The origin of ocean island basalt end-member compositions: trace element and isotopic constraints

Ocean island basalt (OIB) suites display a wide diversity of major element, trace element, and isotopic compositions. The incompatible trace element and isotopic ratios of OIB reflect considerable heterogeneity in the mantle source regions. In addition to the distinctive Sr, Nd and Pb isotopic signatures of the HIMU, EMI and EMII OIB end-members, differences in incompatible trace element ratios among these end-members are of great help in identifying the nature and origin of their sources. Examination of trace element and isotopic constraints for the three OIB end-members suggests a relatively simple model for their origin. The dominant component in all OIB is ancient recycled basaltic oceanic crust which has been processed through a subduction zone, and which carries the trace element and isotopic signature of a dehydration residue (enrichment in HFSE relative to LILE and LREE, low Rb/Sr, but high U/Pb and Th/Pb ratios leading to the development of radiogenic Pb isotope compositions). HIMU OIB are derived from such a source, with little contamination from other components. Both the EMI and EMII OIB end-members are also dominantly derived from this source, but they contain significant proportions (up to 5–10%) of sedimentary components derived from the continental crust. In the case of EMI OIB, ancient pelagic sediment with high LILE/HFSE, LREE/HFSE, Ba/Th and Ba/La ratios, and low U/Pb ratios, is the contaminant. EMII OIB are also contaminated by a sedimentary component, in the form of ancient terrigenous sediment with high LILE/HFSE and LREE/HFSE ratios, but lacking relative Ba enrichment, and with higher U/Pb and Rb/Sr ratios. A model whereby the source for all OIB is ancient (1–2 Ga old) subducted oceanic crust ± entrained sediment (pelagic and/or terrigenous) is therefore consistent with the trace element and isotopic data. Although subducted oceanic lithosphere will accumulate and be dominantly concentrated within the mesosphere boundary layer, forming the source for hot-spots, such material may also become convectively dispersed within the depleted upper mantle as blobs or streaks, giving rise to small-scale chemical heterogeneities in the upper mantle.     

Development of continental lithospheric mantle as reflected in the chemistry of the Mesozoic Appalachian Tholeiites, U.S.A.

Geochemical analyses of dikes, sills, and volcanic rocks of the Mesozoic Appalachian Tholeiite (MAT) Province of the easternmost United States provide evidence that continental tholeiites are derived from continental lithospheric mantle sources that are genetically and geochronologically related to the overlying continental crust. Nineteen olivine tholeiites and sixteen quartz tholeiites from the length of this province, associated in space and time with the last opening of the Atlantic, display significant isotopic heterogeneity: initial ε_Nd = +3.8 to −5.7; initial ⁸⁷Sr/⁸⁶Sr= 0.7044−0.7072; ²⁰⁶Pb/²⁰⁴Pb= 17.49−19.14; ²⁰⁷Pb/²⁰⁴Pb= 15.55−15.65; ²⁰⁸Pb/²⁰⁴Pb= 37.24−39.11. In PbPb space, the MAT define a linear array displaced above the field for MORB and thus resemble oceanic basalts with DUPAL Pb isotopic traits. A regression of this array yields a secondary PbPb isochron age of ≈ 1000 Ma (μ₁ = 8.26), similar to Sm/Nd isochrons from the southern half of the province and to the radiometric age of the Grenville crust underlying easternmost North America. The MAT exhibit significant trace element ratio heterogeneity (e.g., Sm/Nd= 0.226−0.327) and have trace element traits similar to convergent margin magmas [e.g., depletions of Nb and Ti relative to the rare earth elements on normalized trace element incompatibility diagrams, Ba/Nb ratios (19–75) that are significantly greater than those of MORB, and low TiO₂ (0.39–0.69%)].Geochemical and geological considerations very strongly suggest that the MAT were not significantly contaminated during ascent through the continental crust. Further, isotope and trace element variations are not consistent with the involvement of contemporaneous MORB or OIB components. Rather, the materials that control the MAT incompatible element chemistry were derived from subcontinental lithospheric mantle. Thus: (1) the MAT/arc magma trace element similarities; (2) the PbPb and Sm/Nd isochron ages; and (3) the need for a method of introducing an ancient (> 2−3 Ga) Pb component into subcontinental mantle that cannot be much older than 1 Ga leads to a model whereby the MAT were generated by the melting of sediment-contaminated arc mantle that was incorporated into the continental lithosphere during arc activity preceding the Grenville Orogeny (≈ 1000 Ma).     

