富瑞奥砂岩的成岩作用与流体活动及矿物—水的相互作用

富瑞奥组砂岩中由埋藏成岩作用产生的胶结物分怀渗透率和流体活动有关。砂岩成岩作用与流体活动的相互关系表明了岩石改造主要是碎屑矿物，延寿矿物与孔隙中的地层水发生反应的结果。埋藏期间地层水优先流经高孔渗砂岩。     

博兴洼陷沙四上亚段滩坝砂岩次生孔隙形成机制

根据砂岩铸体薄片、扫描电镜、地层压力分析,研究了博兴洼陷沙四上亚段滩坝砂岩次生孔隙的形成机制.研究表明博兴洼陷地层中的上升流为滩坝砂岩次生孔隙的形成创造了条件,硅酸盐和碳酸盐矿物在CO2和有机酸作用下的溶蚀是次生孔隙形成的主要因素,黏土矿物的转化也为次生孔隙的发育做出了贡献.在构造高部位碳酸盐胶结程度较低或断层较发育的区域次生孔隙较发育,在构造高部位侧翼的厚层滩坝砂岩次生孔隙也较发育.依据次生孔隙的结构特征、胶结物的性质和产状、碎屑颗粒的性质将博兴洼陷滩坝砂岩划分为4种成岩相:其中不稳定碎屑溶蚀成岩相控制的区域次生孔隙最为发育,可成为较好的油气聚集区;碳酸盐胶结和压实-溶蚀成岩相控制的地区次生孔隙发育次之,但也可以成为油气聚集区;压实成岩相基本不具储集性能.     

影响塔里木盆地西部碎屑储集岩物性因素分析

在塔里木盆地西部形成、演化的宏观背景控制下，碎屑储集岩本身的骨架颗粒成分、物理化学性质以及填隙物成分和含量等成为影响研究区碎屑储集岩物性的主要内在因素。通过统计不同时代碎屑岩中刚性、塑性和半塑性骨架颗粒含量，表明志留、泥盆系岩屑砂岩中较高的半塑性、塑性颗粒含量和机械压实作用是导致其物性变差的最主要原因。砂岩填隙物中泥质基含量增加与颗粒间接触强度之间存在良好的正相关性。而碳酸盐含量与砂岩孔隙度间的相关分析表明：该区砂岩孔隙间的碳酸盐矿物主要起堵塞孔隙的作用。将成岩作用划分为建设性成岩作用和破坏性成岩作用两大类，有利于从宏观上分析成岩作用对储集的影响。     

广东省海岸表层沉积物矿物表面特征与沉积环境关系的初步研究

作者选择了s7个分布于不同海岸相带及近海河流环境表层碎屑沉积物中的错石、电 气石、长石、石英四种矿物，用扫描电境放大300至iooo。倍观察分析其表面结构特征。观察分析发现，不同环境下的矿物表面结构特征有一定区别.这些区别主要由不同环境因素造成。河流环境的矿物表面结构简单，由物理作用造成;海岸环境的不同相带，矿物表面结构特征比较复杂，但程度有所不同。其特征主要取决于物理作用和所迭加的化学溶蚀作用。热带、亚热带海水对矿物的化学溶蚀和改造十分重要。     

松辽盆地白垩系砂岩长石碎屑的钠长石化作用

松辽盆地白垩系砂岩以长石岩屑砂岩和岩屑长石砂岩为特征。砂岩中发育长石碎屑、岩屑等不稳定组分，而且随着埋藏深度加深（成岩作用加强）钾长石逐渐减少并最终在2700m以下消失。斜长石碎屑中钠长石组分逐渐增多，钙长石组分逐渐减少，最终形成纯钠端元的钠长石。在成岩过程中长石碎屑的钠长石化主要有3种方式：①由离子交代作用导致长石碎屑的钠长石化；②长石碎屑边缘钠长石次生生长；③与长石碎屑溶解伴生的新生钠长石作用。结合热动力学平衡原理分析，斜长石的钠长石化基本不受成岩温度和压力的制约，而钾长石的钠长石化需要较高的成岩温度和压力作用才能进行。因此，斜长石的钠长石化可见于成岩早期，而钾长石的钠长石化只发生于成岩晚期。     

