On the location and orientation of the South Pacific Convergence Zone

Three semi-permanent cloud bands exist in the Southern Hemisphere extending southeastward from the equator, through the tropics, and into the subtropics. The most prominent of these features occurs in the South Pacific and is referred to as the South Pacific Convergence Zone (SPCZ). Similar bands, with less intensity, exist in the South Indian and Atlantic oceans. We attempt to explain the physical mechanisms that promote the diagonal orientation of the SPCZ and the processes that determine the timescales of its variability. It is argued that the slowly varying sea surface temperature patterns produce upper tropospheric wind fields that vary substantially in longitude. Regions where 200?hPa zonal winds decrease with longitude (i.e., negative zonal stretching deformation, or $ {{\partial \overline{U} } \mathord{\left/ {\vphantom {{\partial \overline{U} } {\partial x}}} \right. \kern-0em} {\partial x}} < 0 $ ) reduce the group speed of the eastward propagating synoptic (3?C6?day period) Rossby waves and locally increase the wave energy density. Such a region of wave accumulation occurs in the vicinity of the SPCZ, thus providing a physical basis for the diagonal orientation and earlier observations that the zone acts as a ??graveyard?? of propagating synoptic disturbances. In essence, $ {{\partial \overline{U} } \mathord{\left/ {\vphantom {{\partial \overline{U} } {\partial x}}} \right. \kern-0em} {\partial x}} = 0 $ demarks the boundary of the graveyard while regions where $ {{\partial \overline{U} } \mathord{\left/ {\vphantom {{\partial \overline{U} } {\partial x}}} \right. \kern-0em} {\partial x}} < 0 $ denote the graveyard itself. Composites of the life cycles of synoptic waves confirm this hypothesis. From the graveyard hypothesis comes a more general theory accounting for the SPCZ??s spatial orientation and its longer term variability influenced by the El Ni?o-Southern Oscillation (ENSO), or alternatively, the changing background SST associated with different phases of ENSO.     

Scalar Flux–Gradient Relationships Under Unstable Conditions over Water in Coastal Regions

The scalar flux–gradient relationships of temperature ( $\phi _{T}$ ? T ) and specific humidity ( $\phi _{q}$ ? q ) under unstable conditions are investigated using eddy-covariance measurements of air–sea turbulent fluxes and vertical profiles of temperature and specific humidity collected from a marine meteorological platform. The gradients of temperature and specific humidity are obtained from measurements at five heights above the sea surface using the log-square fitting method and the simpler first-order approximation method. The two methods yield similar results. The proposed flux–gradient relationships $\phi _{T}$ ? T and $\phi _{q}$ ? q covers a wide range of instability: the stability parameter $\zeta $ ζ ranges from $-$ ? 0.1 to $-$ ? 50. The functional form of the proposed flux–gradient relationships is an interpolation between the Businger–Dyer relation and the free convection relation, which includes the “ $-$ ? 1/2” and “ $-$ ? 1/3” scaling laws at two different stability regimes. The widely used COARE 3.0 algorithm, which is an interpolation between the integrals of the Businger–Dyer and the free convection relations, is also evaluated and compared. The analysis and comparisons show that both schemes generate reasonable values of $\phi _{q}$ ? q in the whole unstable regime. The COARE 3.0 algorithm, however, overestimates $\phi _{T}$ ? T values under very unstable conditions. The errors in the flux–gradient relationships induced by the random errors in the turbulence measurements are assessed. When the random errors are taken into account, the observations agree with predictions of various schemes fairly well, implying that the dominant transport mechanism is adequately captured by the Monin–Obukhov similarity theory. The study also shows that $\phi _{q}$ ? q is significantly ${>}\phi _{T}$ > ? T under unstable conditions and that the ratio $\phi _{q}/\phi _{T}$ ? q / ? T increases with $-\zeta $ ? ζ . The ratio of $\phi _{q}$ ? q to $\phi _{T}$ ? T and the ratio of turbulent transport efficiencies of heat and water vapour ( $R_{wT}/R_{wq}$ R wT / R wq ) suggest that heat is transported more efficiently than water vapour under unstable conditions.     

