黑云杉林大气CO2稳定同位素组成δ13C,δ18O的分析

研究CO₂稳定同位素特征可以揭示光合、呼吸作用等众多信息,从而有助于了解生态系统与环境之间的碳循环过程。利用大气CO₂浓度及其稳定同位素的测定资料,分析稳定同位素比δ¹³C、δ¹⁸O,发现两者具有相似的时空分布特征。主要表现在δ¹³C和δ¹⁸O在冠层内具有明显的垂直变化趋势,冠层上部重同位素含量较高,而底部含量较低。从时间变化看,δ¹³C和δ¹⁸O在午后到日落具有较高的水平,而凌晨,δ¹³C和δ¹⁸O较低。运用Keeling图法分析δ¹³C、δ¹⁸O和CO2浓度的关系,发现δ¹³C值主要受光合和呼吸作用影响,与CO₂浓度的高低密切相关;而δ¹⁸O的变化比较复杂,因为δ¹⁸O除受光合、呼吸强度影响外,还取决于环境空气湿度。     

天目山柳杉树轮δ13C对华东地区降水序列的重建

对采自天目山的柳杉树轮进行交叉定年后,得到树轮的δ¹³C年序列。将δ¹³C年序列去除大气CO₂的影响,保留其高频振荡部分。利用华东地区部分气象站的降水资料,通过主成份分析,分析了降水与树轮δ¹³C之间的关系。考虑滞后效应,利用回归方法重建了过去一百多年来的华东地区不同时段的降水序列,并分析其变化特征。     

云南一次持续性暴雨过程的非地转湿Q*

应用非地转湿Q^*,对2001年5月31日至6月2日发生在云南的持续性暴雨天气过程进行诊断分析。结果表明,非地转湿Q矢量辐合区是暴雨发生的有利区域;非地转湿Q矢量的垂直分布反映了次级环流的方向和强弱,云南的暴雨落区位于次级环流的上升支附近。     

冬季南京北郊大气气溶胶中水溶性阴离子特征

2009年冬季在南京北郊进行24 h采样,运用离子色谱法研究大气PM₁₀中水溶性阴离子的分布特征。结果表明:PM₁₀中阴离子的平均总质量浓度在白天和夜间分别为658.21、622.84 μg/m³;PM_2.1则分别为337.86、319.97 μg/m³,阴离子主要存在于细粒子中;主要水溶性阴离子均为SO₄^2-,且海盐对南京北郊大气PM₁₀和PM_2.1中的SO₄^2-质量浓度影响很小。SO₄^2-、Cl^-和F^-粒径谱分布相似,均呈双模态;NO₃^-和NO₂^-主要呈现单模态。SO₄^2-与NO₃^-、F^-与NO₃^-、SO₄^2-与Cl^-的相关系数均大于0.8,相关显著,说明其存在一定的同源性。NO₃^-/SO₄^2-的平均值在白天、夜间分别为0.058 2、0.048 4,说明南京北郊大气污染以固定源为主。分析NO₃^-、SO₄^2-前体物的转化率知道,采样期间SOR和NOR的平均值均大于10%,即SO₄^2-部分来源于SO₂的二次转化,而不是单一来源于一次污染物。     

山东暖区暴雨对流特性和环境参量的统计分析

利用2014-2018年5-9月间山东大监站逐日降水资料、Micaps常规资料以及NCEP再分析资料等,将山东暖区暴雨分为锋前型、暖切变型、副高边缘型和急流型4大类,并对山东暖区暴雨的垂直结构、对流特性以及环境参量特征进行统计。主要结论为：(1)山东暖区暴雨的低空风场主要以西南风或东南风为主,且整层风场随高度顺转。高湿区主要集中在对流层中低层。大气的自由对流高度和云底高度较低,湿层和暖云层深厚,其中急流型湿层和暖云层最为深厚。(2)山东暖区暴雨发生时,K≥30.5℃, 0.72≥SI≥-6.87,假相当位温≥334K,垂直锋区的北界位于37-39°N之间,暴雨落区位于锋区北界南侧2-3个纬距范围内。(3)暖区暴雨上空辐合中心平均值为-3×10^-5 s^-1,辐合中心均出现在700hPa以下；垂直速度中心的平均值为-1.1×10^-5 hPa.s^-1,大值中心出现在对流层中低层；涡度中心的平均值为5×10^-5 s^-1,正涡度主要在低层,且随高度的增加而减小；q925≥16g.kg^-1,q850≥12g.kg^-1,q700≥9g.kg^-1,暖区暴雨的水汽输送主要集中在低层,水汽通量散度平均值,850 hPa是-2.3×10^-6 g.cm^-2.hPa^-1.s^-1, 700 hPa 为-1.2×10^-6 g.cm^-2.hPa^-1.s^-1。     

