The forbidden transitions within 3s 2 3p 5 3d of Fe ix and Ni xi and 3s 2 3p 4 3d of Fe x and Ni xii

Improved level values for 3s ² 3p ⁵ 3d and 3s ² 3p ⁴ 3d of Fe ix and Fe x are derived from the observed forbidden lines with special regard to recent accurate measurements in the vacuum-ultraviolet part of the coronal spectrum. A procedure for estimating expected relative intensities is proposed and used for an additional check on the consistency of the identifications, which now comprise 12 lines of Fe IX and 11 lines of Fe x. Finally, by use of a suitable extrapolation technique the wavelengths of corresponding lines in nickel are predicted, which leads to some new identifications and a total of 6 identified lines of Ni xi and 4 of Ni xii.     

Density dependence of forbidden transitions within 3s 23p 53d of the coronal ion Fe IX

The relative populations of metastable levels within the configuration 3s ²3p ⁵3d of the ion Fe ix have been calculated as a function of electron density N _e . The results are used to derive emissivities of the most intense lines originating from these levels. Comparison with observations confirms the proposed identifications. The density dependence of some line ratios may be used to determine N _e .     

Identification of forbidden coronal lines of Fe x and Ni xii

The transitions 3s ²3p ⁴3d ⁴ D, ⁴ F–3s3p ⁵3d ⁴ F have been studied in the Cl i isoelectronic sequence from Ca iv to Fe x. The determination of the 3s ²3p ⁴3d quartet intervals in Fe x has led to the identification of eleven coronal lines in the region from 1463 Å to 5539 Å as forbidden transitions within this configuration. By extrapolation, an additional coronal line is identified with a similar transition in Ni xii.     

Observation of possible Fe xvii 2p 53p(1S0)-2p 53s(1 P 1, 3 P 1) transitions in spectra of a solar active region and flare

Expected wavelengths and relative intensities are obtained, from calculations of other workers, for the hitherto unobserved transitions 2p ⁵3p(¹ S ₀)-2p ⁵3s(¹ P ₁, ³ P ₁) in Fe xvii. A candidate pair of lines at 197.05 Å and 242.09 Å was found in laboratory spectra and appears to be present in the spectra of a solar active region observed by the OSO-7 Goddard spectroheliograph, and in the spectrum of a Skylab-observed solar flare.     

The Influence of the Electron κ-Distribution in the Solar Corona on the Fe VIII – Fe XV Line Intensities

Changes in the excitation equilibrium of Feviii – Fe xv in the solar corona due to the electron non-thermal κ-distribution are studied. The shape of the distribution affects the electron excitation rate and thus the relative intensities of the spectral lines. Since the shape of the electron distribution function influences also the ionization equilibrium of Fe, both effects change the final intensities of the lines. Possibilities for diagnostics of the shape of the electron distribution in the solar corona are discussed. Synthetic spectrum of Fe for T = 1.58× 10⁶ K and n_e = 10⁸ cm⁻³ is shown together with the synthetic spectra computed with DEM for the quiet Sun.     

The identification of Feix and Nixi in the solar corona

The levels of the configuration 3s ²3 _p ⁵3d of Fe ix have been experimentally determined from their combinations with 3s3 _p ⁶3d ³ D in the region 300–400 Å. Wavelengths can now be accurately predicted for all transitions within 3s ²3 _p 53^d, and eight of these can be identified with coronal lines from 2042 to 4585 Å. Also, identifications of solar lines from 171 to 245 Å with electric-dipole and magnetic-quadrupole transitions to the ground state, 3s ²3p ^{6 1} S, are confirmed and extended. Solar identifications with corresponding transitions in Ni xi, both within 3s ²3 _p ⁵3d and to the ground state, are proposed on the basis of a short extrapolation.     