Investigation of the Flow Structure in Step-Up Street Canyons—Mean Flow and Turbulence Statistics

A step-up street canyon is a characteristic urban element composed of two buildings in which the height of the upwind building ( $H_\mathrm{u}$ ) is less than the height of the downwind building ( $H_\mathrm{d}$ ). Here, the effect of canyon geometry on the flow structure in isolated step-up street canyons is investigated through isothermal wind-tunnel measurements. The measurements were acquired along the vertical symmetry plane of model buildings using two-dimensional particle image velocimetry (PIV) for normal approach flow. The building-height ratios considered were: $H_\mathrm{d}/ H_\mathrm{u} \approx 3$ , and $H_\mathrm{d}/ H_\mathrm{u} \approx 1.67$ . For each building-height ratio, the along-wind lengths (L) of the upwind and downwind buildings, and the street-canyon width (S) were kept constant, with $L \approx S$ . The cross-wind widths (W) of the upwind and downwind buildings were varied uniformly from $W/S \approx 1$ through $W/S \approx 4$ , in increments of $W/S \approx 1$ . The objective of the work was to characterize the changes in the flow structure in step-up canyons as a function of W/S, for fixed L, S, and $H_\mathrm{d}/H_\mathrm{u}$ values. The results indicate that the in-canyon flow structure does not vary significantly for $H_\mathrm{d}/H_\mathrm{u} \approx 3$ for the W/S values considered. Qualitatively, for $H_\mathrm{d}/H_\mathrm{u} \approx 3$ , the upwind building behaves as an obstacle in the upwind cavity of the downwind building. In contrast, the flow patterns observed for the $H_\mathrm{d}/H_\mathrm{u} \approx 1.67$ configurations are unique and counter-intuitive, and depend strongly on building width (W/S). For $W/S \approx 1$ and $W/S \approx 2$ , the effect of lateral flow into the canyon is so prominent that even the mean flow patterns are highly ambiguous. For $W/S \approx 3$ and 4, the flow along the vertical symmetry plane is more shielded from the lateral flow, and hence a stable counter-rotating vortex pair is observed in the canyon. In addition to these qualitative features, a quantitative analysis of the mean flow field and turbulence stress field is presented.     

Vertical Distribution of Radiation and Energy Balance Partitioning Within and Above a Lodgepole Pine Stand Recovering from a Recent Insect Attack

The current outbreak of mountain pine beetle (MPB) that started in the late 1990s in British Columbia, Canada, is the largest ever recorded in the north American native habitat of the beetle. The killing of trees is expected to change the vertical distribution of net radiation ( $Q^*$ Q ? ) and the partitioning of latent ( $Q_\mathrm{E}$ Q E ) and sensible ( $Q_\mathrm{H}$ Q H ) heat fluxes in the different layers of an attacked forest canopy. During an intensive observation period in the summer of 2010, eddy-covariance flux and radiation measurements were made at seven heights from ground level up to 1.34 times the canopy height in an MPB-attacked open-canopy forest stand $(\hbox {leaf area index} = 0.55~\mathrm{{m}}^{2}\ \mathrm{{m}}^{-2})$ ( leaf area index = 0.55 m 2 m - 2 ) in the interior of British Columbia, Canada. The lodgepole pine dominated stand with a rich secondary structure (trees and understorey not killed by the beetle) was first attacked by the MPB in 2003 and received no management. In this study, the vertical distribution of the energy balance components and their sources and sinks were analyzed and energy balance closure (EBC) was determined for various levels within the canopy. The low stand density resulted in approximately 60 % of the shortwave irradiance and 50 % of the daily total $Q^*$ Q ? reaching the ground. Flux divergence calculations indicated relatively strong sources of latent heat at the ground and where the secondary structure was located. Only very weak sources of latent heat were found in the upper part of the canopy, which was mainly occupied by dead lodgepole pine trees. $Q_\mathrm{H}$ Q H was the dominant term throughout the canopy, and the Bowen ratio ( $Q_\mathrm{H}/Q_\mathrm{E}$ Q H / Q E ) increased with height in the canopy. Soil heat flux ( $Q_\mathrm{G}$ Q G ) accounted for approximately 4 % of $Q^*$ Q ? . Sensible heat storage in the air ( $\Delta Q_\mathrm{S,H}$ Δ Q S , H ) was the largest of the energy balance storage components in the upper canopy during daytime, while in the lower canopy sensible heat storage in the boles ( $\Delta Q_\mathrm{S,B}$ Δ Q S , B ) and biochemical energy storage ( $\Delta Q_\mathrm{S,C}$ Δ Q S , C ) were the largest terms. $\Delta Q_\mathrm{S,H}$ Δ Q S , H was almost constant from the bottom to above the canopy. $\Delta Q_\mathrm{S,C}$ Δ Q S , C , $\Delta Q_\mathrm{S,B}$ Δ Q S , B and latent heat storage in the air ( $\Delta Q_\mathrm{S,E}$ Δ Q S , E ) varied more than $\Delta Q_\mathrm{S,H}$ Δ Q S , H throughout the canopy. During daytime, energy balance closure was high in and above the upper canopy, and in the lowest canopy level. However, where the secondary structure was most abundant, ${\textit{EBC}} \le 66\,\%$ EBC ≤ 66 % . During nighttime, the storage terms together with $Q_\mathrm{G}$ Q G made up the largest part of the energy balance, while $Q_\mathrm{H}$ Q H and $Q_\mathrm{E}$ Q E were relatively small. These radiation and energy balance measurements in an insect-attacked forest highlight the role of secondary structure in the recovery of attacked stands.     