镉质量浓度和鱼尺寸对罗非鱼积累和转移镉的影响

为研究尺寸和镉(Cd²⁺)质量浓度对罗非鱼积累和转移水环境中Cd²⁺的影响,用室内培养的方法,选取4种尺寸的罗非鱼,设置不同质量浓度Cd²⁺的暴露试验,分别测定其半致死率、Cd²⁺积累量和对Cd²⁺的转移系数以及罗非鱼的相对增长率.结果表明:不同尺寸的罗非鱼对Cd²⁺的响应不同,其中,幼龄鱼的LC₅₀浓度最低,体长为31.5±3.4 cm的罗非鱼LC₅₀最高;低质量浓度Cd²⁺(0.5 mg/kg)处理下,罗非鱼尺寸不同,相同鱼组织对Cd²⁺的吸收积累量差异显著(P< 0.05),而高质量浓度Cd²⁺处理时,不同尺寸罗非鱼的同一组织对Cd²⁺的积累量无显著性差异;除体长27.4±2.9 cm罗非鱼外,相同尺寸的罗非鱼Cd²⁺转移系数都是低质量浓度显著大于高质量浓度(P< 0.05);高质量浓度Cd²⁺处理对各种尺寸罗非鱼质量增加的抑制率显著高于低质量浓度Cd²⁺处理的抑制率.此外,不同Cd²⁺质量浓度对相同尺寸的罗非鱼也产生不同的影响.因此,罗非鱼的尺寸和Cd²⁺质量浓度都对罗非鱼积累和转移Cd²⁺产生影响.     

利用LAP-3000型风廓线雷达资料对深圳地区湍流耗散率特征的研究

利用2010年1-2月深圳LAP3000型风廓线雷达资料, 对湍流耗散率进行了估算, 针对典型晴天条件下的湍流耗散率ε、折射率结构常数C₂ⁿ、水平风速和风切变, 分析了其时空变化特征。得出如下结论: (1) 深圳地区低空大气ε的量级在10^-7~10^-1 m^-2·s^-3之间, 与理论模拟值基本一致; (2) 时间分布特征为, 2 km以下ε有很明显的日变化特征, 夜晚和上午ε较大, 下午及傍晚减少;(3) 空间分布特征表现为, ε随高度大致呈递减分布;ε量级达10^-2.5 m²·s^-3所在高度可作为深圳地区2010年1月14-15日边界层顶高度的判断依据。     

武汉市冬季灰霾期PM2.5中水溶性无机离子的特征

2018年1月,利用颗粒物采样器采集武汉市大气PM_2.5样品并进行水溶性无机离子（F^-、Cl^-、NO₃^-、SO₄^2-、Na⁺、NH₄⁺、K⁺、Mg²⁺、Ca²⁺）的分析.结果表明,NO₃^-、SO₄^2-、NH₄⁺是PM_2.5中最主要的3种水溶性无机离子,除Mg²⁺与Ca²⁺外,PM_2.5与WSⅡs （水溶性无机离子）之间的相关性显著,且移动源贡献占主导地位.阴阳离子平衡表明武汉市冬季灰霾期PM_2.5呈中性或弱酸性.通过混合单粒子拉格朗日综合轨迹模式模拟并采用分层聚类得出了4种主要的后向气流轨迹及相应的PM_2.5和水溶性离子浓度,结果表明区域传输对此次灰霾期影响较大.     

