Reservoir-induced seismicity in the Longtan reservoir, southwestern China

A pronounced increase in seismicity started in and around Longtan reservoir, southwestern China after October 1, 2006 when it began the impoundment, and by the end of May 14, 2010, about 3,233 earthquakes with ?0.6?≤?M _L?≤?4.2 had been located. This seismicity which occurred in five clusters mainly concentrated in the areas where few earthquakes had occurred before the first filling. There were four water filling periods in the Longtan reservoir, and the observed reservoir-induced seismicity (RIS) shows a strong correlation with the filling cycles. After the first filling, there appears to be an instant undrained response due to an elastic response to the reservoir load in the third and fourth cluster. Then, this seismicity is followed by a delayed, drained response due to pore pressure diffusion, with the seismicity migrating outwards in one or more directions in the second and third filling period. The seismic diffusivity (α _s) we estimated is about 4.54?×?10⁵?cm²/s. The activity levels in the five clusters are different due to differences in the structures and permeabilities of the faults. The delayed seismic response to the filling in the third cluster was due to the combined effects of the lack of local fault intersecting the reservoir and lower permeability of the rock. The b value we obtained for reservoir-induced events was significantly different and higher than that of pre-impoundment natural tectonic earthquakes in the Longtan reservoir. The results of relocated earthquakes based on double difference earthquake location algorithm showed that their focal depths were mainly shallower than about 10 km and the distribution of relocated RIS in four clusters had no relation with these intersecting faults in the Longtan reservoir except the fifth cluster. All these characteristics of RIS in the Longtan reservoir indicate that they may relate to the coupled poroelastic response that includes both pore pressure diffusion and an undrained response, but the pore pressure diffusion and the water permeation appear to play a more important role on inducing the earthquakes in Longtan reservoir.     

汶川地震断裂带水岩相互作用及其对断裂带演化影响

汶川地震断层岩的矿物学和地球化学特征揭示出地震断层经历了漫长时间演化和复杂的水岩相互作用.间震期水岩相互作用导致断层岩中的破碎矿物蚀变,尤其是长石等矿物含量渐渐减少甚至消失,而黏土矿物（蒙脱石、伊利石、伊/蒙混层、绿泥石等）含量逐渐增高,以及如黄铁矿、石膏、重晶石、坡缕石等热液系统中常见的矿物大量出现;Mg、P、Ti、Mn、Fe等元素倾向富集在断层带中,而Si、K和Na等出现明显的亏损;元素的大量迁移导致断层带的体积巨量亏损.实验结果表明,黏土矿物的亲水性引起水渗透率比干燥气体渗透率明显偏低,并且二者偏差无法通过Klinkenberg校正消除.蒙脱石吸水膨胀和黏土矿物颗粒表面吸附孔隙流体造成孔隙度降低是导致水渗透率偏低的重要原因.断层岩碎屑结构使得其中的孔隙可能在600 MPa围压下得以保存,从而有助于流体沿断层带下渗,并在断层带深部形成高流体孔隙压.地震断层的主要矿物学及粒度分布特征并非在地震破裂过程中形成,因此利用断层岩粒度分布资料估算地震破裂能并不合适.     

Nanoscale porosity in SAFOD core samples (San Andreas Fault)

With transmission electron microscopy (TEM) we observed nanometer-sized pores in four ultracataclastic and fractured core samples recovered from different depths of the main bore hole of the San Andreas Fault Observatory at Depth (SAFOD). Cutting of foils with a focused ion beam technique (FIB) allowed identifying porosity down to the nm scale. Between 40 and 50% of all pores could be identified as in-situ pores without any damage related to sample preparation. The total porosity estimated from TEM micrographs (1–5%) is comparable to the connected fault rock porosity (2.8–6.7%) estimated by pressure-induced injection of mercury. Permeability estimates for cataclastic fault rocks are 10^? 21–10^? 19 m² and 10^? 17 m² for the fractured fault rock. Porosity and permeability are independent of sample depth. TEM images reveal that the porosity is intimately linked to fault rock composition and associated with deformation. The TEM-estimated porosity of the samples increases with increasing clay content. The highest porosity was estimated in the vicinity of an active fault trace. The largest pores with an equivalent radius > 200 nm occur around large quartz and feldspar grains or grain-fragments while the smallest pores (equivalent radius < 50 nm) are typically observed in the extremely fine-grained matrix (grain size < 1 μm). Based on pore morphology we distinguish different pore types varying with fault rock fabric and alteration. The pores were probably filled with formation water and/or hydrothermal fluids at elevated pore fluid pressure, preventing pore collapse. The pore geometry derived from TEM observations and BET (Brunauer, Emmett and Teller) gas adsorption/desorption hysteresis curves indicates pore blocking effects in the fine-grained matrix. Observations of isolated pores in TEM micrographs and high pore body to pore throat ratios inferred from mercury injection suggest elevated pore fluid pressure in the low permeability cataclasites, reducing shear strength of the fault.     