The identification of new forbidden coronal lines in the solar EUV spectrum

Identifications are proposed for twenty of the twenty-eight coronal lines observed in the spectra obtained during a rocket flight into the path of the 7 March, 1970 solar eclipse. The methods by which the lines have been identified are discussed. Most of the lines identified are from forbidden transitions between levels in the ground 2p ⁿ and 3p ⁿ configurations in high ions of magnesium, silicon, sulphur, iron, and nickel. The temperature range represented is from 6.9 × 10⁵ K to 2.5 × 10⁶ K. The classification of three lines of Fexii and two of Nixiv has led to a revised identification for the near ultraviolet ² D _3/2-² P _1/2 transition in Fe xii. This transition can be identified with the line at 3072 Å rather than that at 3021 Å as previously suggested in the literature.     

Predicted wavelengths of coronal transitions in the configurations 3s 23p 2, 3s 23p 3 and 3s 23p 4

The level intervals in the ground configurations 3s ²3p ^k(k = 2, 3, 4) have been studied through the isoelectronic sequences up to Ni. Semiempirical expressions for the parameters F ₂(pp) and _p, are derived from observed data and the intervals are recalculated from interpolated or extrapolated values of the parameters. As a result, predicted wavelengths of magnetic-dipole transitions within the configurations are obtained with an estimated uncertainty of one or two Å.     

Wavelength predictions for the 1s2 2p - 1s2p3p satellite transitions

The energy differences between 1s ²2p 1s2p3p transitions and the corresponding 1s ² 1s3p resonances are expressed by means of a polynomial function of the atomic number. The agreement with experimental data from lithium to potassium is very good. Interpolated values for nitrogen to sodium and argon as well as extrapolation for calcium are reported.     

Fe XVIII EMISSION LINES IN SOLAR X-RAY SPECTRA

We have calculated intensity ratios for emission lines of Fexviii in the 13–94 Å wavelength range at electron temperatures characteristic of the solar corona, T _e = 2–10 x 10⁶ K. Our model ion includes data for transitions among the 2s ²2p ⁵ , 2s2p ⁶, 2s ²2p ⁴3l, and 2s2p ⁵3l (l = s, p, and d) states. Test calculations which omit the 2s2p ⁵3l levels show that cascades from these are important. We compare our results with observed ratios determined from four solar X-ray instruments, a rocket-borne spectrograph, and spectrometers on the P78–1, OV1–17 and Solar Maximum Mission (SMM) satellites. In addition, we have generated synthetic spectra which we compare directly with flare observations from SMM. Agreement between theory and observation is generally quite good, with differences that are mostly less than 30%, providing limited support for the accuracy of the atomic physics data used in our calculations. However, large discrepancies are found for ratios involving the 2s ²2p ^{5 2}P_3/2- 2s2p ^{6 2}S line at 93.84 Å, which currently remain unexplained. Our analysis indicates that the FeXVIII feature at 15.83 Å is the 2s ²2p ^{5 2}P_3/2 - 2s ²2p ⁴(³P)3s ⁴P_3/2 transition, rather than 2s ²2p ^{5 2}P_3/2 - 2s ²2p ⁴(³P)3s ²P_3/2, as suggested by some authors.     

The excitation of Fe XVII by electron impacts

The cross-sections for the excitation of Fe XVII are computed using the Coulomb-Born approximation. For the excitation of the configurations 2p⁵ 3s, 2p⁵ 3p and 2p⁵ 3d, the intermediate coupling scheme is used, while an extrapolation is made for the excitation of the 2s 2p⁶ 3s, 2s 2p⁶ 3p and 2s 2p⁶ 3d configurations from the results obtained earlier in the lithium-like ions. It is found that the excitation cross-section Q (2p^{6 1}S₀2p⁵ 3p ¹S₀) is fairly large and partly removes the disagreement between the theoretical and experimental intensity-line ratios.Work supported in part by the Advanced Research Projects Agency (Project DEFENDER) monitored by the U.S. Army Research Office, Durham, N.C., under Contract DA-31 -124-ARD-D-139.Research Associate at J.I.L.A., Boulder, Colo., for the year 1965–1966.NASA-ESRO fellowship at the University of Colorado, Boulder, for the year 1965–1966.     