塔里木盆地沙尘气溶胶的柱质量密度特性

气溶胶质量密度是气溶胶重要的参数,它影响着大气中复杂的化学反应,也与气溶胶的传输过程和空间分布息息相关.基于MERRA-2再分析资料提供的气溶胶柱质量密度数据,研究了我国塔里木盆地1980—2018年长时间序列的沙尘气溶胶柱质量密度的时空分布特征.结果表明,沙尘气溶胶和沙尘PM_2.5气溶胶柱质量密度有很大的变化范围,平均值分别为0.33和0.086 g/m²,同时具有明显的年际、月和季节变化特征.沙尘气溶胶和沙尘PM_2.5气溶胶柱质量密度的年平均值在0.24~0.41和0.06~0.11 g/m²范围内变化;春季最大,其平均值分别为0.47和0.12 g/m²,冬季最小,其平均值分别为0.13和0.04 g/m²;月平均值最大出现在5月,分别为0.57和0.14 g/m²,最小在1月,分别为0.1和0.03 g/m².     

用常规探空资料估算Cn2和ε垂直变化初探

用南京、射阳的常规探空资料建立了估算折射率结构常数C_n²和湍能耗散率ε垂直变化理论模式。结果表明:用该理论模式计算的ε值与用天气脉冲多普勒雷达探测的速度谱宽σ_r²再估算得到的ε值有较好的一致性。     

Free tropospheric reservoir of natural sulfate

¹⁰Be is used as a spike of the natural background atmospheric aerosol to calculate the global flux of sulfur (F_S) into the free troposphere. The sulfate and¹⁰Be concentrations determined in polar snow are compared. On the basis of an annual¹⁰Be production rate of 1.21 10⁶ at.cm^-2, a very low figure of 2.9 Tg S a^-1 is calculated for F_S, which suggests that most of the sulfur emitted at ground level remains in the boundary layer. The role of OCS in the upper tropospheric sulfur budget is reviewed. It is also shown that cataclysmic volcanic eruptions may disturb considerably for 1–2 years this vast background tropospheric sulfur reservoir.     

Partialwellen in den halb- und vierteltäglichen gezeitenartigen Schwingungen der Atmosphäre

Zusammenfassung Es werden die Formen der möglichen Partialwellen in den atmosphärischen Gezeiten angegeben. Eine Analyse der geographischen Verteilung der halbtäglichen Luftdruckschwankung nach diesen Partialwellen zeigt, daß neben den seit langem bekannten Wellentypen, der wandernden (S ₂ ² ₂) und der stehenden (S ₂ ⁰ ₂) Welle, auch noch eine dritte Welle (S ₂ ³ ₃) mit beachtlicher Amplitude auftritt. Sie besteht aus einem System von drei Hoch- und drei Tiefdruckgebieten (Abb. 2), das in 3/2 Tagen die Erde umkreist. Ein Vergleich zwischen entsprechenden Partialwellen im Druck und in der Temperatur führt zur Aufstellung einer empirischen Resonanzkurve für die thermische Erregung. Ebensolche Analysen wurden für die Ortszeitglieder der vierteltäglichen Druckschwankungen und ihre jahreszeitlichen Variationen durchgeführt.

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Summary The patterns of the possible component waves in the atmospheric tides are described. A decomposition of the geographical distribution of the semidiurnal pressure oscillation into these component waves shows, that there exists a third wave (S ₂ ³ ₃) with appreciable amplitude besides the well known migrating (S ₂ ² ₂) and standing (S ₂ ⁰ ₂) waves. It consists of three high and three low pressure areas (Fig. 2) moving around the earth in 3/2 days. Comparisons between corresponding component waves in the pressure and temperature lead to the establishment of an empirical resonance curve for the thermal excitation. Similar decompositions have been made for the local time waves in the six-hourly pressure oscillations and their seasonal variations.

