REE Geochemistry and Mineralization Characteristics of the Zudong and Guanxi Granites,Jiangxi Province

Abstract The Zudong and Guanxi granites are original rocks of the ion adsorption-type HREE and LREE deposits in weathering crust of granites. The ∑REE ¹ ∑REE=REE+Y.
value and LREE ² LREE=∑(La-Eu) and HREE=∑(Gd-Lu)+Y.
/ HREE ratio of the Zudong granite are 264 ppm and 0.81-0.24 respectively, and the average Y/∑REE ratio is 35.8-54.5%. This is mainly due to magmatic crystallization and evolution and deuteric metasomatism (albitization, muscovitization and fluorite-doveritization). These alterations resulted in endogenic mineralizations of yttrium-group REE fluorine carbonates, silicates and arsenates. The Guanxi granite is characterized by LREE enrichment (the average LREE/HREE ratio is 2.43).     

Zonal REE + Y profiles in garnet and their genetic implications: A case study of metapelites from the northern Ladoga region

The objective of this study is to provide insights into the REE and Y behavior during garnet porphyroblast formation in staurolite-bearing schists as a constituent of Late Paleoproterozoic metapelites of the Ladoga Complex. The MnNCKFMASH P–T pseudosection for a single sample and Grt–Bt thermometry indicate that the garnet core grew at 520°C and under 7.0–7.2 kbar in the Grt–Bt–Pl–Chl–Ms–Zo field, whereas the garnet rim was equilibrated at 590–600°C and under 3.5–4.0 kbar. The measured zoning profiles are strongly depleted in REE + Y in the garnet core containing high Mn and Ca concentrations. The intermediate zone of garnet is enriched in La, Ce, Pr, and Nd (inner LREE + Nd annulus), as well as in Dy, Er, Yb, Lu, and Y (outer HREE + Y + Dy annulus). According to pseudosection analysis, these peaks were probably produced owing to breakdown of epidote-group minerals (allanite, REE-rich epidote) at T < 535°C and P > 6.5 kbar. Towards the rim, the HREE + Y contents gradually decrease, whereas MREE (Sm, Eu, Gd) display an inverse trend. The rim also exhibits a negative Eu anomaly. The former tendency reflects an increase in temperature during garnet crystallization and partitioning of elements between garnet and monazite. It is thought that the latter is linked to oppositely directed change in garnet-monazite partition coefficients for HREE and MREE with increasing temperature.     

Distribution of REE,LILE, and HFSE between biotite,feldspar, and the melt in the granulite facies migmatite,nimnyr block,Aldan shield

The behavior of trace elements under conditions of partial melting of granitoid rocks has been studied. The element’s partition coefficients between minerals and the melt D_i^min/melt depends, in the first place, on the composition of the primary melt. In biotite the HREE D_i are a little below 1, while those of LREE, especially D_i for Ce, are 1–3 orders of magnitude less. This leads to an efficient differentiation of REEs in anatexic melts especially when biotite is the main mineral phase of restite. On the contrary, there are feldspars, the D_i of which cannot provide such a magnitude of differentiation. Unlike garnets and pyroxenes, whose stability in restite permits enrichment of anatexic melts produced in migmatization zones with Nb, Ti, and Cr, the presence of biotite in restite causes depletion of melts with those elements as well as with Rb. Feldspars, under conditions of their fractional crystallization or during differentiation of an anatexic melt, deplete the latter with Sr, Ba, and Rb, but enrich it with Nb, Ti, Cr, Y, Zr, and V.     