Laboratory Characterization of Permeability and Its Anisotropy of Chelungpu Fault Rocks

In Taiwan an international project to drill into the Chelungpu fault (TCDP) was initiated after the M _w 7.6 Chi-Chi earthquake in 1999. At Takeng, two vertical holes (A and B) to depths of about 2 km have been drilled through the northern portion of the Chelungpu fault system. In this study, we conducted systematic hydromechanical tests on TCDP drillcores collected from Hole-A at various depths above and below the major slip zone of the Chelungpu fault. We focus on the measurements of permeability as function of pressure and the brittle failure behavior. Evolution of permeability as a function of pressure and porosity was measured using either steady-state flow or a pulse transient technique. When subjected to an effective pressure reaching 100 MPa, permeability values of shaly siltstone samples range from 10^?16 to 10^?19 m². In comparison, permeability values of porous sandstones are at least an order of magnitude higher, ranging from 10^?14 to 10^?18 m². To characterize permeability anisotropy associated with the bedding structure of the rocks of the Chelungpu fault, cylindrical samples were taken from the TCDP drillcores along three orthogonal directions, denoted X, Y and Z respectively. Direction Z is parallel to the TCDP core axis, and the other two directions are perpendicular to the core axis, with X (N105°E) perpendicular and Y (N15°E) parallel to the strike of the bedding. In shaly siltstones, permeability values of samples cored along the strike of bedding (direction Y) can be up to 1 order of magnitude higher than those cored perpendicular to the strike of bedding (direction X). These observations indicate that permeability anisotropy is controlled by the spatial distribution of bedding in Chelungpu fault host rocks. Permeability evolution of fault rocks plays an important role in dynamic weakening processes, which are particularly pertinent to large earthquakes such as the Chi-Chi earthquake. Our experimental data on permeability and its anisotropy of TCDP core samples provide necessary constraints on fault models and proposed weakening mechanisms.     

Water-rock interactions in fault gouge

Measurements were made of the amounts of D,¹⁸O, and H₂O⁺ in fault gouge collected over a depth of 400 m in the San Andreas fault of California. The amounts and isotopic compositions of the pore fluids, also analyzed, suggest that formation waters from adjacent Franciscan rocks have migrated into the gouge and mixed with local meteoric water. Thus the gouge is an open system permeable to fluid flow. This permeability has important implications concerning heat flow along the fault zone.Analyses of the fault gouge itself give information on the amounts, timing, and conditions of formation of the clay minerals.Stable-isotope analyses of materials from fault zones are good indicators of water-rock interactions that bear importantly on processes taking place in seismically active regions.     

Examination of a Rock Failure Criterion Based on Circumferential Tensile Strain

—Uniaxial compression, triaxial compression and Brazialian tests were conducted on several kinds of rock, with particular attention directed to the principal tensile strain. In this paper we aim to clarify the effects of the experimental environment—such as confining pressure, loading rate, water content and anisotropy—on the critical tensile strain, i.e., the measured principal tensile strain at peak load.¶It was determined that the chain-type extensometer is a most suitable method for measuring the critical tensile strain in uniaxial compression tests. It is also shown that the paper-based strain gage, whose effective length is less than or equal to a tenth of the specimen’s diameter and glued on with a rubber-type adhesive, can be effectively used in the Brazilian tests.¶The effect of confining pressure P _C on the critical tensile strain ? _TC in the brittle failure region was between ?0.02 × 10^?10 Pa^?1 and 0.77 × 10^?10 Pa^?1. This pressure sensitivity is small compared to the critical tensile strain values of around ?0.5 × 10^?2. The strain rate sensitivities ?? _TC /?{log(d|?|/dt)} were observed in the same way as the strength constants in other failure criteria. They were found to be from ?0.10 × 10^?3 to ?0.52 × 10^?3 per order of magnitude in strain rate in the triaxial tests. The average magnitude of the critical tensile strain ? _TC increased due to the presence of water by 4% to 20% for some rocks, and decreased by 22% for sandstone. It can at least be said that the critical tensile strain is less sensitive to water content than the uniaxial compressive strength under the experimental conditions reported here. An obvious anisotropy was observed in the P-wave velocity and in the uniaxial compressive strength of Pombetsu sandstone. It was not observed, however, in the critical tensile strain, although the data do show some variation.¶A "tensile strain criterion" was proposed, based on the above experimental results. This criterion signifies that stress begins to drop when the principal tensile strain reaches the critical tensile strain. The criterion is limited to use within the brittle failure region. The critical tensile strain contains an inelastic strain component as well as an elastic one. It is affected by the strain rate, however, it is relatively insensitive to the confining pressure, the presence of water and anisotropy.     

