云南大坪金矿新元古代成矿事件——来自热液锆石和闪长岩U-Pb年代学及Hf同位素的约束

大坪金矿是哀牢山-红河韧性剪切带南段最重要的大型金矿床之一,由于其成矿时代和构造背景一直存在争议,不利于带内金矿床成矿模型的建立和进一步找矿勘探。本文利用LA-ICP-MS对矿区内含金石英脉中热液锆石、闪长岩和花岗闪长岩脉中岩浆锆石开展了U-Pb年代学研究,获得热液锆石U-Pb年龄为760±10 Ma,表明大坪金矿区可能存在新元古代金矿化事件;获得闪长岩和花岗闪长岩脉的锆石U-Pb年龄分别为773±9 Ma和766±9 Ma,与区域上Rodinia超大陆裂解和哀牢山地区的晋宁-澄江期大规模火山-岩浆活动事件时代一致。热液锆石与闪长岩、花岗闪长岩脉具有相似的Hf同位素组成特征和在误差范围内一致的年龄,表明新元古代金矿化事件可能与闪长岩和花岗闪长岩脉的侵入有密切的成因联系。本文新元古代成矿事件的厘定,结合前人的新生代始新世—渐新世为大坪金矿主要成矿时期的研究结果,表明大坪金矿可能是新元古代和新生代不同岩浆-构造-热液事件叠加成矿作用的产物。     

粤西黄泥坑金矿床地质地球化学特征和成矿时代

粤西黄泥坑金矿是近年来新发现的一个中-大型金矿床。其成矿作用分为石英-黄铁矿阶段、石英-多金属硫化物阶段和石英-碳酸盐阶段。其中,石英-黄铁矿阶段为金的主成矿阶段。对含金石英脉进行了流体包裹体Rb-Sr同位素定年,获得等时线年龄为(233.4±8.6)Ma(MSWD=2.3,n=5),表明黄泥坑金矿形成于印支期。对矿区花岗闪长岩进行了锆石LA-ICP-MS U-Pb定年,获得的206Pb/238U加权平均年龄为(451.1±2.7)Ma(MSWD=2.1,n=21),表明其形成于加里东期。综合分析花岗闪长岩和矿石的微量元素分析数据及已有的研究成果显示,黄泥坑金矿床中金的来源并非加里东期花岗闪长岩,可能来自于寒武系及隐伏的晚期岩浆岩。矿床的形成主要受罗定-广宁推覆构造控制,挤压推覆后拉张剪切作用形成的剪切破碎带及其热液蚀变作用与成矿密切相关。     

粤西河台金矿床富硫化物含金石英脉锆石U-Pb 测年及成矿意义

河台金矿是一个强烈受韧性剪切带控制的金矿床,金的成矿主要发生在热液蚀变成矿期的金石英脉阶段和金硫化物阶段,形成的矿石有蚀变糜棱岩型和富硫化物石英脉型.富硫化物含金石英脉中单颗粒锆石U-Pb同位素测年显示早加里东期是河台金矿床主成矿期,成矿年龄为492±16Ma;矿区燕山期伍村花岗岩的单颗粒锆石年龄为153.6±2.1Ma;结合已有的同位素资料,认为河台金矿床是华南加里东期构造-变质-岩浆作用及成矿作用的一个组成部分,是一个早加里东期造山作用同期的造山带型金矿床,并可能有燕山期的热液叠加成矿作用.     

黑龙江省塔河县宝兴沟金矿床地质特征及成矿构造环境

黑龙江省塔河县宝兴沟岩金矿床位于上黑龙江前陆盆地南缘,是近年来发现的具较大找矿潜力的岩金矿床。矿床产于浅成侵入岩与砂岩地层接触部位及侵入体内部。矿床地球化学研究表明,闪长玢岩、石英闪长岩与成矿关系密切,两者同属于高钾钙碱性岩石,富集轻稀土元素, Eu异常不明显,富集大离子亲石元素Rb、Th、K,亏损高场强元素Nb、Ta、Ti、Zr和重稀土元素Yb、Y。单颗粒锆石LA-ICP-MS法U-Pb同位素定年结果表明：石英闪长岩成岩时间为（124.92±1.3）Ma;花岗细晶岩测年结果为150～450 Ma,推测花岗细晶岩成岩时间可能为156 Ma左右。宝兴沟金矿床是在早白垩世由挤压转变为伸展环境的构造-岩浆-热液作用的产物,金矿化作用应发生在107.5～124.92 Ma;大兴安岭北段存在一期与早白垩世岩浆活动相伴的金矿化作用。因此,燕山晚期（早白垩世）岩浆活动地段尤其是浅成侵入体发育地区是今后重要的金矿化找矿方向之一。     