Provenance analyses of the heavy-mineral beach sands of the Annaba coast,northeast Algeria,and their consequences for the evaluation of fossil placer deposit

The paper presents the first study of heavy-mineral sand beaches from the Mediterranean coast of Annaba/Algeria. The studied beaches run along the basement outcrops of the Edough massif, which are mainly composed by micaschists, tourmaline-rich quartzo-feldspathic veins, gneisses, skarns and marbles. Sand samples were taken from three localities (Ain Achir, Plage-Militaire and El Nasr). The heavy-mineral fraction comprises between 74 and 91 vol%. The garnets of the beaches are almandine rich and tourmalines vary with respect to their location from schorl to dravite. Tourmaline at Ain Achir and the Plage-Militaire is schorlits, while at El Nasr beach dravite is ubiquitous. The World Shale Average normalised REE of the sands and the basement outcrops reveal: (i) Ain Achir beach: REE pattern of sand and the coastal rocks from the studied beaches reflects a multiple sources; (ii) Plage-Militaire: the sand and the coastal outcrops show similar LREE and a strong enrichment in HREE, suggesting the presence HREE-rich phases found as inclusions in staurolite; (iii) El Nasr: two types of sand patterns are found: one with flat REE pattern similar to the proximal rocks and other one enriched in HREE suggesting a mixed source.     

Geochemistry and origin of Dehoo manganese deposit,south Zahedan,southeastern Iran

Dehoo manganese deposit is located 52 km to the south of Zahedan in Sistan and Baluchestan Province, southeastern Iran. This deposit that lies in the central part of the Iranian Flysch Zone is lenticular in shape and lies above the micritic limestone-radiolarite cherts of the upper Cretaceous ophiolite unit. It is hosted within the reddish to brown radiolarite cherts and in places interlinks with them, so that the radiolarite chert packages play a key role for Mn mineralization in the region. Investigated ore-paragenetic successions and the geochemical characteristics of the Dehoo deposit were studied by means of major oxide, trace, and rare earth element (REE) contents that provide information as to the mineral origin. Strong positive correlations were found between major oxides and trace elements (Al₂O₃-TiO₂, r = 0.95; TiO₂-MgO, r = 0.94; Fe₂O₃-Al₂O₃, r = 0.90; MgO-Al₂O₃, r = 0.84; MgO-Fe₂O₃, r = 0.88; Fe₂O₃-TiO₂, r = 0.91; Fe₂O₃-K₂O, r = 0.74; Al₂O₃-K₂O, r = 0.69; Al₂O₃-V, r = 0.72; TiO₂-V, r = 0.73, and MgO-V, r = 0.69) that testify to the contribution of mafic terrigenous detrital material to the deposit. Chondrite-normalized REE patterns of all ore samples are characterized by negative Ce (0.06–0.15, average 0.10) and slightly positive Eu (0.29–0.45, average 0.36) anomalies. Based on ratios of Mn/Fe (average 56.23), Co/Ni (average 0.33), Co/Zn (average 0.38), U/Th (average 3.40), La/Ce (average 1.45), La_n/Nd_n (average 2.16), Dy_n/Yb_n (average 0.33), and light REE/heavy REE (average 8.40; LREE > HREE), as well as Ba (average 920 ppm) and total REE contents (average 6.96 ppm) negative Ce and positive Eu anomalies, Dehoo could be considered a predominantly submarine hydrothermal Mn deposit complemented by terrigenous detrital mafic material.     

Altered rocks of the Onguren carbonatite complex in the Western Tansbaikal Region: Geochemistry and composition of accessory minerals