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Résumé L'auteur expose la structure des ondes partielles de la marée atmosphérique. Une analyse de la distribution géographique de la variation semi-diurne de la pression atmosphérique révèle qu'il existe, outre les ondes migratoires (S ₂ ² ₂) et fixes (S ₂ ⁰ ₂) bien connues, une troisième onde (S ₂ ³ ₃) à amplitude notable. Elle consiste en un système de trois aires de hautes et de basses (Fig. 2) pressions circulant autour du globe en un jour et demi. En comparant les ondes partielles de pression et de température, on peut dresser une courbe empirique de résonnance pour l'excitation thermique. Des analyses analogues ont été faites pour les oscillations d'un quart de jour de la pression et leur variation saisonnière.

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Mit 3 Textabbildungen

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Die Untersuchungen, über die hier berichtet wird, wurden bei einem mehrmonatigen Besuch im Department of Meteorology der New York University angestellt. Dieser Besuch wurde ermöglicht durch Zuwendungen des Geophysics Research Directorate of Air Force Cambridge Research Center, Air Research and Development Command, unter dem Contract No. AF 19 (604)-1006.     

Characteristics of ionic components in precipitation in Kitakyushu City,Japan

Precipitation samples were collected by filtrating bulk sampler in Kitakyushu City, Japan, from January 1988 to December 1990. Volume weighted annual mean of pH was 4.93, but the pH distribution indicated that most probable value lay in the range pH 6.0–6.4. Volume weighted annual mean concentrations of major ionic components were as follows; SO ₄ ^2– : 84.2, NO ₃ ^– : 28.1, Cl^–: 86.3, NH ₄ ⁺ : 45.5, Ca²⁺: 63.3, Mg²⁺: 27.0, K⁺: 3.4, Na⁺: 69.0 µ eq l^–1. The highest concentrations of these ionic components were observed in winter and the lowest occurred in the rainy season. The ratio of ex-SO ₄ ^2– /NO ₃ ^– exhibited the lowest ratio in summer, and the highest ratio in winter. Good correlations were obtained between Cl^– and Na⁺, ex-SO ₄ ²⁺ and ex-Ca²⁺, NO ₃ ^– and ex-Ca²⁺, and NH ₄ ⁺ and ex-SO ₄ ^2– , respectively. However, no correlation between Cl^– and Na⁺ with Ca²⁺ was observed. The relationship of H⁺ with (ex-SO ₄ ^2– + NO ₃ ^– ) - (ex-Ca²⁺ + NH ₄ ⁺ ) indicated positive correlation.     

Beryllium-7 Deposition and Its Relation to Sulfate Deposition

Deposition of ⁷Be, a cosmogenic radionuclide, was observed at the Meteorological Research Institute in Tsukuba, Japan from 1986 to 1993 and compared with those of several chemical species observed in Tsukuba over the same period. We found a correlation between the monthly depositions of ⁷ Be and SO ₄ ² -, a major acidic species. The correlation was especially strong for late spring and fall, when both species had high depositional fluxes. This correlation was also observed in precipitation samples collected daily in 1992 at the same site. The cause of this correlation is discussed in connection with the fact that the stratospheric aerosol is composed largely of SO ₄ ² -. ⁷ Be is produced in the upper atmosphere, and detection of ⁷Be, especially in spring and fall in Japan, can be regarded as detection of stratospheric aerosol. However, we conclude that the bulk of the SO ₄ ² - observed did not have a stratospheric or an upper tropospheric origin. The correlation, therefore, may present a new question regarding acidic deposition: Why does the deposition of stratospheric aerosol in Japan coincide with that of nss-SO ₄ ² - originally from anthropogenic sources on the Earth's surface?     

