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1.
李凯  万欢 《物探与化探》2019,(3):494-501
乐平涌山地区隶属于钦杭成矿带东段塔前—赋春铜多金属成矿带。在该地区开展1∶1万土壤地球化学测量工作,分析元素地球化学特征、单元素异常特征、元素组合特征及结合成矿地质背景,共圈定18处综合异常,通过对综合异常进行分类评价及评序,优选出较好的3处异常开展异常详细查证工作。经地表探槽揭露,新发现金矿(化)点2处,揭露金矿体2条,金矿化体2条,取得较好的找矿效果,认为该区找矿前景良好,是寻找矽卡岩型铜矿、韧性剪切型金矿的有利地区。  相似文献   

2.
《四川地质学报》2016,(4):667-671
通过对长田钨多金属矿区开展1∶1万土壤地球化学测量,分析研究了该区元素地球化学特征、单元素异常特征、异常赋存的地质环境等,综合地质资料,在研究区圈定了4个土壤地球化学异常,经查证,其中Ⅰ号、Ⅳ号异常具有较好的找矿前景,为下步找矿工作的重点靶区。  相似文献   

3.
河南省信阳市新县上棋盘地区位于近南北向光山千鹅冲—新县上棋盘钼异常带上,具有较好的钼矿找矿前景。笔者叙述了该区1∶20万、1∶5万水系沉积物测量综合特征,着重探讨了1∶1万土壤地球化学测量异常特征,利用地质累积指数对研究区内的土壤地球化学元素组合进行评价,经槽探和钻探工程验证,发现7条钼矿体,取得了较好找矿成果。  相似文献   

4.
青海多彩当江地区位于三江多金属成矿带,具有较好的找矿前景。以该区1∶5万水系沉积物地球化学测量数据为研究对象,结合研究区内的米扎纳能铜-铅-锌多金属矿床的水系沉积物地球化学结构特征与地质特征进行了剖析,总结了研究区的地质-地球化学找矿标志,并提出了龙格东多铜-锌多金属找矿远景区,为该区的找矿工作提供了新方向。  相似文献   

5.
通过内蒙古额济纳旗沙河北幅1∶5万区域地质调查、1∶5万土壤地球化学测量和1∶1万土壤地球化学剖面测量,结合区域地质特征,对区域土壤地球化学数据进行元素含量特征、单元素异常、元素组合异常的分析,根据异常检查和土壤地球化学剖面验证结果,发现了较好的土壤地球化学异常地段,并对该异常进行解释评价,从而圈定找矿靶区,并提出进一...  相似文献   

6.
通过对长田钨多金属矿区开展1∶1万土壤地球化学测量,分析研究了该区元素地球化学特征、单元素异常特征、异常赋存的地质环境等,综合地质资料,在研究区圈定了4个土壤地球化学异常,经查证,其中Ⅰ号、Ⅳ号异常具有较好的找矿前景,为下步找矿工作的重点靶区。  相似文献   

7.
在赣榆浅覆盖区采用槽型钻采取强风化基岩,开展1∶1万土壤地球化学找矿工作,共圈定10处综合异常,选择Z-3综合异常开展槽探查证,新揭露5条钼铜钨矿体。异常查证结果显示,采用槽型钻采取强风化基岩的土壤地球化学找矿方法具有良好的找矿效果。结合普查区成矿地质条件和土壤地球化学异常特征,初步总结了普查区钼、多金属矿找矿标志,认为找矿指示元素为Au、Cu、Mo等,元素组合、各元素空间套合关系及含量等特征可作为地质找矿标志。研究成果可作为研究区进一步找矿工作的参考。  相似文献   

8.
黑河市大新屯锑-金矿床位于大兴安岭成矿带东北部,区内构造、岩浆活动频繁.1∶5万水系沉积物Sb、Au、Hg异常强度较高,规模较大,是金及多金属成矿有利部位.为了对区内1∶5万水系沉积物异常进行评价,选定了规模最大的新07Hs-35异常,利用土壤地球化学测量工作方法对异常进一步查证.经土壤地球化学测量工作后圈定Sb、Au、Hg、Ag、As、W土壤地球化学异常多处,以Sb、Hg、Au异常为主,各元素异常浓集中心吻合较好.因此利用槽探工程对圈定的土壤地球化学异常进行了验证,发现了锑-金矿体,从而确定了大新屯锑-金矿找矿靶区,说明地球化学勘查快速确定找矿靶区是成功的.  相似文献   