The paper discusses the mineralogy and geochemistry of altered rocks associated with calcite and dolomite–ankerite carbonatites of the Onguren dyke–vein complex in the Western Transbaikal Region. The alteration processes in the Early Proterozoic metamorphic complex and synmetamorphic granite hosting carbonatite are areal microclinization and riebeckitization; carbonates, phlogopite, apatite, and aegirine occur in the near-contact zones of the dolomite–ankerite carbonatite veins; and silicification is displayed within separated zones adjacent to the veins. In aluminosilicate rocks, microclinization was accompanied by an increasing content of K, Fe³⁺, Ti, Nb (up to 460 ppm), Th, Cu, and REE; Na, Ti, Fe³⁺, Mg, Nb (up to 1500 ppm), Zr (up to 2800 ppm), Ta, Th, Hf, and REE accumulated in the inner zone of the riebeckitization column. High contents of Ln _Ce (up to 11200 ppm), U (23 ppm), Sr (up to 7000 ppm), Li (up to 400 ppm), Zn (up to 600 ppm), and Th (up to 700 ppm) are typical of apatite–phlogopite–riebeckite altered rock; silicified rock contains up to (ppm): 2000 Th, 20 U, 13000 Ln _Ce, and 5000 Ва. Ilmenite and later rutile are the major Nb carriers in alkali altered rocks. These minerals contain up to 2 and 7 wt % Nb₂O₅, respectively. In addition, ferrocolumbite and aeschynite-(Ce) occur in microcline and riebeckite altered rocks. Fluorapatite containing up to 2.7 wt % (Ln _Ce)₂O₃, monazite-(Ce), cerite-(Ce), ferriallanite-(Ce), and aeschynite-(Ce) are the REE carriers in riebeckite altered rock. Bastnäsite-(Ce), rhabdophane-group minerals, and xenotime-(Y) are typical of silicified rock. Thorite, monazite-(Ce), and rhabdophane-group minerals are the Th carriers.     

Provenance,tectonic setting and source-area weathering of the lower Cambrian sediments of the Parahio valley in the Spiti basin,India

The geochemical study of siliciclastic rocks from the Lower Cambrian of Parahio Valley has been studied to describe the provenance, chemical weathering and tectonic setting. The K₂O/Al₂O₃ ratio and positive correlation of Co (r=0.85), Ni (r=0.86), Zn (r=0.82), Rb (r=0.98) with K₂O reflects that the presence of clay minerals control the abundances of these elements and suggests a warm and humid climate for this region. The chondrite normalized REE pattern of the samples is equivalent to upper continental crust, which reflects enriched LREE and flat HREE with negative Eu anomaly. The tectonic setting discriminant diagram log[K₂O/Na₂O] vs. SiO₂; [SiO₂/Al₂O₃] vs. log[K₂O/Na₂O]; [SiO₂/20] – [K₂O+Na₂O] – [TiO₂+Fe₂O₃+MgO] indicates transitional tectonic setting from an active continental margin to a passive margin. The discriminant function plot indicates quartzose sedimentary provenance, and to some extent, the felsic igneous provenance, derived from weathered granite, gneissic terrain and/or from pre-existing sedimentary terrain. The CIA value indicates low to moderate degree of chemical weathering and the average ICV values suggests immature sediments deposited in tectonically active settings. The A–CN–K diagram indicates that these sediments were generated from source rocks of the upper continental crust.     

Specifics of the Neoarchean Plume–Lithospheric Processes in the Kola–Norwegian Province of the Fennoscandian Shield: II. Petrology and Geodynamic Nature of Komatiite–Tholeiite Association

Numerical modeling of the generation and evolution of parental melts of the komatiite–tholeiite association of the Uraguba structure was carried out using previously obtained geochemical and isotope data. It was established that komatiite, komatiite and tholeiite basalts depleted in LREE and having ε_Nd(Т = 2.79) = +2.9…+3.2 were generated by equilibrium partial melting (F > 15%) of a depleted source (garnet-bearing Ol_0.63 + Opx_0.22 + Cpx_0.06 + Grt_0.09 mantle peridotite) at 4–8 GPa, while the genesis of primary melts of LREE-enriched komatiites (La_N/Sm_N ~ 1.2–1.6) with ε_Nd(Т = 2.79) = +2.5…+2.2 was related to the equilibrium partial melting (F > 20%) of an “enriched mantle peridotite” (EM–Ol_0.60 + Opx_0.20 + Cpx_0.08 + Grt_0.12) at pressure of 2.5–4 GPa. Coexistence in space and time of two types of melting products of mantle peridotites formed at different depths is explained by melting of different parts of adiabatically ascending mantle plume.     