Latitudinal variation of measured O3 photolysis frequencies J(O1D) and primary OH production rates over the Atlantic Ocean between 50° N and 30° S

The latitudinal variation of the photolysis frequency of ozone to O(¹D) atoms, J(O¹D), was measured using a filter radiometer during the cruise ANT VII/1 of the research vessel Polarstern in September/October 1988. The J(O¹D) noon values exhibited a maximum of 3.6×10^-5 s^-1 (2 sr) at the equator and decreased strongly towards higher latitudes. J(O¹D) reached highest values for clean marine background air with low aerosol load and almost cloudless sky. The J(O¹D) data, measured under these conditions and a temperature of 295 K, can be expressed by: % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaamOsaiaacI% cacaqGpbWaaWbaaSqabeaaiiaacqWF8baFaaGccaqGebGaaeykaiaa% bccacqWF9aqpcaqGGaGaaeyzaiaabIhacaqGWbGaaeiiaiaabUhacq% GHsislcaaI4aGaaiOlaiaaicdacaaIYaGaeyOeI0IaaGioaiaac6ca% caaI4aGaaiiEaiaaigdacaaIWaWaaWbaaSqabeaacqGHsislcaaIZa% aaaOGaaeiiaiaabIhacaqGGaGaam4uaiabgUcaRiaaiodacaGGUaGa% aGinaiaacIhacaaIXaGaaGimamaaCaaaleqabaGaeyOeI0IaaGOnaa% aakiaadofadaahaaWcbeqaaiaaikdaaaGccaGG9bGaaeikaiaaboha% daahaaWcbeqaaiabgkHiTiaaigdaaaGccaGGPaaaaa!5EE9!\[J({\text{O}}^| {\text{D) }} = {\text{ exp \{ }} - 8.02 - 8.8x10^{ - 3} {\text{ x }}S + 3.4x10^{ - 6} S^2 \} {\text{(s}}^{ - 1} )\] where S represents the product of the overhead ozone column (DU) and the secant of the solar zenith angle. The meridional profile of the primary OH radical production rate P(OH) was calculated from the J(O¹D) measurements and simultaneously recorded O₃ and H₂O mixing ratios. While the latitudinal distribution of J(O¹D) and water vapour was nearly symmetric to the equator, high tropospheric ozone levels up to 40 ppb were observed in the Southern Hemisphere, SH, resulting in higher P(OH) in the SH.     

Laboratory Study of O(1S) Formation Process in the Photolysis of O3 and its Atmospheric Implications

A high-sensitive technique to detect O(¹S) atoms using vacuum ultraviolet laser-induced fluorescence (VUV-LIF) spectroscopy has been applied to study the O(¹S) production process from the UV photodissociation of O₃, N₂O, and H₂O₂. The quantum yields for O(¹S) formation from O₃ photolysis at 215 and 220 nm are determined to be (1.4 ± 0.4) × 10⁻⁴ and (5 ± 3) × 10⁻⁵, respectively. Based on thermochemical considerations, the O(¹S) formation from O₃ photolysis at 215 and 220 nm is attributed to a spin-forbidden process of O(¹S)+O₂(X³Σ_g ⁻). Analysis of the Doppler profile of O(¹S) produced from O₃ photolysis at 193 nm also indicates that the O(¹S) atoms are produced from the spin-forbidden process. In the photolysis of N₂O and H₂O₂ at 193 nm, no discernible signal of O(¹S) atoms has been detected. The upper limit values of the quantum yields for O(¹S) production from N₂O and H₂O₂ photolysis at 193 nm are estimated to be 8 × 10⁻⁵ and 3 × 10⁻⁵, respectively. Using the experimental results, the impact of the O(¹S) formation from O₃ photolysis on the atmospheric OH radical formation through the reaction of O(¹S)+H₂O has been estimated. The calculated results show that the contribution of the O(¹S)+H₂O reaction to the OH production rate is ∼2% of that of the O(¹D)+H₂O reaction at 30 km altitude in mid-latitude. Implications of the present laboratory experimental results for the terrestrial airglow of O(¹S) at 557.7 nm have also been discussed.     