Geochemistry of early Paleozoic alkali dyke swarms in south Qinling and its geological significance

The abundant research achievements about Qinling orogeny going through central China were obtained in the last decade[1—3]. However, there is a debate about the early Paleozoic tectonic evolution of south Qinling. Thus, it is undoubted that the systemati…     

Origin of the deep fluids in the paleosubduction zones in western Tianshan: Evidence from Pb- and Sr-isotope compositions of high-pressure veins and host rocks

Fluids in the deep subduction zones play an impor-tant role in the process of crust-mantle interaction. This has been proved by a large number of studies on the geochemistry of island arc volcanic rocks[1―9]. Study on high-pressure metamorphic rocks within orogen shows that the dehydration and devolatilization of subducted oceanic crust and sediments can release amounts of water during progressive metamorph- ism[10―13]. The origin of the fluids in the subduction zones provides important info…     

Siderophile and chalcophile element abundances in oceanic basalts, Pb isotope evolution and growth of the Earth''s core

We have investigated the hypothesis that mantle Pb isotope ratios reflect continued extraction of Pb into the Earth's core over geologic time. The Pb, Sr and Nd isotopic compositions, and the abundance of siderophile and chalcophile elements (W, Mo and Pb) and incompatible lithophile elements have been determined for a suite of ocean island and mid-ocean ridge basalt samples. Over the observed range in Pb isotopic compositions for oceanic rocks, we found no systematic variation of siderophile or chalcophile element abundances relative to abundances of similarly incompatible, but lithophile, elements. The high sensitivity of theMo/Pr ratio to segregation of Fe-metal or S-rich metallic liquid (sulfide) and the observed constantMo/Pr ratio rules out the core formation model as an explanation for the Pb paradox. The mantle and crust have the sameMo/Pr and the sameW/Ba ratios, suggesting that these ratios reflect the ratio in the Earth's primitive mantle.

Our data also indicate that thePb/Ce ratio of the mantle is essentially constant, but the presentPb/Ce ratio in the mantle ( 0.036) is too low to represent the primitive value ( 0.1) derived from Pb isotope systematics. HigherPb/Ce ratios in the crust balance the lowPb/Ce of the mantle, and crust and mantle appear to sum to a reasonable terrestrialPb/Ce ratio. The constancy of thePb/Ce ratio in a wide variety of oceanic magma types from diverse mantle reservoirs indicates this ratio is not fractionated by magmatic processes. This suggests crust formation must have involved non-magmatic as well as magmatic processes. Hydrothermal activity at mid-ocean ridges may result in significant non-magmatic transport of Pb from mantle to crust and of U from crust to mantle, producing a higherU/Pb ratio in the mantle than in the total crust. We suggest that the lower crust is highly depleted in U and has unradiogenic Pb isotope ratios which balance the radiogenic Pb of upper crust and upper mantle. The differences between thePb/Ce ratio in sediments, this ratio in primitive mantle, and the observed ratio in oceanic basalts preclude both sediment recycling and mixing of primitive and depleted reservoirs from being important sources of chemical heterogeneities in the mantle.     

Post-collisional magmatism in Wuyu basin,central Tibet: evidence for recycling of subducted Tethyan oceanic crust

The trachyte and basaltic trachyte and intruded granite-porphyry of Gazacun formation of Wuyu Group in central Tibet are Neogene shoshonitic rocks. They are rich in LREE, with a weak to significant Eu negative anomalies. The enriched Rb, Th, U, K, negative HFS elements Nb, Ta, Ti and P, and Sr, Nd and Pb isotope geochemistry suggest that the volcanic rocks of Wuyu Group originated from the partial melting of lower crust of the Gangdese belt, with the involvement of the Tethyan oceanic crust. It implies that the north-subducted Tethys ocean crust have arrived to the lower crust of Gangdese belt and recycled in the Neogene magmatism.