Fractionation of Rare-Earth Elements in the Processes of Hydrothermal Ore Formation

The data on the distribution of elements in the Pb–Zn cross-section of the Gatsirovskaya vein (the Upper Zgid deposit, North Ossetia, Russia) have shown that the spectra of rare-earth elements (REEs) changed significantly in the ore samples during the vein formation. The sharp growth of the La_N/Yb_N, La_N/Nd_N, Gd_N/Ho_N, and Gd_N/Yb_N ratios is confined to the vein intervals, where the maximum amount of ore components is deposited. The comparison of the REE spectra of ores to the characteristics of the spectra of the rocks surrounding the vein and the host rocks suggests that the vein material deposited from the solutions in which the REE ratio changed with time. REE fractionation occurred due to the mobilization of components by hydrothermal solutions during their interaction with the Paleozoic host granites.     

Elastic behavior of vanadinite,Pb<Subscript>10</Subscript>(VO<Subscript>4</Subscript>)<Subscript>6</Subscript>Cl<Subscript>2</Subscript>, a microporous non-zeolitic mineral

The high-pressure behavior of a vanadinite (Pb₁₀(VO₄)₆Cl₂, a = b = 10.3254(5), c = 7.3450(4) Å, space group P6₃/m), a natural microporous mineral, has been investigated using in-situ HP-synchrotron X-ray powder diffraction up to 7.67 GPa with a diamond anvil cell under hydrostatic conditions. No phase transition has been observed within the pressure range investigated. Axial and volume isothermal Equations of State (EoS) of vanadinite were determined. Fitting the P–V data with a third-order Birch-Murnaghan (BM) EoS, using the data weighted by the uncertainties in P and V, we obtained: V ₀ = 681(1) Å³, K ₀ = 41(5) GPa, and K′ = 12.5(2.5). The evolution of the lattice constants with P shows a strong anisotropic compression pattern. The axial bulk moduli were calculated with a third-order “linearized” BM-EoS. The EoS parameters are: a ₀ = 10.3302(2) Å, K ₀(a) = 35(2) GPa and K′(a) = 10(1) for the a-axis; c ₀ = 7.3520(3) Å, K ₀(c) = 98(4) GPa, and K′(c) = 9(2) for the c-axis (K ₀(a):K ₀(c) = 1:2.80). Axial and volume Eulerian-finite strain (fe) at different normalized stress (Fe) were calculated. The weighted linear regression through the data points yields the following intercept values: Fe _a (0) = 35(2) GPa for the a-axis, Fe _c (0) = 98(4) GPa for the c-axis and Fe _V (0) = 45(2) GPa for the unit-cell volume. The slope of the regression lines gives rise to K′ values of 10(1) for the a-axis, 9(2) for the c-axis and 11(1) for the unit cell-volume. A comparison between the HP-elastic response of vanadinite and the iso-structural apatite is carried out. The possible reasons of the elastic anisotropy are discussed.     

Thermodynamic Properties of Natural Cuspidine

The paper reports pioneering data on the calorimetrically determined enthalpy of formation from elements of cuspidine, Ca fluordiorthosilicate Ca₄Si₂O₇F₂, from the Tyrny-Auz Mo–W deposit in Kabardino- Balkaria, Russia. The data were obtained by high-temperature melt solution calorimetry. The determined value is ΔfH_el° (298.15 K) =–5190 ± 13 kJ/mol. The paper reports estimated S°(298.15 K) and Δ_fG_el° (298.15 K) of cuspidine.     

Influence of the <Emphasis Type="Italic">X</Emphasis>-site composition on tourmaline’s crystal structure: investigation of synthetic K-dravite,dravite, oxy-uvite,and magnesio-foitite using SREF and Raman spectroscopy

