软黏土侧压力系数K0阶段性特征研究

沿海软黏土的侧压力系数K0具有阶段性特征:当试验荷载P＜Pc'(土样的残余结构强度)时,K0值较小,试样的结构性好,呈现出似刚性的材料特征,侧压力系数小;当P＞Pc'时,K0值增大,土的微结构破坏,呈现出弹塑性体的材料特征,侧压力系数增大.而在工程实践中,受成孔、取土等诸多因素干扰,欠固结-正常固结的软黏性土的微结构的结构性易被破坏,使K0指标的阶段性特征不明显.     

隧道施工时地表沉降监测控制标准探讨

地表沉降是判断浅埋隧道地层稳定的一个重要指标。在分析地表沉降监测重要性和隧道埋深的关系基础上,阐述了地表沉降控制标准确定的原则;针对隧道无邻近结构物段,从地层围岩稳定、经验公式和相关规范的角度探讨地表沉降控制标准,并以武广客运专线浏阳河隧道为例子进行验证。结果表明,城市隧道变形控制标准要比山岭隧道更严格,浅埋隧道要比深埋隧道控制标准更严格;围岩越坚硬、跨度越小、边墙高度越小,则允许的位移越小,反之则越大;允许的变形控制标准主要影响因素是围岩自身条件,其次是隧道的跨度     

基于Hyperion数据的江西德兴矿区粘土矿物信息提取及其找矿意义

江西德兴矿区为我国重要的矿产资源基地, 目前面临资源枯竭的困境, 寻找替代的新矿产迫在眉睫.根据研究区野外土壤实测样品分析, 利用连续统去除的方法提取土壤实测光谱的特征吸收位置, 从而建立粘土矿物含量为因变量的预测方程.检验得知, 高岭石相关系数R为0.811, 拟合系数R2达到0.658, F值为5.275, Sig值为0.047 7, 其小于0.05;绿泥石相关系数R为0.893, 拟合系数R2达到0.797, F值为1.602, Sig值为0.016 6, 其小于0.05;伊利石相关系数R为0.783, 拟合系数R2达到0.619, F值为5.57, 对应的Sig值是0.075 4, 其大于0.05, 说明自变量与因变量之间具有高度相关性, 反演精度较好.从反演结果可知, 研究区的高岭石整体含量较高, 整体上粘土矿物高岭石、绿泥石和伊利石在1号坝、2号坝、4号坝和铜矿区含量较低.由于粘土矿物不断地经过地球化学变化、累积, 产生黄铁矿、黄铜矿及赤铁矿, 所以挑选粘土矿物富集并且地质构造活跃的区域为铁矿石及铜矿石预测区.结合研究区地质解译图与粘土矿物反演结果, 在采矿场与IV号尾矿坝向NE方向沿线上圈定两个遥感找矿有利区.      

新疆尼勒克县喀英迪地区铅锌矿地质特征及成因

喀英迪铅锌矿主要产于早石炭世阿克沙克组及其与晚奥陶世呼独克达坂组的接触带上。通过普查工作共圈定15个铅锌矿体。其中主要矿体4个,Ⅰ-4矿体处于晚奥陶世呼独克达坂组灰岩与早石炭世阿克沙克组的不整合接触面上及其两侧,工程控制总长度为523m,最大斜深100m。倾向70°～100°,倾角一般20°～50°,连续性较好。该矿体铅单工程厚0.86～5.64m,平均2.86m,厚度变化系数为70.57%;锌单工程厚0.80～5.64m,平均1.81m,厚度变化系数为93.97%,属于变化较稳定型矿体。铅单工程品位0.62%～16.47%,平均4.53%,品位变化系数114.34%;锌单工程品位0.53%～12.37%,平均3.78%,品位变化系数57.47%。属于有用组分分布较均匀型矿体。通过对矿床地质特征的研究,认为该矿床属沉积岩容矿的、层控的、构造控制非岩浆型低温热液矿床。     

Kinetics of oil group-type generation and expulsion: An integrated application to Dongying Depression,Bohai Bay Basin,China

Pyrolysis of two kerogens isolated from the ${\text{E}}_{2\text{-}3}{\text{s}}_3^3$ and ${\text{E}}_{2\text{-}3}{\text{s}}_4^1$ source rocks in the Niuzhuang sag, Dongying Depression, Bohai Bay Basin, China, was performed in a confined system. The products were extracted with solvent and separated using micro-column chromatography into group-type fractions (saturates, aromatics, resins and asphaltenes) with the kerogen residue in each case undergoing swelling with a variety of solvents. The kinetics for generation and retention of crude oil and its group-type fractions from the kerogens were studied and the kinetic parameters applied to modeling generation and retention of crude oil and its fractions from the ${\text{E}}_{2\text{-}3}{\text{s}}_3^3$ and ${\text{E}}_{2\text{-}3}{\text{s}}_4^1$ source rocks on the basis of burial and thermal history of the Niuzhuang sag. The results show that the “normal oil” was generated at about 4.26 Ma and 24.85 Ma ago, but expelled at about 3.96 Ma and 17.46 Ma ago, respectively, from ${\text{E}}_{2\text{-}3}{\text{s}}_3^3$ and ${\text{E}}_{2\text{-}3}{\text{s}}_4^1$ source rocks. The current proportions of the expelled saturates, aromatics and NSOs are about 60%, 15% and 25%, respectively.     

