新疆阿尔泰红柱石-矽线石型变质带的独居石年龄及其地质意义

新疆阿尔泰地区的红柱石-矽线石型递增变质带,由绿泥石-黑云母带、黑云母-石榴石带、石榴石-十字石带、十字石-红柱石带和矽线石带组成;递增变质作用峰期温度、压力分别为T=580～680℃、P=4.0～5.1kbar;递增变质作用形成的变质岩中含有丰富的独居石副矿物,而且Th-U-Pb含量比较高,适合电子探针独居石化学法定年。依据电子探针独居石Th-U-Pb化学法(CHIME法)定年,变质时代为(262±10)～(264±22)Ma。表明红柱石-矽线石型递增变质带形成于二叠纪中期,为古亚洲洋闭合时间提供了直接的年代学依据。     

滇西石鼓变质带基本特征

石鼓变质带延伸约100多公里,可划分为绿泥石带、黑云母带、铁铝榴石带、十字石带、蓝晶石带及夕线石带。红柱石-蓝晶石稳定共生,属低—中压变质相系的区域变质带。主要变质时期为海西晚期(K-Ar年龄为258Ma)。     

新疆阿尔泰造山带变质作用演化及其地质意义

阿尔泰造山带发育了一系列低压红柱石型与中压蓝晶石型变质带．红柱石型变质带发育了黑云母带、石榴石带、十字石带、十字石-红柱石带、矽线石带、矽线石-堇青石带：蓝晶石型发育了黑云母带、石榴石带、十字石带、蓝晶石带、矽线石带．中压的蓝晶石序列估算温度为445～747．6℃，压力为0．64～0．95GPa中压序列随变质作用增加．压力有增高趋势：低压的红柱石序列温度445～681℃．压力0．3～0．8GP乱自十字石带后．压力明显降低．可能是靠近热源而导致早期中压痕迹消失．因此红柱石型变质带不是一个正常的变质演化系列．蓝晶石型变质早于红柱石型变质．蓝晶石型变质序列可能与晚古生代弧-陆碰撞事件有关．红柱石序列的形成可能与碰撞相关的广泛花岗岩体侵入及中压岩石抬升有关．     

赣中变质岩带变质带的重新划分及变质作用P-T条件的确定

根据随变质作用增强而出现的特征变质矿物及矿物组合,对赣中变质岩带重新划分出五个变质带,由低到高依次为绢云母一绿泥石带、黑云母带、铁铝榴石带、十字石带、夕线石带。在对各变质带变质矿物进行详细研究的基础上,采用石榴石-黑云母(Gt-Bi)、斜长石-角闪石(Pl-Hb)、石榴石-十字石(Gt-St)、石榴石-角闪石(Gt-Hb)、石榴石-斜长石-夕线石-石英(Gt-Pl-Sil-Q)、石榴石-斜长石-黑云母-白云母(Gt-Pl-Bi-Mu)等多种地质温压计确定了各变质带的形成温度、压力,绢云母-绿泥石带的形成温度为250-350℃,压力为0.25-0.35GPa;黑云母带的形成温度为350-450℃±,压力为0.25-0.40GPa±;铁铝榴石带的形成温度为450-550℃±,压力为0.40～0.60GPa±;十字石带的形成温度为550-600℃±,压力为0.50-0.60GPa±;夕线石带的形成温度为600-650℃±,压力为0.55-0.65GPa±,赣中变质岩带峰期变质作用已达到角闪岩相。     

中国阿尔泰造山带变质作用PTSt演化和热-构造-片麻岩穹窿形成机制

中国阿尔泰造山带中发育了一系列热-构造-片麻岩穹窿(简称 TSG穹窿)。由低级变质区向TSG穹窿中心,发育了绢云母-绿泥 石带、黑云母带、石榴石带、十字石带、蓝晶石(红柱石)带、夕线石- 堇青石(夕线石-石榴石)带、混合岩带、混合花岗片麻岩岩田。递增 变质带、混合岩带、混合花岗片麻岩的形成演化顺序与其由外部向 TSG穹窿中心在空间上的排布序列一致。由黑云母带至混合花岗片 麻岩,变质作用及花岗岩化作用的高峰温度由400℃递增至800℃, 而压力由1.05GPa递减至0.10GPa。造山带变质作用过程可以 用压力-温度-空间-时间模式(PTSt)描述。TSG穹窿是主期造山幕中,沿造山带中一系列区域热动力异常中心,深部热流、构造流上涌,发生递增变质作用、花岗岩化作用以及差异性隆起的过程中形成的。     

新疆阿尔泰造山带低压变质带与泥质麻粒岩

新疆阿尔泰造山带位于西伯利亚板块西南缘,该区递增变质带十分典型,可分为两种类型:蓝晶石型和红柱石型[1].前者从低向高出现黑云母带→石榴子石带→十字石带→十字石-蓝晶石带→矽线石带;后者出现黑云母带→石榴子石带→十字石带→十字石-红柱石带→矽线石带,在高温地段发育石榴子石-堇青石带(泥质麻粒岩).     

