The evolution of a tropical rainforest/grassland mosaic in southeastern Brazil since 28,000 C yr BP based on carbon isotopes and pollen records

The lack of paleoecological records from the montane Atlantic Rainforest of coastal Brazil, a hotspot of biological diversity, has been a major obstacle to our understanding of the vegetational changes since the last glacial cycle. We present carbon isotope and pollen records to assess the impact of the glaciation on the native vegetation of the Serra do Mar rainforest in São Paulo, Brazil. From ca. 28,000 to  22,000 ¹⁴C yr BP, a subtropical forest with conifer trees is indicative of cool and humid conditions. In agreement carbon isotopic data on soil organic matter suggest the presence of C₃ plants and perhaps C₄ plants from  28,000 to  19,000 ¹⁴C yr BP. The significant increase in the sedimentation rate and algal spores from  19,450 to  19,000 ¹⁴C yr BP indicates increasing humidity, associated to an erosion process between  19,000 and  15,600 ¹⁴C yr BP. From  15,600 ¹⁴C yr BP to present there is a substantial increase in arboreal elements and herbs, indicating more humid and warmer climate. From  19,000 to  1000 ¹⁴C yr BP, δ¹³C values indicated the predominance of C₃ plants. These results are in agreement with studies in speleothems of caves, which suggest humid conditions during the last glacial maximum.     

Latest Pleistocene and Holocene glaciation of Baffin Island, Arctic Canada: key patterns and chronologies

Melting glaciers and ice caps on Baffin Island contribute roughly half of the sea-level rise from all ice in Arctic Canada, although they comprise only one-fourth of the total ice in the region. The uncertain future response of arctic glaciers and ice caps to climate change motivates the use of paleodata to evaluate the sensitivity of glaciers to past warm intervals and to constrain mechanisms that drive glacier change. We review the key patterns and chronologies of latest Pleistocene and Holocene glaciation on Baffin Island. The deglaciation by the Laurentide Ice Sheet occurred generally slowly and steadily throughout the Holocene to its present margin (Barnes Ice Cap) except for two periods of rapid retreat: An early interval 12 to 10 ka when outlet glaciers retreated rapidly through deep fiords and sounds, and a later interval 7 ka when ice over Foxe Basin collapsed. In coastal settings, alpine glaciers were smaller during the Younger Dryas period than during the Little Ice Age. At least some alpine glaciers apparently survived the early Holocene thermal maximum, which was several degrees warmer than today, although data on glacier extent during the early Holocene is extremely sparse. Following the early Holocene thermal maximum, glaciers advanced during Neoglaciation, beginning in some places as early as 6 ka, although most sites do not record near-Little Ice Age positions until 3.5 to 2.5 ka. Alpine glaciers reached their largest Holocene extents during the Little Ice Age, when temperatures were 1–1.5 °C cooler than during the late 20th century. Synchronous advances across Baffin Island throughout Neoglaciation indicate sub-Milankovitch controls on glaciation that could involve major volcanic eruptions and solar variability. Future work should further elucidate the state of glaciers and ice caps during the early Holocene thermal maximum and glacier response to climate forcing mechanisms.     

Paleoenvironment of Jawa basalt plateau, Jordan, inferred from calcite speleothems from a lava tube

This paper explores the environmental conditions that faced the people of ancient Jawa during the Holocene, as well as previous prehistoric periods of the mid-late Pleistocene. Calcite speleothems in a lava tube are dated using the U-Th method, to marine oxygen isotope stage 7 from  250 to 240 ka and from  230 to  220 ka; and the stage 5/4 transition between  80 and 70 ka. The available evidence indicates general aridity of the Black Desert during most of the mid-late Quaternary, punctuated by short wetter periods, when the Mediterranean cyclonic systems intensified and penetrated the north Arabian Desert. These Mediterranean systems had a longer and more intense effect on the desert fringe closer to the Mediterranean and only rarely penetrated the Black Desert of Jawa. The results do not exclude some increase of rainfall which did not change water availability dramatically during the warm Holocene. The ancient Jawa city appears to have depended on technological ability to build elaborate runoff-collection systems, which became the prime condition for success.     