Mechanism for calcite dissolution and its contribution to development of reservoir porosity and permeability in the Kela 2 gas field,Tarim Basin,China

This study is undertaken to understand how calcite precipitation and dissolution contributes to depth-related changes in porosity and permeability of gas-bearing sandstone reservoirs in the Kela 2 gas field of the Tarim Basin, Northwestern China. Sandstone samples and pore water samples are col-lected from well KL201 in the Tarim Basin. Vertical profiles of porosity, permeability, pore water chem-istry, and the relative volume abundance of calcite/dolomite are constructed from 3600 to 4000 m below the ground surface within major oil and gas reservoir rocks. Porosity and permeability values are in-versely correlated with the calcite abundance, indicating that calcite dissolution and precipitation may be controlling porosity and permeability of the reservoir rocks. Pore water chemistry exhibits a sys-tematic variation from the Na2SO4 type at the shallow depth (3600-3630 m), to the NaHCO3 type at the intermediate depth (3630―3695 m),and to the CaCl2 type at the greater depth (3728―3938 m). The geochemical factors that control the calcite solubility include pH, temperature, pressure, Ca2 concen-tration, the total inorganic carbon concentration (ΣCO2), and the type of pore water. Thermodynamic phase equilibrium and mass conservation laws are applied to calculate the calcite saturation state as a function of a few key parameters. The model calculation illustrates that the calcite solubility is strongly dependent on the chemical composition of pore water, mainly the concentration difference between the total dissolved inorganic carbon and dissolved calcium concentration (i.e., [ΣCO2] -[Ca2 ]). In the Na2SO4 water at the shallow depth, this index is close to 0, pore water is near the calcite solubility. Calcite does not dissolve or precipitate in significant quantities. In the NaHCO3 water at the intermedi-ate depth, this index is greater than 0, and pore water is supersaturated with respect to calcite. Massive calcite precipitation was observed at this depth interval and this intensive cementation is responsible for decreased porosity and permeability. In the CaCl2 water at the greater depth, pore water is un-der-saturated with respect to calcite, resulting in dissolution of calcite cements, as consistent with microscopic dissolution features of the samples from this depth interval. Calcite dissolution results in formation of high secondary porosity and permeability, and is responsible for the superior quality of the reservoir rocks at this depth interval. These results illustrate the importance of pore water chemis-try in controlling carbonate precipitation/dissolution, which in turn controls porosity and permeability of oil and gas reservoir rocks in major sedimentary basins.     

Geometry of the Nojima Fault at Nojima-Hirabayashi, Japan – I. A Simple Damage Structure Inferred from Borehole Core Permeability

The 1995 Kobe (Hyogo-ken Nanbu) earthquake, M = 7.2, ruptured the Nojima fault in southwest Japan. We have studied core samples taken from two scientific drillholes that crossed the fault zone SW of the epicentral region on Awaji Island. The shallower hole, drilled by the Geological Survey of Japan (GSJ), was started 75 m to the SE of the surface trace of the Nojima fault and crossed the fault at a depth of 624 m. A deeper hole, drilled by the National Research Institute for Earth Science and Disaster Prevention (NIED) was started 302 m to the SE of the fault and crossed fault strands below a depth of 1140 m. We have measured strength and matrix permeability of core samples taken from these two drillholes. We find a strong correlation between permeability and proximity to the fault zone shear axes. The half-width of the high permeability zone (approximately 15 to 25 m) is in good agreement with the fault zone width inferred from trapped seismic wave analysis and other evidence. The fault zone core or shear axis contains clays with permeabilities of approximately 0.1 to 1 microdarcy at 50 MPa effective confining pressure (10 to 30 microdarcy at in situ pressures). Within a few meters of the fault zone core, the rock is highly fractured but has sustained little net shear. Matrix permeability of this zone is approximately 30 to 60 microdarcy at 50 MPa effective confining pressure (300 to 1000 microdarcy at in situ pressures). Outside this damage zone, matrix permeability drops below 0.01 microdarcy. The clay-rich core material has the lowest strength with a coefficient of friction of approximately 0.55. Shear strength increases with distance from the shear axis. These permeability and strength observations reveal a simple fault zone structure with a relatively weak fine-grained core surrounded by a damage zone of fractured rock. In this case, the damage zone will act as a high-permeability conduit for vertical and horizontal flow in the plane of the fault. The fine-grained core region, however, will impede fluid flow across the fault.     