The crystal structures of synthetic K-dravite [^XK^YMg ₃ ^Z Al ₆ ^T Si₆O₁₈(BO₃) ₃ ^V (OH) ₃ ^W (OH)], dravite [^XNa^YMg ₃ ^Z Al ₆ ^T Si₆O₁₈(BO₃) ₃ ^V (OH) ₃ ^W (OH)], oxy-uvite [^XCa^YMg ₃ ^Z Al ₆ ^T Si₆O₁₈(BO₃) ₃ ^V (OH) ₃ ^W O], and magnesio-foitite [^X?^Y(Mg₂Al)^ZAl ₆ ^T Si₆O₁₈(BO₃) ₃ ^V (OH) ₃ ^W (OH)] are investigated by polarized Raman spectroscopy, single-crystal structure refinement (SREF), and powder X-ray diffraction. The use of compositionally simple tourmalines characterized by electron microprobe analysis facilitates the determination of site occupancy in the SREF and band assignment in the Raman spectra. The synthesized K-dravite, oxy-uvite, and magnesio-foitite have significant Mg–Al disorder between their octahedral sites indicated by their respective average 〈Y–O〉 and 〈Z–O〉 bond lengths. The Y- and Z-site compositions of oxy-uvite (^YMg_1.52Al_1.48(10) and ^ZAl_4.90Mg_1.10(15)) and magnesio-foitite (^YAl_1.62Mg_1.38(18) and ^ZAl_4.92Mg_1.08(24)) are refined from the electron densities at each site. The Mg–Al ratio of the Y and Z sites is also determined from the relative integrated peak intensities of the Raman bands in the O–H stretching vibrational range (3250–3850 cm^?1), producing values in good agreement with the SREF data. The unit cell volume of tourmaline increases from magnesio-foitite (1558.4(3) ų) to dravite (1569.5(4)–1571.7(3) ų) to oxy-uvite (1572.4(2) ų) to K-dravite (1588.1(2) ų), mainly due to lengthening of the crystallographic c-axis. The increase in the size of the X-site coordination polyhedron from dravite (Na) to K-dravite (K) is accommodated locally in the crystal structure, resulting in the shortening of the neighboring O1–H1 bond. In oxy-uvite, Ca²⁺ is locally associated with a deprotonated W (O1) site, whereas vacant X sites are neighbored by protonated W (O1) sites. Increasing the size of the X-site-occupying ion does not detectably affect bonding between the other sites; however, the higher charge of Ca and the deprotonated W (O1) site in oxy-uvite are correlated to changes in the lattice vibration Raman spectrum (100–1200 cm^?1), particularly for bands assigned to the T ₆O₁₈ ring. The Raman spectrum of magnesio-foitite shows significant deviations from those of K-dravite, dravite, and oxy-uvite in both the lattice and O–H stretching vibrational ranges (100–1200 and 3250–3850 cm^?1, respectively). The vacant X site is correlated with long- and short-range changes in the crystal structure, i.e., deformation of the T ₆O₁₈ ring and lengthening of the O1–H1 and O3–H3 bonds. However, X-site vacancies in K-dravite, dravite, and oxy-uvite result only in the lengthening of the neighboring O1–H1 bond and do not result in identifiable changes in the lattice-bonding environment.     

Contrasting origin of two A-type rhyolite series from the Early Permian Nomgon bimodal volcanic association (Southern Mongolia)

A-type rhyolites of contrasting compositions and eruption characters were revealed among two volcanic series of the Early Permian bimodal association in the Nomgon graben. Rhyolites of the lower volcanic series formed extrusions, lava domes, and tuff horizons. They had low FeO_t, Zr, Hf, Nb, Ta, Y, and REE concentrations and also a moderately depleted Nd isotope composition (ε_Nd(Т) = 6.7–7.1). Their formation was related to anatexis of the juvenile continental crust, triggered by the thermal effect of mafic magmas. Rhyolites of the upper volcanic series formed extensive lava flows and dikes. Their composition was characterized by high FeO_t, Zr, Hf, Nb, Ta, Y, and REE concentrations, and also depleted Nd isotope characteristics (ε_Nd(Т) = 7.7–9.0). These rhyolite melts formed under long-term crystallizational differentiation of basaltoids in the intracrustal magmatic chambers, with limited participation of crustal contamination. The source of magmas for the upper volcanic series was the sublithospheric mantle.     