高喜马拉雅变质岩“夕线石带”的地质意义

通过对聂拉木高喜马拉雅结晶岩系石榴子石带-十字石带-蓝晶石带-夕线石带倒转变质的研究,认为除夕线石带以外的其它变质带主要由固相变质反应形成。夕线石的出现并非蓝晶石或十字石带递增变质所致。"倒转变质"不应包括所谓的夕线石带。实际上,夕线石化与深熔作用之后的溶液（或熔体）活动更为密切。时间顺序上应是递增变质作用及分带→深熔作用→夕线石化,夕线石的出现不是深熔作用的开始,而是深熔作用的结束。夕线石的形成主要与变形作用过程中黑云母和／或钾长石的分解及碱（土）金属组分的迁移有关,关键在于溶液（或熔体）组分沿裂隙迁移过程中发生的组分逐步沉淀,最早沉凝的Al、Si组分形成夕线石和石英,之后陆续有其它的组分的结晶;细夕线石粗粒化即进一步转化形成柱状夕线石的同时形成蠕英结构和斜长石生长边。夕线石化可能与深熔花岗（片麻）岩的上升过程有关。     

闽北麻源群变质流体对变质反应温度缓冲作用研究

闽北麻源群在空间上表现为巴罗式递增变质带：绿泥石带→黑云母带→石榴石带→十字石带→蓝晶石带→夕线石带。变质温度计算结果表明，区内蓝晶石带变质温度（４７０℃～５００℃）明显低于石榴石带和十字石带变质温度（５００℃～５５０℃），即蓝晶石带在石榴石带和十字石带之前出现。这显然与传统的递增变质带理论相悖。流体组成化学平衡计算和变质反应热力学分析研究表明，蓝晶石带较低的变质温度并非是压力或退化变质作用所致，而是低ＸＨ２Ｏ流体对形成蓝晶石的脱水变质反应温度缓冲的结果，缓冲温度值高达１００℃～２００℃。本文从热力学理论上解释了缓冲作用的机制并估算了缓冲的温度范围，据此讨论了变质流体在变质相带研究方面的重要意义。     

泥质变质岩系主要的矿物温度计与压力计

简要介绍泥质变质岩中常用的温度计和压力计,对其可适用性、适用范围、质量优劣等进行了评述。经过对这些温度计和压力计的比较研究,我们发现石榴石-黑云母温度计、石榴石-白云母温度计、石榴石-蓝晶石(夕线石、红柱石)-斜长石-石英(GASP)压力计、石榴石-黑云母-斜长石-石英(GBPQ)压力计、石榴石-白云母-斜长石-石英(GMPQ)压力计、石榴石-黑云母-白云母-蓝晶石(夕线石、红柱石)-石英(GBMAQ)压力计、石榴石-金红石-钛铁矿-斜长石-石英(GRIPS)压力计的准确度较高,可以为地质工作者所采用。二云母温度计、白云母-斜长石温度计准确度还有待大幅度改进。石榴石-金红石-蓝晶石(夕线石、红柱石)-钛铁矿-石英(GRAIL)压力计、石榴石-堇青石温度计和石榴石-堇青石-蓝晶石(夕线石、红柱石)-石英(GCAQ)压力计等温压计的准确度及其可适用性,还有待于进一步研究。     

新疆阿尔泰造山带低压变质作用相平衡研究

通过对阿尔泰造山带低压型变质序列中典型泥质岩石进行详细的岩相学及相平衡研究,获得黑云母带变质作用的温度为445～550℃和压力为0.2～0.6 GPa;石榴石带为480～566℃、0.54±0.22 GPa;十字石带601±20℃、0.8±0.25GPa;十字石-红柱石带540±20℃、0.32±0.05 GPa,而632.4℃、0.785 GPa这个值不是红柱石的稳定范围,这可能是其早期中压变质作用条件;矽线石带为640℃、0.43 GPa左右,由于石榴石中有蓝晶石包体,因此其早期也可能经历中压条件的变质;堇青石-矽线石带740～800℃、0.4～0.7 GPa。阿尔泰造山带低压变质序列不是一个正常的变质序列,其野外变质梯度呈现“Z”字型特征。阿尔泰造山带低压变质作用可能形成于早期中压变质岩的挤压抬升和以此相关的大量花岗岩侵入的构造环境中。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.