Compressional- and shear-wave velocities as a function of confining stress in dry sandstones

A laboratory study was carried out to investigate the influence of confining stress on compressional- and shear-wave velocities for a set of rock samples from gas-producing sandstone reservoirs in the Cooper Basin, South Australia. The suite of samples consists of 22 consolidated sublitharenites with helium porosity ranging from 2.6% to 16.6%. We used a pulse-echo technique to measure compressional- and shear-wave velocities on dry samples (cylindrical 4.6 × 2 cm) at room temperature and at elevated confining stress (≤ 60 MPa). Compressional- and shear-wave velocities in samples increase non-linearly with confining stress. A regression equation of the form V = A ? Be^?DP gives a good fit to the measured velocities with improved prediction of velocities at high confining stresses compared with equations suggested by other studies. The predicted microcrack-closure stresses of the samples show values ranging from 70 MPa to 95 MPa and insignificant correlation with porosity, permeability or clay content. There is a positive correlation between change in velocity with core porosity and permeability, but this association is weak and diminishes with increasing confining stress. Experimental results show that pore geometry, grain-contact type, and distribution and location of clay particles may be more significant than total porosity and clay content in describing the stress sensitivity of sandstones at in situ reservoir effective stress. The stress dependence of Cooper Basin sandstones is very large compared with data from other studies. The implication of our study for hydrocarbon exploration is that where the in situ reservoir effective stress is much less than the microcrack-closure stress of the reservoir rocks, the variation of reservoir effective stress could cause significant changes in velocity of the reservoir rocks. The velocity changes induced by effective stress in highly stress-sensitive rocks can be detected at sonic-log and probably surface-seismic frequencies.     

Effects of cyclic confining pressure on the deformation characteristics of natural soft clay

To investigate the coupling effects of cyclic deviator stress and cyclic confining pressure on the deformation behavior of natural soft clay under partially-drained conditions, a series of one-way cyclic triaxial tests with and without cyclic confining pressure were carried out. Test results show that, at the same amplitude of cyclic deviator stress, the increase of cyclic confining pressure amplitude will accelerate the accumulation of both permanent volumetric and axial strain significantly. The comparison between test results for different amplitudes of cyclic confining pressure shows that tests with a cyclic confining pressure corresponding to a stress path of η^ampl=p^ampl/q^ampl=1 lead to a 1.4 times larger permanent volumetric strain and a 1.2 times larger permanent axial strain compared to the conventional cyclic triaxial tests with constant confining pressure (η^ampl=1/3). In case of η^ampl=2 the permanent strains are found to be even 2.0 or 1.5 times larger compared to the standard tests. Finally, an empirical formula is proposed for the prediction of permanent axial deformations of natural soft clays under partially-drained conditions, considering the effects of cyclic confining pressure.     

Hydrogeologic Controls on Induced Seismicity in Crystalline Basement Rocks Due to Fluid Injection into Basal Reservoirs