Comparison of the magnetic properties of leading and following spots and the overlying ultraviolet emission

SDO/HMI and SDO/AIA data for the 24th solar-activity cycle are analyzed using a quicker and more accurate method for resolving π ambiguities in the transverse component of the photospheric magnetic field, yielding new results and confirming some earlier results on the magnetic properties of leading and following magnetically connected spots and single spots. The minimum inclination of the field lines to the positive normal to the solar surface α _min within umbrae is smaller in leading than in following spots in 78% of the spot pairs considered; the same trend is found for the mean angle 〈α〉 in 83% of the spot pairs. Positive correlations between the α _min values and the 〈α〉 values in leading and following spots are also found. On average, in umbrae, the mean values of 〈B〉, the umbra area S, and the angles α _min and 〈α〉 decrease with growth in the maximum magnetic field B _max in both leading and following spots. The presence of a positive correlation between B _max and S is confirmed, and a positive correlation between 〈B〉 and S in leading and following spots has been found. Themagnetic properties of the umbrae of magnetically connected pairs of spots are compared with the contrast of the He II 304 emission above the umbrae, C ₃₀₄. Spots satisfying certain conditions display a positive correlation between C _304?L and 〈α _L 〉 for the leading (L) spots, and between C _304?L /C _304?F and l _L /l _F , where l _L (l _F ) are the lengths of the field lines connecting leading (L) or following (F) spots from the corresponding spot umbrae to the apex of the field line.     

Atmospheric chemical abundances of the components of the quadruple system ADS 11061. 40 Draconis

As part of our study of the components of the hierarchic quadruple system ADS 11061, we acquired spectroscopic observations of the binary 40 Dra. Echelle spectra showing the separation of the components’ lines were obtained in the spectral range 3700–9200 Å. Effective temperatures and surface gravities were derived for the components from BV photometry and the hydrogen-line profiles. The components of the 40 Dra system have parameters close to T _eff ^a = 6420 K, log g _a = 4.17, T _eff ^b = 6300 K, and log g _b = 4.20. We find the microturbulence velocity in the component atmospheres to be V _t = 2.6 km/s. The abundances of iron, carbon, nitrogen, and oxygen in the atmospheres of both components are estimated to be log N(Fe)^a = 7.50, log N(Fe)^b = 7.46, log N(C)^a = 8.39, log N(C)^b = 8.45, log N(N)^a = 8.12, log(N)^b = 8.15, log N(O)^a = 8.77, log N(O)^b = 8.74.     

Refinement of the mangan-neptunite crystal structure

The crystal structure of mangan-neptunite, a manganese analogue of neptunite, has been refined in two space groups (Cc and C2/c). The mineral is monoclinic, with the correct space group Cc; the unit-cell dimensions are: a = 16.4821(6), b = 12.5195(4), c = 10.0292(3) Å, β = 115.474(1)°, and V = 1868.31 ų. The crystal structure has been refined to R ₁ = 0.0307 (wR ₂ = 0.0901) on the basis of 4892 observed reflections with |F _hkl | ≥ 4σ|F _hkl |. The most plausible acentric model is caused by the Ti- and (Fe, Mn, Mg)-ordering in the structure. Ti-octahedrons are strongly distorted and consist of short bond Ti-O (1.7 Å), one long bond (2.2 Å), and four equal bonds (2.0 Å). Fe-octahedrons are regularly shaped, with all Fe-O bonds being approximately identical.     

Evolution of lacustrine basin in relation to variation in palaeowater depth and delta development: Neogene Bohai Bay Basin,Huanghekou area,northern China