Improvements in Sensible Heat-Flux Parametrization in the High-Resolution Regional Model (HRM) Through the Modified Treatment of the Roughness Length for Heat

We discuss the impact of the differential treatment of the roughness lengths for momentum and heat ( $z_{0\mathrm{m}}$ and $z_{0\mathrm{h}}$ ) in the flux parametrization scheme of the high-resolution regional model (HRM) for a heterogeneous terrain centred around Thiruvananthapuram, India (8.5°N, 76.9°E). The magnitudes of sensible heat flux (H) obtained from HRM simulations using the original parametrization scheme differed drastically from the concurrent in situ observations. With a view to improving the performance of this parametrization scheme, two distinct modifications are incorporated: (1) In the first method, a constant value of 100 is assigned to the $z_{0\mathrm{m}}/z_{0\mathrm{h}}$ ratio; (2) and in the second approach, this ratio is treated as a function of time. Both these modifications in the HRM model showed significant improvements in the H simulations for Thiruvananthapuram and its adjoining regions. Results obtained from the present study provide a first-ever comparison of H simulations using the modified parametrization scheme in the HRM model with in situ observations for the Indian coastal region, and suggest a differential treatment of $z_{0\mathrm{m}}$ and $z_{0\mathrm{h}}$ in the flux parametrization scheme.     

Some Statistics of the Temperature Structure Parameter in the Convective Boundary Layer Observed by Sodar

The characteristics of the temporal and height variations of the temperature structure parameter $C_\mathrm{T}^{2}$ in strongly convective situations derived from the sodar echo-signal intensity measurements were analyzed for the first 100 m. It was corroborated that the probability density function (pdf) of the logarithm of $C_\mathrm{T}^{2}$ in the lower convective boundary layer is markedly non-Gaussian, whereas turbulence theory predicts it to be normal. It was also corroborated that the sum of two weighted Gaussians, which characterize the statistics of $C_\mathrm{T}^{2}$ within convective plumes and in their environment and the probability of plume occurrence, well approximates the observed pdfs. It was shown that the height behaviour of the arithmetic mean of $ C_\mathrm{T}^{2}$ (both total and within plumes) follows well a power law $C_\mathrm{T}^{2} (z) \sim z^{-q}$ with the exponent $q$ close to the theoretically predicted value of 4/3. But for the geometrical means of $C_\mathrm{T}^{2}$ (both total and within the plumes), $q$ is close to 1. The difference between arithmetically and geometrically averaged $C_\mathrm{T}^{2}$ profiles was analyzed. The vertical profiles of the standard deviation, skewness and kurtosis of $\hbox {ln}C_\mathrm{T}^{2}$ pdfs were analyzed to show their steady behaviour with height. The standard deviations of the logarithm of $C_\mathrm{T}^{2}$ within the plumes and between them are similar and are 1.5 times less than the total standard deviation. The estimate of the variability index $F_\mathrm{T}$ and its height behaviour were obtained, which can be useful to validate some theoretical and modelling predictions. The vertical profiles of the skewness and kurtosis show the negative asymmetry of pdfs and their flatness, respectively. The spectra of variations in $\hbox {ln}C_\mathrm{T}^{2}$ are shown to be satisfactorily fitted by the power law $f^{-\gamma } $ in the frequency range 0.02 and 0.2 Hz, with the average exponent $\approx $ 1.27  $\pm $  0.22.     

