与溢流性玄武岩有关的铜镍硫化物矿床地质地球学特征与成矿潜力分析——以广西罗城县清明山铜镍硫化物矿床为例

广西罗城县清明山铜镍硫化物矿床,镁铁质-超镁铁侵入岩与玄武岩广泛分布,时空关系密切,两者岩石化学成分丰度相同,均具有富MgO、贫SiO2、TiO2、K2O的特征,微量元素、稀土特征相同,具有成因上的联系和有先后演化的特征。含矿镁铁质岩体岩石化学成分SiO2含量为42.68～50.63%,K2O含量0.052～2.54%,TiO2含量0.326～0.63%;微量元素Rb,Ba富集,Ta、Nb亏损的特征,稀土元素含量中等ΣREE=27.56～52.36(10-6),ΣLREE/ΣHREE=7.17～12.31,(La/Yb)N=2.48～8.17,δEu=0.93～1.43,轻稀土富集,配分曲线右倾,无δEu负异常;硫同位素δ34S值4.52～17.04‰。镁铁质-超镁铁岩和铜镍硫化矿主要物质来源于幔源,有壳源混染;地质特征、地球化学特征等与美国Duluth铜镍硫化物矿床特征相同,为国内一种新的与溢流玄岩有关的岩浆铜镍硫化物矿床,资源潜力巨大。     

中国西北地区岩浆铜镍矿床地质特点与找矿潜力

西北地区是中国岩浆铜镍硫化物矿床最为发育的地区,主要有3个重要成矿期,其地质特点、成矿条件、形成标志等存在明显不同.笔者梳理了 目前诸多学者对岩浆铜镍硫化物矿床的研究工作,并结合野外实际,发现大陆裂谷是形成巨型-超大型岩浆铜镍硫化物矿床的构造背景条件,铁质系列的镁铁-超镁铁质岩体才可能形成有经济价值的岩浆铜镍硫化物矿体...     

金平镁铁质-超镁铁质岩铜镍矿床成矿条件

按构造环境控岩控矿特点,划分区内铜镍型成矿（岩）带,分析成矿条件,研究与该类矿床成矿有关的镁铁质岩、超镁铁质岩分布规律及铜镍硫化物成矿特征,指出找矿方向和建议。     

内蒙古中部镁铁质-超镁铁质岩带铜镍成矿潜力探讨

华北陆块北缘是中国铜镍(铂)硫化物矿床的重要成矿区带之一.近年来,在位于该成矿带的内蒙古中部先后发现多处铜镍矿床(点),空间上构成一条重要的镁铁质-超镁铁质岩成矿带.为了探讨该镁铁质-超镁铁质岩带内额布图、温更、克布、黄花滩及小南山等赋矿岩体的成矿潜力,笔者通过搜集和研究国内外典型铜镍硫化物矿床数据,建立有利成矿信息评...     