     

Chemical heterogeneity of the Archaean mantle,composition of the earth and mantle evolution

New rare earth element (REE) data for Archaean basalts and spinifex-textured peridotites (STP) show a range of La/Sm ratios (chondrite-normalized) from 0.36 to 3.5, with the bulk of the data in the range 0.7–1.3. This supports the hypothesis, based on Sr isotope initial ratios, that the Archaean mantle was chemically heterogeneous. We suggest that the bulk mantle source for Archaean basaltic magmas was close to an undepleted earth material. An average chemical composition of the Archaean mantle is estimated using chemical regularities observed in Archaean STP and high-magnesian basalts. TiO₂ and MgO data show an inverse correlation which intersects the MgO axis at about 50% MgO (Fo₉₂). TiO₂ abundance in the mantle source is measured on this plot by assigning anMgO= 38% for the mantle. Concentrations of other elements are also estimated and these data are then used to obtain a composition for the bulk earth. We suggest an earth model with about 1.35 times ordinary chondrite abundances of refractory lithophile elements and about 0.2 times carbonaceous type 1 chondrite abundances of moderately volatile elements (such as Na, Rb, K, Mn). P shows severe depletion in the model earth relative to carbonaceous chondrites, a feature either due to volatilization or core formation (preferred). Our data support the hypothesis of Ringwood that the source material for the earth is a carbonaceous chondrite-like material.The generation of mid-ocean ridge basalts (MORB) is examined in the light of the model earth composition and Al₂O₃/TiO₂, CaO/TiO₂ ratios. It is suggested that for primitive basalts, these values can be used to predict the residual phases in their source. Comparison of chemical characteristics of inferred sources for 2.7-b.y. Archaean basalts and modern “normal” MORB indicates that the MORB source is severely depleted in highly incompatible elements such as Cs, Ba, Rb, U, Th, K, La and Nb, but has comparable abundances of less incompatible elements such as Ti, Zr, Y, Yb. The cause of the depletion in the MORB source is examined in terms of crust formation and extraction of silica-undersaturated melts. The latter seems to be a more likely explanation, since the degree of enrichment of highly incompatible elements in the crust only accounts for up to 40% of their abundances in the bulk earth and cannot match the depletion pattern in normal MORB. A large volume of material, less depleted than the source for normal MORB must therefore exist in the mantle and can serve as the source for the ocean island basalts and “normal” MORB.Three different mantle evolution models are examined and each suggests that the mantle is stratified with respect to abundances of incompatible trace elements. We suggest that no satisfactory model is available to fully explain the spectrum of geochemical and geophysical data. In particular the Pb and Sr isotope data on oceanic basalts, the depletion patterns of MORB and the balance between lithophile abundances in the crust and mantle, are important geochemical constraints to mantle models. Further modelling of the mantle evolution will be dependent on firmer information on the role of subduction, mantle convection pattern, and basalt production through geologic time together with a better understanding of the nature of Archaean crustal genesis.     

Nb/Ta,Zr/Hf and REE in the depleted mantle: implications for the differentiation history of the crust–mantle system