Alkyl nitrate formation from the reaction of a series of branched RO2 radicals with NO as a function of temperature and pressure

Alkyl nitrate yields from the NO _x photooxidations of neopentane, 2-methylbutane and 3-methylpentane have been determined over the temperature and pressure ranges 281–323 K and 54–740 torr, respectively. The formation of the alkyl nitrates is attributed to the reaction pathway (1b) $${\text{RO}}_{\text{2}} + {\text{NO}}^{{\text{ }}\underrightarrow {\text{M}}} {\text{ RONO}}_{\text{2}}$$ and rate constant ratios k _1b/(k _1a+k _1b) are estimated, where (1a) is the reaction pathway (1a) $${\text{RO}}_{\text{2}} + {\text{NO}} \to {\text{RONO}}_{\text{2}} .$$ A method for estimating this rate constant ratio for primary, secondary and tertiary alkyl peroxy radicals is presented.     

A Semi-Analytical Approach for Parametrization of the Obukhov Stability Parameter in the Unstable Atmospheric Surface Layer

A semi-analytical scheme is proposed to parametrize the Obukhov stability parameter \(\zeta \) (= \(z/L\) ; \(z\) is the height above the ground and \(L\) is the Obukhov length) in terms of the bulk Richardson number ( \(R_{iB}\) ) in unstable conditions within the framework of Monin–Obukhov similarity (MOS) theory. The scheme involves, (i) a solution of a cubic equation in \(\zeta \) whose coefficients depend on the gradient Richardson number ( \(R_{i}\) ), and (ii) a relationship between \(R_{i}\) and \(R_{iB}\) . The proposed scheme is applicable for a wide range (i) \(-5\le R_{iB}\le 0\) , (ii) \(0\le \hbox {ln}(z_{0}/z_{h})\le 29.0\) , and (iii) \(10\le z/z_{0}\le 10^{5}\) and performs relatively better than all other schemes in terms of accuracy in computation of surface-layer transfer coefficients. The absolute errors in computing the transfer coefficients do not exceed 7 %. The analysis presented here is found to be valid for different \(\gamma _{m}\) and \(\gamma _{h}\) appearing in the expressions of the similarity functions \(\varphi _{m}\) and \(\varphi _{h}\) (representing non-dimensional wind and temperature profiles), so long as the ratio of \(\gamma _{m}\) to \(\gamma _{h} \ge 1\) . The improved scheme can be easily employed in atmospheric modelling for a comprehensive range of \(R_{iB}\) and a variety of surfaces.     

An Approach to Minimizing Artifacts Caused by Cross-Sensitivity in the Determination of Air–Sea \text{ CO }_{2} Flux Using the Eddy-Covariance Technique