A series of M_b 3.8–5.5 induced seismic events in the midcontinent region, United States, resulted from injection of fluid either into a basal sedimentary reservoir with no underlying confining unit or directly into the underlying crystalline basement complex. The earthquakes probably occurred along faults that were likely critically stressed within the crystalline basement. These faults were located at a considerable distance (up to 10 km) from the injection wells and head increases at the hypocenters were likely relatively small (～70–150 m). We present a suite of simulations that use a simple hydrogeologic‐geomechanical model to assess what hydrogeologic conditions promote or deter induced seismic events within the crystalline basement across the midcontinent. The presence of a confining unit beneath the injection reservoir horizon had the single largest effect in preventing induced seismicity within the underlying crystalline basement. For a crystalline basement having a permeability of 2 × 10^?17 m² and specific storage coefficient of 10^?7/m, injection at a rate of 5455 m³/d into the basal aquifer with no underlying basal seal over 10 years resulted in probable brittle failure to depths of about 0.6 km below the injection reservoir. Including a permeable (k_z = 10^?13 m²) Precambrian normal fault, located 20 m from the injection well, increased the depth of the failure region below the reservoir to 3 km. For a large permeability contrast between a Precambrian thrust fault (10^?12 m²) and the surrounding crystalline basement (10^?18 m²), the failure region can extend laterally 10 km away from the injection well.     

颗粒组成对粉土动强度的影响分析

以天津汉沽地区某挡土墙地基粉土为研究对象,首先对不同颗粒组成的粉土做固结不排水动三轴剪切试验,采用各向等压固结,周围压力等于100kPa。固结完成后在不排水条件下施加轴向激振力,试验波形为正弦波,振动频率1.0Hz,试验中以试样在周期剪切时轴向周期应变达到5%作为破坏标准,得出粉土的动强度受颗粒组成的影响。细颗粒含量越大,其动强度越小,黏粒含量为7.2%的粉土循环剪应力比CSR约为20.3%黏粒含量粉土的2倍。粉土的动强度可以用循环剪应力比和破坏振次建立的幂函数关系式较好地拟合。在剪切过程中,粉土的孔隙水压力一直没有达到所施加的围压数值,最终稳定在75%~85%围压之间。同时,试验还得出孔隙水压力的增长模式不能用统一的Seed模型拟合,孔压增长规律的影响因素较多。     

温度压力孔隙压力对断层泥强度及滑动性质的影响

在不同的压力、温度和孔隙压力下进行了含四种不同断层泥标本的强度试验。碎屑型断层泥对压力很敏感,对温度无反应,对孔隙压力的反应符合有效应力律。粘土类断层泥则对温度和孔隙压力有明显响应。这些力学性质的差别反映了具体变形机制的差别     

Characteristics and accumulation mechanisms of the Dongfang 13-1 high temperature and overpressured gas field in the Yinggehai Basin,the South China Sea

The Dongfang 13-1 is located in the diapiric structure belt of the Yinggehai Basin. The formation pressure of its main gas reservoir in the Miocene Huangliu Formation is up to 54.6 MPa(pressure coefficient=1.91) and the temperature is as high as 143°C(geothermal gradient 4.36°C/100 m), indicating that it is a typical high-temperature and overpressured gas reservoir. The natural gas is interpreted to be coal-type gas derived from the Miocene mature source rocks containing type II2-III kerogens as evidenced by high dryness index of up to 0.98 and heavy carbon isotopes, i.e., the δ13C1 ranging from -30.76‰ to -37.52‰ and δ13C2 ranging from -25.02‰ to -25.62‰. The high temperature and overpressured Miocene petroleum system is related mainly to diapir in the Yinggehai Basin and contains more pore water in the overpressured reservoirs due to undercompaction process. The experimental and calculated results show that the solubility of natural gas in formation water is as high as 10.5 m3/m3 under the temperature and pressure conditions of the Sanya Formation, indicating that at least part of the gas may migrate in the form of water-soluble phase. Meanwhile, the abundant gas source in the Basin makes it possible for the rapid saturation of natural gas in formation water and exsolution of soluble gas. Therefore, the main elements controlling formation of the Dongfang 13-1 gas pool include that(1) the diapir activities and accompanying changes in temperature and pressure accelerate the water-soluble gas exsolution and release a lot of free gas;(2) submarine fan fine sandstone in the Huangliu Formation provides good gas-water segregation and accumulation space; and(3) the overlying overpressured mud rocks act as effective caps. The accumulation mechanism reveals that the high temperatural and high pressure structure belt near the diapir structures has a good potential for large and medium-sized gas field exploration.     