新疆哈图-包古图金铜矿集区锆石年龄及成矿特点

晚古生代,新疆西准噶尔地区发生了强烈的构造-岩浆活动和广泛的金、铜成矿作用,形成了哈图-包古图大型金铜矿集区。锆石SHRIMP U-Pb年龄测量表明,含矿闪长岩体形成于312.3±2.2Ma～332.0±2.8Ma,矿集区岩浆活动及其成矿作用发生在石炭纪。哈图-包古图矿集区成矿作用有4个显著特点:(1)地幔流体活动强烈;(2)构造应力转化快速;(3)拉斑系列和钙碱性系列岩浆成矿;(4)多种矿化类型集中发育等。哈图-包古图矿集区发育石英脉型-蚀变岩型金矿床、斑岩型铜矿床和同期的石英脉型-蚀变岩型金矿床以及热液脉型铜金矿床的成矿系列。     

吉林夹皮沟金矿带岩脉和蚀变绢云母定年及金矿成矿时代

吉林夹皮沟金矿床的矿化年龄一直存在争议。采用先进的SHRIMP测年方法测得夹皮沟二道沟金矿床的花岗闪长岩脉锆石的2 0 6Pb/ 2 3 8U年龄为 (2 2 3± 2 )Ma ;八家子金矿床的石英正长斑岩锆石的2 0 6Pb/ 2 3 8U年龄为 (2 41± 6 )～ (2 18± 6 )Ma。这一结果与前人测得的K Ar年龄基本相符。这两条岩脉与含金石英脉同构造空间 ,形成时代相近 ,因此上述岩脉年龄大体反映了金矿化年龄。同时还测得八家子金矿床蚀变绢云母的 4 0 Ar 3 9Ar等时线年龄为(2 0 3 975± 0 5 2 7)Ma ,进一步证明金矿化发生在中生代印支期。矿石中含有大量的方铅矿 ,还存在矿物及元素的分带 ,这些特征表明夹皮沟金矿床不太可能是新太古代或元古代形成的变质热液矿床 ,更大可能是中生代与岩浆活动有关的岩浆热液矿床     

皖东苏家湾地区三里陈岩体LA-ICP-MS锆石U-Pb年代学研究

三里陈岩体位于长江中下游成矿带滁县-庐江铜金成矿亚带中部,岩性主要为闪长岩和花岗闪长斑岩,LA-ICP-MS锆石U-Pb定年测得闪长岩年龄为126.9±1.8Ma,花岗闪长斑岩锆石U-Pb年龄为126.0±1.0Ma,两者均为早白垩世岩浆活动的产物。闪长岩中存在的大量继承锆石的年龄分布在2.5～1.9Ga之间,峰值为2.0Ga,暗示其岩浆源区主要为华南板块,可能混有华北板块源区的物质。结合滁县-庐江铜金成矿亚带成岩时代及矿化特征,发现三里陈岩体与铜金矿床(点)成矿岩体的形成时代相近,岩性一致,与围岩接触带发育的蚀变和矿化特征相似,认为这些侵入岩体均为同一构造-岩浆-成矿事件的产物,三里陈岩体及其外围地区具有寻找一定规模矽卡岩型铜金矿床的潜力。     

东昆仑巴隆河西金矿地质特征与找矿标志

巴隆河西金矿床是东昆仑金成矿带近年来新发现的金矿床,其形成时代、地质特征与矿床类型尚不明确。本次在详细野外地质调查的基础上,通过构造-蚀变填图、锆石U-Pb定年和综合对比等方法,研究巴隆河西矿床的成矿特征和岩体侵位时代,以确定该矿床的成因类型与成矿时代。构造-蚀变填图发现巴隆河西矿床的金矿化赋存于花岗质岩体的9条构造蚀变带,明确了5个金矿体呈带状分布于北西西向断裂中,揭示金矿化与高岭土化、褐铁矿化、硅化和黄铁矿化等蚀变密切相关。赋含金矿化的花岗闪长岩和花岗斑岩的锆石U-Pb定年结果表明,其侵位时代分别为202.5±1.8 Ma和222.1±1.1Ma,属于印支晚期,约束了巴隆河西金矿的形成时代。结合区域岩浆活动时限、巴隆金矿地质特征、矿体产状与中低温矿物组合特征,提出巴隆河西矿床为造山带型金矿,推断逆断层及其伴随的热液活动是巴隆河西矿床金元素活化、迁移和富集的关键因素,指出北西西向构造蚀变带是该区带金矿成矿的有利部位。     