High-precision Nb, Ta, Zr, Hf, Sm, Nd and Lu concentration data of depleted mantle rocks from the Balmuccia peridotite complex (Ivrea Zone, Italian Alps) were determined by isotope dilution using multiple collector inductively coupled plasma mass spectrometry (MC-ICPMS) and thermal ionisation mass spectrometry (TIMS). The Zr/Hf ratios of all investigated samples from the Balmuccia peridotite complex are significantly lower than the chondritic value of 34.2, and the most depleted samples have Zr/Hf ratios as low as 10. Correlated Zr/Hf ratios and Zr abundances of the lherzolites preserve the trend of a mantle residue that has been depleted by fractional melting. This trend confirms experimental studies that predict Hf to behave more compatibly than Zr during mantle melting. Experimentally determined partition coefficients imply that the major Zr and Hf depletion most likely occurred in the spinel stability field, with (D_Zr/D_Hf)^cpx≈0.5, and not in the garnet stability field, where (D_Zr/D_Hf)^grt is probably close to one. However, minor amounts of melting must have also occurred in a garnet facies mantle, as indicated by low Sm/Lu ratios in the Balmuccia peridotites. The Nb/Ta ratios of most lherzolites are subchondritic and vary only from 7 to 10, with the exception of three samples that have higher Nb/Ta ratios (18–24). The overall low Nb/Ta ratios of most depleted mantle rocks confirm a higher compatibility of Ta in the mantle. The uniform Nb/Ta ratios in most samples imply that even in ‘depleted’ mantle domains the budget of the highly incompatible Nb and Ta is controlled by enrichment processes. Such a model is supported by the positive correlation of Zr/Nb with the Zr concentration. However, the overall enrichment was weak and did barely affect the moderately incompatible elements Zr and Hf. The new constraints from the partitioning behaviour of Zr–Hf and Nb–Ta provide important insights into processes that formed the Earth’s major silicate reservoirs. The correlation of Zr/Hf and Sm/Nd in depleted MORB can be assigned to previous melting events in the MORB source. However, such trends were unlikely produced during continental crust formation processes, where Sm/Nd and Zr/Hf are decoupled. The different fractionation behaviour of Zr/Hf and Sm/Nd in the depleted mantle (correlated) and the crust (decoupled) indicates that crustal growth by a simple partial melting process in the mantle has little effect on the mass budget of LREE and HFSE between crust and mantle. A more complex source composition, similar to that of modern subduction rocks, is needed to fractionate the LREE, but not Zr/Hf and the HREE.     

Enrichment of the continental lithosphere by OIB melts: Isotopic evidence from the volcanic province of northern Tanzania

Alkali basalts and nephelinites from the southern end of the East African Rift (EAR) in northern Tanzania have incompatible trace element compositions that are similar to those of ocean island basalts (OIB). They define a considerable range of Sr, Nd and Pb isotopic compositions (⁸⁷Sr/⁸⁶Sr= 0.7035−0.7058,ε_Nd = −5to+3, and²⁰⁶Pb/²⁰⁴Pb= 17.5−21.3), each of which partially overlaps the range found in OIB. However, they occupy a unique position in combined Nd, Sr and Pb isotopic compositional space. Nearly all of the lavas have radiogenic Pb, similar to HIMU with high time-integrated²³⁸U/²⁰⁴Pb coupled with unradiogenic Nd (+2 to −5) and radiogenic Sr (>0.704), similar to EMI. This combination has not been observed in OIB and provides evidence that these magmas predominantly acquired their Sr, Nd and Pb in the subcontinental lithospheric mantle rather than in the convecting asthenosphere. These data contrast with compositions for lavas from farther north in the EAR. The Pb isotopic compositions of basalts along the EAR are increasingly radiogenic from north to south, indicating a fundamental change to sources with higher time-integratedU/Pb, closer to the older cratons in the south. An ancient underplated OIB melt component, isolated for about 2 Ga as enriched lithospheric mantle and then remelted, could generate both the trace element and isotopic data measured in the Tanzanian samples. Whereas the radiogenic Pb in Tanzanian lavas requires a source with high time-integratedU/Pb, most continental basalts that are thought to have interacted with the continental lithospheric mantle have unradiogenic Pb, requiring a source with a history of lowU/Pb. Such lowU/Pb is readily accomplished with the addition of subduction-derived components, since the lower averageU/Pb of arc basalts (0.15) relative to OIB (0.36) probably reflects addition of Pb from subducted oceanic crust. If the subcontinental lithosphere is normally characterized by low time-integratedU/Pb it would appear that subduction magmatism is more important than OIB additions in supplying the Pb inventory of the lithospheric mantle. However,U/Pb ratios of xenoliths derived from the continental lithospheric mantle suggest that both processes may be important. This apparent discrepancy could be because xenoliths are not volumetrically representative of the subcontinental lithospheric mantle, or, more likely, that continental lithospheric mantle components in basalts are normally only identified as such when the isotopic ratios are dissimilar from MORB or OIB. Lithospheric enrichment from subaccreted OIB components appears to be more significant than generally recognized.     