Holocene Relative Sea Level Changes along the Seattle Fault at Restoration Point, Washington

At a marsh on the hanging wall of the Seattle fault, fossil brackish water diatom and plant seed assemblages show that the marsh lay near sea level between 7500 and 1000 cal yr B.P. This marsh is uniquely situated for recording environmental changes associated with past earthquakes on the Seattle fault. Since 7500 cal yr B.P., changes in fossil diatoms and seeds record several rapid environmental changes. In the earliest of these, brackish conditions changed to freshwater 6900 cal yr B.P., possibly because of coseismic uplift or beach berm accretion. If coseismic uplift produced the freshening 6900 cal yr B.P., that uplift probably did not exceed 2 m. During another event about 1700 cal yr B.P., brackish plant and diatom assemblages changed rapidly to a tidal flat assemblage because of either tectonic subsidence or berm erosion. The site then remained a tideflat until the most recent event, when an abrupt shift from tideflat diatoms to freshwater taxa resulted from 7 m of uplift during an earthquake on the Seattle fault 1000 cal yr B.P. Regardless of the earlier events, no Seattle fault earthquake similar to the one 1000 cal yr B.P. occurred at any other time in the past 7500 years.     

A late Quaternary paleotemperature record from Hanging Lake, northern Yukon Territory, eastern Beringia

The late Quaternary paleoclimate of eastern Beringia has primarily been studied by drawing qualitative inferences from vegetation shifts. To quantitatively reconstruct summer temperatures, we analyzed lake sediments for fossil chironomids, and additionally we analyzed the sediments for fossil pollen and organic carbon content. A comparison with the δ¹⁸O record from Greenland indicates that the general climatic development of the region throughout the last glaciation–Holocene transition differed from that of the North Atlantic region. Between  17 and 15 ka, mean July air temperature was on average 5°C colder than modern, albeit a period of near-modern temperature at  16.5 ka. Total pollen accumulation rates ranged between  180 and 1200 grains cm^− 2 yr^− 1. At  15 ka, approximately coeval with the Bølling interstadial, temperatures again reached modern values. At  14 ka, nearly 1000 yr after warming began, Betula pollen percentages increased substantially and mark the transition to shrub-dominated pollen contributors. Chironomid-based inferences suggest no evidence of the Younger Dryas stade and only subtle evidence of an early Holocene thermal maximum, as temperatures from  15 ka to the late Holocene were relatively stable. The most recognizable climatic oscillation of the Holocene occurred from  4.5 to 2 ka.     

Late Pleistocene and Holocene palaeogeography of the Lower Tagus Valley (Portugal): effects of relative sea level, valley morphology and sediment supply

Because of the deep glacial incision, the Lower Tagus Valley hosts a sedimentary record since 20 000 cal BP, making this a unique site along the European Atlantic margin with respect to palaeogeographic and sea level changes. Based on nine cross-sections and 55 radiocarbon dates together with a newly created relative sea level curve, we constructed five palaeogeographic maps of the infill of the Lower Tagus Valley since 20 000 cal BP. We illustrate that relative sea level rise and fluvial sediment supply were the prime forcing factors determining the depositional history and palaeogeographic changes. Around 20 000 cal BP a deeply incised braided river existed, which was directly connected to the ocean across the narrow continental shelf. After that (12 000 cal BP) the gradually moister and warmer climate caused a change to a single-channel river. During the following period (12 000–7000 cal BP) relative sea level rise resulted in a transgression in the Lower Tagus Valley and the establishment of extensive tidal environments. After relative sea level rise had ended (7000 cal BP) the valley was progressively filled by a fluvial wedge and tidally influenced bayhead delta. Since 1000 cal BP the valley-fill history was dominated by increased sediment input due to human-induced degradation of catchment slopes. Generally, climate was of subordinate importance during the entire studied period, merely causing a single-channel river resulting from the change from the cold Heinrich event 1 to the temperate Bölling–Allerød interstadial. Despite the tectonic activity in the region, neotectonic uplift or subsidence was limited, as supported by the horizontal relative sea level curve since 7000 cal BP. Neotectonics played a minor role due to the large distance from the Fennoscandian ice sheet and the narrow continental shelf, which prohibited strong glacio- and hydro-isostatic movements.     