Helium isotopes in the Izu Peninsula,Japan: Relation of magma and crustal activity

The relation of magma and crustal activity has been studied from spatial distribution of ³He/⁴He ratios of gas and/or water samples over the Izu Peninsula, where significant crustal deformation associated with seismic swarm activities has been observed since 1970s. The air-corrected values of ³He/⁴He ratios ranged from 3.5 to 8.2 R_A, where R_A is the atmospheric ³He/⁴He ratio = 1.4 × 10^? 6, indicating that helium is mostly of magmatic origin. Among the three pressure sources proposed to explain the crustal deformation, two inflation sources beneath the inland of northeast and the mid east coast of the Izu Peninsula locate in the broad distribution of high ³He/⁴He ratios, which supports relation of magma to the crustal uplift. In contrast, the distribution of ³He/⁴He ratios around the tensile fault assumed in the area of seismic swarms appears not to indicate existence of significant amount of magma below the tensile fault. Alternatively, the results suggest magma below a point several kilometers south of the tensile fault. The seismic swarms are explained either by fluid pressurization of thermal water heated by this magma or by intrusion of magma to the tensile fault moved obliquely from the deep magma reservoir.     

Gas exsolution and flow during supersaturated water injection in porous media: II. Column experiments and continuum modeling

Degassing and in situ development of a mobile gas phase takes place when an aqueous phase equilibrated with a gas at a pressure higher than the subsurface pressure is injected in water-saturated porous media. This process, which has been termed supersaturated water injection (SWI), is a novel and hitherto unexplored means of introducing a gas phase in the subsurface. We give herein a first macroscopic account of the SWI process on the basis of continuum scale simulations and column experiments with CO₂ as the dissolved gas. A published empirical mass transfer correlation [Nambi IM, Powers SE. Mass transfer correlations for nonaqueous phase liquid dissolution from regions with high initial saturations. Water Resour Res 2003;39(2):1030. doi:10.1029/2001WR000667] is found to adequately describe non-equilibrium transfer of CO₂ between the aqueous and gas phases. Remarkably, the dynamics of gas-water two-phase flow, observed in a series of SWI experiments in homogeneous columns packed with silica sand or glass beads, are accurately predicted by traditional two-phase flow theory and the corresponding gas relative permeability is determined. A key consequence of this finding, namely that the displacement of the aqueous phase by gas is compact at the macroscopic scale, is consistent with pore scale simulations of repeated mobilization, fragmentation and coalescence of large gas clusters (i.e., large ganglion dynamics) driven entirely by mass transfer. The significance of this finding for the efficient delivery of a gas phase below the water table is discussed in connection to the alternative process of in situ air sparging, and potential advantages of SWI are highlighted.     

Effects of ultrafiltration on salt migration and isotopic composition of pore water in groundwater depression area in Hengshui,NCP

Clay aquitards are semipermeable membranes that allow groundwater flow while retarding solute migration has been researched extensively but also subjected to much debate. At present, there is no evidence of whether the physical and chemical properties of clay soil and the isotopic composition of pore water affect the semipermeable membrane effect. In this study, we collected clay samples from drilling cores (30–90 m) in the Hengshui area located in the North China Plain (NCP), then extracted pore water using a high-pressure squeezing device. Vertical hydrochemical and isotopic profile variation trends for the pore water were revealed using hydrochemical (Cl⁻, Na⁺, Ca²⁺, K⁺, Mg²⁺, and SO₄²⁻) and stable isotopic measurements of H, O and Cl. The results showed that the hydrochemical clay interlayer pore water of the saline aquifer is Cl/SO₄-Na/Mg type and the average total dissolved solids (TDS) are 10.17 g/L. However, the hydrochemical clay aquitard pore water is of the Cl/SO₄-Na/Ca type with an average TDS of 1.90 g/L. The hydrochemical clay interlayer pore water of aquifer II is of Cl-Na/Ca type with an average TDS of 1.10 g/L. Our results showed that the water quality of the aquifer II is not affected by the upper part of the saline aquifer, thus the clay aquitard acts as a significant barrier to salt movement. A polarization layer concentrated in ions was formed between the upper part of the saline aquifer and the clay aquitard. The concentration polarization layer increases the salt-inhibition effect. H, O and Cl isotopic composition results showed significant fractionation. The pore water of aquifer II lacked heavy isotopes (²H, ¹⁸O, ³⁷Cl), but had significant heavy isotope enrichment in the concentrated polarized layer (the δ²H value was −76‰, the δ¹⁸O value was −8.4‰, and the δ³⁷Cl value was 1.59‰). Hyperfiltration thus played a significant role in isotope fractionation.     