粒度指标指示的坝上御道口地区8 000 a B.P.环境变化

承德坝上御道口地区是对气候变化非常敏感的生态环境脆弱带,认识本区气候变化对未来增温背景下采取应对措施有重要意义。粒度是气候环境变化敏感代用指标,粒度分析结果可推测沉积物形成条件和环境。文章对御道口地区YDK剖面沉积物进行粒度测试。通过对粒度数据进行组分分离和敏感粒级的提取,利用AMS14C测年结果建立年代框架,探讨了坝上御道口地区8000 a B.P.以来的古气候古环境变化。结果显示气候变化经历了三个阶段:（1）8 000~6 100 a B.P.,粒度指标指示此时段动力较大,粉尘距源区较近,风沙活动较强,携带较多粗颗粒物质造成粒径较粗,估计此时段气候干燥,区域植被较差。（2）6 100~1 700 a B.P.,此时段粒度指标指示动力较小,粉尘距源区较远,粗颗粒物质减少,估计此时段气候湿润,区域植被较好,风沙活动减弱。（3）1 700 a B.P.至今,动力较大,粉尘距源区较近,估计此时段气候变干,区域植被较差,风沙活动强。     

分形结构土体强度研究

分形结构是土体中普遍存在的一种现象,通过对分形结构连接部位所占据的影响域（Voronoi域）的分析,将颗粒连接承载能力换算为影响域上的应力强度,由此获得了一些有益的结果。土体颗粒系统结构分维值的大小对土体强度有着明显的影响;基本结构单元的颗粒数越多,形成的环的长度越长,占据的空间就越大,从力学上讲就越不稳定,因此,其强度越低;土体中分形结构的级数实际上决定了土体中最大孔隙的尺寸,分形结构的级数越多,其相应的最大孔隙越大,等效应力强度会越低;发现偶应力强度与基本结构单元的面积（二维）成反比,即基本结构体越大,偶应力强度就越小,由此可推论出：在其他条件相同的情况下,颗粒越大,偶应力强度就会越低。     

斜发沸石矿物材料处理生活污水实验研究

研究选用的斜发沸石矿物材料属单斜面晶系,颜色为白色、淡黄色,硬度为4左右,介电常数为7.0～7.5,比重为2.16.扫描电镜图表明,该斜发沸石呈宽板条状,细板条状、不规则粒状等,粒径在0.02～0.05mm,长宽比为4∶1.化学成分分析表明,w(SiO2)为69.12％,w(Al2O3)为11.27％,w(CaO)为7...     

基于动力学和材料软化特性的边坡渐进破坏特征研究

边坡的失稳是一个从量变到质变的动态渐进破坏过程,此问题也是边坡领域研究的重点与难点之一。在考虑岩土材料软化特性和动力学求解的基础上,建立了边坡渐进破坏仿真的理论框架;利用ABAQUS软件的动力显式求解模块实现了边坡的渐进破坏仿真;根据塑性应变揭露了剪切带的扩展过程,由软化本构确定了滑面材料的分区演化规律,根据等效塑性应变确定了边坡的滑面,通过滑面位置将边坡分为滑体、滑带、滑床,并分别研究了边坡各分区内部特征点运动学变量的发展过程,从而揭示了边坡的渐进破坏过程;基于材料参数沿滑面的时空分布,利用矢量和法得到了边坡不同演化阶段的安全系数。对比该方法与Bishop法确定的滑面位置与安全系数,发现两种方法峰值和残余强度对应的安全系数比较接近,该方法搜索所得滑面位于Bishop法自动搜索的滑面之间,验证了此方法的合理性及可靠性。最后分析了材料软化特征对边坡稳定性的影响,在保持其他参数不变的条件下,增大残余黏聚力,边坡的滑面位置加深,安全系数的初始值减小,安全系数的快速减小阶段有所推迟,并且快速减小阶段经历的时间有所延长,稳定后的安全系数有所增大。保持其他参数不变,增大残余黏聚力对应的等效塑性应变阈值,边坡的滑面位置加深,安全系数的初始值减小,安全系数的快速减小阶段有所推迟,但快速减小阶段经历的时间基本不变,达到稳定的时间有所推迟,同时稳定后的安全系数略微有所增大。     