皖南东至查册桥金矿岩浆岩锆石U Pb年龄及其成矿意义

安徽省东至县查册桥金矿是近年来在江南过渡带上新发现的具一定规模的金矿床,包括多个矿段(点)。矿体受NNE向、NE向及近EW向断裂控制。矿化类型以高硫浅成低温热液型金(锑)矿化为主。其矿床的形成与燕山期岩浆活动有密切的时空和成因联系,区内岩浆岩主要有花岗斑岩、花岗闪长岩、花岗闪长斑岩、闪长玢岩及英安玢岩。本文通过对区内岩浆岩LA-ICP-MS锆石U-Pb测年,确定了区内岩体成岩时间晚侏罗世到早白垩世之间,花岗闪长斑岩在143~148Ma侵位,花岗闪长岩侵位年龄为145Ma,闪长玢岩略晚(142Ma),金多金属矿化稍晚,且持续时间较长。矿区岩浆岩中均发育大量继承锆石,反映有大量成岩物质来源于古老地壳基底,与岩浆岩的成因类型(壳幔同熔型)对应,并与所处的江南过渡带的大地构造位置(江南过渡带)及地质构造发展历史有关。(2522±72Ma)古老的继承锆石年龄,指示本区存在太古代基底物质;较为广泛的新元古代600~1000Ma继承锆石年龄数据,反映了江南过渡带晋宁期扬子陆块与华夏陆块碰撞造山过程所形成的物质再循环到本区燕山期岩浆活动与成矿过程中去。查册桥金矿成矿作用与岩浆期后大规模热液蚀变相联系,并在持续的岩浆活动和热液作用下富集和成矿。综合成矿地质背景、成岩成矿年代学,可以认为,查册桥金矿是一个受断裂构造控制的、与燕山期中酸性岩浆作用密切相关的浅成低温热液型金矿床。     

辽东半岛五龙金矿成矿系统新认识：来自外围热液角砾岩型铅锌矿化的指示

五龙金矿是辽东半岛形成于早白垩世的代表性石英脉型金矿。本文报道了在五龙矿区边部新发现的热液角砾岩型铅锌矿化及其密切相关的闪长岩的特征,这对进一步认识五龙成矿系统提供了新的指示。热液角砾岩属于岩浆热液爆破角砾岩,铅锌矿化分布在角砾岩石英胶结物和石英脉内。角砾岩下伏和旁侧的闪长岩内可见梳状结构和晶洞结构,也可见蚀变和矿化发育,指示闪长岩与角砾岩具有密切的成因联系。角砾岩的石英胶结物和含矿石英脉的δ~(18) O_(H_2O)在-2.7‰～0.1‰之间、δD_(V-SMOW)在-71.5‰～-85.9‰之间,指示矿化流体为岩浆水和大气降水混合成因,与五龙金矿晚阶段成矿流体性质基本相同。闪长岩的锆石U-Pb测年指示其结晶年龄为120.9 ± 1.3Ma,与五龙金矿成矿时代近于一致。闪长岩与五龙成矿系统具有密切的时间、空间和成因联系,可以作为"桥梁"连接岩浆作用和成矿作用。闪长岩属于高钾钙碱性系列,具有轻稀土富集、无铕异常的稀土配分模式,以及富集大离子亲石元素(Rb、Ba)而亏损高场强元素(Nb、Zr、Hf)的微量元素特征,其(~(87)Sr/~(86)Sr)_t值在0.711～0.712之间、ε_(Hf)(t)值在-8.2～-9.0之间、ε_(Hf)(t)值在-21.2～-22.8之间,推测其主要为富集岩石圈地幔部分熔融的产物,认为富含相容元素的幔源岩浆源区是金成矿的重要物质基础。五龙矿床石英脉型金矿与热液角砾岩型铅锌矿化属于同一岩浆热液系统的不同位置的表现样式,预测整个成矿系统深部可能发育有赋存于岩体(株)内外接触带的席状石英脉型矿化和浸染状矿化。     

Police, politics, and the right to the city

Space and spatiality have recently been at the core of debates concerning the political possibilities of the city. The arguments advanced in this paper might be seen as an attempt to contribute to these debates through a reflection on the spatiality of (in) justice, politics, and the right to the city. The case of French urban policy, with its focus on distressed urban areas, and the `suburban problem' in France are used as examples to make arguments more concrete.     