The Magnitude and Proximate Cause of Ice-Sheet Growth Since 35,000 yr B.P.

The magnitude of late Wisconsinan (post-35,000 yr B.P.) ice-sheet growth in the Northern Hemisphere is not well known. Ice volume at 35,000 yr B.P. may have been as little as 20% or as much as 70% of the volume present at the last glacial maximum (LGM). A conservative evaluation of glacial–geologic, sea level, and benthic δ¹⁸O data indicates that ice volume at 35,000 yr B.P. was approximately 50% of that extant at the LGM (20,000 yr B.P.); that is, it doubled in about 15,000 yr. On the basis of literature for the North Atlantic and a sea-surface temperature (SST) data compilation, it appears that this rapid growth may have been forced by low-to-mid-latitude SST warming in both the Atlantic and Pacific Oceans, with attendant increased moisture transport to high latitudes. The SST ice-sheet growth notion also explains the apparent synchroneity of late Wisconsinan mountain glaciation in both hemispheres.     

Experimental frictional heating of coal gouge at seismic slip rates: Evidence for devolatilization and thermal pressurization of gouge fluids

High velocity (1 m/s) friction experiments on bituminous coal gouge display several earthquake-related phenomena, including devolatilization by frictional heating, gas pressurization, and slip weakening. Stage I is characterized by sample shortening and reduction in the coefficient of friction (μ) from  1 to 0.6. Stage II is characterized by high frequency ( 5 Hz) oscillations in stress and strain records and by gas emissions. Stage III is marked by rapid weakening (μ  0.1 to 0.35) and sample shortening, together with continued gas emissions. Stage IV produces stable stress records and continued weakness (μ  0.2), but without gas emission. Stage I shortening is due to compaction of the gouge and the weakening is attributed to mechanical or thermal effects. Stage II behavior is interpreted as due to coal gasification and fluctuations in fluid pressure, resulting in high frequency stick-slip type behavior. Dramatic reduction in shear stress in stage III is attributed to gas pressurization by pore collapse and corresponds to a frictional instability, analogous to nucleation of an earthquake. Microstructural observations indicate the deformation was brittle during stages I and II but ductile during stages III and IV. Time dependent finite element frictional heat models indicate the center of the samples became hot ( 900 °C) during stage II, whereas the edge of samples remained relatively cold (< 300 °C). Vitrinite reflectance of coal samples shows an increase in reflectance from  0.5 to  0.8% over the displacement interval 20–40 m (20–40 s), indicating that the reflectance responds to frictional heating on a short time scale. The energy expended per unit area in these low stress, large displacement experiments is similar to that of higher stress ( 50 MPa), short displacement ( 1 m) earthquakes ( 10⁷ J/m²).     

Evolution of mineralizing fluids in the Zn–Pb–Cu(–Ag ± Au) skarn and epithermal deposits of the world-class San Martín district, Zacatecas, Mexico