Gamma Emitters on Micro-Becquerel Activity Level in Air at Kraków (Poland)

The Petryanov air filters combined into half-year sets were analyzed for the presence of ⁴⁰K, ¹³⁷Cs and ²²Na by means of low-background gamma rays spectrometry. Each sample contains aerosols from more than 1 Mm³ of air. Samples were collected in ground level air at Kraków (Southern Poland) from 1996 to 2002. Activity concentrations of ⁴⁰K are almost constant with the mean of 14.7± 4.5 Bq m^–3. Activity concentrations of ¹³⁷Cs, which are on the level of single Bq m^{– 3} show exponential decrease with effective half-life time of 7.07± 0.77 years. The cosmogenic ²²Na shows a strong seasonal variation with significant different mean values activity concentration between 0.333± 0.095 Bq m^–3 and 0.137± 0.045 Bq m^–3, for summer and winter, respectively. Moreover, the activity ratio for two cosmogenic radionuclides: ²²Na and measured previously ⁷Be show also changes with statistically significant seasonal differences. The lower values were found during winters. The mechanisms which might govern this ratio are discussed. The conclusion is that transport of ²²Na during summer seems to be so much effective, that results in kind of relative depletion of stratosphere of this nuclide.     

Size distributions of aerosol number concentrations and water-soluble constituents in Toyama, Japan: A comparison of the measurements during Asian dust period with non-dust period

Size-separated aerosol number concentrations and water-soluble constituents were measured in Toyama, the Hokuriku district, near the coast of the Japan Sea, during the spring and summer in 2003. The number concentrations of coarse particles were significantly high in April, which was due to Asian dust events called Kosa in Japanese. Particulate nssCa²⁺, which is mostly present in the coarse-mode particles, was significantly high in April. On the other hand, the concentrations of NH₄⁺ and nssSO₄²⁻, which mainly exist as the accumulation-mode particles were not high in April. The mass-size distributions of water-soluble constituents were compared with the size-separated number concentrations of particles. Backward trajectory analysis was also employed to examine the transport process of the air mass in Toyama.     

Characterization of iron and manganese species in atmospheric aerosols from anthropogenic sources

Electron paramagnetic resonance (EPR) was used to study the chemical form of iron, manganese and other paramagnetic species in airborne particles collected on southern coastal part of the North Sea, located in France. In parallel, chemical analysis was performed to obtain the metal concentrations in samples whereas an individual analysis of particles was provided by scanning electron microscopy coupled to an energy-dispersive X-ray spectrometer (SEM-EDX). EPR spectra have evidenced Fe³⁺ and Mn²⁺ ions in the form of isolated or agglomerated species, as well as carbonaceous products with variable signal intensities according to the wind direction. The monitoring of a signal of isolated Mn²⁺ ions on a distance close to 90 km was proposed as tracer of particles from a Mn local emission source. Fe³⁺ signals are relative to agglomerated species and differences in the type of interaction between these species were evidenced following the wind direction. Fe³⁺ EPR signals parameters revealing antiferromagnetic contribution in Fe-rich particles were found for an industrial origin at Dunkerque.     

Swaying of trees in response to wind and thinning in a stand of Scots pine

Observations have been made of the windspeed, wind direction, and tree movement at the edge and 20 m within a stand of Scots pine (Pinus sylvestris L.) close to 11 m in height. The spectra of windspeed near canopy top, together with the output of accelerometers and video observations of tree movement at mid-crown, were compared in the same stand prior and two years after first thinning. Furthermore, the transfer of wind energy into tree movement was investigated by calculating the mechanical transfer function (H _m ² ) between the wind spectrum (S _uu) and the tree's response (S _yy), i.e. H _m ² = S_yy/S_uu. Trees were found to behave like damped harmonic oscillators. They reacted to sudden increases in windspeed, reached their greatest displacement during the first cycle, and then returned to their rest position under the influence of damping. The spectral peak frequencies in S _yy and in H _m ²coincided with the estimated natural sway frequency of trees. Response in the second mode was, however, also evident, especially within the unthinned stand. The periodogram plots showed a consistent trend of a marked decrease in the response of the tree to increase in frequency. Almost no difference in the wind energy transfer, i.e. peak frequencies and peak width, and damping of the system was found between Scot pine at 2700 and 1500 stems per hectare. However, along the stand edge tree movement was greater than within the stand indicating greater wind energy transfer and damping of the system along the stand edge than within the stand.