9.
在智利北部地区的地质找矿工作中,对安托法加斯塔Henan D矿区开展了岩屑粒度试验和1∶10 000岩屑地球化学测量。粒度试验表明,采集B+C层或C层-5~+40目岩屑样品能较好的反映地质特征;岩屑测量圈定了6处Cu-Au-Ag综合异常,通过槽探和钻探异常查证,发现了良好的找矿线索,该区具有找到铁氧铜金型铜矿的潜力。工作表明,在智利安托法加斯塔大区荒漠化景观区实施岩屑测量能够达到明确找矿目标、缩小找矿范围、确定找矿靶区的目的。  相似文献   

10.
四川马头金矿位于冕宁—盐源走滑造山带,属深切割第四系覆盖区,地表找矿线索有限。本次找矿阶段通过1∶10 000土壤地球化学测量工作,圈定了综合异常区,并实施槽探工程验证,发现了金矿体,取得了较好的找矿效果。同时,结合工作区地质、地球化学异常特征,建立了以HT3异常区为主体的地质—地球化学找矿模型,并提出了下一步找矿方向。  相似文献   

11.
Most sulfide-rich magmatic Ni-Cu-(PGE) deposits form in dynamic magmatic systems by partial melting S-bearing wall rocks with variable degrees of assimilation of miscible silicate and volatile components, and generation of barren to weakly-mineralized immiscible Fe sulfide xenomelts into which Ni-Cu-Co-PGE partition from the magma. Some exceptionally-thick magmatic Cr deposits may form by partial melting oxide-bearing wall rocks with variable degrees of assimilation of the miscible silicate and volatile components, and generation of barren Fe ± Ti oxide xenocrysts into which Cr-Mg-V ± Ti partition from the magma. The products of these processes are variably preserved as skarns, residues, xenoliths, xenocrysts, xenomelts, and xenovolatiles, which play important to critical roles in ore genesis, transport, localization, and/or modification. Incorporation of barren xenoliths/autoliths may induce small amounts of sulfide/chromite to segregate, but incorporation of sulfide xenomelts or oxide xenocrysts with dynamic upgrading of metal tenors (PGE > Cu > Ni > Co and Cr > V > Ti, respectively) is required to make significant ore deposits. Silicate xenomelts are only rarely preserved, but will be variably depleted in chalcophile and ferrous metals. Less dense felsic xenoliths may aid upward sulfide transport by increasing the effective viscosity and decreasing the bulk density of the magma. Denser mafic or metamorphosed xenoliths may also increase the effective viscosity of the magma, but may aid downward sulfide transport by increasing the bulk density of the magma. Sulfide wets olivine, so olivine xenocrysts may act as filter beds to collect advected finely dispersed sulfide droplets, but other silicates and xenoliths may not be wetted by sulfides. Xenovolatiles may retard settling of – or in some cases float – dense sulfide droplets. Reactions of sulfide melts with felsic country rocks may generate Fe-rich skarns that may allow sulfide melts to fractionate to more extreme Cu-Ni-rich compositions. Xenoliths, xenocrysts, xenomelts, and xenovolatiles are more likely to be preserved in cooler basaltic magmas than in hotter komatiitic magmas, and are more likely to be preserved in less dynamic (less turbulent) systems/domain/phases than in more dynamic (more turbulent) systems/domains/phases. Massive to semi-massive Ni-Cu-PGE and Cr mineralization and xenoliths are often localized within footwall embayments, dilations/jogs in dikes, throats of magma conduits, and the horizontal segments of dike-chonolith and dike-sill complexes, which represent fluid dynamic traps for both ascending and descending sulfides/oxides. If skarns, residues, xenoliths, xenocrysts, xenomelts, and/or xenovolatiles are present, they provide important constraints on ore genesis and they are valuable exploration indicators, but they must be included in elemental and isotopic mass balance calculations.  相似文献   

