively. Compared to sediment, concentrations of THg in hydrophytes were 2–3 orders of magnitude lower but MMHg was comparable or higher, indicating that the bioaccumulation in plants was distinct for the two Hg species studied. The data suggest that a significant load of Hg has been released into the northwestern coastal region of the Bohai Sea.  相似文献   

16.
Average concentrations of Pb, Zn, Cu, and other metals, as well as S and As, were calculated for the Aue granitic cupola, the contact aureole of which hosts the large vein-type uranium deposit of Schlema-Alberoda and the Schneeberg uranium-base metal deposit (Erzgebirge, Germany). The cupola was exposed by mine workings and boreholes, which provided an opportunity to evaluate variations in the abundances of metals in the granites over a vertical interval of more than 2.5 km and estimate their losses in the upper oxidized part of the investigated volume of the cupola (coefficient of iron oxidation, KO Fe, increases in the granites from bottom to top from 7 to 70%) compared with the lower unaltered and unoxidized part (with a KO Fe plateau at about 5%). The average concentrations of metals in the upper part of the cupola are lower than those in the lower part by a factor of 2.5 for Pb, 1.56 for Zn, 1.45 for Cu, 1.3 for Co, etc. A similar decrease in the abundances of ore elements along the vertical section associating with the relative epigenetic alteration and oxidation of the granite was previously described by us for U and Th and for the components of high-temperature ores, W, Sn, and Mo. The removal of ore elements from the granite was accompanied by a decrease in the bulk contents of sulfur and arsenic by a factor of 1.35 and 1.65, respectively. The leaching of trace metals from the granites of the upper part of the Aue cupola was followed by their partial redeposition above the cupola in the ore veins of the Schlema and Schneeberg deposits. Original Russian Text ? Vikt. L. Barsukov, N.T. Sokolova, O.M. Ivanitskii, 2006, published in Geokhimiya, 2006, No. 9, pp. 967–982.  相似文献   

17.
The behavior of trace elements under conditions of partial melting of granitoid rocks has been studied. The element’s partition coefficients between minerals and the melt Dimin/melt depends, in the first place, on the composition of the primary melt. In biotite the HREE Di are a little below 1, while those of LREE, especially Di for Ce, are 1–3 orders of magnitude less. This leads to an efficient differentiation of REEs in anatexic melts especially when biotite is the main mineral phase of restite. On the contrary, there are feldspars, the Di of which cannot provide such a magnitude of differentiation. Unlike garnets and pyroxenes, whose stability in restite permits enrichment of anatexic melts produced in migmatization zones with Nb, Ti, and Cr, the presence of biotite in restite causes depletion of melts with those elements as well as with Rb. Feldspars, under conditions of their fractional crystallization or during differentiation of an anatexic melt, deplete the latter with Sr, Ba, and Rb, but enrich it with Nb, Ti, Cr, Y, Zr, and V.  相似文献   

18.
Text, talk, things, and the subpolitics of performing place   总被引:1,自引:0,他引:1  
This article tells the story of how a group of Dutch and Belgian citizens organized themselves to promote an area that they valued, to put it on the map, to raise awareness about its qualities, and to protect it from urban and industrial development. Our theoretical perspective focuses on the performative and political aspects of this place-making process and the discursive and material practices involved. We connect this to Beck’s concept of subpolitics.Our findings show how the group performed this place not only through text and talk - giving the area a name, using their knowledge and expertise to raise awareness about its values, lobbying and cooperating with decision-makers -, but also through things - installing art objects and information signs that articulate certain characteristics and values of the area. Our findings demonstrate the struggles involved in these performances. The group involved multiple perspectives on what the important values and characteristics of the area are and on what strategies would work best in trying to influence decision-making and protect the area. However, the use of expertise as the main strategy to gain influence excluded the more critical and activist strategies and privileging archaeological and historical values and characteristics came at the expense of attention on agricultural and natural values.Our findings make clear that performing place cannot be taken to be homogeneous and that it inevitably involves multiple perspectives and demands. The struggles, power relations and dynamics of inclusion and exclusion that this multiplicity implicates reveal a form of sub-politics that involves both politicization and depoliticization. Also, it is a form of subpolitics that is more diverse and ambiguous than Beck’s conceptualization presupposes by its emphasis on the role of outsiders as a homogeneous group.  相似文献   

19.
The dielectric constants and dielectric loss values of 4 Ca-containing minerals were determined at 1 MHz using a two-terminal method and empirically determined edge corrections. The results are: vesuvianitel κ′ a=9.93 tan δ=0.006 κ′ c=9.79 tan δ=0.005 vesuvianitel κ′ a=10.02 tan δ=0.002 κ′ c=9.85 tan δ=0.003 zoisite1 κ′ a =10.49 tan δ=0.0006 κ′ b =15.31 tan δ=0.0008 κ′ c=9.51 tan δ=0.0008 zoisite2 κ′ a =10.55 tan δ=0.0011 κ′ b =15.45 tan δ=0.0013 κ′ c=9.39 tan δ=0.0008 epidote κ′ 11= 9.52 tan δ=0.0008 κ′ 22=17.1 tan δ=0.0009 κ′ 33= 9.37 tan δ=0.0006 fluorapatite1 κ′ a =10.48 tan δ=0.0008 κ′ c = 8.72 tan δ=0.0114 fluorapatite2 κ′ a =10.40 tan δ=0.0010 κ′ c=8.26 tan δ=0.0178 The deviation (δ) between measured dielectric polarizabilities as determined from the Clausius-Mosotti equation and those calculated from the sum of oxide polarizabilities according to α D (mineral)=∑ α D (oxides) for vesuvianite is ~ 0.5%. The large deviations of epidote and zoisite from the additivity rule with Δ=+ 10.1 and + 11.7%, respectively, are attributed to “rattling” Ca ions. The combined effects of both a large F thermal parameter and possible F-ion conductivity in fluorapatite are believed to be responsible for Δ=+2–3%. Although variation of oxygen polarizability with oxygen molar volume (Vo) is believed to affect the total polarizabilities, the variation of Vo in these Ca minerals is too small to observe the effect.  相似文献   

20.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

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