Mineralizing fluids at the San Martín skarn show an evolution characterized by prograde and retrograde associations. The prograde mineral associations consist of (1) a massive garnet zone, (2) a tremolite ± garnet zone, and (3) a late association of quartz, sphalerite, calcite and fluorite lining the vugs in the garnet zone. The fluids of the prograde associations exhibit decreasing temperatures of homogenization (Th) and variable salinities. The fluids of the massive garnet zone have salinities of 36 wt.% NaCl equiv. and Th of 645 to 570 °C, corresponding to pressures of 1055 bar. At the tremolite ± garnet zone, Th range from 438 to 354 °C. In the late association at the endoskarn, the following evolution can be drawn: (a) salinities of 50 to 42 wt.% NaCl equiv., and Th of 455 to 346 °C in quartz, (b) salinities of 46 wt.% NaCl equiv., and Th of 415 to 410 °C in sphalerite, (c) salinities of 50 to 37 wt.% NaCl equiv., and Th of 479 to 310 °C in calcite, (d) salinities of 33 to 28 wt.% NaCl equiv. and of 24 to 22 wt.% KCl in fluorite, and (e) two types of fluids with salinities of 2 and 39 wt.% NaCl equiv. and Th 344 and 300 °C, respectively, in later saccharoidal quartz segregations. The retrograde mineral associations comprise pervasive propylitic alteration to carbonization, and mantos with sulfides. Fluids in epidote have salinities of 7.6 wt.% NaCl equiv. and Th of 287 to 252 °C, and in calcite have salinities of 9.2 to 1 wt.% NaCl equiv. and Th of 188 to 112 °C. Fluids in the sulfide assemblages in the mantos have salinities of 8 to 3 wt.% NaCl equiv. and Th 300 °C, with corresponding pressures of 94 bar. Fluids in late epithermal veins close to the intrusive body have salinities of 10 to 5 wt.% NaCl equiv. and Th of 275 to 200 °C, and distal veins show salinities of 2 to 1 wt.% NaCl equiv. and Th of 160 °C.     

Holocene activity of the Scilla Fault, Southern Calabria: Insights from coastal morphological and structural investigations

Integration of on-land and offshore geomorphological and structural investigations coupled to extensive radiometric dating of co-seismically uplifted Holocene beaches allows characterization of the geometry, kinematics and seismotectonics of the Scilla Fault, which borders the eastern side of the Messina Strait in Calabria, Southern Italy. This region has been struck by destructive historical earthquakes, but knowledge of geologically-based source parameters for active faults is relatively poor, particularly for those running mostly offshore, as the Scilla Fault does. The  30 km-long normal fault may be divided into three segments of  10 km individual length, with the central and southern segments split in at least two strands. The central and northern segments are submerged, and in this area marine geophysical data indicate a youthful morphology and locally evidence for active faulting. The on-land strand of the western segment displaces marine terraces of the last interglacial (124 to 83 ka), but seismic reflection profiles suggest a full Quaternary activity. Structural data collected on bedrock faults exposed along the on-land segment provide evidence for normal slip and  NW-SE extension, which is consistent with focal mechanisms of large earthquakes and GPS velocity fields in the region. Detailed mapping of raised Holocene marine deposits exposed at the coastline straddling of the northern and central segments supplies evidence for two co-seismic displacements at  1.9 and  3.5 ka, and a possible previous event at  5 ka. Co-seismic displacements show a consistent site value and pattern of along-strike variation, suggestive of characteristic-type behaviour for the fault. The  1.5–2.0 m average co-seismic slips during these events document M_e  6.9–7.0 earthquakes with  1.6–1.7 ka recurrence time. Because hanging-wall subsidence cannot be included into slip magnitude computation, these slips reflect footwall uplift, and represent minimum average estimates. The palaeoseismological record based on the palaeo-shorelines suggests that the last rupture on the Scilla Fault during the February 6, 1783 M_w = 5.9–6.3 earthquake was at the expected time but it may have not entirely released the loaded stress since the last great event at  1.9 ka. Comparison of the estimated co-seismic extension rate based on the Holocene shoreline record with available GPS velocities indicates that the Scilla Fault accounts for at least  15–20% of the contemporary geodetic extension across the Messina Strait.     

Lake Manly(?) Shorelines in the Eastern Mojave Desert, California

Near Mesquite Spring on the southern edge of the Soda Lake basin in the Mojave Desert, there is a shoreline of an ancient lake at an elevation of 340 m above sea level. At present, Soda Lake would overflow at 280 m; a lake surface at 340 m would extend 240 km northward, to the northern end of Death Valley. Shorelines and lacustrine deposits near the Salt Spring and Saddle Peak Hills, 75 km north of Mesquite Spring, are at 180 m; a lake surface at this elevation today would also extend to the northern end of Death Valley. The most prominent shoreline of the pluvial lake that occupied Death Valley during the Pleistocene, Lake Manly, is that of the Blackwelder stand which ended 120,000 yr ago. This shoreline is 90 m above sea level. The Mesquite Spring and Salt Spring Hills shorelines were probably formed by the Blackwelder stand and subsequently displaced with respect to one another, tectonically, due to transpression in the northeastern Mojave Desert and NW–SE extension across Death Valley. This tectonic regime would result in subsidence of Death Valley and the Salt Spring Hills relative to Mesquite Spring. A reconstruction suggests that the topography at the time of the Blackwelder stand would have had a sill near the level of the highest lake, and also one 20 m lower, corresponding to the next most prominent shoreline in Death Valley. Expansion of the lake over these sills would have increased evaporation, thus possibly stabilizing the lake level.     