The air–sea $\text{ CO }_{2}$ flux was measured from a research vessel in the North Yellow Sea in October 2007 using an open-path eddy-covariance technique. In 11 out of 64 samples, the normalized spectra of scalars ( $\text{ CO }_{2}$ , water vapour, and temperature) showed similarities. However, in the remaining samples, the normalized $\text{ CO }_{2}$ spectra were observed to be greater than those of water vapour and temperature at low frequencies. In this paper, the noise due to cross-sensitivity was identified through a combination of intercomparisons among the normalized spectra of three scalars and additional analyses. Upon examination, the cross-sensitivity noise appeared to be mainly present at frequencies ${<}0.8\,\text{ Hz }$ . Our analysis also suggested that the high-frequency fluctuations of $\text{ CO }_{2}$ concentration (frequency ${>}0.8\,\text{ Hz }$ ) was probably less affected by the cross-sensitivity. To circumvent the cross-sensitivity issue, the cospectrum in the high-frequency range 0.8–1.5 Hz, instead of the whole range, was used to estimate the $\text{ CO }_{2}$ flux by taking the contribution of the high frequency to the $\text{ CO }_{2}$ flux to be the same as the contribution to the water vapour flux. The estimated air–sea $\text{ CO }_{2}$ flux in the North Yellow Sea was $-0.039\,\pm \,0.048\,\text{ mg } \text{ m }^{-2}\,\text{ s }^{-1},$ a value comparable to the estimates using the inertial dissipation method and Edson’s method (Edson et al., J Geophys Res 116:C00F10, 2011).     

Air–Sea \mathrm{CO}_{2} Gas Transfer Velocity in a Shallow Estuary

The air–sea transfer velocity of $\mathrm{CO}_{2}\, (k_{\mathrm{CO}_{2}})$ was investigated in a shallow estuary in March to July 2012, using eddy-covariance measurements of $\mathrm{CO}_{2}$ fluxes and measured air–sea $\mathrm{CO}_{2}$ partial-pressure differences. A data evaluation method that eliminates data by nine rejection criteria in order to heighten parametrization certainty is proposed. We tested the data evaluation method by comparing two datasets: one derived using quality criteria related solely to the eddy-covariance method, and the other derived using quality criteria based on both eddy-covariance and cospectral peak methods. The best parametrization of transfer velocity normalized to a Schmidt number of 600 $(k_{600})$ was determined to be: $k_{600} = 0.3\,{U_{10}}^{2.5}$ where $U_{10}$ is the wind speed in m $\mathrm{s}^{-1}$ at 10 m; $k_{600}$ is based on $\mathrm{CO}_{2}$ fluxes calculated by the eddy-covariance method and including the cospectral peak method criteria. At low wind speeds, the transfer velocity in the shallow water estuary was lower than in other coastal waters, possibly a symptom of low tidal amplitude leading to low intensity water turbulence. High transfer velocities were recorded above wind speeds of 5 m $\mathrm{s}^{-1}$ , believed to be caused by early-breaking waves and the large fetch (6.5 km) of the estuary. These findings indicate that turbulence in both air and water influences the transfer velocity.     

Transfer Coefficients of Momentum, Heat and Water Vapour in the Atmospheric Surface Layer of a Large Freshwater Lake

In studies of lake–atmosphere interactions, the fluxes of momentum, water vapour and sensible heat are often parametrized as being proportional to the differences in wind, humidity and air temperature between the water surface and a reference height above the surface. Here, the proportionality via transfer coefficients in these relationships was investigated with the eddy-covariance method at three sites within an eddy-covariance mesonet across Lake Taihu, China. The results indicate that the transfer coefficients decreased with increasing wind speed for weak winds and approached constant values for strong winds. The presence of submerged macrophytes reduced the momentum transfer (drag) coefficient significantly. At the two sites free of submerged macrophytes, the 10-m drag coefficients under neutral stability were 1.8 $(\pm \,0.4) \times \,10^{-3}$ ( ± 0.4 ) × 10 ? 3 and $1.7\,(\pm \,0.3) \times \,10^{-3 }$ 1.7 ( ± 0.3 ) × 10 ? 3 at the wind speed of $9\,\text{ m } \text{ s }^{-1}$ 9 m s ? 1 , which are 38 and 34 % greater than the prediction by the Garratt model for the marine environment.     

Turbulent Schmidt Numbers Above a Wheat Crop

Measurements of vertical fluxes and concentration differences above a spring wheat crop (height $h=0.9$ – $0.95$  m, row spacing 0.25 m, displacement height $d=0.5$ – $0.6$  m) were analyzed to determine the Schmidt numbers for water vapour ( $S^\mathrm{v}$ ) and carbon dioxide ( $S^\mathrm{c}$ ) based on concentration differences between intakes 2.55 and 3.54 m above the ground. During nearly-neutral stratification $S^\mathrm{v}(0) = 0.68 \pm 0.1$ while $S^\mathrm{c} = 0.78 \pm 0.2$ , implying that the roughness sublayer extended above $2.5 h$ .     

