华北中元古界古地磁测试新结果与Columbia超级大陆研究

华北地块中元古代杨庄组的古地磁研究提供了一个同时通过褶皱检验和倒转检验的古地磁极,极位置为经度190.4°、纬度2.4°。通过与Laurentia、Baltica和Siberia可靠的古地磁数据对比,支持了古—中元古代可能存在Columbia超级大陆的假说。华北地块与Laurentia、Baltica和Siberia视极移曲线的对比表明华北地块与Baltica在古—中元古代可能长期相连。     

新疆北部古地磁研究

通过和布克赛尔、克拉玛依、玛纳斯—乌鲁木齐地区泥盆纪到白垩纪古地磁研究,主要取得以下结果:(1)首次建立了准噶尔西北缘及南缘石炭纪—白垩纪古地磁极移曲线,由石炭纪到二叠纪的古地磁极位置基本在同一区间,说明该时期这些地区为一个统一的构造单元,而其古地磁极明显与塔里木、哈萨克斯坦、西伯利亚地块存在着差异。(2)该地区侏罗纪及白垩纪古地磁结果与塔里木地块结果一致,侏罗纪乌鲁木齐与和布克赛尔磁偏角相差30°左右,说明和布克赛尔地区相对乌鲁木齐地区逆时针旋转了30°左右,晚古生代以后曾发生过南向移动,而侏罗、白垩纪以来均向北发生了相当规模的北向运动,并发生了相对旋转,目前东、西准噶尔的构造格局可能就是由于局部相对旋转造成的。(3)中国大陆在早二叠世还不是一个联合的整体,而是以相互分离的独立块体分布于45°N—15°S的古特提斯洋中。(4)该地区二叠纪的磁偏角为165°—168°,而塔里木为218°,哈萨克斯坦为229°,说明存在35°—55°的逆时针旋转,这个旋转可能是由于西部推覆构造造成的。如果将西准噶尔超基性岩带顺时针旋转35°—55°后,东准噶尔超基性岩带、西准噶尔超基性岩带和斋桑泊—鲁布佐夫斯克超基性岩带应在同一构造带上。(5)该地区晚古生代古纬度变化不明显,位于30°—45     

滇东早第三纪的古地磁极位置及磁性地层特征

为开展中国几个主要陆块的古地磁研究,在扬子地块西南缘的路南盆地和昆明盆地第三纪地层中分别采集了105块标本,制备成145块样品,对它们进行热退磁方法处理,用同一台旋转磁力仪测量,所得结果表明: 路南盆地早第三纪时的古地磁极位置是343.1°E,84.4°N,昆明盆地相应时代的古地磁极位置是309.1°E,83.8°N,而路南盆地和昆明盆地的古纬度分别为21.9°N和19.1°N。     

甘肃玉门地区二叠系-三叠系古地磁研究

玉门大山口白杨河一带古地磁研究结果:下二叠统的特征磁化方向为Ds=108.1°,Is=-46.1°;极点位置为λ=30.5°N,ψ=18.6°;古纬度为27.6°N.上二叠统的特征磁化方向为Ds=139.4°,Is=-47.4°;极点位置为λ=54.7N,ψ=359.9°;古纬度为28.2°N;下三叠统的特征磁化方向为Ds=150.8°,Is=-48.1°;极点位置为λ=63.7°N,ψ=351.1°;古纬度为29.1°N.说明二叠纪玉门地区所在的阿拉善地块已是华北地块的一部分,晚二叠世-早三叠世华北地块大体处于吐哈地块和华南地块之间,与俄罗斯地块的古纬度相近;华北、吐鲁番-哈密和塔里木地块都大体位于劳亚大陆的东南部.     

新疆东部古地磁研究

沿富蕴—二台—苏古泉—七角井—沙泉子—柳园—阿克塞对奥陶系—上第三系进行古地磁研究,主要获得以下成果:(1)建立了北准噶尔地片和东准噶尔地片极移曲线,认为准噶尔洋形成于泥盆纪—石炭纪,在二叠纪闭合。这两个地片在早古生代是一个统一的构造单元,位于30°S左右,泥盆纪拉开距离达1000km,其北边的地片位移于20°—30°N左右,早古生代晚期到晚古生代早期是地块快速北向移动时期;(2)获得了七角井、沙泉子和柳园地区石炭、二叠纪古地磁极位置及古纬度,其中的柳园、沙泉子地区极点位置明显与准噶尔不一致,而与哈萨克斯坦西天山(伊犁地块)、塔城地块、吐哈地块、鄂尔多斯地块及华北地块等古地磁极接近,说明这些地块在晚古生代已处于南、北大陆之间,成为独立的中间地体;(3)通过新疆东部和北部晚古生代到早第三纪古地磁研究,进一步证明了东亚地区从中生代开始南向移动的存在;(4)准噶尔地块在晚古生代处于30°—35°N的古纬度区,准噶尔洋主要为近EW向拉开,如果存在SN向移动,其相对移动距离也不会超过1500km。(b)从晚古生代以来的北方大陆块体构造演化模式来看,准噶尔地块大致遵循了北方大陆块体统一的构造演化规律,说明准噶尔地块是北方大陆的组成部分。     