The measurement of D/H ratio in alkenones and their isotopic heterogeneity

Previous paleoenvironmental studies reported the δD values of a mixture of coeluting alkenones. Here, we present a semi-preparative normal-phase high-performance liquid chromatography–mass spectrometry (NP-HPLC–MS) method for purifying long chain (C₃₇ and C₃₈) unsaturated methyl and ethyl ketones (alkenones) on the basis of chain length and degree of unsaturation.The method was applied to purify alkenones in suspended particles and surface sediments from a site in Chesapeake Bay, eastern USA. The hydrogen isotopic composition of di- and triunsaturated C₃₇ and C₃₈ alkenones differed significantly on the basis of chain length and the degree of unsaturation, demonstrating the importance of gas chromatography–isotope ratio-mass spectrometry (GC–irMS) analysis of individual alkenones for accurate paleoenvironmental reconstruction. Constant fractionation factors between alkenones with different chain length but the same degree of unsaturation (${\alpha }_{{\text{C}}_{37:2}''–''{\text{C}}_{38:2}}\text{and}{\alpha }_{{\text{C}}_{37:3}''–''{\text{C}}_{38:3}}=1.01$) and those with the same chain length but different degree of unsaturation (${\alpha }_{{\text{C}}_{37:2}''–''{\text{C}}_{37:3}}\text{and}{\alpha }_{{\text{C}}_{38:2}''–''{\text{C}}_{38:3}}=0.97$) in all samples suggest that the values may represent hydrogen isotope fractionation associated with elongation and desaturation during alkenone biosynthesis.     

三轴应力条件下上海灰色粘土的CT细观试验研究

采用CT实时实验对上海灰色粘土在三轴应力条件下的特性进行系统的实验研究。研究结果表明，上海灰色粘土的变形有两种形式，一是以均匀性变形为主，二是以局部变形为主。在三轴应力条件下后者细观变形基本上分为三个阶段：微裂纹萌生轻微发展阶段、局部变形快速发展阶段和软化破坏阶段。粘土具有初始各向异性，变形也是各向异性的。     

Isotopic tracing of perchlorate sources in groundwater from Pomona,California

The groundwater of Pomona, California, is contaminated with perchlorate (${\text{ClO}}_4^{-}$). This water is treated to reduce the ${\text{ClO}}_4^{-}$ concentration to less than 6 μg L⁻¹ for compliance with California Department of Public Health drinking water regulations. A study of the isotopic composition of oxygen and chlorine in ${\text{ClO}}_4^{-}$ has been conducted to determine the source of the contamination. Isotopic compositions were measured for ${\text{ClO}}_4^{-}$ samples extracted from 14 wells, yielding ranges of δ¹⁸O values from −10.8‰ to −8.0‰, Δ¹⁷O values from +4.6‰ to +7.5‰, and δ³⁷Cl values from −12.8‰ to −8.9‰. Evaluation of mixing proportions using published isotopic data for three ${\text{ClO}}_4^{-}$ end-members (synthetic, Atacama, and indigenous natural ${\text{ClO}}_4^{-}$) indicates that contamination is dominantly (85–89%) Atacama ${\text{ClO}}_4^{-}$ derived from past use of imported Chilean nitrate fertilizer in citrus cultivation. This interpretation is consistent with (1) aerial photography archives showing extensive citrus fields surrounding Pomona in the early- to mid-20th century, (2) mass-balance estimates for ${\text{ClO}}_4^{-}$, and (3) numerical hydrologic models yielding travel-times for ${\text{ClO}}_4^{-}$ from fields to wells that are in the range of 15 to >100 years. The hydrologic models predict that ${\text{ClO}}_4^{-}$ contamination of Pomona groundwater will persist for decades into the future.     

Bulk modulus of Fe-rich olivines corrected for non-hydrostaticity

In situ X-ray diffraction was used to measure the isothermal bulk modulus at room conditions (K_T0) of synthetic olivines with different iron contents. The chemical formulae of the olivine samples were ${({\mathrm{Fe}}_x,{\mathrm{Mg}}_{1?x})}_2\mathrm{Si}{\mathrm{O}}_4$ with x = 0.45; 0.64; 0.82; 1, with 1% standard deviation (referenced as Fa45, Fa64, Fa82 and Fa100, respectively). All experiments were performed in the multi-anvil apparatus installed at NSLS beamline X17B2, to pressures up to about 7 GPa. Unit-cell volumes under hydrostatic conditions and differential stresses present in the samples were calculated using the method developed by Singh et al. (1998), and pressures measured using NaCl as a standard were then corrected for these stresses. Using a second-order Birch–Murnaghan equation of state, we obtained the isothermal bulk modulus of each composition: $K_{T0}^{\mathrm{Fa45}}=131.4\pm 2.6$ GPa, $K_{T0}^{\mathrm{Fa64}}=132.1\pm 3.1$ GPa, $K_{T0}^{\mathrm{Fa82}}=136.3\pm 1.7$ GPa and $K_{T0}^{\mathrm{Fa100}}=134.8\pm 1.4$ GPa. These values combined with data available in the literature show that the K_T0 of Fe-rich olivines increases very slowly with the Fe content, but possibly not in a simple linear trend.