A comparison of theoretical line strengths for the 2s 22p 2 − 2s2p 3 transitions in Ne v with solar data

Results are presented for several theoretical line ratios in Nev involving transitions between multiplets in the 2s ²2p ² and 2s2p ³ configurations. A comparison of these with solar data from the S082A and S-055 instruments on board Skylab reveals generally good agreement between theory and experiment, especially in the case of the high-resolution (S082A) observations. However the 2s ²2p ^{2 1} D – 2s2p ^{3 1} P (365.6 Å) and 2s ²2p ^{2 3}P – 2s2p ^{3 3} S (359 Å) lines appear to be blended, possibly with transitions in Fex and Fexi/Fexiii, respectively. We note that the intensity ratio I(365.6 Å)/I(416.2 Å) should be a valuable calibration check for a high-resolution extreme ultraviolet instrument in the spectral range 360–420 Å.     

Z-dependence of the level intervals in 2s 2 2p 2, 2s 2 2p 3 and 2s 2 2p 4

Values of the level intervals in the ground configurations 2s ² 2p ², 2s ² 2p ³ and 2s ² 2p ⁴ have been critically compiled from laboratory observations and from observations of nebular and coronal forbidden transitions. The data are represented within experimental errors by means of semi-empirical extrapolation formulae which contain from 3 to 5 adjusted parameters. The results provide means for checking laboratory and astrophysical identifications and measurements. Tables of best level values are given for the configurations concerned.     

Theoretical intensities of Fexiv in the solar EUV spectrum

Equilibrium population of Fexiv levels in coronal conditions was calculated including configurations 3s ²3p, 3s3p ², 3s ²3d, 3p ³, 3s3p3d, 3s ²4s, 3s ²4p, 3s ²4d, 3s ²4f. Relative populations of selected levels are given in Table VII. Figure 1 shows the dependence of relative intensities of the strongest lines on electron density. Certain line ratios can be used for the determination of N _e .E.g., at T=2 × 10⁶ K and with a dilution factor 0.4, the intensity ratio of λ211.3 and λ219.0 changes by a factor of 65 if N _e increases from 10⁷ to 10¹¹ (Table VIII). Cascades from the 3s3p3d and 3p ³ configurations are important in the population of some levels of 3s3p ² (Table VI). A possibility of identification of additional lines in the solar spectrum is indicated. NAS-NRC Resident Research Associate.     

Low-Order p Modes From Virgo Irradiance Data

Several candidates for low-order p modes (n 5) and possibly g modes were found by applying mode-detection techniques such as multivariate spectral regression analysis and time-frequency analysis to the VIRGO full-disc solar irradiance data. Three out of the candidates for low-order p modes could be confirmed by significant peaks in the un-treated power spectra in good agreement with theoretical predictions. The frequency of a fourth candidate for a low-order p mode lies some 2.8 Hz below the predicted frequency. The candidates found for g modes are less reliable, since none of them could be confirmed neither by significant peaks in the un-treated power spectra nor by the detection of multiplets.     

Transitions between the n = 2 and n = 3 levels of Ne VII in the solar spectrum

Theoretical populations of the 2s3l levels of Ne vii are presented for electron temperatures from 2.5 × 10⁵ K to 4 × 10⁶ K and electron densities from 10⁸ cm^–3 to 10¹² cm^–3. These, in conjunction with intensities of previously observed solar Ne vii lines and wavelengths and intensities observed in the laboratory, are used to identify further Ne vii lines in the solar spectrum. The dependence on temperature of intensity ratios such as I(2s2p ¹ P – 2s3d ¹ D)/I(2s2p ³ P – 2s3d ³ D) is demonstrated and the advantages of the small wavelength separation of such lines for solar electron temperature diagnostics are discussed.     