A New Sensitivity Analysis and Solution Method for Scintillometer Measurements of Area-Averaged Turbulent Fluxes

Scintillometer measurements of the turbulence inner-scale length $l_\mathrm{o }$ l o and refractive index structure function $C_n^2$ C n 2 allow for the retrieval of large-scale area-averaged turbulent fluxes in the atmospheric surface layer. This retrieval involves the solution of the non-linear set of equations defined by the Monin–Obukhov similarity hypothesis. A new method that uses an analytic solution to the set of equations is presented, which leads to a stable and efficient numerical method of computation that has the potential of eliminating computational error. Mathematical expressions are derived that map out the sensitivity of the turbulent flux measurements to uncertainties in source measurements such as $l_\mathrm{o }$ l o . These sensitivity functions differ from results in the previous literature; the reasons for the differences are explored.     

Numerical simulation of particle trajectories in inhomogeneous turbulence,III: Comparison of predictions with experimental data for the atmospheric surface layer

It is shown that predictions of a numerical trajectory-simulation method agree closely with the Project Prairie Grass observations of the concentrations 100 m downwind of a continuous point source of sulphur dioxide if the height (z) dependence of the Lagrangian length scale Λ _L is chosen as: whereL is the Monin-Obukhov length. The value of 0.5 for Λ _L /z in neutral conditions is consistent with the findings of Reid (1979) for the Porton experiment, and is also shown to be the best choice for simulation of an experiment in which concentration profiles were measured a short distance (< 40 m) downwind of an elevated point source of glass beads (40 μn diameter). $$\begin{gathered} \Lambda _L = 0.5z\left( {1 - 6\frac{z}{L}} \right)^{{1 \mathord{\left/ {\vphantom {1 4}} \right. \kern-\nulldelimiterspace} 4}} L< 0 \hfill \\ \Lambda _L = 0.5z/\left( {1 + 5\frac{z}{L}} \right)L > 0 \hfill \\ \end{gathered} $$      

Variability of the Structure Parameters of Temperature and Humidity Observed in the Atmospheric Surface Layer Under Unstable Conditions

The structure parameters of temperature and humidity are important in scintillometry as they determine the structure parameter of the refractive index of air, the primary atmospheric variable obtained with scintillometers. In this study, we investigate the variability of the logarithm of the Monin-Obukhov-scaled structure parameters (denoted as $\log ({\widetilde{C_{s}^2}_{\mathrm {}}})$ ) of temperature and humidity. We use observations from eddy-covariance systems operated at three heights (2.5, 50, and 90 m) within the atmospheric surface layer under unstable conditions. The variability of $\log ({\widetilde{C_{s}^2}_{\mathrm {}}})$ depends on instability and on the size of the averaging window over which $\log ({\widetilde{C_{s}^2}_{\mathrm {}}})$ is calculated. If instability increases, differences in $\log ({\widetilde{C_{s}^2}_{\mathrm {}}})$ between upward motions (large $C_{s}^2$ ) and downward motions (small $C_{s}^2$ ) increase. The differences are, however, not sufficiently large to result in a bimodal probability density function. If the averaging window size increases, the variances of $\log ({\widetilde{C_{s}^2}_{\mathrm {}}})$ decrease. A linear regression of the variances of $\log ({\widetilde{C_{s}^2}_{\mathrm {}}})$ versus the averaging window size for various stability classes shows an increase of both the offset and slope (in absolute sense) with increasing instability. For temperature, data from the three heights show comparable results. For humidity, in contrast, the offset and slope are larger at 50 and 90 m than at 2.5 m. In the end we discuss how these findings could be used to assess whether observed differences in $C_{s}^2$ along a scintillometer path or aircraft flight leg are just within the range of local variability in $C_{s}^2$ or could be attributed to surface heterogeneity. This is important for the interpretation of data measured above a heterogeneous surface.     