Post-collisional magmatism in Wuyu basin,central Tibet: evidence for recycling of subducted Tethyan oceanic crust

The trachyte and basaltic trachyte and intruded granite-porphyry of Gazacun formation of Wuyu Group in central Tibet are Neogene shoshonitic rocks. They are rich in LREE, with a weak to significant Eu negative anomalies. The enriched Rb, Th, U, K, negative HFS elements Nb, Ta, Ti and P, and Sr, Nd and Pb isotope geochemistry suggest that the volcanic rocks of Wuyu Group originated from the partial melting of lower crust of the Gangdese belt, with the involvement of the Tethyan oceanic crust. It implies that the north-subducted Tethys ocean crust have arrived to the lower crust of Gangdese belt and recycled in the Neogene magmatism.     

Transition from platemargin to intraplate environment: Geochemistry of basalts in Paleogene Liaohe basin,northeastern China

Mesozoic and Cenozoic volcanic rocks are widely distributed in the circum-Pacific area of eastern China. These rocks have long been genetically linked to westward subduction of the paleo-Pacific oceanic plate to the eastern Asia continent[1,2]. Research in re-cent years[3―6] has attained conclusions that a simple paleo-Pacific subduction model does not work well in interpreting all the volcanic rocks in eastern China, although some of them could be attributed to circum-Pacific interaction …     

Isotopic inferences on the chemical structure of the mantle

Variations in the isotopic composition of rocks derived from the upper mantle can be used to infer the chemical history and structure of the Earth's interior. The most prominent material in the upper mantle is the source of mid-ocean ridge basalts (MORB). The MORB source is characterized by a general depletion in incompatible elements caused by the extraction of the continental crust from the mantle. At least three other isotopically distinct components are recognized in the suboceanic mantle. All three could be generated by the recycling of near surface materials (oceanic crust, pelagic sediments, continental lithospheric mantle) into the mantle by subduction. Therefore, the isotope data do not require a compositionally layered mantle, but neither do they deny the existence of such layering. Correlations between the volumetric output of plume volcanism with the reversal frequency of the Earth's magnetic field, and between the geographic distribution of isotopic variability in oceanic volcanism with seismic tomography suggest input of deep mantle material to surface volcanism in the form of deep mantle plumes. Volcanism on the continents shows a much wider range in isotopic composition than does oceanic volcanism. The extreme isotopic compositions observed for some continental magmas and mantle xenoliths indicate long-term (up to 3.3 Gyr) preservation of compositionally distinct material in thick (>200 km) sections of continental lithospheric mantle.     

Petrogenesis of diabase from accretionary prism in the southern Qiangtang terrane,central Tibet: Evidence from U–Pb geochronology,petrochemistry and Sr–Nd–Hf–O isotope characteristics

The Bangong–Nujiang suture (BNS) between the Lhasa and Qiangtang terranes is an important boundary and its petrogenesis is controversial. Diabase from the accretionary prism in the southern Qiangtang terrane yields a zircon U–Pb age of 181.3 ± 1.4 Ma. All the diabases show tholeiitic basalt compositions, gentle enrichment patters of light rare earth elements (REE), variable enrichment in incompatible element concentrations (e.g. Th and Rb), and no anomaly in high field strength elements (e.g. Nb and Ta), similar to that of enriched mid‐ocean ridge basalt (E‐MORB). They have relatively homogeneous whole rock Nd (εNd(t) = 7.3–9.1) and zircon Hf–O isotopic compositions (εHf(t) = 14.8–16.1, and δ¹⁸O = 4.57–6.12‰), possibly indicating melting of the depleted mantle and no significant crustal contamination during the petrogenesis. The element variations suggest that the diabases were formed by plume–ridge interaction at a mid‐ocean ridge within the Bangong–Nujiang ocean.     