四川力马河镁铁-超镁铁质岩体的地球化学特征及成岩成矿分析

四川会理力马河镍矿是峨眉山大火成岩省最重要的岩浆硫化物矿床之一,成矿岩体为一小型锾铁-超镁铁岩侵入体,由含斜长石的超镁铁岩(包括舍长辉石橄榄岩和斜长橄榄辉石岩)和辉长岩类的镬铁质岩组成.矿床富含硫化物,成矿元素组合为铜、镍,铂族元素含量很低,没有铂族元素的工业富集,是蛾眉山大火成岩省中富铜镍贫铂族元素的代表性岩浆硫化物矿床.本文对力马河镍矿成矿岩体的镁铁、超镁铁岩及矿床中各种硫化物矿石进行了主量元素、微量元素及铂族元素含量分析.分析结果表明,力马河岩体的镁铁、超镁铁岩属拉斑玄武岩成因系列,岩石特征微量元素比值大致与高钛的峨眉山玄武岩相当、与低钛的峨眉山玄武岩有明显区分,但估计原始岩浆强不相容微量元素绝对含量大大低于高钛玄武岩,因此,其成矿岩体不是与一般的低钛或高钛峨眉山玄武岩(不包括苦橄岩在内)直接对应的深成相.岩体超镁铁岩及矿石铂族元素组成特征表现为无钌亏损的型式,钯/铱比值较小、在5左右,也显著不同于一般的峨眉山玄武岩,而类似于峨眉山大火成岩省苦橄岩的铂族元素组成.运用岩石地球化学研究方法计算,原始岩浆为苦橄质成分:MgO含量约17%、SiO2含量约48%.估计原始岩浆形成于130公里左右的深度,由类似于洋岛玄武岩岩浆源区成分的地幔经19%左右的部分熔融形成.超镁铁岩及硫化物矿石铂族元素含量一般在10-9～10-8暑级,铂族元素相对铜镍强烈亏损,铜/钯比值高于原始地幔10～100倍,铜镍铂族元素组成的原始地幔标准化曲线呈铂族元素显著亏损的“U“型.模式分析说明,导致铂族元素亏损的原因是岩浆成矿演化过程中多阶段硫化物熔离作用造成的,早期熔离出来的硫化物被丢失并造成岩浆中铂族元素亏损,其铂族元素亏损后的岩浆(第)二次硫化物熔离富集形成铂族元素亏损的矿石.     

中国岩浆铜镍矿床的形成特点与找矿方向

与幔源镁铁-超镁铁质岩浆密切相关的铜镍硫化物矿床,因深部地幔动力学机制不同在地球表壳的分布极不均衡。中国岩浆铜镍硫化物矿床分布不均匀,主要产出于板块内部或其边缘。为认识中国铜镍矿床的形成特点,进一步明确找矿方向,通过综合分析已有典型岩浆铜镍硫化物矿床,发现该类矿床基本形成于新元古代晚期、早古生代晚期及晚古生代晚期,且均无一例外地就位于板块内部或其边缘的造山带中,是硫化物熔离后的岩浆多期侵位的结果。通过系统研究岩浆铜镍矿床深部过程及地质、物探、化探、遥感有利成矿信息,结合找矿突破的最新勘查进展,指出中国西北部是岩浆铜镍硫化物矿床的重要成矿潜力地区,稳定地块边缘仍是主要的找矿方向。     

新疆北部镁铁-超镁铁质岩的PGE成矿问题

铂族元素(PGE)矿化主要与镁铁-超镁铁杂岩有关,成矿类型主要为岩浆型矿床,这类PGE矿床的形成主要依赖两个条件:一是岩浆中富含PGE;二是具备PGE从岩浆中分离和富集的机制,主要是在岩浆演化过程中硫达到饱和。新疆北部镁铁-超镁铁质杂岩发育,并产有喀拉通克、黄山、黄山东、图拉尔根4个大型铜镍矿床和香山、土墩、葫芦、白石泉等中、小型铜镍矿,以及香山西、尾亚等中型钒钛磁铁矿矿床,但迄今尚未发现成型的PGE矿床。文中通过对PGE矿床的形成机制与镁铁-超镁铁杂岩源区特征研究,探讨了北疆地区PGE矿床的成矿问题。综合分析认为,新疆北部后碰撞镁铁-超镁铁质岩的岩石类型为经过了分离结晶形成的铁质岩石系列,是PGE矿床的有利容矿岩石;矿床的Sr、Nd、Pb、O、Os和S同位素和含矿岩石地球化学特征表明,铜镍硫化物矿床含矿岩浆在岩浆演化和成矿过程中有地壳物质加入并可导致硫化物熔离作用,说明在成矿机制上也存在形成岩浆型PGE矿化的条件。新疆北部PGE矿化微弱的原因可能在于该区广泛发育的亏损型地幔源(具正的εNd值特征),这一亏损型地幔可能部分源于洋壳熔融,与产于后碰撞造山带环境、发育于"洋壳"或"不成熟"陆壳基底之上有关,由此决定了原始岩浆为贫PGE的源区,因此不利于PGE的富集成矿。     

内蒙古镁铁质-超镁铁质岩型铜镍矿床成矿条件与找矿远景分析

按构造环境控岩控矿特点,划分区内铜镍型矿成矿(岩)带,分析成矿条件,研究了与该类矿床成矿有关的镁铁质岩、超镁铁质岩分布规律及铜镍硫化物成矿特征,提出了找矿方向和建议.     