广东省海岸表层沉积物矿物表面特征与沉积环境关系的初步研究

作者选择了67个分布于不同海岸相带及近海河流环境表层碎屑沉积物中的锆石、电气石、长石、石英四种矿物,用扫描电境放大300至10000倍观察分析其表面结构特征。观察分析发现,不同环境下的矿物表面结构特征有一定区别。这些区别主要由不同环境因素造成。河流环境的矿物表面结构简单,由物理作用造成;海岸环境的不同相带,矿物表面结构特征比较复杂,但程度有所不同。其特征主要取决于物理作用和所迭加的化学溶蚀作用。热带、亚热带海水对矿物的化学溶蚀和改造十分重要。     

砂岩成岩类型及控制成岩作用的主要因素

<正> 砂岩具有共同的碎屑矿物、沉积环境和埋藏史,也具有共同的成岩史。据对世界各地100处砂岩的成岩史研究,已识别出五种共同的、可复原的和能预测的成岩类型,每种类型都有特定的相似矿物组合(图1)。1 成岩类型石英为主其中常见有少量新生成的粘土(如高岭石和     

东濮凹陷桥口地区沙三碎屑岩成岩作用与储层特征

东濮凹陷桥口地区沙三段碎屑岩经历了复杂的成岩历史。砂岩的主要成岩事件有：机械压实、碳酸盐胶结、石英加大、黄铁矿生成、高岭石的形成和转化、绿泥石生成、伊利石沉淀、斜长石的钠长石化、石膏和重晶石的形成，以及沸石矿物的生成和次生孔隙的产生。混层蒙皂石－伊利石化随埋深增加而增强，相邻页岩的成岩演化是砂岩胶结物成分的最重要来源。砂岩的成岩作用主要受沉积相的控制，处于中成岩晚期阶段的沙三段砂岩可划分为四种岩相：（1）碳酸盐结成岩相；（2）石英加大自生成岩相；（3）粘土蚀度成岩相；（4）不稳定碎屑溶蚀成岩相。四种成岩相组成了四种不同的储层类型，储层性质的对比分析对识别致密气层中的油气产层具有重要意义。     

西藏南部侏罗纪—古近纪砂岩重矿物分析：探讨岩浆弧与大陆地块物源差异性

物源分析是古地理重建与盆地分析的关键,典型的物源区包括岩浆弧、大陆地块、再旋回造山带等。重矿物种类多样,蕴含丰富的母岩信息,是物源分析的重要对象。现代砂的研究表明,不同大地构造背景下形成的沉积物具有不同的重矿物组合。遗憾的是,由于古代沉积的重矿物组合在成岩过程中会被改造,现代砂的重矿物组合与物源区的耦合规律并不能直接应用于古代砂岩。科学界尚不清楚岩浆弧与大陆地块来源的古代砂岩的重矿物特征。西藏日喀则弧前盆地与特提斯喜马拉雅侏罗纪—古近纪砂岩物源明确,要么来自亚洲大陆的冈底斯弧,要么来自印度大陆地块,是探讨岩浆弧与大陆地块来源的古代砂岩重矿物特征的绝佳场所。16件砂岩重矿物定量分析结果表明,两个物源区来源的砂岩重矿物组合均被成岩作用严重改造,辉石、角闪石等不稳定矿物消失,绿帘石等自生矿物出现;冈底斯弧来源的砂岩以出现大量绿帘石或磷灰石为特征,ZTR指数小于40;印度大陆地块来源的砂岩以出现大量锆石、电气石和金红石为特征,ZTR指数大于75。这一结果指示岩浆弧与大陆地块来源的砂岩的重矿物组合具有明显差异性,可以用来探讨物源的大地构造背景。     

硅质碎屑砂岩中胶结物来源的新认识

分析了浅埋藏砂岩的成岩环境,并从岩石学、矿物学、同位素及质量平衡估算方面论证硅质碎屑砂岩中的胶结物主要来源于砂岩浅埋藏期间的地下水,进而分析浅埋藏带内地下水的流动机制及早期胶结作用对晚期成岩作用的影响。     

A Reconstruction and Discussion of the Effect of Diagenetic Environment on Hydrocarbon Generation Based on Diagenetic Mineral Assemblage in Mudstone

