塔河油田奥陶系古岩溶洞穴识别及预测

在塔河油田奥陶系中蕴藏着丰富的石油资源，碳酸盐岩储层的主要储集空间为裂缝和溶蚀孔、洞，其中岩溶洞穴是最主要的储集空间，研究岩溶洞穴的展布具重要意义．应用钻井、测井、地震等资料分析了岩溶洞穴的识别标志，并利用地震反射结构和振幅变化率技术预测了岩溶洞穴在塔河油田某区的展布．     

桂林岩溶洞穴发育的古老性及热带岩溶发育历史的探讨

通过不同高程上岩溶洞穴、溶隙、洼地内充填和残存的不同时代的地层实际资料，结合对本区热带岩溶发育历史的研究认为，桂林热带岩溶发育可上推到中三叠世初期的桂西运动就开始了，岩溶洞穴发育最古老者也可上推到中三叠世。在热带岩溶地貌发育上，贡献最大的时期，一是中、晚三叠世，二是第三纪。前者奠定了本区热带岩溶地貌轮廓雏形；后者基本上形成了现代热带岩溶地貌的总形态。岩溶洞穴的发育，最发育时期是中、晚三叠世、第三纪，其它时期主要是利用、改造前期洞穴，只在有利部位发育一些新生小洞穴，在新生大型洞穴方面无重要贡献。现垂向上的岩溶洞穴，是不同时代发育形成的一个混杂体，不存在传统认识上的成层性。     

对岩溶洞穴成层性观念的再思考

本文对岩溶地区洞穴成层性的传统观念提出了质疑，并进行了一定的再思考和讨论。笔者认为，岩溶地区垂向上发育的岩溶洞穴，不存在着以前传统的洞穴成层性观念。不同高程的岩溶洞穴，是不同时代发育形成的、相互交叉、相互叠置的混杂体。不能牵强地将垂向发育的洞穴和河流冲积阶地进行联系对比，也不能笼统地以洞穴化学堆积物、古脊椎动物、古人类化石的年代来代表洞穴发育的年代。用洞穴内机械堆积物的年代资料也要特别慎重。尽管鉴别、区分这些洞穴发育形成的年代比较困难，但仍是可以认识和区分的。     

贵州荔波岩溶洞穴发育特征

荔波位于云贵高原岩溶向广西岩溶丘陵和孤峰岩溶平原过渡的岩溶斜坡地带。区内岩溶洞穴极其发育,岩溶洞穴(在时空分布上受区域碳酸盐岩地层分布的控制,表现出对地层岩性的选择性和洞穴发育的成层性特点,岩溶洞穴的发育规模、方向明显受断裂、裂隙构造的控制,表现出极强的方向性。本文主要依据洞穴的形成条件、洞穴空间展布的控制特征以及洞穴沉积物的特征等,论述了区内岩溶洞穴的发育特征。      

试论桂林岩溶洞穴发育的古老性及形成时代探讨

中、晚三叠世是桂林热带岩溶、岩溶洞穴强烈发育的一个重要时期。早侏罗世，气候条件仍然有利，热带岩溶继承发育，但因碳酸盐岩被晚三叠世内陆湖盆堆积物覆盖，一定程度上减低了热带岩溶发育的强度。中侏罗世至白垩世，气候干旱炎热，降雨 ，“三水”活动不强烈，岩溶、岩溶洞穴不发育。晚白垩世，广泛发育内陆湖盆，岩溶作用有一定改善，但因仍处于干旱、炎热环境，湖水浅，堆积迅速，不利于大型洞穴的形成。第三纪是本区热带岩溶     

岩溶洞穴的分形弯曲度

本文对岩溶洞穴提出了分形弯曲度的概念,并且以洛塔地区岩溶洞穴为例,计算了各岩溶洞穴的分形弯曲度,对岩溶洞穴的形状研究,具有一定的意义。      

塔河油田奥陶系岩溶洞穴发育特征及其与油气的关系

溶蚀孔、洞是塔河油田奥陶系油气的主要储集场所。为深入了解奥陶系的油气分布,研究了该区奥陶系岩溶洞穴的发育特征,介绍岩溶洞穴在钻井录井、岩心、测井、地震等资料上的识别标志,并识别了本区14口井的岩溶洞穴;恢复了本区海西早期的岩溶古地貌。研究发现：岩溶斜坡靠近岩溶高地和岩溶谷地一侧是岩溶洞穴发育且保存最好的所在地,岩溶洞穴主要分布在“双峰灰岩”顶面下40~80 m、110~130 m、150~190 m、230~260 m的深度范围内,多数井在岩溶洞穴发育段表现出了极好的油气生产能力。     

圆梁山隧道毛坝向斜段岩溶洞穴的发育深度探讨

在剖析岩溶发育深度控制模式的基础上，分析了毛坝向斜岩溶发育的控制性基准面，认为毛家院子以前，向斜核部及东翼，岩溶洞穴发育深度在海拔900m以上；向斜西翼及毛家院子以北的核部及东翼，岩溶洞穴发育深度应在海拔850m以上。     

轮古西奥陶系潜山洞穴型岩溶储层发育特征与充填规律

洞穴型岩溶储层是塔里木盆地轮古油田缝洞型碳酸盐岩油藏的主要储集空间类型,多数高效井均钻遇大型洞穴型岩溶储层。依据轮古西奥陶系潜山大量单井资料分析,洞穴型岩溶储层可分为充填洞穴、半充填洞穴和未充填洞穴三种类型。结合古地貌精细刻画与岩溶垂向分带成果,认为古地貌位置由岩溶台地向岩溶缓坡和岩溶盆地逐渐降低,而洞穴发育和充填程度在逐渐增高。未充填与半充填洞穴主要发育在岩溶台地和岩溶缓坡的溶峰边坡、溶丘边坡及沟槽谷洼地边坡等地貌单元。表层岩溶带、径流溶蚀带洞穴型岩溶储层发育频率最高,其次为垂直渗滤带和潜流溶蚀带。未充填与半充填洞穴型岩溶储层主要发育在表层岩溶带。     

基于岩溶洞穴旅游活动中洞穴环境因子的研究

随着人们生活水平的不断提高,岩溶洞穴旅游活动日益频繁,使得对洞穴环境的综合研究以及洞穴旅游管理变得尤为重要。通过调研国内外岩溶洞穴旅游管理的现状,结合岩溶洞穴环境的研究成果,综合分析岩溶洞穴环境因子,如温度、相对湿度、洞穴CO2浓度等,对岩溶景观的影响,探讨溶洞环境的自净能力以及景观保护与修复措施等问题;针对目前岩溶洞穴旅游开发的有限空间与无序客流的矛盾,提出了合理调控洞穴旅游客流量,增强洞穴旅游景观资源保护意识,从地学、旅游、环境以及健康等角度评估和开发洞穴,使旅游活动对环境因子的影响限制在可控范围,实现洞穴旅游的可持续发展。      

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

Mountains,nations, parks,and conservation

Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km² and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).