Cirque glacier activity in arctic Norway during the last deglaciation

Numerous cirques of the Lofoten–Vesterålen archipelago in northern Norway have distinct moraine sequences that previously have been assigned to the Allerød-Younger Dryas ( 13,400 to 11,700 yr BP) interval, constraining the regional distribution of the equilibrium-line altitude (ELA) of cirque and valley glaciers. Here we present evidence from a once glacier-fed lake on southern Andøya that contests this view. Analyses of radiocarbon dated lacustrine sediments including rock magnetic parameters, grain size, organic matter, dry bulk density and visual interpretation suggest that no glacier was present in the low-lying cirque during the Younger Dryas-Allerød. The initiation of the glacial retreat commenced with the onset of the Bølling warming ( 14,700 yr BP) and was completed by the onset of Allerød Interstade ( 13,400 yr BP). The reconstructed glacier stages of the investigated cirque coincide with a cool and dry period from  17,500 to 14,700 yr BP and a somewhat larger Last Glacial Maximum (LGM) advance possibly occurring between  21,050 and 19,100 yr BP.     

Continental Oxygen Isotopic Record of the Last 170,000 Years in Jerusalem

A long radiometrically dated oxygen isotopic record of continental climatic variations since the penultimate glaciation was obtained from a stalagmite deposited in a sealed cave in Jerusalem. This record shows that speleothems have the potential of assigning dates to long- and short-term climatic events, with possible refining of Milankovitch tuning of ice and marine records which themselves are not datable. Short-term (1000-yr) events are very significant in the region, reaching 50% of glacial/interglacial fluctuations. The Mediterranean Sea was the most probable source of local precipitation throughout the last glacial cycle.     

Analysis of crustal deformation in Luzon, Philippines using geodetic observations and earthquake focal mechanisms

We utilize regional GPS velocities from Luzon, Philippines, with focal mechanism data from the Harvard Centroid Moment Tensor (CMT) Catalog, to constrain tectonic deformation in the complex plate boundary zone between the Philippine Sea Plate and Eurasia (the Sundaland block). Processed satellite imagery and digital elevation models are used with existing gravity anomaly, seismicity, and geologic maps to define a suite of six elastic blocks. Geodetic and focal mechanism data are inverted simultaneously to estimate plate rotations and fault-locking parameters for each of the tectonic blocks and faults comprising Luzon. Major tectonic structures that were found to absorb the plate convergence include the Manila Trench (20–100 mm yr^− 1) and East Luzon Trough ( 9–15 mm yr^− 1)/Philippine Trench ( 29–34 mm yr^− 1), which accommodate eastward and westward subduction beneath Luzon, respectively; the left-lateral strike-slip Philippine Fault ( 20–40 mm yr^− 1), and its northward extensions, the Northern Cordillera Fault ( 17–37 mm yr^− 1 transtension), and the Digdig Fault ( 17–27 mm yr^− 1 transpression). The Macolod Corridor, a zone of active volcanism, crustal thinning, extension, and extensive normal and strike-slip faulting in southwestern Luzon, is associated with left-lateral, transtensional slip of  5–10 mm yr^− 1. The Marikina Fault, which separates the Central Luzon block from the Southwestern Luzon block, reveals  10–12 mm yr^− 1 of left-lateral transpression. Our analysis suggests that much of the Philippine Fault and associated splays are locked to partly coupled, while the Manila and Philippine trenches appear to be poorly coupled. Luzon is best characterized as a tectonically active plate boundary zone, comprising six mobile elastic tectonic blocks between two active subduction zones. The Philippine Fault and associated intra-arc faults accommodate much of the trench-parallel component of relative plate motion.     

