Determination of Ga,Ge, Mo,Ag, Cd,In, Sn,Sb, W,Tl and Bi in USGS Whole‐Rock Reference Materials by Standard Addition ICP‐MS |
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| Authors: | Richard M Gaschnig Roberta L Rudnick William F McDonough |
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| Affiliation: | Department of Geology, University of Maryland, College Park, MD, USA |
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| Abstract: | A procedure for determining a wide range of chalcophile and siderophile elements in typical crustal rocks using standard addition and ICP‐SFMS (inductively coupled plasma sector field mass spectrometry) is presented. New results for Ga, Ge, Mo, Ag, Cd, In, Sn, Sb, W, Tl and Bi abundances in USGS whole‐rock reference materials AGV‐2, BHVO‐1, BIR‐1, G‐2, GSP‐1 and W‐2 are reported using this analytical procedure. Intermediate precision of means based on multiple dissolved aliquots of each USGS reference material was 10% RSD or better for Ga, Ge, In and Sn in all, and similarly good for Ag, Cd, Sb, Tl and Bi in most reference materials. Poorer intermediate precision of Mo and W measurements in several reference materials is probably due to higher analytical blanks on these elements and powder heterogeneity due to a sulfide‐related nugget effect in the specific case of Mo in GSP‐1. Results for all elements fell within the range of available published data with the exception of Ag, which yielded systematically higher concentrations than found in the literature for five of the six reference materials, likely reflecting interference from unresolved polyatomic species. |
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| Keywords: | siderophile elements chalcophile elements trace elements reference material data recommended value standard additions inductively coupled plasma‐mass spectrometry é lé ments sidé rophiles é lé ments chalcophiles é lé ments traces donné es de maté riaux de ré fé rence valeur recommandé e ajouts de standard spectromé trie de masse à source plasma |
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