Inorganic minerals in mudstone are composed of clay minerals,carbonate and detrital minerals.Detrital minerals(such as quartz and feldspar)are mainly original deposit.However,clay minerals(kaolinite,illite,and chlorite)and carbonate(calcite and dolomite)are mostly diagenetic minerals.Furthermore,conversion of the four kinds of clay minerals are common.The formation of clay minerals and carbonate is controlled by temperature,pressure,p H,Eh and type of cations during diagenesis.Therefore mineral assemblage can indicate the characteristics and change of diagenetic environment.In addition to inorganic minerals,there are also organic matter of different sources and chemical properties in mudstone.Traditionally,it is considered that evolution of organic matter is controlled by thermal effect.Now studies show that inorganic and organic matter can interact with each other and form clay-organic complexes.This suggest that attention should be paid to the influence of diagenetic mineral assemblage and diagenetic environment on the evolution of organic matter* Samples of mudstone from 1500-4500m of the Palaeogene in the Dongying Depression,China,were collected to investigate the changes of mudstone diagenetic environment.XRD,thin section and SEM were used to detect diagenetic minerals and assemblage characteristics.Results showed that content of detrital minerals,which are floating in mud matrix or preserved as silt laminae,is basically unchanged from shallow to deep strata.Clay minerals which are gathered as argillaceous matrix or preserved as argillaceous laminae have growth and decline relation to carbonate which mainly appear as micropoikilitic ferriferous calcite and ferriferous dolomite.All these characteristics indicate that detrital minerals are exogenetic,whereas carbonate is diagenetic minerals.Based on the SEM analysis of the clay minerals,it was found that smectite present honeycomb and reticulate structure,while illite present filiform and schistose structure and there are growth and decline relationship between them.Nevertheless,hexagonal tabular and stratified kaolinite has the highest content from 2400m to3300m.Rosette and stratified chlorite shows increase trend when the burial depth is deeper than 3300m.These characteristics indicated that clay minerals are diagenetic minerals and there are conversions among the four types.Therefore form shallow to deep,three diagenetic mineral assemblage zones can be divided based on the characteristics of carbonate and clay minerals in mudstone.Namely,smectite+illite/smectite zone in the depth of 2000-2500m;kaolinite+illite/smectite zone in the depth of 2500-3300m and illite+chlorite+carbonate zone below 3300m.Previous studies showed that kaolinite is stable under acidic conditions,while other clay minerals and carbonate are stable under alkaline conditions.Hence according to mineral assemblages feature,it was inferred that diagenetic environment of mudstonehasundergonethechangeof alkaline-acid-alkaline.For the organic matter with different chemical properties in mudstone,the hydrocarbon generation will be different in the acidic and alkaline diagenetic environment even if the conditions of temperature and pressure are the same.Therefore,for hydrocarbon generation we should not only focus on thermal effect,but also pay more attention to the differences of diagenetic environment which have great significance for the understanding of hydrocarbon generation,hydrocarbon expulsion and reservoir formation in mudstone.     