Taconic Orogeny in Pennsylvania: A 15 –20 m.y. Apennine-style Ordovician event viewed from its Martic hinterland

In Pennsylvania, the Taconic Orogeny lasted from 461 to 443 Ma as Cambro-Ordovician slope deposits were deformed into mountains edging the Laurentian craton at the same time that materials from an adjacent deep-water basin were being transported 50 –70 km across a carbonate platform into foreland basins. This paper focuses on shelf-edge hinterland features, mostly the Martic Zone as a folded, stack of imbricate thrust sheets of slope materials that corresponds to Vermont's Taconic Mountains and Southern Quebec's zone of Taconic allochthons. Work of the last century is summarized, corrected, and combined with a new 450 Ma radiometric date and fluid inclusion data from the Pequea Mine within the Martic Zone. These and abundant new graptolite and conodont dates in the foreland paint a revised Pennsylvania picture differing from the northern Taconic areas. Differences are: (1) transport of very large allochthonous masses of deep-water material, the Dauphin Formation, far across the carbonate platform, and (2) deformation migrating progressively across that platform during a 15 –20 m.y. period, incorporating it and its foreland cover into alpine-scale, recumbent folds and thrusts. The scenario has many analogies to Italy's modern Apennine Mountains minus the Latian volcanics.     

Geochronology of Quaternary glaciations from the tropical Cordillera Huayhuash, Peru

The Cordillera Huayhuash in the central Peruvian Andes (10.3°S, 76.9°W) is an ideal mountain range in which to study regional climate through variations in paleoglacier extents. The range trends nearly north-south with modern glaciers confined to peaks >4800 m a.s.l. Geomorphology and geochronology in the nearby Cordillera Blanca and Junin Plain reveal that the Peruvian Andes preserve a detailed record of tropical glaciation. Here, we use ASTER imagery, aerial photographs, and GPS to map and date glacial features in both the western and eastern drainages of the Cordillera Huayhuash. We have used in situ produced cosmogenic ¹⁰Be concentrations in quartz bearing erratics on moraine crests and ice-polished bedrock surfaces to develop an exposure age chronology for Pleistocene glaciation within the range. We have also collected sediment cores from moraine-dammed lakes and bogs to provide limiting ¹⁴C ages for glacial deposits. In contrast to the ranges to the north and south, most glacial features within the Cordillera Huayhuash are Lateglacial in age, however we have identified features with ages that span 0.2 to 38 ka with moraine sets marking the onset of glacier retreat at 0.3 ka, 9–10 ka, 13–14 ka, 20–22 ka, and >26 ka. The range displays a pronounced east-west variation in maximum down-valley distance from the headwall of moraine crests with considerably longer paleoglaciers in the eastern drainages. Importantly, Lateglacial paleoglaciers reached a terminal elevation of 4000 m a.s.l. on both sides of the Cordillera Huayhuash; suggesting that temperature may have been a dominant factor in controlling the maximum glacier extent. We suggest that valley morphology, specifically valley slope, strongly influences down-valley distance to the maximum glacier extent and potential for moraine preservation. While regionally there is an extensive record of older (>50 ka) advances to the north (Cordillera Blanca) and to the south (Junin region), the apparent lack of old moraines in this locality may be explained by the confined morphology of the Cordillera Huayhuash valleys that has inhibited the preservation of older glacial geomorphic features.     