东昆仑夏日哈木镍铜硫化物矿床成矿岩浆条件:流体挥发份化学组成与碳同位素组成制约

夏日哈木镍铜硫化物矿床是我国东昆仑造山带新发现的全球岛弧环境最大的岩浆镍铜硫化物矿床。早泥盆世镁铁-超镁铁质成矿岩体中不同类型岩石的辉石中流体挥发份化学组成和碳同位素组成表明,流体挥发份总量较低,平均含量为888mm~3.STP/g(STP:标准温度和大气压)。流体挥发份组成以H_2O为主(48mol%),其次为H_2(26%)、CO_2(15%)和CO(5%)。H_2S含量从二辉橄榄岩(10mm~3/g)、橄榄辉石岩(18mm~3/g)到二辉辉石岩(28mm~3/g)逐渐增加,表明岩浆就位结晶演化过程中含硫组分的加入。CO_2的δ~(13)C值(-23.5‰~-5.0‰)位于地壳和地幔值范围之间。CH_4同系物碳同位素组成随碳数具有总体正序、局部反序的分布特征,显示大洋沉积有机质热裂解成因特征。夏日哈木成矿镁铁-超镁铁质岩体流体组分中较低的H2_O含量和较高的H_2含量表明,岩浆演化处于还原性挥发份条件,地幔岩浆源区存在俯冲洋壳沉积有机质,岩浆房围岩的混染和富S流体的加入可能是夏日哈木岩浆镍铜硫化物矿床硫饱和的主要机制。     

新疆哈密黄山地区铜镍硫化物矿床的稀土元素特征及意义

通过对新疆哈密黄山铜镍矿带典型矿床矿石矿物和含矿岩石的稀土元素地球化学研究,发现产于造山带的铜镍硫化物矿床的容矿镁铁-超镁铁质岩具有富水特征,部分硫化物稀土曲线呈特殊的“三重弯曲”模式,反应出由于多种液相(流体和熔体)共存,硫化物熔体中含有大量热液流体,在主成矿期(岩浆熔离期)后逐渐演化出富含气液的成矿流体。本区矿床稀土特征不同于克拉通边缘的铜镍矿床,造成上述热液流体参与成矿的原因在于含矿岩体本身富水,可能与碰撞后富水洋壳的拆沉熔融有关。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案(1999/30/EC),对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

Mountains,nations, parks,and conservation

Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km² and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.     

岩石密度和超高压岩石折返速率

在常温常压条件下对中国大陆科学钻CCSD主孔100-3000米岩心样品进行了密度测量,建立了密度连续剖面,并界定了不同超高压岩石的密度值。通过对比高温高压物性实验资料,岩石密度随着退变程度增强而降低,榴辉岩密度变化序列为3.52g/cm3→3.49g/cm3→3.07g/cm3→2.93g/cm3。超高压长英质岩石密度变化序列为3.00g/cm→2.80g/cm3→2.65g/cm3。上述实验资料是讨论不同折返阶段岩石所受浮力的基础,为研究折返速率大小提供了基本参数。本文通过折返板块运动平衡时,上浮力与粘滞力平衡这一关系式,定量研究了大陆俯冲板块的折返速率,认为密度差产生上浮力从而引起折返,温度对板块折返速率的影响最为显著;密度差大小、折返角度、折返板块大小对折返速率也有直接的影响。定量模拟分析表明,在温度高于850℃时,板块的折返速率可以超过100mm/a;当温度降至700℃时,折返速率则低于1.5mm/a。作者认为在折返早期,温度较高,板块快速折返至60-70km榴辉岩相深度;随着传导散热,温度降低,板块以较慢的速率折返至中下地壳。折返速率的估算表明,浮力是板块折返第一阶段(从>100km深部折返至<40km的中下地壳)的主要驱动力。     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).