Geochemical and Sm–Nd isotopic characteristics of metabasites from central Hainan Island, South China and their tectonic significance

Abstract   Major and trace elements and Sm–Nd isotopic data are presented for metabasites that are present as lenses within Paleozoic metasediments in the Chenxing and Bangxi regions, central Hainan Island, Southeast (SE) China. Most metabasites are metamorphosed cumulated gabbroic rocks tholeiitic in nature, and characterized by varying degrees of depletion in Th, Nb, Ta and light rare earth elements (LREE). Moreover, they show high positive ∈Nd(T) values of approximately +7, similar to those of mid-ocean ridge basalts (MORB). A Sm–Nd isochron age of 333 ± 12 Ma obtained for the metabasites is interpreted as their crystallization age. The combined geochemical and Sm–Nd isotopic data suggest that the metabasites were generated by dynamic partial melting from a MORB-like mantle source in an oceanic regime. These rocks probably represent remnants of fragmented oceanic crust of the eastern part of Paleo-Tethys. They were obducted onto the continental crust as part of the 'Shilu Mélange' in earliest Mesozoic time when southern Hainan (part of the Indochina block) collided with northern Hainan (part of South China). Alternatively, they could be formed in a volcanic rifted passive margin at the sea-floor spreading stage as part of MORB-like seaward-dipping reflector break-up packages.     

Thermochemical convection in the mantle with oceanic crust recirculation

Basalts of mid-ocean ridges are depleted in incompatible elements that have passed into the continental crust. Basalts of hot spots (oceanic islands and igneous provinces) have a chemical composition close to the primary uniform mantle and are even somewhat enriched in incompatible elements. At present, for explaining the reason for this difference, there are different qualitative schemes of differentiation and mixing of substance in the mantle. In the present work, the results of numerical modeling of the two-component thermochemical convection in the mantle are given. They quantitatively demonstrate with which parameters in the mantle the layers of different chemical composition can remain unchanged. Models with different density contrasts and with variable viscosity are examined. The times of the partial mixing of layers depending on the values of these parameters are calculated. For retaining the stratified mantle for two Ga, the density contrast must be more than 2%. If the layer D″ contains a substance of the primary composition, then, its upper boundary can be the place of origin of the plumes that feed the hot spots of the Earth. The enrichment in the incompatible elements and the variety of the chemical composition of hot spots can be explained by the mixing of the substance of the slowly eroded D″ layer and the oceanic crust accumulated in it.     

Geochemistry of late Cenozoic lavas on Kunashir Island, Kurile Arc

Middle Miocene to Quaternary lavas on Kunashir Island in the southern zone of the Kurile Arc were examined for major, trace, and Sr–Nd–Pb isotope compositions. The lavas range from basalt through to rhyolite and the mafic lavas show typical oceanic island arc signatures without significant crustal or sub-continental lithosphere contamination. The lavas exhibit across-arc variation, with increasingly greater fluid-immobile incompatible element contents from the volcanic front to the rear-arc; this pattern, however, does not apply to some other incompatible elements such as B, Sb, and halogens. All Sr–Nd–Pb isotope compositions reflect a depleted source with Indian Ocean mantle domain characteristics. The Nd and Pb isotope ratios are radiogenic in the volcanic front, whereas Sr isotope ratios are less radiogenic. These Nd isotope ratios covary with incompatible element ratios such as Th/Nd and Nb/Zr, indicating involvement of a slab-derived sediment component by addition of melt or supercritical fluid capable of mobilizing these high field-strength elements and rare earth elements from the slab. Fluid mobile elements, such as Ba, are also elevated in all basalt suites, suggesting involvement of slab fluid derived from altered oceanic crust. The Kurile Arc lavas are thus affected both by slab sediment and altered basaltic crust components. This magma plumbing system has been continuously active from the Middle Miocene to the present.     