Rb-Sr, K-Ar, H-and O-Isotope systematics of the Middle Riphean shales from the Debengda Formation, the Olenek Uplift, North Sibera

Clay subfractions (SFs) of <0.1, 0.1–0.2, 0.2–0.3, 0.3–0.6, 0.6–2 and 2–5 μm separated from Middle Riphean shales of the Debengda Formation are studied using the TEM, XRD, K-Ar and Rb-Sr isotopic methods. The oxygen and hydrogen isotope compositions in the SFs are studied as well. The low-temperature illite-smectite is dominant mineral in all the SFs except for the coarsest ones. The XRD, chemical and isotopic data imply that two generations of authigenic illite-smectite different in age are mixed in the SFs. The illite crystallinity index decreases in parallel with size diminishing of clay particles. As compared to coarser SFs, illite of fine-grained subfractions is enriched in Al relative to Fe and Mg, contains more K, and reveals higher K/Rb and Rb/Sr ratios. The Rb-Sr age calculated by means of the leachochron (“inner isochron”) method declines gradually from 1254-1272 Ma in the coarsest SFs to 1038-1044 Ma in finest ones, while the K-Ar age decreases simultaneously from 1225–1240 to 1080 Ma. The established positive correlation of δ¹⁸O and δD values with dimensions of clay particles in the SFs seems to be also consistent with the mixing systematics. The isotopic systematics along with data on mineral composition and morphology lead to the conclusion that mixedlayer illite-smectite was formed in the Debengda shales during two periods 1211–1272 and 1038–1080 Ma ago. The first period is likely close to the deposition time of sediments and corresponds to events of burial catagenesis, whereas the second one is correlative with the regional uplift and changes in hydrological regime during the pre-Khaipakh break in sedimentation.     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Influences of the unsaturated,saturated, and riparian zones on the transport of nitrate near the Merced River,California, USA

Transport and transformation of nitrate was evaluated along a 1-km groundwater transect from an almond orchard to the Merced River, California, USA, within an irrigated agricultural setting. As indicated by measurements of pore-water nitrate and modeling using the root zone water quality model, about 63% of the applied nitrogen was transported through a 6.5-m unsaturated zone. Transport times from recharge locations to the edge of a riparian zone ranged from approximately 6 months to greater than 100 years. This allowed for partial denitrification in horizons having mildly reducing conditions, and essentially no denitrification in horizons with oxidizing conditions. Transport times across a 50–100-m-wide riparian zone of less than a year to over 6 years and more strongly reducing conditions resulted in greater rates of denitrification. Isotopic measurements and concentrations of excess N₂ in water were indicative of denitrification with the highest rates below the Merced River. Discharge of water and nitrate into the river was dependent on gradients driven by irrigation or river stage. The results suggest that the assimilative capacity for nitrate of the groundwater system, and particularly the riverbed, is limiting the nitrate load to the Merced River in the study area.     

扬子北缘马元铅锌矿床闪锌矿微量元素及S-Pb-He-Ar-C同位素地球化学研究

马元铅锌矿床是近年扬子陆块北缘铅锌找矿的新突破。矿体呈层状、似层状产于碑坝隆起翼部震旦系灯影组角砾状白云岩层间构造带中,围岩蚀变很弱。矿石中硫化物以闪锌矿、方铅矿为主,中粗粒晶质结构,充填于白云岩角砾间。闪锌矿富集Cd、Ge、Ag,贫In、Tl、Se,Ga/In为6~132,Ge/In多1000,成矿温度以中-低温为主。金属硫化物ε~(34)S值相对集中,为12.9‰~19.4‰,平均为17.4‰,来自于海相硫酸盐的还原。铅同位素组成稳定,~(206)Pb/~(204)Pb为17.858~17.918:~(207)Pb/~(204)Pb为15.603~15.694;~(208)Pb/~(204)Pb为37.756~38.046,具有造山带和上地壳铅的特征,震旦系可能提供了金属成矿物质。闪锌矿中流体包裹体的~3He/~4He为0.03Ra~1.05Ra,~(40)Ar/~(36)Ar为326.1~765.1,~(38)Ar/~(36)Ar为0.183~0.204,表明成矿流体主要为地壳流体和饱和大气水(大气降水或海水)的混合。闪锌矿内流体包裹体挥发分δ~(13)C_(CH_4)值为-36.01‰~-28.80‰,δ~(13)C_(C_2H_6)值为-27.72‰~-22.44‰,δ~(13)C_(CO_2)值为-23.24‰~-9.68‰,表明有机流体参与了成矿作用。石英、方解石的H-O同位素结果表明具有海水和有机水混合的特征。可见,成矿流体具有两种流体混合的特征,一为蒸发海水与围岩反应所形成的盆地卤水,二为有机流体。推测矿区可能存在一个古油气藏,由于TSR生成一高硫气藏,为区内还原性有机流体的主要来源。当富含Pb、Zn等成矿物质的成矿流体运移至富含CH_4和H_2S的还原性流体的矿区角砾岩带时,两种流体混合,Pb、Zn等遇到H_2S发生反应而沉淀成矿,并伴生热液白云石等,形成了马元铅锌矿床。综上所述,我们认为马元矿床属MVT型铅锌矿床。     