Determination of the Fe oxidation state of the Chassigny kaersutite: A microXANES spectroscopic study

Abstract— In order to elucidate the formation of low‐H kaersutites in Martian meteorites, the Fe³⁺/ΣFe ratio of Chassigny kaersutites in magmatic inclusions was directly determined by the synchrotron microXANES analysis. XANES analysis for standard kaersutites with known Fe³⁺/ΣFe ratios shows a linear relationship between centroid energy positions of XANES pre‐edge spectra and the Fe³⁺/ΣFe ratio. Based on the linear relationship, the Fe³⁺/ΣFe ratio of Chassigny kaersutites is estimated to be about 0.05. The low Fe³⁺/ΣFe ratio clearly suggests that low‐H kaersutites in Chassigny are not likely to be formed by the oxidation‐dehydrogenation reactions. The low‐H content of the Chassigny kaersutites is mainly due to the presence of a Ti oxy‐component.     

Homogeneous distribution of Fe isotopes in the early solar nebula

To examine the iron (Fe) isotopic heterogeneities of CI and ordinary chondrites, we have analyzed several large chips (approximately 1 g) from three CI chondrites and three ordinary chondrites (LL5, L5, and H5). The Fe isotope compositions of five different samples of Orgueil, one from Ivuna and one from Alais (CI chondrites), are highly homogeneous. This new dataset provides a δ⁵⁶Fe average of 0.02 ± 0.04‰ (2SE, n = 7), which represents the best available value for the Fe isotopic composition of CI chondrites and probably the best estimate of the bulk solar system. We conclude that the homogeneity of CI chondrites reflects the initial Fe isotopic homogeneity of the well‐mixed solar nebula. In contrast, larger (up to 0.26‰ in δ⁵⁶Fe) isotopic variations have been found between separate approximately 1 g pieces of the same ordinary chondrite sample. The Fe isotope heterogeneities in ordinary chondrites appear to be controlled by the abundances of chondritic components, specifically chondrules, whose Fe isotope compositions have been fractionated by evaporation and recondensation during multiple heating events.     

General time elements for the two body problem

When integrating a perturbed two-body problem, very often the propagation of the numerical error is reduced by using a new time variables defined by dt/ds=|q| ⁿ , (|q| is the radial distance,t the time). This paper introduces a time element for such transformations, i.e., a new variablet _n is defined so that dt _n/ds=1+ (perturbing terms) andt=F _n(t_n), whereF _n is a known function. The time element equation should be useful in reducing the error in the determination of the timet.F _n is given explicitly forn=1, 3/2, 2, 5/2 and 3, and a general expression is given for other values.The work was performed while the author was an NRC Senior Research Associate, Goddard Space Flight Center, Greenbelt, Md., U.S.A.     

Calcul des probabilités de transition pour divers états excités du Fe XII

Résumé On a calculé les probabilités de transition pour les raies interdites ou permises entre les états (3p²3d-3p³), (3p²4s-3p³), (3s3p⁴-3s²3p³), (3p²4d-3P³) du FeXII. Les niveaux d'énergie ²D_3/2, ²D_5/2, ²P_1/2, ²P_3/2 ont été obtenus par extrapolation le long de la séquence isoélectronique P1. On discute brièvement les effets d'un écart aux conditions de couplage L-S dus aux interactions spin-orbite et de configuration.

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Transition probabilities have been computed for forbidden or permitted lines within the (3p²3d-3p³), (3p²4s-3p³), (3s3p⁴-3s²3p³), (3p²4d-3p³) configurations in FeXII. Energy levels ²D_3/2, ²D_5/2, ²P_1/2, ²P_3/2 have been predicted by extrapolation along the isoelectronic sequence P1. The effects of departures from L-S coupling due to spin-orbit and configuration interaction are briefly discussed.