A late Quaternary pollen sequence from Mfabeni Peatland, South Africa: Reconstructing forest history in Maputaland

This paper documents a continuous  44,000-yr pollen record derived from the Mfabeni Peatland on the Maputaland Coastal Plain. A detailed fossil pollen analysis indicates the existence of extensive Podocarpus-abundant coastal forests before  33,000 cal yr BP. The onset of wetter local conditions after this time is inferred from forest retreat and the development of swampy conditions. Conditions during the last glacial maximum ( 21,000 cal yr BP) are inferred to have been colder and drier than the present, as evidenced by forest retreat and replacement of swampy reed/sedge communities by dry grassland. Forest growth and expansion during the Holocene Altithermal ( 8000–6000 cal yr BP) indicates warm, relatively moist conditions. Previous records from Maputaland have suggested a northward migration of Podocarpus forest during the late Holocene. However, we interpret a mid-Holocene decline in Podocarpus at Mfabeni as evidence of deforestation. Forest clearance during the mid-Holocene is supported by the appearance of Morella serrata, suggesting a shift towards more open grassland/savanna, possibly due to burning. These signals of human impact are coupled with an increase in Acacia, indicative of the development of secondary forest and hence disturbance.     

Changes in Zn speciation during soil formation from Zn-rich limestones

In order to better understand the long-term speciation and fractionation of Zn in soils, we investigated three soils naturally enriched in Zn (237–864 mg/kg Zn) from the weathering of Zn-rich limestones (40–207 mg/kg Zn) using extended X-ray absorption fine structure (EXAFS) spectroscopy and sequential extractions. The analysis of bulk EXAFS spectra by linear combination fitting (LCF) indicated that Zn in the oolitic limestones was mainly present as Zn-containing calcite (at site Dornach), Zn-containing goethite (Gurnigel) and Zn-containing goethite and sphalerite (Liestal). Correspondingly, extraction of the powdered rocks with 1 M NH₄-acetate at pH 6.0 mobilized only minor fractions of Zn from the Gurnigel and Liestal limestones (<30%), but most Zn from the Dornach rock (81%). In the Dornach soil, part of the Zn released from the dissolving limestone was subsequently incorporated into pedogenic hydroxy-interlayered vermiculite (Zn-HIV, 30%) and Zn-containing kaolinite (30%) and adsorbed or complexed by soil organic and inorganic components (40%). The Gurnigel and Liestal soils contained substantial amounts of Zn-containing goethite (50%) stemming from the parent rock, smaller amounts (20%) of Zn-containing kaolinite (and possibly Zn-HIV), as well as adsorbed or complexed Zn-species (30%). In the soil from Liestal, sphalerite was only found in trace amounts, indicating its dissolution during soil formation. In sequential extractions, large percentages of Zn (55–85%) were extracted in recalcitrant extraction steps, confirming that Zn-HIV, Zn-containing kaolinite and Zn-containing goethite are highly resistant to weathering. These Zn-bearing phases thus represent long-term hosts for Zn in soils over thousands of years. The capability of these phases to immobilize Zn in heavily contaminated soils may however be limited by their uptake capacity (especially HIV and kaolinite) or their abundance in soil.     

Kinematic variations across Eastern Cordillera at 24°S (Central Andes): Tectonic and magmatic implications

The Eastern Cordillera (Central Andes,  24°S) consists of a basement-involved thrust system, resulting from Miocene–Quaternary eastward migrating compression, separating the Puna plateau from the Santa Barbara System foreland. The inferred Tertiary strains arising from shortening in the Eastern Cordillera and Santa Barbara System are similar, higher than in the Puna. Slip data collected on the major  N–S trending faults of Eastern Cordillera show a westward progression from dip-slip (contraction) to dextral and sinistral motions. This, consistently with established tectonic models, may result from partitioning due to the oblique Mio-Quaternary underthrusting of the Brazilian Shield north of 24°S. This strain partitioning has three main implications. (1) As the dextral and sinistral shear in the Eastern Cordillera are  62% and 29% of the compressive strain respectively, the Eastern Cordillera results more strained than Santa Barbara System foreland, contrary to previous estimates. (2) The partitioning in the Eastern Cordillera may find its counterpart in that to the west of the Central Andes, giving a possible structural symmetry to the Central Andes. (3) The easternmost N–S strike-slip structures in the Eastern Cordillera coincide with the easternmost Mio-Pliocene magmatic centres in the Central Andes, at  24°S. Provided that, further to the east, the crust is partially molten, the absence of magmatic centres may be explained by the presence of pure compressive structures in this portion of the Eastern Cordillera.