西藏北部西雅尔岗地区白垩-第三系红层的成岩作用及成岩环境

西雅尔岗地区位于羌塘高原腹地，地理范围为东经88°00′至89°00′，北纬32°40′至33°40′.大地构造位置从属于羌塘地块的玛依岗日一阿木冈基底隆断带.在晚白坚一第三纪时期，受青藏高原整沐抬升的影响，沉积了一套巨厚的红色陆屑建造，其基本特征为沉积厚度大、粗粒沉积所占比例高、沉积类型复杂、横向及纵向上相变快、岩石的颜色多为红色及紫色.沉积相类型主要为冲积扇、扇三角洲及湖泊.化石类型卖要为植物〔柏型枝)，孢粉和鸟足印化石.反映了在干操气候条件下，快速堆积的沉积特征. 根据对该区岩石学的研究，发现岩石的矿物组合和结构类型皆因成岩作用的影响而发生了很大的变化.矿物组合的变化是由于沉积后附加的陆源机械渗人粘土，在地表条件下不稳定矿物及岩屑的溶解作用以及在成岩过程中自生矿物的形成作用所造成的.导致结构类型改变的原因是(1)机械渗人的碎屑粘土及自生的粘土矿物形成孔隙间的粘土质“成岩杂基”.而这些孔隙在最初沉积时则没有杂基存在;(2)松散沉积物在成岩过程中，结构颖粒的溶解作用;(3)由于压实及压溶作用而形成粉砂级及其它细小的颗粒;(4)交代作用及重结晶作用.这些成岩过程明显地反映了整个区域岩石的演化历史. 显微镜、扫描电镜的观察以及红外光谱的侧定结果表明该区红层的形成是由于在成岩过程中赤铁矿的沉淀而造成的.在扫描电镜下可清楚地识别出赤铁矿的自生晶形.由此可以断定赤铁矿在其形成过程中显然是起了染色剂的作用.它的形成主要受孔隙水的氧化还原条件所控制，似乎于气候的关系不大，尽管它是产于干旱条件的沉积物中. 基于对该区岩石的成岩作用及成岩历史演化序列的研究，建立了该区沉积后的成岩环境模式，亦即(l)早期的表生成岩浅埋藏环境，该环境明显受到沉积环境、沉积作用控制以及气候因素的影响;(2)晚期的成岩深埋藏环境，该环境则主要受地温梯度、压力、温度和孔隙水的地球化学条件的控制.     

铝硅酸盐矿物成岩演化对形成过渡带气的影响

生油成气的过程不只是简单的有机物之间的转化，而是无机和有机两个系统综合运动的产物，它们之间相互联系相互制约。成岩作用伊始，两系统独立演化，均受成岩环境的制约。一旦环境适合于有机物裂化分解，两系统就共同发挥作用，通过质子的转移而相互作用。由于生物热催化过渡带气埋藏浅、热演化程度不高等特点，铝硅酸盐矿物成岩作用主要表现为:砂质岩以机械压实作用、胶结作用、溶解作用、矿化交代、自生矿物充填作用为主，泥质岩最显著的变化就是矿物的成岩演化，即蒙脱石→伊／蒙混层→伊利石，及蒙脱石→绿／蒙→绿泥石的成岩演化，其实质是有机与无机相互作用，即赋存在粘土中有机质的有机酸使砂质岩发生溶解，和碎屑岩溶解孔隙水中的Ａｌ３＋替代蒙脱石晶层间的Ｓｉ４＋，形成质子酸，对有机质形成过渡带气起着催化作用。     

孔隙衬里绿泥石的成因及对储层性能的影响

孔隙衬里绿泥石发育的砂岩大多属于优质储层,前人将其归功于绿泥石对孔隙的保护作用。按照孔隙衬里绿泥石形成的铁质来源,可划分为同沉积黏土膜转化型、富铁镁物质溶蚀再结晶型和转化与直接结晶混合型3种类型。通过国内外富孔隙衬里绿泥石砂岩实例的对比研究表明,孔隙衬里绿泥石可以通过抑制自生石英生长、提高抗压实能力、指示早期碱性溶蚀发育程度和堵塞孔喉等4种方式影响储层性能,且不同成因的孔隙衬里绿泥石对储层性能影响方式不同,同一成因绿泥石在不同成岩阶段的影响方式也不同。中成岩A期以前,转化型孔隙衬里绿泥石通过占据孔喉和提高抗压能力影响储层,而溶蚀结晶型孔隙衬里绿泥石主要指示火山物质发生碱性溶蚀的程度;只有砂岩成岩阶段达到中成岩B期以后,孔隙衬里绿泥石对石英生长的抑制作用才得到充分体现。     

Fluvial architecture and diagenesis of the Mt Eclipse Sandstone,northern Ngalia Basin,Australia