Relative depletion of niobium in some arc magmas and the continental crust: partitioning of K, Nb, La and Ce during melt/rock reaction in the upper mantle

Depletion of Nb relative to K and La is characteristic of lavas in subduction-related magmatic arcs, as distinct from mid-ocean ridge basalts. Nb depletion is also characteristic of the continental crust. This and other geochemical similarities between the continental crust and high-Mg# andesite magmas found in arcs suggests that the continental crust may have formed by accretion of andesites. Previous studies have shown that the major element characteristics of high-Mg# andesites may be produced by melt/rock reaction in the upper mantle. In this paper, new data on partitioning of K, Nb, La and Ce between garnet, orthopyroxene and clinopyroxene in mantle xenoliths, and on partitioning of Nb and La between orthopyroxene and liquid, show that garnet and orthopyroxene have Nb crystal/liquid distribution coefficients which are much larger than those of K and La. Similar fractionations of Nb from K and La are expected in spinel and olivine. For this reason, reactions between migrating melt and large masses of mantle peridotite can produce substantial depletion of Nb in derivative liquids. Modeling shows that reaction between ascending, mantle-derived melts and mantle peridotite is a viable mechanism for producing the trace element characteristics of high-Mg# andesite magmas and the continental crust.

Alternatively, small-degree melts of metabasalt and/or metasediment in the subducting slab may leave rutile in their residue, and will thus have large Nb depletions relative to K and La [1]. Slab melts are too rich in light rare earth elements and other incompatible elements, and too poor in compatible elements, to be parental to arc magmas. However, ascending slab melts may be modified by reaction with the mantle. Our new data permit modeling of the trace element effects of reaction between small-degree melts of the slab and mantle peridotite. Modeling shows that this type of reaction is also a viable mechanism for producing the trace element characteristics of high-Mg# andesites and the continental crust. These findings, in combination with previous results, suggest that melt/rock reaction in the upper mantle has been an important process in forming the continental crust and mantle lithosphere.     

Geology and geochemistry of the Bingdaban ophiolitic mélange in the boundary fault zone on the northern Central Tianshan Belt,and its tectonic implications

The properties and tectonic significance of the fault bound zone on the northern margin of the Central Tianshan belt are key issues to understand the tectonic framework and evolutionary history of the Tianshan Orogenic Belt. Based on the geological and geochemical studies in the Tianshan orogenic belt, it is suggested that the ophiolitic slices found in the Bingdaban area represent the remaining oceanic crust of the Early Paleozoic ocean between the Hazakstan and Zhungaer blocks. Mainly composed of basalts, gabbros and diabases, the ophiolites were overthrust onto the boundary fault between the Northern Tianshan and Central Tianshan belts. The major element geochemistry is characterized by high TiO₂ (1.50%–2.25%) and MgO (6.64%–9.35%), low K₂O (0.06%–0.41%) and P₂O₅ (0.1%–0.2%), and Na₂O>K₂O as well. Low ΣREE and depletion in LREE indicate that the original magma was derived from a depleted mantle source. Compared with a primitive mantle, the geochemistry of the basalts from the Bingdaban area is featureded by depletion in Th, U, Nb, La, Ce and Pr, and unfractionated in HFS elements. The ratios of Zr/Nb, Nb/La, Hf/Ta, Th/Yb and Hf/Th are similar to those of the typical N-MORB. It can be interpreted that the basalts in the Bingdaban area were derived from a depleted mantle source, and formed in a matured mid-oceanic ridge setting during the matured evolutionary stage of the Northern Tianshan ocean. In comparison with the basalts, the diabases from the Bingdaban area show higher contents of Al₂O₃, ΣREE and HFS elements as well as unfractionated incompatible elements except Cs, Rb and Ba, and about 10 times the values of the primitive mantle. Thus, the diabases are thought to be derived from a primitive mantle and similar to the typical E-MORB. The diabases also have slight Nb depletion accompanying no apparent Th enrichment compared with N-MORB. From studies of the regional geology and all above evidence, it can be suggested that the diabases from the Bingdaban area were formed in the mid-oceanic ridge of the Northern Tianshan ocean during the initial spreading stage. Supported by the Major State Research Program of PRC (Grant No. 2001CB409801), the National Natural Science Foundation of China (Grant Nos. 40472115 and 40234041) and the State Research Program of China Geological Survey (Grant No. 2001130000-22)     