Surface influence upon vertical profiles in the nocturnal boundary layer

Near-surface wind profiles in the nocturnal boundary layer, depth h, above relatively flat, tree-covered terrain are described in the context of the analysis of Garratt (1980) for the unstable atmospheric boundary layer. The observations at two sites imply a surface-based transition layer, of depth z _*, within which the observed non-dimensional profiles Φ _M ⁰ are a modified form of the inertial sub-layer relation \(\Phi _M \left( {{z \mathord{\left/ {\vphantom {z L}} \right. \kern-0em} L}} \right) = \left( {{{1 + 5_Z } \mathord{\left/ {\vphantom {{1 + 5_Z } L}} \right. \kern-0em} L}} \right)\) according to $$\Phi _M^{\text{0}} \simeq \left( {{{1 + 5z} \mathord{\left/ {\vphantom {{1 + 5z} L}} \right. \kern-\nulldelimiterspace} L}} \right)\exp \left[ { - 0.7\left( {{{1 - z} \mathord{\left/ {\vphantom {{1 - z} z}} \right. \kern-\nulldelimiterspace} z}_ * } \right)} \right]$$ , where z is height above the zero-plane displacement and L is the Monin-Obukhov length. At both sites the depth z _* is significantly smaller than the appropriate neutral value (z _*N ) found from the previous analysis, as might be expected in the presence of a buoyant sink for turbulent kinetic energy.     

Tropospheric degradation products of CH2FCF3 (HFC-134a)

Chlorine atom-initiated photooxidations of CH₂FCF₃ (HFC-134a) in O₂-N₂ diluent were carried out to identify the products formed from the \(CF_3 CHF\dot O\) radical reactions and to determine the product yields as a function of temperature, pressure and O₂ concentration. CF₃C(O)F and HC(O)F were the major ‘first-generation’ products observed, along with smaller yields of C(O)F₂ and, as yet, undetermined yields of CF₃OOOCF₃ and CF₃OOC(O)F. The relative importance of the two major \(CF_3 CHF\dot O\) reaction pathways, is expressed by the rate constant ratio $$k_{O_2 } /k_d = 3.2 \times 10^{ - 25} e^{(3510 \pm 470)/T} cm^3 molecule^{ - 1}$$ The decomposition reaction leading to HC(O)F and ?F₃ radical products is predicted to be the dominant pathway at the Earth's surface while mainly CF₃C(O)F formation will occur at the tropopause.     

Parametrization of orographical effects in the planetary boundary layer

Studies of the influence of orography on the dynamics of atmospheric processes usually assume the following relation as a boundary condition at the surface of the Earth, or at the top of the planetary layer: $$w = u\frac{{\delta z_0 }}{{\delta x}} + v\frac{{\delta z_0 }}{{\delta y}}$$ where u, v and w are the components of wind velocity along the x, y and z axes, respectively, and z ₀ = z₀(x, y) is the equation of the Earth's orography. We see that w, and consequently the influence of orography on the dynamics of atmospheric processes, depend on the wind (u, v) and on the slope of the obstacle (δz ₀/δx, δz₀/δy). In the present work, it is shown that the above relation for w is insufficient to describe the influence of orography on the dynamics of the atmosphere. It is also shown that the relation is a particular case of the expression: $$\begin{gathered} w_h = \left| {v_g } \right|\left[ {a_1 (Ro,s)\frac{{\delta z_0 }}{{\delta x}} + a_2 (Ro,s)\frac{{\delta z_0 }}{{\delta y}}} \right] + \hfill \\ + \frac{{\left| {v_g } \right|^2 }}{f}\left[ {b_1 (Ro,s)\frac{{\delta ^2 z_0 }}{{\delta x^2 }} + b_2 (Ro,s)\frac{{\delta ^2 z_0 }}{{\delta y^2 }} + b_3 (Ro,s)\frac{{\delta ^2 z_0 }}{{\delta x\delta y}}} \right] \hfill \\ \end{gathered} $$ where ¦vv _g¦ is the strength of the geostrophic wind, a ₁, a₂, b₁, b₂, b₃ are functions of Rossby number Ro and of the external stability parameter s. The above relation is obtained with the help of similarity theory, with a parametrization of the planetary boundary layer. Finally, the authors show that a close connection exists between the effects described by the above expression and cyclo- and anticyclogenesis.