The Upper Devonian to Carboniferous Mt Eclipse Sandstone is a basin-wide host to uranium mineralisation in the Ngalia Basin, NT. The fluvial depositional architecture and diagenesis of the Mt Eclipse Sandstone at the Bigrlyi uranium deposit on the northern margin of the basin are deduced from hyperspectral mineral results captured from 200 drill holes, combined with core and outcrop observations across a ~10 km strike length. The succession hosting the uranium mineralisation is interpreted to be deposited in the lower parts of a mature alluvial fan system with low slope angle and dominated by immature, kaolinised, medium-grained subarkosic sandstones and patchy calcite cement. This study reveals the fluvial channel sequence is estimated to be 3 km wide, 100–200 m thick and sourced from the north. This multidisciplinary study also uncovers the complex interaction and codependencies between fluvial/groundwater activity, evaporation, oxidation, fluctuating pH and detrital mineralogy controlling early diagenetic processes in the alluvial fan sediments. Carbon isotope data identify calcite cements as groundwater calcrete, while strontium isotope data suggest limited prolonged water–rock interaction prior and during calcite cementation. The petrographic data reveal the importance of early calcite cement occluding all pore space and preserving detrital minerals from later diagenetic processes. The hyperspectral results highlight the intermittent distribution of the calcite cement and the commonly repetitive mineralogical zonation throughout the 200 drill holes, including the inverse spatial correlation between kaolinite ± goethite ± gypsum vs white mica ± hematite dominated zones. X-ray diffraction and the hyperspectral data reveal the scarcity of early diagenetic clay minerals such as montmorillonite. This paper is the first to report on a systematic mineralogical and sedimentological study for the Mt Eclipse Sandstone. By focusing on the diagenesis and fluvial architecture of this stratigraphic unit, a framework to support exploration for sediment-hosted uranium deposits is established.     

华北下古生界碳酸盐岩中一些结构的形成

碳酸盐岩的结构是在特定的沉积环境或成岩环境里形成,因此,能反映岩石的成因与发展史。某些典型的结构不仅是有指“相”意义,而且能作为找矿标志。本文对华北下古生界碳酸盐岩中的正延性玉髓、石膏型方解石假晶和具有多圈层氧化铁薄膜结构的高能鲕粒等三类结构的形成与环境意义和找矿意义依次进行了论述。     

Origins of authigenic minerals and their impacts on reservoir quality of tight sandstones: Upper Triassic Chang-7 Member,Yanchang Formation,Ordos Basin,China

Reservoir quality is critical for sweet-spot evaluation in tight sandstone plays, but few studies have focused on the origin of authigenic minerals in tight sandstones and their impact on reservoir quality. This study integrates petrographic analysis, carbon and oxygen isotopic data and mercury injection capillary pressure data of the Upper Triassic Chang-7 tight sand reservoir samples in the Ordos Basin, China to understand the origin of authigenic minerals and the impact of authigenic minerals on reservoir quality. Carbonate minerals, including calcite, ferroan calcite and dolomite, and kaolinite, are the major authigenic minerals in the Chang-7 sandstone. They were derived from the chemical diagenetic alteration of detrital feldspar and biotite, with the involvement of ions that are believed to be primarily from the connate water in interstitial pore space of the interbedded mudstones. Meteoric water and organic fluids from hydrocarbon generation may also have been involved in the alteration processes of the minerals in the Chang-7 tight sandstone. The origin of kaolinite indicates that the porosity was increased by dissolution of detrital grains, offsetting the porosity loss from burial compaction. Authigenic minerals appear to have a weak correlation with pore structure, suggesting that the pore structure of the Chang-7 tight sandstone is not only controlled by major authigenic minerals but also affected by other geological factors.     

东海表层沉积物碎屑矿物组合分布特征及其物源环境指示

为进一步明确东海陆架区的沉积物物源及水动力环境,对研究区表层沉积物的碎屑矿物进行了鉴定分析。研究区共鉴定出49种重矿物、8种轻矿物。根据碎屑矿物的组合分布结合矿物形态特征,将东海陆架区划分为三个矿物区,内陆架矿物区、外陆架矿物区及虎皮礁矿物区。内陆架矿物区,动力分选是影响碎屑矿物分布的主要因素,物质来源相对单一,碎屑矿物主要来源于现代长江物质,闽浙沿岸近岸河流的输入,人类活动也对该区的矿物组成产生一定的影响;外陆架矿物区,重矿物分布的主控因素是长期的分选作用,主要是长江物质经后期改造形成,现代长江物质可从内陆架中北部扩散至124.5°E左右,此外外陆架东南部地形的变化也对碎屑矿物的分布起到一定控制作用;虎皮礁矿物区,有来自黄河、长江、火山物质的多重影响,且水动力环境相对复杂。     