A re-appraisal of the use of trace elements to classify and discriminate between magma series erupted in different tectonic settings

The hygromagmatophile element composition of basic lavas from several tectonic environments are compared with the estimated composition of the primordial mantle. The observed variations are used to subdivide mid-ocean ridge basalts (MORB) into two main types according to the tectonic character of the ridge segment from which they were erupted. Ridge segments with positive residual gravity, depth and heat flow anomalies erupt E-type MORB which are predominantly enriched in the more hygromagmatophile elements, but also include magma types which are depleted in most of these elements. Both enriched and depleted E-type MORB can be distinguished from the basalts erupted at normal ridge segments (N-type MORB) by their La/Ta ratios (in E-type MORB La/Ta ～10, in N-type MORB La/Ta is ～15) and by Hf/Ta ratios (in E-type MORB Hf/Ta> 7, in N-type MORB Hf/Ta> 7). E-type MORB can be distinguished from the basalts erupted at ocean islands by their higher Hf/Ta ratios (>2). A Th-Hf-Ta triangular diagram is used to discriminate between the different ocean floor basalts as well as those erupted at destructive plate margins, which are depleted in Ta and Nb. This diagram can also distinguish between silicic lavas from the different tectonic environments as well as identifying lavas that have been contaminated with continental crust.     

Sangay volcano, Ecuador: structural development, present activity and petrology

Sangay (5230 m), the southernmost active volcano of the Andean Northern Volcanic Zone (NVZ), sits 130 km above a >32-Ma-old slab, close to a major tear that separates two distinct subducting oceanic crusts. Southwards, Quaternary volcanism is absent along a 1600-km-long segment of the Andes. Three successive edifices of decreasing volume have formed the Sangay volcanic complex during the last 500 ka. Two former cones (Sangay I and II) have been largely destroyed by sector collapses that resulted in large debris avalanches that flowed out upon the Amazon plain. Sangay III, being constructed within the last avalanche amphitheater, has been active at least since 14 ka BP. Only the largest eruptions with unusually high Plinian columns are likely to represent a major hazard for the inhabited areas located 30 to 100 km west of the volcano. However, given the volcano's relief and unbuttressed eastern side, a future collapse must be considered, that would seriously affect an area of present-day colonization in the Amazon plain, 30 km east of the summit. Andesites greatly predominate at Sangay, there being few dacites and basalts. In order to explain the unusual characteristics of the Sangay suite—highest content of incompatible elements (except Y and HREE) of any NVZ suite, low Y and HREE values in the andesites and dacites, and high Nb/La of the only basalt found—a preliminary five-step model is proposed: (1) an enriched mantle (in comparison with an MORB source), or maybe a variably enriched mantle, at the site of the Sangay, prior to Quaternary volcanism; (2) metasomatism of this mantle by important volumes of slab-derived fluids enriched in soluble incompatible elements, due to the subduction of major oceanic fracture zones; (3) partial melting of this metasomatized mantle and generation of primitive basaltic melts with Nb/La values typical of the NVZ, which are parental to the entire Sangay suite but apparently never reach the surface and subordinate production of high Nb/La basaltic melts, maybe by lower degrees of melting at the periphery of the main site of magma formation, that only infrequently reach the surface; (4) AFC processes at the base of a 50-km-thick crust, where parental melts pond and fractionate while assimilating remelts of similar basaltic material previously underplated, producing andesites with low Y and HREE contents, due to garnet stability at this depth; (5) low-pressure fractionation and mixing processes higher in the crust. Both an enriched mantle under Sangay prior to volcanism and an important slab-derived input of fluids enriched in soluble incompatible elements, two parameters certainly related to the unique setting of the volcano at the southern termination of the NVZ, apparently account for the exceptionally high contents of incompatible elements of the Sangay suite. In addition, the low Cr/Ni values of the entire suite—another unique characteristic of the NVZ—also requires unusual fractionation processes involving Cr-spinel and/or clinopyroxene, either in the upper mantle or at the base of the crust.