贵州岑巩羊桥罗家塘杷榔动物群的发现及其后生动物早期演化的意义

岑巩县羊桥乡罗家塘杷榔组仅出露中-上部地层,岩性单一,均为青灰、灰绿色粉砂质泥、页岩.在其上部层位发现了俞氏贵州始海百合(Guizhoueocrinus yui Zhao,Parsley et Peng,2007),计有棘皮动物始海百合、腕足动物、软体动物-软舌螺、节肢动物-三叶虫等8属9种,包括了2个未定名的新种和1...     

Breakthroughs in the biodiversity, biogeography, biostratigraphy, and basin analysis of the Beaufort group

Over the past decade researchers working on the rocks of the Beaufort Group in the main Karoo Basin of South Africa have vastly increased our understanding of this important Permo-Triassic sequence. Many new fossil forms have been discovered, allowing for breakthroughs into the biodiversity, biogeography and biostratigraphy of the group. Taxonomic and phylogenetic advances are many and varied, and cover most of the vertebrate taxa, but with emphasis placed on the temnospondyl amphibians, archosauriforms and non-mammalian synapsids, in particular the anomodontia. Biostratigraphic breakthroughs have centered on the Middle Permian Eodicynodon and Tapinocephalus assemblage zones, the Late Permian Dicynodon Assemblage Zone, and the Triassic Lystrosaurus and Cynognathus assemblage zones. Correlation of these biozones with better dated sequences in Europe, Russia and China has allowed for many chronostratigraphic refinements, which are in turn vital for sequence stratigraphical analysis of the basin fill. Based on fossil data, both the lower (Ecca–Beaufort) and upper (Beaufort–Molteno) contacts of the group have been proved to be highly diachronous. The refined chronostratigraphic framework has also allowed for a better analysis of the basin evolution through time, particularly in terms of the correlation of external stimuli that affect basin sedimentation patterns.     

Delivery of Trace Metals (Al,Fe, Mn,V, Co,Ni, Cu,Cd, Ag,Pb) from the Trinity River Watershed Towards the Ocean

The Trinity River (Texas, USA) contains in its watershed 23 different reservoir lakes, the largest one being Lake Livingston situated in the lower Trinity River watershed and two potentially polluting metroplexes, Dallas and Houston. In order to determine fluxes of nutrients and trace metals to Galveston Bay, a survey that included 24 discreet samples collected over a year and at various stages of discharge was carried out during 2000–2001. Geochemical (i.e., sorption by Fe oxyhydroxides), biological (i.e., seasonal uptake by sinking algae in Lake Livingston), and hydrological (i.e., dilution effects by increasing flow rates) controls were found to be mainly responsible for variations in dissolved trace metal concentrations rather than pollution sources. The Trinity River loads of suspended sediments and pollutant trace metals entering Galveston Bay at Anahuac were <20% of those reaching Lake Livingston, and only a few percent of the total upstream trace metal load is entering the Gulf of Mexico. Thus, during the transit through the 23 man-made lakes and an estuary, >96% of the pollutant trace metal load is lost to sediments.     

深港西部通道填海区地下水铜、钒、铊、镉、钨迁移的实验研究

填海工程使滨海地区的地下水物理化学条件改变,导致该区域地下水中重金属浓度升高。本文以深港西部通道填海区为例,采用实验室模拟填海条件的办法,初步探讨了影响填海区地下水重金属迁移的关键因素。模拟实验结果表明,填海区地下水中钨元素含量升高与地下水淡化、淤泥氧化过程以及填料风化有关;铜元素含量升高则与淤泥氧化过程以及填料风化有关;钒元素含量升高与地下水淡化和淤泥氧化过程有关,而其他元素含量升高则主要与填料风化释放有关。