Relationship of diagenetic chlorite rims to depositional facies in Lower Cretaceous reservoir sandstones of the Scotian Basin

The relationship between diagenetic chlorite rims and depositional facies in deltaic strata of the Lower Cretaceous Missisauga Formation was investigated using a combination of electron microprobe, bulk geochemistry and X‐ray diffraction data. The succession studied comprises several stacked parasequences. The delta progradational facies association includes: (i) fluvial or distributary channel sandstones (some with tidal influence); (ii) thick‐bedded delta‐front graded beds of sandstone interpreted as resulting from fluvial hyperpycnal flow during floods and storms; and (iii) more distal muddier delta‐front and prodeltaic facies. The transgressive facies association includes lag conglomerate, siderite‐cemented muddy sandstone and mudstone, and bioclastic sandy limestone. Chlorite rims are absent in the fluvial facies and best developed in thick sandstones lacking mudstone baffles. Good quality chlorite rims are well correlated with Ti in bulk geochemistry. Ti is a proxy for Fe availability, principally from the breakdown of abundant detrital ilmenite (FeTiO₃). Under conditions of sea floor diagenesis, the abrupt decrease in sedimentation rate at transgressive surfaces caused progressive shallowing of the sulphate‐depletion level and of the overlying Eh‐controlled diagenetic zones, resulting in conditions suitable for diagenetic formation of berthierine to migrate upwards through the packet of reservoir sandstones. This early diagenetic berthierine suppressed silica cementation and later recrystallized to chlorite. Thick euhedral outer chlorite rims were precipitated from formation water in sandstone lacking muddy baffles on this chlorite substrate and inhibited late carbonate cementation. This study thus shows that the preservation of porosity by chlorite rims is a two‐stage process. Rapidly deposited delta‐front turbidite facies create early diagenetic conditions that eventually lead to the formation of chlorite rims, but the best quality chlorite rims are restricted to sandstones with high permeability during burial diagenesis.     

Relationships among sedimentology, stratigraphy, and diagenesis in the Proterozoic Thelon Basin, Nunavut, Canada: implications for paleoaquifers and sedimentary-hosted mineral deposits

The Thelon Basin, Nunavut, Canada, is host to unconformity-type uranium mineralisation and has the potential to host other economic deposits. The Thelon Formation (ca. 1750 Ma) is composed of thick (meters to tens of meters), poorly sorted, trough cross-bedded conglomerate and coarse-grained lithic arenite beds, and to a lesser extent, well-sorted, medium- to coarse-grained quartz arenite beds. Relatively rare, 1–12 cm thick, clay-rich siltstones to fine-grained sandstone layers punctuate the coarser lithofacies. Based on regional analysis of drill cores and outcrops, multiple unconformity-bounded sequences are defined in this fluvial-dominated sedimentary succession. Stratigraphic correlations are based on detailed lithofacies analysis, distinct changes in fining-upward cycle thickness, and intraformational surfaces (unconformities, transgressive surfaces, and paleosols).Diagenetic and paragenetic relationships vary systematically with sedimentology and stratigraphy of the Thelon and provide a framework for understanding the evolution of fluid-flow systems in the context of basin hydrostratigraphy. Stratigraphic units with well-sorted textures, which lacked clay and unstable framework grains, originally were aquifers (depositional aquifers) during early basin evolution. However, pervasive, early quartz cementation radically reduced the porosity and permeability of these units, occluding pore throats and transforming them into aquitards. Proximal fluvial and alluvial fan lithofacies that contained detrital, mechanically infiltrated, and diagenetic clay minerals and/or unstable detrital grains originally had low permeabilities and only experienced minor quartz cementation. In the deep burial setting (2–7 km), these units retained sufficient permeability to allow diagenetic fluid flow (diagenetic aquifers) as suggested by feldspar dissolution, quartz dissolution, and formation and recrystallization of illite and other diagenetic reactions. Tracing potential diagenetic aquifer and aquitard units across the study area allowed development of a hydrostratigraphic model. In this model, diagenetic aquifers onlap onto, and focused basinal fluids into basement rocks to the east in the Thelon Basin (in the vicinity of the Kiggavik uranium deposit).