This paper presents revision of the Neogene chronostratigraphic framework of the Huanghekou area in the Bohai Bay Basin, northern China, on the basis of integration of palaeomagnetic data and Neogene seismic stratigraphy. The modern Lake Dongting was selected for analyses of bottom sediments, water depth and elemental composition. Four elements, namely Al, V, Ni and Ga with R ² value larger than 0.7, were chosen to establish a quantitative relationship (F _P) between elemental composition and water depth of bottom sediments. A water depth of ~2.4 m was identified as an accumulation depth of Candoniella albicans, which is used to derive environmental variable (Φ) of formula F _P. Candoniella albicans is also found within the Neogene well W10 in the Huanghekou area. Considering 2.4 m as D value in formula F _p and measured element values at different depths of W10, Φ values were obtained at different depths. The quantitative palaeowater depths of each drilling well were estimated for the first time in this area by considering elemental composition of chip samples of four drilling wells in the Huanghekou area, which are directly iterated to the F _F. Palaeowater depth reconstruction of the Neogene in the Huanghekou area indicates an initial deepening trend and a later shallowing trend during the evolution, with average and deepest bathymetry at ~2.3 and ~4.8 m, respectively. Frequent fluctuations of palaeowater depth control the sand dispersal pattern in a shallow delta during the lower part of the Lower Member of Minghuazhen Formation.     

Seismic Pullout Capacity of Inclined Anchor Plates in Sand

By using the lower bound finite elements limit analysis, the pullout capacity of an inclined strip anchor plate embedded in a cohesionless soil medium has been computed with an inclusion of pseudo-static horizontal earthquake body forces. The variation of the pullout capacity factor (F _γ ) with changes in horizontal earthquake acceleration co-efficient (α _h ) has been computed by varying the inclination angle (β) of the anchor plate between 0° and 90°. The results clearly reveal that the pullout capacity factor (F _γ ) decreases significantly with an increase in the value of α _h . The reduction in the pullout resistance due to seismic forces (1) becomes much more extensive for a vertical anchor plate as compared to the horizontal anchor, (2) decreases generally with increases in the soil friction angle (?) and (3) increases with an increase in friction angle between soil and anchor plate (δ). The developments of the failure zone around the anchor plate were also examined by varying α _h and β. The results obtained from the analysis compare well with the solutions reported in literature.     

Crystal structure and refined formula of garyansellite Mg<Subscript>2</Subscript>Fe<Superscript>3+</Superscript>(PO<Subscript>4</Subscript>)<Subscript>2</Subscript>(OH) · 2H<Subscript>2</Subscript>O

Single-crystal study of the structure (R = 0.0268) was performed for garyansellite from Rapid Creek, Yukon, Canada. The mineral is orthorhombic, Pbna, a = 9.44738(18), b = 9.85976(19), c = 8.14154(18) Å, V = 758.38(3) ų, Z = 4. An idealized formula of garyansellite is Mg₂Fe³⁺(PO₄)₂(OH) · 2H₂O. Structurally the mineral is close to other members of the phosphoferrite–reddingite group. The structure contains layers of chains of M(2)O₄(OH)(H₂O) octahedra which share edges to form dimers and connected by common edges with isolated from each other M(1)O₄(H₂O)₂ octahedra. The neighboring chains are connected to the layer through the common vertices of M(2) octahedra and octaahedral layers are linked through PO₄ tetrahedra.     

Possible reasons for the frequency splitting of the harmonics of type II solar radio bursts

AIA/SDO data in the 193 Å channel preceding a coronal mass ejection observed at the solar limb on June 13, 2010 are used to simultaneously identify and examine two different shock fronts. The angular size of each front relative to the CME center was about 20°, and their propagation directions differed by ≈25° (≈4° in position angle). The faster front, called the blast shock, advanced the other front, called the piston shock, by R ≈ (0.02-0.03)R⊙ (R⊙ is the solar radius) and had a maximum initial speed of V_B ≈ 850 km/s (with V_P ≈ 700 km/s for the piston shock). The appearance and motion of these shocks were accompanied by a Type II radio burst observed at the fundamental frequency F and second harmonic H. Each frequency was split into two close frequencies f₁ and f₂ separated by Δf = f₂ - f₁ ? F, H. It is concluded that the observed frequency splitting Δf of the F and H components of the Type II burst could result from the simultaneous propagation of piston and blast shocks moving with different speeds in somewhat different directions displaying different coronal-plasma densities.