华北基性岩墙群的古地磁极及其哥伦比亚超大陆重建意义

从华北克拉通的中西部和东部发育的基性岩墙群获得三个精确定年的实际古地磁极位置(VGPs)。华北克拉通中西部恒山GU岩墙的斜锆石U-Pb年龄为1769±3Ma,该岩墙的古地磁给出古地磁极位置在北纬36°,东经247° (dp=2, dm=4); 华北克拉通东部DY岩墙的斜锆石U-Pb年龄为1620.8±6.9Ma, 获得的古地磁极位置为北纬6.9°东经81.9°(dp=4.31, dm=6.09); 东部另一条岩墙LW4的SHRIMP U-Pb 年龄为1157±18Ma, 获得的古地磁极位置为北纬27.1°东经162°(dp=15.8, dm=18.7)。通过将这三个从基性岩墙获得的华北克拉通古地磁极位置与加拿大地盾的中元古代视极移曲线对比,在中元古代早期（1800~1600Ma）,华北克拉通与加拿大地盾一起同属哥伦比亚超大陆,而在中元古代晚期（1600~1200Ma）,华北克拉通与加拿大地盾分离,响应哥伦比亚超大陆的最终裂解事件。     

川滇菱形地块白垩纪古地磁学特征

在位于川滇菱形地块的西昌西南大德里向斜两翼的白恶系红和岩内采集古地磁学定向样品９６个,进行了古地学研究,研究结果表明,西昌晚白垩世末期的古地磁偏角为５．９°,古地磁倾角为４５．８°,地磁极位置为北纬８４．７°,东径１９３．３°,将该数据与作前期研究结果对比,则可见自楚雄至无谋,进而至西昌,其古地磁偏角逐渐靠近正北,而古地磁极纬度渐次升高,这反映了川滇菱形地块内的断块呈自西南至东北逐渐减弱的顺时针     

塔里木盆地古董山地区早二叠世古地磁特征 及其地质意义

通过对塔里木盆地内古董山地区早二叠世玄武岩的古地磁测定,揭示了1组高温特征剩磁分量。实验结果表明,其特征剩磁方向为：Dg=213.7°, Ig=26.9°,κg=19.7, N=9,α95=13.7°; Ds=217.7°, Is=-37.5°, κs=15.4,α95=13.6°,相对应的古地磁极位置为：53.2°N、 187.5°E,A95=12.3°,古纬度为21.0°N。由于采样剖面所获得的早二叠世古地磁结果全部为反极性特征,认为这一高温特征剩磁分量很可能代表了研究区早二叠世时期的原生特征剩磁。对比塔里木地块西北缘早二叠世的古地磁结果,认为研究地区与塔里木地块西北缘之间在古地磁误差范围内并未发生明显的相对构造运动。依据塔里木早二叠世古地磁极与哈萨克斯坦地块同时期古地磁极的一致性,结合二者的古生物资料,提出早二叠世时期塔里木地块可能已经与哈萨克斯坦地块碰撞相连,至晚二叠世,二者之间的海水完全退出,碰撞造山使得天山雏形基本形成。结合前人古地磁研究成果,对塔里木地块及周边主要块体早二叠世的古地理进行了重建。     

喜马拉雅山北坡奥陶纪—古近纪构造古地磁新数据

在喜马拉雅山北坡奥陶系—古近系近乎连续的沉积地层中系统采集古地磁样品3791件,其中测试统计样品数为2920件,基本获取了统级年代古地磁数据,绘制出喜马拉雅地块奥陶纪—古近纪古地磁极移曲线和古纬度变化曲线。喜马拉雅地块在向北漂移过程中曾发生了多次旋转,最后一次约28°的顺时针旋转发生在始新世,可能与西喜马拉雅构造结形成有关;晚三叠世和晚侏罗世曾发生了纬度为2°和3.8°的向南回返,可能与雅鲁藏布新特提斯洋弧后扩张有关。根据古纬度数据推算:中白垩世雅鲁藏布新特提斯洋盆的宽度至少为2200km;始新世以来的喜马拉雅陆-陆碰撞造山运动导致印度地块-喜马拉雅褶冲带-拉萨地块之间的地壳缩短量至少为1000km。     