Evidence that piezometers vent gas from peat soils and implications for pore‐water pressure and hydraulic conductivity measurements

Entrapped gas bubbles in peat can alter the buoyancy, storativity, void ratio and expansion/contraction properties of the peat. Moreover, when gas bubbles block water‐conducting pores they can significantly reduce saturated hydraulic conductivity and create zones of over‐pressuring, perhaps leading to an alteration in the magnitude and direction of groundwater flow and solute transport. Some previous researches have demonstrated that these zones of over‐pressuring are not observed by the measurements of pore‐water pressures using open‐pipe piezometers in peat; rather, they are only observed with pressure transducers sealed in the peat. In has been hypothesized that open‐pipe piezometers vent entrapped CH₄ to the atmosphere and thereby do not permit the natural development of zones of entrapped gas. Here we present findings of the study to investigate whether piezometers vent subsurface CH₄ to the atmosphere and whether the presence of piezometers alters the subsurface concentration of dissolved CH₄. We measured the flux of methane venting from the piezometers and also determined changes in pore‐water CH₄ concentration at a rich fen in southern Ontario and a poor fen in southern Quebec, in the summer of 2004. Seasonally averaged CH₄ flux from piezometers was 1450 and 37·8‐mg CH₄ m^?2 d^?1 at the southern Ontario site and Quebec site, respectively. The flux at the Ontario site was two orders of magnitude greater than the diffusive flux at the site. CH₄ pore‐water concentrations were significantly lower in open piezometers than in water taken from sealed samplers at both the Ontario and Quebec sites. The flux of CH₄ from piezometers decreased throughout the season suggesting that CH₄ venting through the piezometer exceeded the rate of methanogenesis in the peat. Consequently we conclude that piezometers may alter the gas dynamics of some peatlands. We suggest that less‐invasive techniques (e.g. buried pressure transducers, tracer experiments) are needed for the accurate measurement of pore‐water pressures and hydraulic conductivity in peatlands with a large entrapped gas component. Furthermore, we argue that caution must be made in interpreting results from previous peatland hydrology studies that use these traditional methods. Copyright © 2009 John Wiley & Sons, Ltd.     

Depositional processes and gas pore pressure in pyroclastic flows: an experimental perspective

The depositional processes and gas pore pressure in pyroclastic flows are investigated through scaled experiments on transient, initially fluidized granular flows. The flow structure consists of a sliding head whose basal velocity decreases backwards from the front velocity (U _f) until onset of deposition occurs, which marks transition to the flow body where the basal deposit grows continuously. The flows propagate in a fluid-inertial regime despite formation of the deposit. Their head generates underpressure proportional to U _f ² whereas their body generates overpressure whose values suggest that pore pressure diffuses during emplacement. Complementary experiments on defluidizing static columns prove that the concept of pore pressure diffusion is relevant for gas-particle mixtures and allow characterization of the diffusion timescale (t _d) as a function of the material properties. Initial material expansion increases the diffusion time compared with the nonexpanded state, suggesting that pore pressure is self-generated during compaction. Application to pyroclastic flows gives minimum diffusion timescales of seconds to tens of minutes, depending principally on the flow height and permeability. This study also helps to reconcile the concepts of en masse and progressive deposition of pyroclastic flow units or discrete pulses. Onset of deposition, whose causes deserve further investigation, is the most critical parameter for determining the structure of the deposits. Even if sedimentation is fundamentally continuous, it is proposed that late onset of deposition and rapid aggradation in relatively thin flows can generate deposits that are almost snapshots of the flow structure. In this context, deposition can be considered as occurring en masse, though not strictly instantaneously.     

Forced oscillation measurements of seismic attenuation in fluid saturated sandstone

Adopting the method of forced oscillation, attenuation was studied in Fontainebleau sandstone (porosity 10%, permeability 10 mD) at seismic frequencies (1–100 Hz). Confining pressures of 5, 10, and 15 MPa were chosen to simulate reservoir conditions. First, the strain effect on attenuation was investigated in the dry sample for 11 different strains across the range 1 × 10^?6–8 × 10^?6, at the confining pressure of 5 MPa. The comparison showed that a strain of at least 5 × 10^?6 is necessary to obtain a good signal to noise ratio. These results also indicate that nonlinear effects are absent for strains up to 8 × 10^?6. For all the confining pressures, attenuation in the dry rock was low, while partial (90%) and full (100%) saturation with water yielded a higher magnitude and frequency dependence of attenuation. The observed high and frequency dependent attenuation was interpreted as being caused by squirt flow.