12.
《Chemical Geology》2007,236(1-2):13-26
We examined the coprecipitation behavior of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides under two different fluoride forming conditions: at < 70 °C in an ultrasonic bath (denoted as the ultrasonic method) and at 245 °C using a Teflon bomb (denoted as the bomb method). In the ultrasonic method, small amounts of Ti, Mo and Sn coprecipitation were observed with 100% Ca and 100% Mg fluorides. No coprecipitation of Ti, Mo, Sn and Sb in Ca–Al–Mg fluorides occurred when the sample was decomposed by the bomb method except for 100% Ca fluoride. Based on our coprecipitation observations, we have developed a simultaneous determination method for B, Ti, Zr, Nb, Mo, Sn, Sb, Hf and Ta by Q-pole type ICP-MS (ICP-QMS) and sector field type ICP-MS (ICP-SFMS). 9–50 mg of samples with Zr–Mo–Sn–Sb–Hf spikes were decomposed by HF using the bomb method and the ultrasonic method with B spike. The sample was then evaporated and re-dissolved into 0.5 mol l 1 HF, followed by the removal of fluorides by centrifuging. B, Zr, Mo, Sn, Sb and Hf were measured by ID method. Nb and Ta were measured by the ID-internal standardization method, based on Nb/Mo and Ta/Mo ratios using ICP-QMS, for which pseudo-FI was developed and applied. When 100% recovery yields of Zr and Hf are expected, Nb/Zr and Ta/Hf ratios may also be used. Ti was determined by the ID-internal standardization method, based on the Ti/Nb ratio from ICP-SFMS. Only 0.053 ml sample solution was required for measurement of all 9 elements. Dilution factors of ≤ 340 were aspirated without matrix effects. To demonstrate the applicability of our method, 4 carbonaceous chondrites (Ivuna, Orgueil, Cold Bokkeveld and Allende) as well as GSJ and USGS silicate reference materials of basalts, andesites and peridotites were analyzed. Our analytical results are consistent with previous studies, and the mean reproducibility of each element is 1.0–4.6% for basalts and andesites, and 6.7–11% for peridotites except for TiO2.  相似文献   

13.
Partition coefficients of Hf,Zr, and REE between zircon,apatite, and liquid   总被引:25,自引:2,他引:25  
Concentration ratios of Hf, Zr, and REE between zircon, apatite, and liquid were determined for three igneous compositions: two andesites and a diorite. The concentration ratios of these elements between zircon and corresponding liquid can approximate the partition coefficient. Although the concentration ratios between apatite and andesite groundmass can be considered as partition coefficients, those for the apatite in the diorite may deviate from the partition coefficients. The HREE partition coefficients between zircon and liquid are very large (100 for Er to 500 for Lu), and the Hf partition coefficient is even larger. The REE partition coefficients between apatite and liquid are convex upward, and large (D=10–100), whereas the Hf and Zr partition coefficients are less than 1. The large differences between partition coefficients of Lu and Hf for zircon-liquid and for apatite-liquid are confirmed. These partition coefficients are useful for petrogenetic models involving zircon and apatite.  相似文献   

14.
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16.
针对兖州煤田下组煤深部开采受奥灰高承压水威胁以及当地大型煤化工企业生产用水量大的现状,在已进行的水文地质勘探及放水试验基础上,评价奥灰富水性,并采用有限差分法进行奥灰疏水降压数值模拟研究,提出水煤共采观点。研究结果表明:兖州煤田深部奥灰水压高,合理布置水煤共采孔,可以实现奥灰水位的有效疏降,疏降中心区水位最大降深可达110 m,突水系数显著下降,提高了下组煤开采的安全性;同时可提供煤化工43200 m3/d的供水量,能达到可持续的、水资源保护性的供水效果,实现下组煤的水煤共采。  相似文献   

17.
The distribution of Cu, Co, As and Fe was studied downstream from mines and deposits in the Idaho Cobalt Belt (ICB), the largest Co resource in the USA. To evaluate potential contamination in ecosystems in the ICB, mine waste, stream sediment, soil, and water were collected and analyzed for Cu, Co, As and Fe in this area. Concentrations of Cu in mine waste and stream sediment collected proximal to mines in the ICB ranged from 390 to 19,000 μg/g, exceeding the USEPA target clean-up level and the probable effect concentration (PEC) for Cu of 149 μg/g in sediment; PEC is the concentration above which harmful effects are likely in sediment dwelling organisms. In addition concentrations of Cu in mine runoff and stream water collected proximal to mines were highly elevated in the ICB and exceeded the USEPA chronic criterion for aquatic organisms of 6.3 μg/L (at a water hardness of 50 mg/L) and an LC50 concentration for rainbow trout of 14 μg/L for Cu in water. Concentrations of Co in mine waste and stream sediment collected proximal to mines varied from 14 to 7400 μg/g and were highly elevated above regional background concentrations, and generally exceeded the USEPA target clean-up level of 80 μg/g for Co in sediment. Concentrations of Co in water were as high as in 75,000 μg/L in the ICB, exceeding an LC50 of 346 μg/L for rainbow trout for Co in water by as much as two orders of magnitude, likely indicating an adverse effect on trout. Mine waste and stream sediment collected in the ICB also contained highly elevated As concentrations that varied from 26 to 17,000 μg/g, most of which exceeded the PEC of 33 μg/g and the USEPA target clean-up level of 35 μg/g for As in sediment. Conversely, most water samples had As concentrations that were below the 150 μg/L chronic criterion for protection of aquatic organisms and the USEPA target clean-up level of 14 μg/L. There is abundant Fe oxide in streams in the ICB and several samples of mine runoff and stream water exceeded the chronic criterion for protection of aquatic organisms of 1000 μg/L for Fe. There has been extensive remediation of mined areas in the ICB, but because some mine waste remaining in the area contains highly elevated Cu, Co, As and Fe, inhalation or ingestion of mine waste particulates may lead to human exposure to these elements.  相似文献   