松潘—阿坝地块三叠系古地磁结果及运动学意义

迄今为止,位于扬子地块的西北缘,夹持于扬子、华北、塔里木和羌塘—昌都地块之间呈倒三角形构造区块的巴颜喀拉褶皱带尚未有构造古地磁研究成果报导。为配合该区油气勘查与油气资源评价,并对构造区块定位提供定量数据,开展了松潘—阿坝地块的古地磁研究。采样区集中在西秦岭构造区南亚带(摩天岭和若尔盖)、中亚带(洮河)和巴颜喀拉构造区的马尔康复向斜带(巴颜喀拉褶皱区)4个微地块。采样地层单元主要为三叠系。共采集57个采点,376块岩心标本。通过对岩石样品测试数据的分析和计算,获得洮河、巴颜喀拉、摩天岭和若尔盖(后两者夹于前两者之间)4个微地块古地磁极极点位置:经度为191.4°E~202.9°E,纬度为49.5°N~58.5°N。洮河和巴颜喀拉两微地块在晚三叠世的古纬度同为26.2°N,表明晚三叠世这4个被断裂相隔的微地块已构成一个统一的较大的地块。洮河和巴颜喀拉地块在三叠纪时的古纬度变化分别从早三叠世的13.4°N和11.3°N向北移动到晚三叠世的26.2°N,同时在北向移动过程中从早三叠世至晚三叠世分别发生了约40°和16°的逆时针旋转。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Bellechester,Minnesota, USA,lagoon collapses

Bellechester, Minnesota, is a small community of approximately 155 residents located on the county line between Goodhue and Wabasha counties in southeast Minnesota's karst region. Bellechester is served by a 21-year-old wastewater treatment facility (WWTF) consisting of three waste-stabilization ponds. On 28 April 1992 six sinkholes were discovered to have drained cell 2 of the WWTF resulting in the loss of approximately 8.7×10⁶ 1 of partially treated effluent and about 600 m³ of soil into previously undetected subsurface voids of unknown dimensions. In the week following the collapse, approximately 200 water wells located within a 5-km radius of the WWTF were sampled in an after-the-fact, emergency sampling program. Twelve samples with elevated fecal coliform levels, 18 samples with nitrate-nitrogen greater than the 10 mg/1 standard, and no samples with elevated chlorides were found. However, the elevated levels could not be unambiguously attributed to the WWTF collapse. This is the third WWTF to fail by sinkhole collapse in southeast Minnesota since 1974. All three collapsed lagoons have been located in similar geomorphic and stratigraphic settings. However, at least two lagoons have collapsed in the adjacent area in northeast Iowa, and these lagoons are located at different stratigraphic positions. Twenty-two WWTFs constructed in southeast Minnesota's karst region in the last 25 years have been identified as subject to potential sinkhole collapse. An unknown but significant number of manure storage lagoons, flood control structures, etc., have also been constructed in the karst region and are at risk. Public agencies are beginning to develop plans to deal with the risk associated with existing and future waste lagoons in this environment. The critical hydrogeologic parameters that can be used to prioritize the risk of collapse at existing facilities include: (1) the lithology of the first bedrock beneath each lagoon, (2) the thickness of surficial materials between the lagoon and the bedrock surface, (3) the presence and construction of liners (seepage rate), and (4) the proximity to existing sinkholes.     

Mercury,arsenic, antimony,and selenium contents of sediment from the Kuskokwim River,Bethel, Alaska,USA

The Kuskokwim River at Bethel, Alaska, drains a major mercury-antimony metallogenic province in its upper reaches and tributaries. Bethel (population 4000) is situated on the Kuskokwim floodplain and also draws its water supply from wells located in river-deposited sediment. A boring through overbank and floodplain sediment has provided material to establish a baseline datum for sediment-hosted heavy metals. Mercury (total), arsenic, antimony, and selenium contents were determined; aluminum was also determined and used as normalizing factor. The contents of the heavy metals were relatively constant with depth and do not reflect any potential enrichment from upstream contaminant sources.     

滇东南花岗岩与锡、银、铜、铅、锌多金属矿床的成因关系

滇东南锡、银、铅、锌多金属矿床主要分布在个旧、白牛厂、都龙3个矿区,而滇东南较大的3个花岗岩体又分别出露在3个矿区或附近.花岗岩体均形成于燕山晚期,岩石化学、矿物成分相似,富含锡、银、铅、锌、钨、铜等成矿元素.矿床主金属元素组合与岩体之间的距离由远而近出现由锡、钨、(铍、铌、钽)→锡、钨、(铁)、铜、铟→锡、铅、锌、银、铟、(锑)有规律的变化.花岗岩浆是成矿物质来源和成矿热源.岩浆侵入初期使上覆地层隆起产生背斜(凹陷部位成向斜);同时使地层产生一系列裂隙、压性断层或层间断裂;岩浆侵入晚期,这些断层再次活动,表现为张性,岩浆产生的含矿热液沿由其活动所造成的断裂迁移、充填、交代、沉淀而形成矿床.