18.
This paper reports the first results of a study of 11 isotope systems (3He/4He, 40Ar/36Ar, 34S/32S, 65Cu/63Cu, 62Ni/60Ni, 87Sr/86Sr, 143Nd/144Nd, 206–208Pb/204Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.  相似文献   

19.
The dielectric constants and dielectric loss values of 4 Ca-containing minerals were determined at 1 MHz using a two-terminal method and empirically determined edge corrections. The results are: vesuvianitel κ′ a=9.93 tan δ=0.006 κ′ c=9.79 tan δ=0.005 vesuvianitel κ′ a=10.02 tan δ=0.002 κ′ c=9.85 tan δ=0.003 zoisite1 κ′ a =10.49 tan δ=0.0006 κ′ b =15.31 tan δ=0.0008 κ′ c=9.51 tan δ=0.0008 zoisite2 κ′ a =10.55 tan δ=0.0011 κ′ b =15.45 tan δ=0.0013 κ′ c=9.39 tan δ=0.0008 epidote κ′ 11= 9.52 tan δ=0.0008 κ′ 22=17.1 tan δ=0.0009 κ′ 33= 9.37 tan δ=0.0006 fluorapatite1 κ′ a =10.48 tan δ=0.0008 κ′ c = 8.72 tan δ=0.0114 fluorapatite2 κ′ a =10.40 tan δ=0.0010 κ′ c=8.26 tan δ=0.0178 The deviation (δ) between measured dielectric polarizabilities as determined from the Clausius-Mosotti equation and those calculated from the sum of oxide polarizabilities according to α D (mineral)=∑ α D (oxides) for vesuvianite is ~ 0.5%. The large deviations of epidote and zoisite from the additivity rule with Δ=+ 10.1 and + 11.7%, respectively, are attributed to “rattling” Ca ions. The combined effects of both a large F thermal parameter and possible F-ion conductivity in fluorapatite are believed to be responsible for Δ=+2–3%. Although variation of oxygen polarizability with oxygen molar volume (Vo) is believed to affect the total polarizabilities, the variation of Vo in these Ca minerals is too small to observe the effect.  相似文献   

20.
The contents of As, Cd, Cu, Cr, Mg, Mn, Ni, Pb and Zn have been determined in sediment and water samples from Valle de las Garzas estuary and Port Manzanillo (Colima, Mexico) using ICP-AES. The concentrations of these elements were used for a comparative study to determine the distribution of heavy metals and to evaluate which elements reflect natural or anthropogenic backgrounds. For this purpose, seven sampling points were selected: Four of them correspond to the lagoon, and three were situated in the port. Statistical analysis of the mineral content was assessed. Initially, data comparison was assessed by statistical tests for each variable. Principal component analysis was then applied considering the influence of all variables at the same time by obtaining the distribution of samples according to their scores in the principal component space. In this way, four studies were carried out: (1) study of sediments collected during the dry season; (2) study of sediments collected during the rainy season; (3) comparative study between sediments from rainy and dry season; and (4) study of water composition collected during rainy season. From the results of the performed analyses, it can be concluded that metals distribution pattern reflected natural and anthropogenic backgrounds (e.g., sediments from the lagoon, situated at the beginning of the rain channel, presented high contents of Zn and Cu, perhaps related to anthropogenic activities or the influence of igneous sediments).  相似文献   

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